Chemical Engineering Commons^™

Aqueous Iron Electrowinning: From Electrolyte Engineering To The Unexplored Potential Of Acetate Systems, Chodwell N. Verenga

Dissertations, Master's Theses and Master's Reports

Iron electrowinning and electrodeposition sit at the intersection of classical metallurgy and developing sustainable manufacturing. With the iron and steel industry responsible for 7 - 9% of global CO₂ emissions, low-temperature electrochemical pathways for iron production have garnered significant research interest. This review examines the fundamental electrochemical principles governing iron deposition, the thermodynamic constraints imposed by the iron-water system, and the kinetic challenges posed by the parasitic hydrogen evolution reaction (HER). The three key electrolyte systems are objectively evaluated: acidic sulfate and chloride electrolytes, alkaline suspension electrolytes and water-in-salt electrolytes. Their operating parameters, faradaic efficiencies, energy consumption and deposit characteristics …

The Composition Of Gases From A Diffusion Flame Above Longleaf Pine Needle Fuel Beds, David R. Weise, Thomas H. Fletcher, Timothy J. Johnson, Weimin Hao, Russell G. Tonkyn, Catherine A. Banach, Javier Palarea-Albaladejo, Mahsa Alizadeh, Stephen Baker

Faculty Publications

The gas and tar composition of a wildland fire diffusion flame from longleaf pine needles is currently relatively unmeasured and more data are needed to fill in the gap between pyrolysis data and smoke plume data, thus improving physical and chemical modeling of wildland smoke formation. A pilot experiment to measure light gas and tar composition of such a flame is described for three flame zones: persistent flame (flame base), intermittent flame, and smoke plume. Flame gases from 24 experimental fires were collected in canisters and analyzed for CO2, CO, H2, CH4, and C2 to C7 hydrocarbon gases. Other light …

Performance Investigation Of Microchannel Heat Sink With Biomimetic Trefoil Cavities On Different Walls, Sadiq Ali, Numan Habib, Faraz Ahmad, Aamer Sharif, Ana Vafadar

Research outputs 2022 to 2026

The modern world is shifting towards digitalization and miniaturization, leading to higher flux densities in electronic components and machines. However, conventional cooling methods, such as air-cooled smooth channels, are proving inadequate for removing the huge amounts of heat generated, thereby compromising the reliability and operational lifespan of electronic systems. This necessitates urgently exploring and analyzing modern techniques like microchannel cooling to improve its efficiency. This work uses ANSYS to conduct numerical simulations and investigates the heat transfer and flow behavior in a microchannel heat sink. The smooth channel is used to investigate and validate the flow behavior with the available …

Harnessing Mono-2-(Methacryloyloxy) Ethyl Succinate Grafting For Robust Micro/Nanoplastic-Resistant Ultrafiltration Membranes, Mohadeseh Najafi, Javad Farahbakhsh, Mitra Golgoli, Michael Johns, Masoumeh Zargar

Research outputs 2022 to 2026

The growing presence of microplastics (MPs) and nanoplastics (NPs) in water systems poses a serious threat to conventional treatment processes, particularly membrane filtration. This study focuses on a surface modification strategy for commercial ultrafiltration (UF) membranes via plasma-induced grafting of mono-2-(methacryloyloxy) ethyl succinate (MMES) to enhance resistance against MP/NPs fouling. The membranes were characterised using advanced analytical techniques, including high-resolution scanning electron microscopy (HRSEM), X-ray photoelectron spectroscopy (XPS), and atomic force microscopy (AFM), confirming successful grafting, increased hydrophilicity, and a more negative surface charge. At optimal conditions of grafting (2 min pretreatment, 0.5 M monomer concentration, and 3 h grafting …

Effects Of Electroshock Treatment On Microstructure Evolution And Mechanical Properties Of Ti-8al-1mo-1v Alloy, Jian Zhou, Yu Peng Yao, Hong Xin Sun, Chang Liu, Yan Wen, Li Qiang Wang, Lai Chang Zhang, Le Chun Xie, Lin Hua

Research outputs 2022 to 2026

The effect mechanism of electroshock treatment (EST) on microstructure evolution and mechanical property variations of Ti-8Al-1Mo-1V alloy was investigated. The results show that EST results in the phase transformation from the acicular secondary αs to β phase. While the EST time is 0.12 s, the acicular martensitic phase (αM) precipitates. The results of electron backscattered diffraction (EBSD) reveals that the average grain size decreases from 3.95 to 2.53 μm after EST, indicating that the grains are refined, and the significant recrystallization behavior and martensitic transformation occur. The orientation distribution reveals a more uniform distribution of texture, which is caused by …

