Chemical Engineering Commons^™

Next Generation Of Applications Of Metal-Organic Frameworks For Energy And Environmental Sustainability, Qian Liu

Graduate Theses, Dissertations, and Problem Reports (ETD)

My PhD work aimed at using Metal-organic frameworks (MOFs) for mitigating the environmental issues and energy crisis associated with anthropogenic activities. Specifically, we developed robust platforms and/ or systems using MOF as “scaffolds” to allow for model pollutant detection and CO₂ sequestration and benign transformation respectively.

First, I detailed how photocatalytic properties of 2,5-furandicarbocylic acid (FDCA) in its alone and its MOF- integrated form (MIL-160) were used for the first time for the reduction of Ag⁺ at room conditions. Such photocatalytic activities could then be used in user-designed hybrids (i.e., Ag/MIL-160) to form sensorial platforms for prevalent phenol …

Application Of Decline Curve Analysis To Unconventional Reservoir, Ahmed Wasel Alqattan

Graduate Theses, Dissertations, and Problem Reports (ETD)

The oil and gas industry has been dealing with the unconventional reservoirs for about only two decades. Consequently, many challenges remain in evaluating the unconventional reservoirs. A few of these obstacles are the absence of the adequate production history, understanding the fluid flow regime after hydraulic fracturing, and estimating the drainage volume of the reservoir. One of the essential elements for evaluation of the oil and reservoir is to estimate the production rates over time in order to investigate the economic potential of the project.

Decline Curve Analysis (DCA) is most common the methodology for predicting the production rates over …

A Study On The Hydrodynamics Of A Bench-Scale Top-Fed Bubbling Fluidized Bed Gasifier Using Biomass And Coal As Feedstocks, Ali Can Sivri

Graduate Theses, Dissertations, and Problem Reports (ETD)

The production of synthetic gas (syngas) from renewable or carbon-neutral sources can significantly reduce greenhouse and other emissions associated with conventional fuels. One of the most promising technologies to efficiently convert carbonaceous feedstocks such as biomass, coal, or municipal waste into syngas for transportation, power, heat, electricity generation, and or production of added-value chemicals is the bubbling fluidized-bed gasifier (BFBG). However, the gasification process inside a BFBG is a very complex high-temperature multiphase flow phenomena still not well understood, particularly when binary mixtures are investigated. As a result, despite the numerous correlations in the literature developed to predict the hydrodynamics …

Process Modeling And Techno-Economic Analysis Of Thermo-Catalytic Dimethyl Ether Synthesis And Microwave-Based Aromatics Production Technologies From Shale Gas, Chirag Mevawala

Graduate Theses, Dissertations, and Problem Reports (ETD)

Production of dimethyl ether (DME) and direct non-oxidative methane dehydroaromatization (DHA) to aromatics via conventional and microwave (MW)-assisted processes are investigated in this research. Plant-wide models of the shale gas to DME process with integrated CO₂ capture via direct and indirect synthesis routes have been developed. Optimal parameter estimation, and model validation are undertaken for various sections of the process including the pre-reforming reactor, auto-thermal reforming reactor, DME synthesis reactors, CO₂ capture units and separation sections. A novel DME separation process has been developed for efficient separation of DME, syngas, and CO₂. Plant-wide techno-economic optimization is …

Dynamic Study Of Mo/Zsm-5 Catalyst For Ch4 Dehydroadomation, Hadi Yahya Almusawa

Graduate Theses, Dissertations, and Problem Reports (ETD)

Methane dehydroaromatization (CH₄-MDA) is a highly promising venture for natural gas utilization/exploitation, i.e., direct conversion of methane (CH₄) to liquid aromatics (benzene) and hydrogen. This process is a catalytic reaction and therefore, is subject to all the advantages and constraints of catalysis. This study discussed the structure and reactivity of Mo/ZSM-5 zeolite catalysts and their effect on the active conversion of methane to valuable aromatic products such as benzene: 1) The preparation and characterization of Mo/ZSM-5, which are crucial steps in any catalytic reaction process since a better performing catalyst consequently leads to better outcomes; 2) …

Time-Dependent Reliability Framework For Durability Design Of Frp Composites, Rajneesh Kumar Bharil

Graduate Theses, Dissertations, and Problem Reports (ETD)

The life-cycle performance, durability, and aging characteristics of Fiber Reinforced Polymer (FRP or Structural Composites) have been of keen interest to the engineers engaged in the FRP design, construction, and manufacturing. Unlike conventional construction materials such as steel and concrete, the design guidelines to account for the aging of FRP are somewhat scattered or not available in an approved or consistent format. Loss of strength over time or aging of any structural material should be of concern to engineers as the in-service lifespan of many engineering structures is expected to exceed 100 years. Use of durability strength-reduction factors or factors …

Exploring Wellbore And Reservoir Temperature Profiles In Fluid Circulation And Production Operations, Ahmed Qasim Al Saedi

