Chemical Engineering Commons^™

Scaling Realistic Fire Scenarios, James G. Quintiere

Progress in Scale Modeling, an International Journal

A review is made of work on scale modeling in fire and presented from the experience of the author. Primarily, scale modeling in air is discussed but there is a brief discussion of a scale model with salt and fresh water for smoke movement. A complete set of dimensionless groups is presented for fire, then it is illustrated how selections were made for the partial scaling of specific fire scenarios. Studies have been motivated by basic research interests as well as for fire investigations. The dynamics of floorcovering fire spread in a corridor is studied to reveal many features of …

New Modeling Approaches For The Prediction Of Combustion Pollutants, Phillip R. Johnson

McKelvey School of Engineering Graduate Student Theses & Dissertations

Combustion processes are ubiquitous to human technological development and provide many benefits such as large-scale power generation for electricity and transportation along with residential and commercial heating for manufacturing, cooking, and warmth. However, these various processes can also have harmful effects on human health and the environment via emission of CO2 and other pollutants such as NOx and particulate matter (PM; often in the form of soot). For these reasons, there is a continued need for controlling, improving, and optimizing combustion processes. Modeling of these processes provides powerful insights into system-level dynamics and their control. Due to the size and …

Advanced Materials For Air Pollutants Removal In A Combustion System, Sungyoon Jung

McKelvey School of Engineering Graduate Student Theses & Dissertations

Air pollutants directly or indirectly impact human health and the environment. Large quantities of CO2, volatile organic compounds (VOCs), and particulate matter are emitted from combustion systems, and cause climate change, smog formation, and pose serious health risks. The increasing demand for the remediation of air pollutants at the source has drawn much attention to the use of advanced materials due to their high reactivities and special properties. In order to achieve the successful application of advanced materials for the remediation of problematic emissions, three aspects, (1) synthesis method, (2) characterization of materials’ structural properties, and (3) evaluation of materials’ …

Structural Organization And Chemical Activity Revealed By New Developments In Single-Molecule Fluorescence And Orientation Imaging, Tianben Ding

McKelvey School of Engineering Graduate Student Theses & Dissertations

Single-molecule (SM) fluorescence and its localization are important and versatile tools for understanding and quantifying dynamical nanoscale behavior of nanoparticles and biological systems. By actively controlling the concentration of fluorescent molecules and precisely localizing individual single molecules, it is possible to overcome the classical diffraction limit and achieve 'super-resolution' with image resolution on the order of 10 nanometers.

Single molecules also can be considered as nanoscale sensors since their fluorescence changes in response to their local nanoenvironment. This dissertation discusses extending this SM approach to resolve heterogeneity and dynamics of nanoscale materials and biophysical structures by using positions and orientations …

Growth Of Small Particles In Nonequilibrium Plasmas, Necip Berker Üner

McKelvey School of Engineering Graduate Student Theses & Dissertations

Nonequilibrium plasma (NEP) is an extraordinary environment for material synthesis. NEP is comprised of hot electrons with temperatures greater than 10000 K and of cold ions and neutrals that are usually at few hundred kelvins above room temperature. Due to this large difference in species’ temperatures, the assumption of local thermal equilibrium does not hold in NEP. Therefore, NEP can act as a unique processor of mass, and it can transform materials along pathways that are not accessible by methods wherein local thermal equilibrium is valid. For decades, NEPs have been employed in the semiconductor industry to manufacture many thin …

Particle Studies In The Lab And Pilot-Scale Coal Combustion Systems, Dishant Khatri

McKelvey School of Engineering Graduate Student Theses & Dissertations

In the past century, coal contributed more to the global electricity supply than any other source. Currently, it alone accounts for over 35% of the global electricity supply. Though coal is globally well-distributed and can provide cheap, stable, and reliable energy on demand, it emits a large amount of carbon dioxide—a greenhouse gas responsible for global warming. Additionally, it is a major source of particulate matter (PM) pollution. Thus, in recent years, to reduce the impact of coal on climate, several policies have been introduced to phase out coal. However, replacing coal with intermittent renewables has led to a reduction …

Aligned Fingolimod-Releasing Electrospun Fibers Increase Dorsal Root Ganglia Neurite Extension And Decrease Schwann Cell Expression Of Promyelinating Factors, Devan L. Puhl, Jessica L. Funnell, Anthony R. D'Amato, Jonathan Bao, Dmitri V. Zagorevski, Yelena Pressman, Daniel Morone, Agnes E. Haggerty, Martin Oudega, Ryan J. Gilbert

Chemical and Biochemical Engineering Faculty Research & Creative Works

Researchers are investigating the use of biomaterials with aligned guidance cues, like those provided by aligned electro spun fibers, to facilitate axonal growth across critical-length peripheral nerve defects. To enhance the regenerative outcomes further, these aligned fibers can be designed to provide local, sustained release of therapeutics. The drug fingolimod improved peripheral nerve regeneration in preclinical rodent models by stimulating a pro-regenerative Schwann cell phenotype and axonal growth. However, the systemic delivery of fingolimod for nerve repair can lead to adverse effects, so it is necessary to develop a means of providing sustained delivery of fingolimod local to the injury. …