Numerically Evaluating The Effect Of Extrusion Angle On Material Flow And Thermal Behaviour During Additive Friction Extrusion Deposition (Afed), Numan Habib, Ferdinando Guzzomi, Ana Vafadar

Research outputs 2022 to 2026

Additive Friction Extrusion Deposition (AFED), also known as “SoftTouch”, is an emerging friction-based Additive Manufacturing (AM) technology allowing material to soften before the deposition, increasing the printing speed and reducing cost [1]. However, high power is required during the process, as excessive force is needed to extrude enough material through the printing head. This study investigates how extrusion angle and tool rotational speed affect thermal distribution and material flow in AFED to minimise power consumption. A three-dimensional computational fluid dynamics (CFD) model is proposed, and ANSYS ^® Workbench CFD code (Fluent) is used to discretise the CFD model. A User-Defined …

Additive Manufacturing And Heat Treatment Of Zero Poisson’S Ratio Self-Expanding Nitinol Stents, Farhana Yasmin, Vafadar, Majid Tolouei-Rad

Research outputs 2022 to 2026

Additive manufacturing (AM) has recently gained attention as an effective approach for printing patient-specific, self-expanding Nitinol (NiTi alloy) stents with complex structural designs for the treatment of peripheral arterial disease (PAD). However, achieving the desired phase transformation temperature and superelastic performance remains challenging due to compositional variations, phase imbalance and microstructural inhomogeneities introduced during the printing process. In this study, self-expanding Nitinol stents with a zero Poisson’s ratio (ZPR) structural design were fabricated via laser powder bed fusion (PBF-LB). The printed stents showed no evidence of cracks or structural defects, confirming PBF-LB’s capability to produce mechanically sound stent geometries. However, …

Photocatalytic Degradation Of Cephalexin, Amoxicillin, And Phenol Red Using A Green-Synthesized Folic Acid–Zno–Bi2o3 Nanoporous System, M. Sarani, Haghighi, P. Tamaddon, A. Najafidoust, P. Faghani-Eskandarkolaei, N. Sattarahmady

Research outputs 2022 to 2026

The persistent presence of pharmaceutical pollutants like amoxicillin (AMX) and cephalexin (CPX), and industrial dyes such as phenol red (PR) in wastewater poses serious ecological and public health risks, including antibiotic resistance. It necessitates efficient and low-cost remediation technologies. Photocatalysts employing innovative and engineered nanomaterials such as bismuth oxide (Bi2O3) and zinc oxide (ZnO) nanostructures exhibit considerable potential for eliminating pollutants. This study focused on the photodegradation of AMX, CPX, and PR utilizing green-synthesized folic acid–ZnO–Bi2O3 nanoparticles (F-Zn-Bi NPs) under visible light irradiation. Characterization of the synthesized photocatalyst was conducted using various techniques of powder x-ray diffraction (PXRD), field emission …

Material Degradation And Analysis Of N-Doped Graphene/Mof Nanocatalysts For Orr In Electrochemical Energy Systems, Niladri Talukder

Dissertations

The development of advanced electrochemical energy conversion and storage systems is crucial for achieving sustainable energy security. As alternatives to precious metal-based catalysts in electrochemical systems, especially for the oxygen reduction reaction (ORR), Nitrogen-doped Graphene with Metal-organic Frameworks (N-G/MOF) nanocatalysts have shown exceptional promise in recent years. This research advances the understanding of N-G/MOF nanocatalysts by systematically examining their structural features, degradation traits, correlated performance losses, and other aspects related to catalytic activities.

First, nitrogen-doped graphene (N-G) nanocatalysts were thoroughly investigated, resolving their physical properties, the influence of synthesis parameters, molecular-level material structures, and chemical and electronic structural details of …

Effect Of Local Steel Slag Incorporation On The Mechanical Properties Of Concrete, Ahmed Safaa Tariq Karmah, Wissam Khadum Alsaraj, Luma A. Zghair

Al-Esraa University College Journal for Engineering Sciences

The increasing interest in the production of concrete through the utilization of inexpensive materials has caused a rise in the number of studies concerning the use of materials with cementitious properties, such as Silica Fume, Slag, Fly Ash and other pozzolanic materials. Moreover, the increasing amounts of Steel Slag being produced from local factories that are being deposited without an available method of disposal provides an opportunity to harness the Slag in the production of an inexpensive, and possibly better concrete. Slag has been used as both an addition and substitution of the cement and fine aggregate. The mixtures included …

