Chemical Engineering Commons^™

Evaluation Of A Novel Re-Crosslinkable Preformed Particle Gel For Conformance Control In Ultra-High Temperature Reservoirs, Yanbo Liu, Tao Song, Caleb Kwasi Darko, Thomas P. Schuman, Mingzhen Wei, Baojun Bai

Chemistry Faculty Research & Creative Works

Preferential fluid flow remains a major challenge in subsurface energy production and gas storage operations, resulting in excessive water production in mature oil fields, reduced heat extraction in geothermal reservoirs, and low sweep and storage efficiency in CO₂-EOR projects. Polymer gels are widely used to mitigate high-permeability channels; however, conventional systems exhibit limited plugging efficiency and short lifetimes in ultra-high-temperature reservoirs due to poor thermal stability. This study presents a novel ultra-high-temperature-resistant preformed particle gel (UHT-PPG) developed for conformance control in reservoirs with temperatures of 150–275 °C and severe super-K or channeling problems. The material was evaluated in …

Re-Crosslinkable Hyper-Branched Polymer Gels Based On A Transamidation Reaction, Tao Song, Baojun Bai, Thomas P. Schuman

Patents

The present invention generally relates to the field of conformance control in oil fields, particularly to a re-crosslinkable preformed particle gel system, and composition thereof. The composition of the re-crosslinkable preformed particle gel system contains monomers, crosslinkers, a polymer matrix, and additives. Components in the composition for re-crosslinkable preformed particle gel in the present invention have excellent compatibility with each other, and the obtained gel has excellent long term high-temperature resistance property. Different from prior products, in the recrosslinkable preformed particle gel compositions according to embodiments of the present invention, the components that are used to re-crosslink the particle gels …

Improving Modeling Of Corrosion Products In The Primary Circuit Of Light Water Reactors Through The Experimental Determination Of Crud Characteristics, Sri Saravana Konganapuram Narasimma Bharathi

Electronic Theses & Dissertations (2024 - present)

High-temperature water flowing through the coolant circuits in pressurized water reactors (PWRs) creates a harsh environment, deteriorating these materials. This corrosion results in the formation of oxide layer(s) primarily composed of nickel ferrites, iron oxides, nickel oxides, and other nickel-iron-chrome spinel oxides. Being exposed to fluid with high flow rates and pressure, these oxide layers can be eroded, resulting in particulate fouling due to the release of corrosion products (Chalk River Unidentified Deposits, CRUD) into the coolant circuit. When CRUD subsequently deposits on fuel surfaces, it negatively affects the fuel performance (heat transfer and fuel failure); in addition, the particles …

Harnessing Mono-2-(Methacryloyloxy) Ethyl Succinate Grafting For Robust Micro/Nanoplastic-Resistant Ultrafiltration Membranes, Mohadeseh Najafi, Javad Farahbakhsh, Mitra Golgoli, Michael Johns, Masoumeh Zargar

Research outputs 2022 to 2026

The growing presence of microplastics (MPs) and nanoplastics (NPs) in water systems poses a serious threat to conventional treatment processes, particularly membrane filtration. This study focuses on a surface modification strategy for commercial ultrafiltration (UF) membranes via plasma-induced grafting of mono-2-(methacryloyloxy) ethyl succinate (MMES) to enhance resistance against MP/NPs fouling. The membranes were characterised using advanced analytical techniques, including high-resolution scanning electron microscopy (HRSEM), X-ray photoelectron spectroscopy (XPS), and atomic force microscopy (AFM), confirming successful grafting, increased hydrophilicity, and a more negative surface charge. At optimal conditions of grafting (2 min pretreatment, 0.5 M monomer concentration, and 3 h grafting …

Ai-Enhanced Smart Sensors For Heavy Metal Detection In Water Treatment, Fatemeh Noorisafa, Amir Razmjou, Asghar Taheri-Kafrani, Fatemeh Ejeian, Mohsen Asadnia, Hamidreza Akbari Ghavamabadi

Research outputs 2022 to 2026

Artificial intelligence (AI) enhances biosensor design by efficiently processing and modeling environmental data. This study employs machine learning algorithms to optimize biosensor parameters for the detection of trace-level heavy metals in aquatic environments, utilizing enzymes, DNAzymes, and aptamers as recognition elements. Machine learning models, including decision trees, random forests, gradient boosting, ensemble neural networks, and GLMM,were trained on extensive laboratory datasets. Among these, the random forest model exhibited the highest predictive accuracy, achieving 71 % for the limit of detection (LOD), 75 % for the minimum concentration of linearity, and 62 % for the maximum concentration of linearity. The AI-driven …