A Review Of Coal Heating Value Correlations With Application To Coal Char, Tar, And Other Fuels, Andrew P. Richards, Denver Haycock, Jacob F. Frandsen, Thomas H. Fletcher

Faculty Publications

Accurately measuring a fuel’s heating value is one of the first steps in the classification of a new fuel. Heating values are widely used in coal combustion research and are becoming more useful in other fuel types as well. Many different empirical correlations to predict heating values based on primary organic (CHONS) elemental composition are found in the literature, many of which were originally created to predict heating values of parent coal, and some of which have been extended for biomass. However, no correlations exist for heating values of coal chars and tars. Thirteen literature heating value correlations (10 model …

Aqueous Redox Flow Batteries With Boron Doped Diamond As An Electrode., Alex M. Bates

Electronic Theses and Dissertations

As the interest and implementation of renewable energy accelerates, so does that of grid energy storage. It is widely believed that a cost-effective energy storage technology will bring about the proliferation of renewable energy. Redox flow battery (RFB) technology represents a promising solution to cost-effective grid energy storage. Compared to other technologies, RFBs have a long lifetime, high efficiency, are non-flammable, significantly reduce cost, and separately scale power and energy. The separation of power and energy enables increased energy capacity by simply adding electrolyte volume. Of the challenges facing RFB technology, one readily apparent is the cost of the active …

Nanoceria Distribution And Effects Are Mouse-Strain Dependent, Robert A. Yokel, Michael T. Tseng, D. Allan Butterfield, Matthew L. Hancock, Eric A. Grulke, Jason M. Unrine, Arnold J. Stromberg, Alan K. Dozier, Uschi M. Graham

Pharmaceutical Sciences Faculty Publications

Prior studies showed nanoparticle clearance was different in C57BL/6 versus BALB/c mice, strains prone to Th1 and Th2 immune responses, respectively. Objective: Assess nanoceria (cerium oxide, CeO₂ nanoparticle) uptake time course and organ distribution, cellular and oxidative stress, and bioprocessing as a function of mouse strain. Methods: C57BL/6 and BALB/c female mice were i.p. injected with 10 mg/kg nanoceria or vehicle and terminated 0.5 to 24 h later. Organs were collected for cerium analysis; light and electron microscopy with elemental mapping; and protein carbonyl, IL-1β, and caspase-1 determination. Results: Peripheral organ cerium significantly increased, generally more …

Interactions Between Control And Process Design Under Economic Model Predictive Control, Henrique Oyama, Helen Durand

Chemical Engineering and Materials Science Faculty Research Publications

conomic model predictive control (EMPC) is a model-based control scheme that integrates process control and economic optimization, which can potentially allow for time-varying operating policies to maximize economic performance. The manner in which an EMPC operates a process to optimize economics depends on the process dynamics, which are fixed by the process design. This raises the question of how process and EMPC designs interact. Works which have addressed process and control design interactions for steady-state operation have sought to simultaneously develop process designs and control law parameters to find the most profitable way to operate a process that is able …

Development Of Novel Catalysts For Hydrogen Gas Production From Biomass Compounds, Boanerges Bamaca

Department of Agricultural and Biological Systems Engineering: Dissertations, Theses, and Student Research

Hydrothermal biomass gasification technologies (sub- and supercritical water gasification and aqueous-phase reforming) have considerable economic, environmental, and technical advantages over other energy-extensive technologies (e.g. natural gas reforming) for hydrogen gas production. However, lack of economically feasible and highly active catalysts is a main challenge that impedes upscaling of these technologies for hydrogen gas production.

The goal of this study was to develop innovative, economically feasible and active heterogeneous supported metal catalysts for hydrothermal processes for producing hydrogen gas from biomass-derived compounds. Because of its stable structure and chemical inertness, graphene was used as catalyst support. Graphene supported metal catalysts were …

A Comparison Study Using Particle Swarm Optimization Inversion Algorithm For Gravity Anomaly Interpretation Due To A 2d Vertical Fault Structure, Neil Lennart Anderson, Khalid S. Essa, Mahmoud Elhussein

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

A new approach to the inversion of gravity data utilizing the Particle Swarm Optimization (PSO) algorithm is used to model 2D vertical faults. The PSO algorithm is stochastic in nature; its development was motivated by the communal in-flight performance of birds looking for food. The birds are represented by particles (or models). Individual particles have a location and a velocity vector. The location vectors represent the parameter value. PSO is adjusted with random particles (models) and searches for targets by updating generations. Herein, the PSO algorithm is applied to three synthetic data sets (residual only with and without noise, residual …

The Kinetic Study Of Dpt Using Mathematica As An Efficient Optimization Tool, M. H. El Dewaik, Mamdouh Gadalla, M. A. Radwan, M. A. Sadek, Hany A. Elazab