Decoding Climate Change: A Comprehensive Statistical Insight Into Temperature Anomalies In Iraq And Its Neighboring Countries, Jameel T. Al-Naffakha, Mohammed R. Al-Qassabanda, Israa Jafar

Al-Esraa University College Journal for Engineering Sciences

This study applies advanced statistical techniques, including the Mann-Kendall Trend Test and ARIMA forecasting, to validate and predict temperature anomalies across Iraq and its neighboring countries (2014–2024). Findings confirm a statistically significant warming trend (p < 0.00000005) across all nations, with Syria (1.02°C) and Turkey (0.97°C) experiencing the highest anomalies. GIS-based spatial analysis highlights regional disparities, identifying climate-vulnerable zones. The persistent rise in temperature anomalies correlates with worsening water scarcity, desertification, and extreme weather events, including prolonged droughts and heatwaves. Iraq’s peak anomaly (1.48°C) has exacerbated heat stress, agricultural decline, and reduced river inflows, while Kuwait and Saudi Arabia struggle to maintain critical infrastructure under record-breaking temperatures exceeding 50°C. These climate shifts pose severe risks to water availability, food security, and energy demand, necessitating urgent policy interventions. Key recommendations include enhanced water resource management, climate-adaptive agriculture, and renewable energy expansion. If left unaddressed, rising temperatures could destabilize the region, increasing socio-economic vulnerabilities and escalating resource conflicts. This study underscores the need for cross-border collaboration and sustainable adaptation policies to mitigate the long-term impacts of climate change in the Middle East.

Optimal Power Flow Control In The Iraqi Power Grid Using Artificial Intelligence Algorithms For Carbon Emission Reduction, Mohammed Shakir Juber

Al-Esraa University College Journal for Engineering Sciences

Iraq’s power sector remains in a protracted and severe crisis characterized by a significant mismatch between supply and demand, high levels of losses during transmission and distribution, as well as an increasing challenge to the resources base being largely unfavourably. These inefficiencies impose heavy costs on the national economy in excess of 40 billion annually and they also reinforce greenhouse gas emissions, and exacerbate environmental issues. To deal with these problems, we proposed in this paper that a new hybrid AI tool should be developed for the solution of multi-objective optimization problem based on purpose Genetic Algorithm (GA) merger with …

Applying Machine Learning Techniques For Early Detection Of Cyber Attacks On Iot Devices, Noor Adnan Allamy

Al-Esraa University College Journal for Engineering Sciences

This research designs, implements, and evaluates a machine learning-based framework for the early detection of cyber attacks targeting Internet of Things (IoT) devices, with a specific focus on the context and challenges present in Iraq. The study conducts a comparative analysis of three supervised learning algorithms—Support Vector Machine (SVM), Random Forest (RF), and Deep Neural Networks (DNN)—using a combination of benchmark datasets (NSL-KDD, CIC-IDS-2017, Bot-IoT) and a synthesized dataset adapted to simulate the Iraqi threat landscape. Key performance metrics, including accuracy, precision, recall, and F1-score, were used for evaluation. The proposed Random Forest model demonstrated superior performance, achieving an accuracy …

Ai-Enhanced Heat Transfer Optimization In Magnetic Bio-Nanofluids, Hasan Attyah Shaboot

Al-Esraa University College Journal for Engineering Sciences

This study presents a hybrid Artificial Intelligence–Computational Fluid Dynamics (AI-CFD) framework for optimizing heat transfer in magnetic bio-nanofluids subjected to external magnetic fields. Magnetic bio-nanofluids, composed of biocompatible base fluids containing superparamagnetic nanoparticles, exhibit tunable thermal and flow behavior, making them promising for biomedical and micro-cooling applications. Conventional optimization methods based on experiments or brute-force CFD are computationally expensive and limited in exploring the full design space. To overcome these challenges, an Artificial Neural Network (ANN) surrogate model was developed to predict two key performance indicators, the Nusselt number and the friction factor, with high accuracy (R² > 0.997). The surrogate …

Hybrid Experimental–Computational Study On The Energy Absorption Of Graphene Nanoplatelet-Reinforced Sandwich Structures, Hamdan Yousif Hamdan