Effects Of Electroshock Treatment On Microstructure Evolution And Mechanical Properties Of Ti-8al-1mo-1v Alloy, Jian Zhou, Yu Peng Yao, Hong Xin Sun, Chang Liu, Yan Wen, Li Qiang Wang, Lai Chang Zhang, Le Chun Xie, Lin Hua

Research outputs 2022 to 2026

The effect mechanism of electroshock treatment (EST) on microstructure evolution and mechanical property variations of Ti-8Al-1Mo-1V alloy was investigated. The results show that EST results in the phase transformation from the acicular secondary αs to β phase. While the EST time is 0.12 s, the acicular martensitic phase (αM) precipitates. The results of electron backscattered diffraction (EBSD) reveals that the average grain size decreases from 3.95 to 2.53 μm after EST, indicating that the grains are refined, and the significant recrystallization behavior and martensitic transformation occur. The orientation distribution reveals a more uniform distribution of texture, which is caused by …

Numerically Evaluating The Effect Of Extrusion Angle On Material Flow And Thermal Behaviour During Additive Friction Extrusion Deposition (Afed), Numan Habib, Ferdinando Guzzomi, Ana Vafadar

Research outputs 2022 to 2026

Additive Friction Extrusion Deposition (AFED), also known as “SoftTouch”, is an emerging friction-based Additive Manufacturing (AM) technology allowing material to soften before the deposition, increasing the printing speed and reducing cost [1]. However, high power is required during the process, as excessive force is needed to extrude enough material through the printing head. This study investigates how extrusion angle and tool rotational speed affect thermal distribution and material flow in AFED to minimise power consumption. A three-dimensional computational fluid dynamics (CFD) model is proposed, and ANSYS ^® Workbench CFD code (Fluent) is used to discretise the CFD model. A User-Defined …

Photocatalytic Degradation Of Cephalexin, Amoxicillin, And Phenol Red Using A Green-Synthesized Folic Acid–Zno–Bi2o3 Nanoporous System, M. Sarani, Haghighi, P. Tamaddon, A. Najafidoust, P. Faghani-Eskandarkolaei, N. Sattarahmady

Research outputs 2022 to 2026

The persistent presence of pharmaceutical pollutants like amoxicillin (AMX) and cephalexin (CPX), and industrial dyes such as phenol red (PR) in wastewater poses serious ecological and public health risks, including antibiotic resistance. It necessitates efficient and low-cost remediation technologies. Photocatalysts employing innovative and engineered nanomaterials such as bismuth oxide (Bi2O3) and zinc oxide (ZnO) nanostructures exhibit considerable potential for eliminating pollutants. This study focused on the photodegradation of AMX, CPX, and PR utilizing green-synthesized folic acid–ZnO–Bi2O3 nanoparticles (F-Zn-Bi NPs) under visible light irradiation. Characterization of the synthesized photocatalyst was conducted using various techniques of powder x-ray diffraction (PXRD), field emission …

Sustainable Textiles Through Electrospinning: Addressing Environmental Challenges, Nicole Sharples, Omid Doustdar, Miguel Carmona‐Cabello, Shayan Abrishami, Jose M. Herreros, Ali Sadaghiani, Karl D. Dearn

Research outputs 2022 to 2026

The textile industry, known for its significant environmental footprint, faces growing pressure to adopt sustainable practices. This review identifies the textile industry’s sustainability challenges and examines electrospinning as a promising technology to mitigate its environmental impact. Electrospinning enables the production of nanofibers with enhanced properties suitable for various textile applications, offering potential solutions to reduce resource consumption and waste generation. This review discusses the current uses of electrospinning in textile manufacturing and analyses emerging trends in textile recycling, emphasising the role of electrospinning in transforming waste textiles into value-added products. Prospects for advancing electrospinning techniques to achieve efficient textile recycling …

Performance Investigation Of Microchannel Heat Sink With Biomimetic Trefoil Cavities On Different Walls, Sadiq Ali, Numan Habib, Faraz Ahmad, Aamer Sharif, Ana Vafadar

Research outputs 2022 to 2026

The modern world is shifting towards digitalization and miniaturization, leading to higher flux densities in electronic components and machines. However, conventional cooling methods, such as air-cooled smooth channels, are proving inadequate for removing the huge amounts of heat generated, thereby compromising the reliability and operational lifespan of electronic systems. This necessitates urgently exploring and analyzing modern techniques like microchannel cooling to improve its efficiency. This work uses ANSYS to conduct numerical simulations and investigates the heat transfer and flow behavior in a microchannel heat sink. The smooth channel is used to investigate and validate the flow behavior with the available …