Chemical and Biochemical Engineering Faculty Research & Creative Works

Mathematica is a powerful program for computing both numeric and algebraic calculations as well as graphing two- and three-dimensional curves and surfaces. It is used increasingly in many fields of science now such as physics, engineering, chemistry and even biology because of the fast interaction of mathematics with almost the fields of science nowadays. Synthesis of Cyclotetramethylene Tetramine through the action of nitrating mixture formed of ammonium nitrate and fuming nitric acid on hexamine in presence of acetic acid, acetic anhydride and p-formaldehyde has been proven. The pathway is relatively long and Hexamine Dinitrate and Dinitro Pentamethylene Tetramine (DPT) are …

Investigation Of Various Techniques For Controlled Void Formation In Fiberglass/Epoxy Composites, Donald A. Klosterman, Charles Browning, Issa Hakim, Kyle Lach

Chemical and Materials Engineering Faculty Publications

The effect of porosity in composite materials has been studied for years due to its deleterious effects on mechanical properties, especially matrix dominated properties. Currently there is an increasing use of composites in infrastructure worldwide, for example bridge components, residential and building structures, marine structures such as piers and docks, and large industrial chemical tanks. Most of these applications use fiberglass composites. Unfortunately, most of the published literature has focused on carbon fiber composites, in which fiber diameter and gas-fiber interactions are different than fiberglass composites. Therefore, the present study was undertaken to revisit the effect of porosity but specifically …

Investigations Of Air-Water Multiphase Flow In Tubes: Computational Fluid Dynamics, Wei Hong Goo

Student Works (2020-2029)

Mixing is a very crucial process in many industries, such as food processing industry, minerals processing industry, petrochemicals and refining industry, pulp and paper industry, polymer industry, pharmaceuticals industry and many more. There are different types of mixing, such as liquid-gas mixing, liquid-liquid mixing, solid-liquid mixing and many more. The definition of multiphase flow is the simultaneous flow of materials with multiple thermodynamic phases. A lot of process industries require multiphase flows during operation. Bubbly flow is defined as the flow of liquids that contains dispersed gas bubbles. One of the main applications of multiphases flows and bubbly flows is …

Study Of Heat Transfer And Friction Loss Of Nanofluid Suspension Flow In Square Pipe Heat Exchanger, Krishnan Jayprasanth

Student Works (2020-2029)

An experimentational analysis was done to evaluate heat transfer features of graphene oxide (GO) nanofluid inside the cross section of square cross tube that was exposed to a uniform constant heat flux of the test segments. Lately huge figures of researches have been are proceeded out to examine the outcome of nanofluid in augmentation of the heat transfer rate in numerous heat exchangers particularly using hummer method to attain GO. In this case, advanced hummer method was used to obtain GO and further analyses the effect of the nanofluids. The viscosity and thermal conductivity for the (GO) nanofluids at the …

Waste Cooking Oil Classification Using Artificial Intelligence Technology, Kar Sin Lau

Student Works (2020-2029)

Palm oil – one of the most common edible oil consumed in Malaysia. It is because Malaysia is one of the countries which supply palm oil to the global market and it is cheap to obtain for the consumer in Malaysia. Most of the Malaysian consume it via food preparation such as deep-frying and cooking. However, due to widely available for Malaysians, consumers also lacking awareness in dealing after using the edible oil. Most of the household consumers discard excess waste cooking oil (WCO) into sewage and with courtesy, some of them stored them in containers and sell to NGOs. …

Thermodynamic Analysis And Optimization Of Organic Rankine Cycles Using 1-Butylpyridinium Tetrafluoroborate As A Geothermal Fluid, Kazemi Shabnam

Student Works (2020-2029)

Organic Rankine cycle (ORC) is a promising technology for electricity generation by utilizing heat sources at low to moderate temperature that ranges between 80-350° C. In the present work, an ionic liquid (1-butylpyridinium tetrafluoroborate, C9H14NBF4), a known green chemical and non-volatile compound with good thermal and chemical stability, significant heat capacity, low vapor pressure and a wide liquid temperature range (25 to 459 °C), is utilized as a geothermal fluid. Simulation and optimization were conducted for a basic organic Rankine cycle (basic ORC), a regenerative organic Rankine cycle (RORC) and a two-stage evaporative organic Rankine cycle (TSORC) by maximizing exergy …

Quantitative Risk Assessment And Dispersion Modelling Using Aloha For Chlorine Gas Handling Facility, Kusala Uvaraja

Student Works (2020-2029)

Malay-Sino Chemical Industries Sdn Bhd (Lahat) is a chlor-alkali industry consist of Emergency Chlorine Gas Handling Facility (ECGHF) which have the tendency to affect the plant workers and nearby residential area in the event of accidental chlorine gas release. HAZOP tool with risk assessment was used to identify the hazard and quantifying the hazards in order to prioritize the recommendations at the ECGHF. Possible incident scenario was selected from the HAZOP outcome which was the chlorine gas release from the stack due to scrubbing flow failure. The consequences of the released chlorine gas to the atmosphere was simulated by using …