Al-Esraa University College Journal for Engineering Sciences

Background: Sandwich composites are widely used in aerospace, automotive, and marine applications because of their lightweight, stiffness, and strength, but they remain prone to out-of-plane impacts and barely visible impact damage (BVID). Graphene Nanoplatelets (GNPs) have shown strong potential to improve fracture toughness and impact resistance. However, hybrid experimental–computational studies applying such reinforcement are still lacking in developing contexts like Iraq, where practical and accessible solutions are essential. Aims: The study investigates the effect of GNP reinforcement on the low-velocity impact behavior and energy absorption of glass fiber/epoxy sandwich panels with PVC foam and balsa wood cores. Objectives include fabricating …

Effect Of Thick Closed Walls Of West And South Elevations Of Iraqi Middle And South Territory Housing Building On Reducing Energy Use, Abeer Qasim Jbur, Shaimaa M. Hamza, Mayyadah Lutfi Abdulwahhab

Al-Esraa University College Journal for Engineering Sciences

Thermal insulation is one of the most important factors in achieving sustainability, increasing efficiency, and reducing energy consumption, but modern insulation materials are expensive, in addition to their availability. Therefore, through our research, we resorted to investigating the issue of reducing thermal load in buildings through the use of thick-walled facades in the southern and western facades, where we studied a building with two windows with windows on the southern and western facades and another without these windows and with thick walls, for two locations, the first in central Iraq, which is the city of Baghdad, and the second in …

The Impact Of Ethyl Levulinate Additive On Diesel Engine Performance And Emissions: An Experimental Study, Maha Ali Ghadbaan

Al-Esraa University College Journal for Engineering Sciences

This study explores the environmental and operational impact of adding Ethyl Levulinate—a biodegradable ester derived from biomass—to diesel fuel. A fuel blend known as B5El6 (comprising 5% biodiesel and 6% Ethyl Levulinate) was prepared and tested experimentally using a single-cylinder diesel engine operating at a constant speed of 1500 rpm under full load conditions. Performance metrics and emission data were recorded, and a Life Cycle Assessment (LCA) was conducted using the IMPACT2002+ methodology.

The results revealed that B5El6 significantly reduced greenhouse gas emissions (100 kg CO2 eq) and improved ecosystem quality. However, it presented challenges in terms of human health …

The Role Of The Scenario In Formulating The Contemporary Architectural Text, Rounaq Arif Mohsin, Abbas Ali Hamza, Bashar Shamil Alkhafaji

Al-Esraa University College Journal for Engineering Sciences

In order to create an integrated architectural text, which is a complicated art that blends beauty and practical elements, a rigorous design procedure is necessary. In this situation, the scenario’s role becomes crucial in developing the current architectural text and directing architectural approaches. In order to better understand how the scenario influences the design process and the interactions between various architectural aspects, this project intends to explore and analyze the impact of the scenario in developing and refining architectural text formulation approaches.

The study looks at the idea of a scenario and how it has been used in architecture, as …

Investigation Of Some Physical Properties Of Slurry Infiltrated Fibrous Concrete (Sifcon) Under Different Curing Times, Rand Kh. Mahmoud, Mohmmed Juad Khadhim, Fayq Hasan Jabbar

Al-Esraa University College Journal for Engineering Sciences

This research studied the effects of different types fibers (Basalt, Carbon and Basalt-Carbon hybrid mix) and curing ages (7, 14, 28 and 56 days) on some physical properties of - Slurry infiltrated fibrous concrete (SIFCON). Density, ultrasonic pulse velocity UPV, Poisson’s ratio and water absorption were measured for the experimental study with 30% cement replacement by Class F fly ash to increase sustainability. It was found that properties were significantly affected by the type and dosage of fiber admixture. The UPV was enhanced by basalt fibers and the absorption reduced up to an optimal range of 3–5% after which agglomeration …

Mechanical And Durability Properties Of Cement Panels Reinforced With Hybrid And Pva Fibers, Shukran H. Faraj, Mohammed J. Kadhim

Al-Esraa University College Journal for Engineering Sciences

This study examines the synergistic effects of hybrid fibers (HF) and polyvinyl alcohol (PVA) fibers on the structural and thermal properties of silica-fume cement panels. Scanning electron microscopy (SEM) was employed to examine mortar mixtures with varying fiber content to assess their enhancement of microstructure. We conducted several experiments on compressive, flexural, and splitting tensile strength, in addition to water absorption and thermal conductivity. The results indicate that 1% HF exhibits superior mechanical qualities, with a compressive strength of 46.89 MPa, a flexural strength of 8.56 MPa, and a reduced thermal conductivity of 0.83 W/m•K. PVA fibers at 2% enhance …