Towards Carbon Geosequestration: Comparing The Wettability Performance Of Western Australian Altered Basaltic Rock/Co2/Water Systems, Seyi Philemon Akanji, Rossen Sedev, Lionel Esteban, Ausama Giwelli, Trevor Beardsmore, Heather Howard, Joel Sarout, Alireza Keshavarz, Stefan Iglauer

Research outputs 2022 to 2026

Geosequestration of carbon dioxide in basaltic rock formations is considered to have the potential to safely and permanently store significant quantities of this greenhouse gas and thereby mitigate its potential global warming effect. The success of this storage method is primarily dependent on the wettability behaviour of the rock-water-CO2 system, which significantly affects fluid distribution, fluid transport, storage capacity and containment security. This study investigates the wettability performance of several Western Australian altered basaltic rocks, of similar geochemistry, porosity and inter-connection. The wettability behaviour of the basaltic materials is assessed using water containing ions that have been leached from the …

Tribological Properties Of Woven Carbon Fiber/Peek Composites From Ambient To 200 °C: Ultra-Low Wear And Performance Evolution, Zheng Bo Xu, Shu Qing Kou, Feng Qiu, Liang Yu Chen, Hong Yu Yang, Jun Nan Dai, Shi Li Shu, Ruifen Guo, Qi Chuan Jiang, Lai Chang Zhang

Research outputs 2022 to 2026

The limited mechanical and tribological stability of carbon fiber reinforced PEEK matrix composites at elevated temperatures remains a major obstacle to their widespread application in extreme service environments. In this work, stain-woven carbon fiber (60 wt%) reinforced PEEK composite (CP60) was fabricated via compression molding, and its temperature-dependent mechanical and wear performance was systematically evaluated. Friction and wear behavior were systematically investigated using pin-on-disc tests under dry sliding conditions. Experiments were conducted at two distinct temperatures (room temperature (RT) and 200 °C) with diverse loads (200–400 N) and sliding velocities (0.47 and 0.94 m/s). The composite exhibited lower average friction …

Solubility And Dissolution Mechanism Of Novel Multi-Ester Headgroup Surfactants In Supercritical Co2, Ning Xu, Yan Ling Wang, Baojun Bai, Shi Zhang Cui, Yu Zhang, Wen Jing Shi, Zhao Nian Zhang, Wen Hui Ding, Pei Xu Ma, Zan Gao

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

To address the limited solubility and applicability of conventional hydrocarbon surfactants in supercritical CO₂, a series of multi-ester headgroup surfactants were designed and synthesized by leveraging the CO₂-philic properties of ester groups. The molecular structures were characterized using Fourier transform infrared (FT-IR) spectroscopy and ¹H NMR. A custom-designed laser-based apparatus was developed to quantify surfactant solubility and systematically investigate phase behavior in CO2. Molecular dynamics (MD) simulations were employed to elucidate structure–solubility relationships across multiple scales, including solubility parameters, interaction energies, radial distribution functions (RDFs), and free volume fractions. Results indicate that, at 323.15 K, …

Enhanced Strength And Corrosion Resistance Of Ti-13nb-12ta-10zr-4sn Alloy By Aging Treatment, Yuhua Li, Rong Zhao, Qian Zhang, Haojie Wang, Yujing Liu, Lai Chang Zhang

Research outputs 2022 to 2026

This work investigates the effect of aging treatment on the mechanical properties and corrosion resistance of Ti-13Nb-12Ta-10Zr-4Sn (TNTZS) alloy prepared by vacuum arc melting. The as-cast TNTZS alloy was solution-treated and aged at 450°C (HT450) and 550°C (HT550). Microstructural characterization revealed significant changes in the phase proportion (in vol%), which transformed from 64% β, 19% α, and 17% α″ in as-cast condition to 54% β, 13% α, and 33% α″ for HT450 and 55% β, 25% α, and 20% α″ for HT550, respectively. The tensile strength and yield strength increased from 608 and 424 MPa in as-cast condition to 1192 …

Age-Related Hearing Loss Involves Mitochondrial Dna Instability And Copy Number Depletion In The Cochlea: Insights From In Vivo And In Vitro Models, Akil Turner, Bo Ding, Xiaoxia Zhu, Tam Nguyen, Parveen Bazard, Robert D. Frisina