Doctoral Dissertations

"The wellbore heat flow occurs during different well operations resulting from any temperature differences between the wellbore fluid and the adjacent formation. Understanding the direction and mechanism of heat flow whether it is conduction or convection help to represent this heat exchange mathematically. However, the only available factor used to understand the heat flow behavior is the measured wellbore temperature which can be obtained from the direct measurement while drilling or circulation operations, well logging, well test, or from the production operations. Also, the initial geothermal formation temperature resulting from the geothermal gradient will help to understand the undistributed formation …

Factors Impacting The Transport And Enhanced Oil Recovery Potential Of Polymeric Nanogel In Sandstone, Haifeng Ding

Doctoral Dissertations

"Enhanced oil recovery (EOR) using nanometer-sized particles has drawn great attention in the oil industry because of their various advantages brought by size. However, their applications on a field scale are very limited, especially for deformable nanoparticles. The objective of this research is to explore the transport behavior of deformable polymeric nanoparticles (nanogel), the factors impacting these behavior, and their EOR potentials. First, 240 published nanoparticle core flooding experiment data were collected and analyzed about the extent to what the nanoparticles can improve oil recovery. Results show that on the laboratory scale the incremental oil recovery could be as high …

Evaluation Of The Performance Of Different Polymer Gel Systems As An In-Depth Gel Treatment Using Numerical Simulation, Tariq K. Khamees

Doctoral Dissertations

"Oil production from heterogeneous and naturally fractured reservoirs are usually hindered due to the presence of high-permeability streaks and natural fractures networks. Oil production could be more lowered if there is a crossflow from the high- to the low-permeability layers and high mobility ratio. These problems are called conformance problems and the treatment is called conformance improvement technologies (CITs). The aims of CIT is to correct the heterogeneity of the reservoir and to lower the unfavorable mobility ratio. These technologies are leading to the diversion of post-treatment water into the low-permeability layers and to increase the viscosity of the displacing …

Experimental And Modeling Studies Using Packed Bed Reactors: Liquid Phase Ethylene Production By Hydrogenation Of Acetylene, Humayun Shariff

Doctoral Dissertations

"Gas-phase catalytic hydrogenation of acetylene to produce ethylene, commonly practiced in industries, has green oil formation, which leads to catalyst deactivation and sometimes reactor runaway risks due to high exothermicity. To overcome these issues as well as to increase the selectivity and conversion, liquid-phase hydrogenation of acetylene was investigated in packed bed reactors (PBR) using a commercial catalyst. The reactor performance of two-phase flow PBRs was assessed experimentally complemented by a validated mathematical model at different scales.

The selective hydrogenation of acetylene in the liquid phase over a commercial 0.5 wt% Pd/Al₂O₃ catalyst was investigated in a …

Polymeric Nanoparticle As A New Platform For High Removal Of Endotoxins From Biopharmaceutical Solutions, Sidharth Razdan

Doctoral Dissertations

"Presently, approximately one-third of all biopharmaceutical drugs are derived from biological sources like gram-negative bacteria. Gram-negative bacteria like E.coli are much cheaper to cultivate and provide higher biotherapeutic yield compared to mammalian cells. On extracting the useful biotherapeutics from the gram-negative bacterial cells (E.coli), endotoxin present in the bacteria is released in the surrounding media thus contaminating the lifesaving biotherapeutics. Application of the endotoxin-contaminated therapeutics to humans or animals can cause serious health issues like septic shock, tissue injury and ultimately death. Hence, thorough purification of biotherapeutics before parenteral application is necessary. Although there are multiple methods for …

Integrated Approach To Investigate The Wellbore Integrity Under Downhole Conditions, Weicheng Zhang

Doctoral Dissertations

“The integrity of the cement sheath is the key part to maintain zonal isolation and prevent the inter-zonal communication. Loads arising from multiple stages of wellbore life span may induce various modes of cement failure within the cement (disking and radial cracks) and at the cement-casing and the cement-formation interfaces (debonding fractures). This research utilizes the integrated laboratory and numerical approach to investigate the cement hardening process, to predict the cement failure under various loading conditions. An innovative experimental setup is established to measure the cement pore pressure variation during the hardening process under downhole conditions, and a staged 3D …

Investigation On Nanoparticle Based Combination Therapy For Targeted Cancer Treatment, Muhammad Raisul Abedin

Doctoral Dissertations

“The current treatment methods in cancer are associated with toxicity in healthy tissues, partial therapeutic response, drug resistance and finally recurrence of the disease. The cancer drugs are challenged by non-specific binding, undesired toxicity in healthy cells, low therapeutic index and finally poor therapeutic outcome. In this work, a targeted nanoscale therapeutic system Antibody Drug Nanoparticle (ADN) was engineered to selectively inhibit the breast cancer cell growth with reduced toxicity in healthy cells. The ADNs were designed by synthesizing rod shaped anoparticles using pure chemotherapeutic drug and covalently conjugating a therapeutic monoclonal antibody (mAb) on the surface of the drug …

Strategies To Improve The Electrochemical Performance Of Lithium-Ion Batteries By Stabilizing The Interface Of Electrode/Electrolyte, Ye Jin

Doctoral Dissertations

”Lithium-ion batteries (LIBs) provide great potential for electric vehicles, and smart grids as future energy-storage devices. However, there are many challenges in the development of the LIB industry, including low energy and power density of electrode materials, poor rate performance, short cycle life of electrode materials, and safety issues caused by the flammability of the conventional organic liquid electrolytes.