Chemical and Biochemical Engineering Faculty Research & Creative Works

Age-related hearing loss (ARHL) is a highly prevalent sensory neurodegenerative disorder that involves various molecular mechanisms. The present study investigated if age-related oxidative stress (OS) induces alterations in mitochondrial DNA (mtDNA) copy number and heteroplasmy, using complementary in vivo and in vitro models. Aged (30-month) CBA/CaJ mice have elevated auditory brainstem response (ABR) thresholds amplitudes vs. young (3-month) CBA/CaJ mice, a key physiological characteristic of ARHL The in vitro experiments employed the strial SV-K1 cochlear cell line treated with hydrogen peroxide (H₂O₂). Both the aged cochleae and H₂O₂-treated cells exhibited a significant …

Insights Of Quantitative Imaging And Instantaneous Heat Transfer Coefficient Measurement In Spouted Bed Column, Hasan A. Abdulwahab, Abbas J. Sultan, Amer A. Abdulrahman, Haydar A.S. Aljaafari, Ali A. Yahya, Zahraa W. Hasan, Malik M. Mohammed, Laith S. Sabri, Bashar J. Kadhim, Jamal M. Ali, Muthanna H. Al-Dahhan

Chemical and Biochemical Engineering Faculty Research & Creative Works

In this study, the heat transfer behavior of a conical spouted bed column was imaged for the first time across its entire cross-sectional area and at multiple axial heights. To achieve this, a custom-built quantitative imaging approach was developed. This method combined FluxTeq heat flux sensors with an Arduino-based data acquisition system. The experimental setup enabled instantaneous, spatially resolved measurements of surface temperature, heat flux, and local heat transfer coefficients (LHTC) under various operating conditions. Measurements at different radial locations, angles, and heights provided a comprehensive view of heat transfer behavior throughout the column. The obtained cross-sectional images show that …

Ansys Discovery And Fluent Files For Modeling A Hydrocyclone With Scco2 And Coal Fly Ash, Isaiah Morones, Catherine Brewer

Chemical & Materials Engineering: Datasets

No abstract provided.

Flow Field Characterization Of The Hyperreact Vitiated Hypersonic Wind Tunnel, Erik R. Fernandez

Graduate Studies Theses and Dissertations 2026

Reliable interpretation of hypersonic ground-test data requires knowledge of the thermochemical state delivered to the test section, especially in combustion-heated facilities where the gas is chemically altered before nozzle expansion. This thesis investigates the HyperReact vitiated hypersonic wind tunnel using the effective specific-heat ratio, γeff, as an experimentally inferred indicator of the coupled chemical and gas-dynamic behavior of hydrogen-air vitiated flow. HyperReact produces high stagnation temperatures through hydrogen-air combustion before expanding the mixture through interchangeable converging-diverging nozzles. During this expansion, temperature-dependent specific heats, molecular-weight changes, finite-rate chemistry, and internal energy relaxation can modify the relationship between Mach number, pressure ratio, …

Investigation On Selective Catalytic Reduction For Retrofit Of Commercial Aviation Aircraft Engines, Connor M. Wall

Graduate Studies Theses and Dissertations 2026

As the aviation industry continues to grow, the ever-increase of emissions from the sector becomes a growing concern. While the International Civil Aviation Organization (ICAO) set a goal of net-zero carbon emissions by 2050, there are other emissions like contrails and NOx that must still be addressed. Selective Catalytic Reduction (SCR) has been used in the transportation and power generation industry for over two decades and has been an effective solution for NOx reduction. Even with the success SCR has had in other industries, its capabilities in the aviation industry have been trivially investigated. Aircraft engines pose an unique challenge …

First-Principles Insights Into Electronic And Magnetic Structure At Hybrid Interfaces And Low-Dimensional Materials And Reaction On Surfaces, Bushra Ashraf

Graduate Studies Theses and Dissertations 2026

Low-dimensional materials and transition metal surfaces/interfaces provide complementary platforms for understanding how dimensionality, symmetry, spin–orbit coupling (SOC), and interfacial charge transfer/hybridization jointly control electronic structure, emergent magnetism, and surface reactivity. Using first-principles modeling with experimental comparisons, this work aims to establish interfacial structure–property relationships across low-dimensional systems.

Strained Pd adlayers on 2H-MoS₂(0001) provide a controlled platform to separate strain-driven exchange from interface-induced quenching in an itinerant d-electron metal. Although expansive strain promotes magnetism in free-standing Pd, strong Pd–MoS₂ hybridization and charge transfer suppress the monolayer moment and leave a narrow thickness window where magnetism re-emerges in …