In this research, we were committed to using general approach to efficiently and economically synthesize or modify LIB materials by stabilizing the interface between electrode and electrolyte. Atomic layer deposition (ALD) method was used to coat metal oxide thin films on …

Fabrication Of Micro-/Nanofluidic Models And Their Applications For Enhanced Oil Recovery Mechanism Study, Yandong Zhang

Doctoral Dissertations

”Micro-/nanofluidic model, as a potential powerful tool, has been used for decades for investigating fluid flow at pore-scale in energy field. It is still increasingly imperative nowadays to use different micromodels to direct observe pore-level fluid flow and analyze mechanisms of different enhanced oil recovery methods. In this work, three main tasks including three dimensional micromodels (1D,2D,3D) are proposed to fabricate and use for investigating different mechanisms of different enhanced oil recovery methods. For 1D capillary tube micromodel, we fabricate and use it to investigate the dynamics of a trapped oil droplet under seismic vibration. Seismic stimulation is a promising …

Catalytic Utilization Of Carbon Dioxide As Renewable Feedstock For Production Of Chemicals And Fuels, Abbas Alaa Jawad

Doctoral Dissertations

"The utilization of CO₂ as a renewable feedstock for producing commodity chemicals and fuels is an interesting challenge to explore new concepts and opportunities in catalysis and industrial chemistry. This sustainable approach not only leads to production of useful chemicals, but also has the potential to mitigate anthropogenic CO₂ emissions to the atmosphere. CO₂ itself is a sustainable and inexhaustibly available carbon source, however, it is inextricably linked to its inherent inertness. It is a thermodynamically stable molecule (ΔG_f = -394.01 kJ.mol^-1) with high oxidation state, hence, reactions of CO₂ must be combined …

Enhanced Electrochemical Performance Of Li-Ion Battery Cathodes By Atomic Layer Deposition, Yan Gao

Doctoral Dissertations

”Li-ion battery now plays an irreplaceable role in supplying green and convenient energy. In this work, atomic layer deposition (ALD) was used to modify Li-ion battery cathode particles for performance enhancement.

An ultrathin and conductive CeO₂ ALD film was deposited on Li-rich layered cathode particles, of which the specific capacity and cyclic stability were significantly improved. On the same cathode particles, FeO_x ALD and post-annealing resulted in a stable and conductive surface spinel phase to improve the performance.

Synergetic TiN coating and Ti doping were performed on a LiFePO₄ (LFP) cathode and extended its cycle life. The …

Structured Catalysts Designed And Manufactured By 3d-Printing Technique For Functional Integration Of Catalytic Systems, Fatima Magzoub

Doctoral Dissertations

"Microporous zeolites are widely used as heterogeneous catalysts in a wide variety of chemical and petrochemical industries to produce value-added chemicals and fuels, owing to their large surface area, acid-base properties, high thermal stability, and excellent shape-selectivity.

The overall goal of this research was to shape engineer composite zeolites and fine-tune their physiochemical properties to improve the catalytic production of dimethyl ether (DME) and light olefins that are typically used as substitution to diesel fuel and polymer precursors, respectively. Specifically, HZSM-5 and silicalite-1 zeolites were formulated into monolithic contactors using 3D printing technique, followed by subsequent SAPO-34 crystals growth through …

Investigation Of Urea Decomposition And Deposit Formation In Diesel Exhaust After-Treatment System, Anand Alembath

Doctoral Dissertations

“Urea-selective catalytic reduction (SCR) system has proved to be an effective solution to reduce NO_x emissions in commercial vehicle (CV) diesel engines. A significant challenge in urea injection is to comprehend its decomposition chemistry that leads to formation of undesired deposits in the exhaust system unit. Due to complex interaction of multi-phase fluid flow and transport processes, significant uncertainty is associated with the identification of interacting factors that control the deposit initiation and its growth. To meet the future ultra-low NO_x emissions and to deliver ammonia without deposit formation, there is an imminent need to develop the urea-SCR …

Formulation Strategies To Enhance Solubility And Permeability Of Small Molecules For Drug Delivery Applications, Pradeep Kumar Bolla

Open Access Theses & Dissertations

All the new chemical entities/drug molecules intended for therapeutic use must be administered using an appropriate delivery system/dosage form to achieve maximum bioavailability. However, designing a drug delivery system is complex as several factors such as lipophilicity, molecular mass, crystallinity, ionic charge, polymorphic forms and hydrogen bonding) affect the solubility and permeability of these molecules. Biopharmaceutics drug classification system (BCS) categorizes the existing drugs into four classes based on the aqueous solubility and membrane permeability and it is reported that >70% of the drugs are poorly soluble and belong to BCS class II and BCS class IV. Several physical, chemical …