Mechanical Engineering Commons^™

Characterization Techniques And Electrolyte Separator Performance Investigation For All Vanadium Redox Flow Battery, Zhijiang Tang

Doctoral Dissertations

The all-vanadium redox flow battery (VRFB) is an excellent prospect for large scale energy storage in an electricity grid level application. High battery performance has lately been achieved by using a novel cell configuration with advanced materials. However, more work is still required to better understand the reaction kinetics and transport behaviors in the battery to guide battery system optimization and new battery material development. The first part of my work is the characterization of the battery systems with flow-through or flow-by cell configurations. The configuration difference between two cell structures exhibit significantly different polarization behavior. The battery output can …

Scaling Reversible Adhesion In Synthetic And Biological Systems, Michael David Bartlett

Open Access Dissertations

Geckos and other insects have fascinated scientists and casual observers with their ability to effortlessly climb up walls and across ceilings. This capability has inspired high capacity, easy release synthetic adhesives, which have focused on mimicking the fibrillar features found on the foot pads of these climbing organisms. However, without a fundamental framework that connects biological and synthetic adhesives from nanoscopic to macroscopic features, synthetic mimics have failed to perform favorably at large contact areas. In this thesis, we present a scaling approach which leads to an understanding of reversible adhesion in both synthetic and biological systems over multiple length …

Numerical Modeling Of Solidification Process And Prediction Of Mechanical Properties In Magnesium Alloys, Mehdi Farrokhnejad

Electronic Thesis and Dissertation Repository

A formulation used to simulate the solidification process of magnesium alloys is developed based upon the volume averaged finite volume method on unstructured collocated grids. To derive equations, a non-zero volume fraction gradient has been considered and resulting additional terms are well reasoned. For discretization the most modern approximations for gradient and hessians are used and novelties outlined. Structure-properties correlations are incorporated into the in-house code and the proposed formulation is tested for a wedge-shaped magnesium alloy casting. While the results of this study show a good agreement with the experimental data, it was concluded that a better understanding of …

Ramjet Combustion Chamber, Paul Cameron Stone

Aerospace Engineering

A ramjet combustion chamber is designed and some initial assembly fabrication and test completed as a component of a ramjet graduate project for California Polytechnic State University, San Luis Obispo Supersonic Wind Tunnel. The combustor design is driven by a theoretical model created by a Cal Poly graduate student, Harrison Sykes. Temperature, pressure, and fuel flow will be measured.

Potenciar El Módulo De Procesos Electroquímicos Para El Control De Nivel Y Temperatura, Nathalia Ruiz Manrique, Cristhian Andres Rey Casadiego

Ingeniería en Automatización

En los laboratorios del programa de Ingeniería en automatización se dispone de un sistema integrado de manufactura en el cual se realiza el proceso de mecanizado y ensamblado de piezas de metal desde la alimentación de materia prima hasta su almacenamiento. Uno de los módulos incluidos en este sistema es el de procesos electroquímicos en el cual por medio de un robot cartesiano se manipula la pieza proveniente de la banda transportadora simulando la limpieza y el tratamiento electroquímico, para eliminar los residuos de impurezas y lubricantes en los diferentes tanques del módulo por medio del control de nivel y …

Two-Phase Flow In Microchannels: Morphology And Interface Phenomena, Alexandru Herescu

Dissertations, Master's Theses and Master's Reports - Open

The existence and morphology, as well as the dynamics of micro-scale gas-liquid interfaces is investigated numerically and experimentally. These studies can be used to assess liquid management issues in microsystems such as PEMFC gas flow channels, and are meant to open new research perspectives in two-phase flow, particularly in film deposition on non-wetting surfaces. For example the critical plug volume data can be used to deliver desired length plugs, or to determine the plug formation frequency. The dynamics of gas-liquid interfaces, of interest for applications involving small passages (e.g. heat exchangers, phase separators and filtration systems), was investigated using high-speed …

The Role Of Transport Phenomena In The Direct Oxidation Of Solid Fuels, Charles J. Banas

Master's Theses

Direct carbon fuel cells have shown promise for stationary power generation by utilizing the direct oxidation of a solid carbon fuel source at the anode. In laboratory settings, researchers have reported up to 300mA/cm2 of current density from these cells types which suffer from mass transport losses. This paper studies the surface properties of the solid fuel source, and describes the process of CO2 evolution through an analogy to pool boiling. In nucleate boiling (a subset of pool boiling) vapor bubbles grow from nucleation sites where gas are trapped in micro-cavities on the surface. Carbon surfaces possess these same features, …

Improved Non-Linear Solution Of Dip Coating Flow, Omar Bin Yusuf

Electronic Thesis and Dissertation Repository

A thin layer of film is developed on the surface of a substrate in the dip coating process where the substrate is initially immersed into the coating fluid and then withdrawn continuously from the coating fluid bath. In this study a two dimensional flow of the thin film for a Newtonian fluid is examined theoretically by dividing the film into three separate regions. A general formulation is developed for a thin film flow, which then simplifies for each region upon considering appropriate assumptions to each region. The influence of inertia and surface tension in the presence of gravity is investigated …

Numerical Simulation Of Catalytic Ozone Decomposition Reaction In A Gas-Solids Circulating Fluidized Bed Riser, Lei Kong

Electronic Thesis and Dissertation Repository

Computational fluid dynamics (CFD) modeling of catalytic ozone decomposition reaction in a circulating fluidized bed (CFB) riser using iron impregnated FCC particles as catalyst is carried out. The catalytic reaction is defined as a one-step reaction with an empirical coefficient. Eularian-Eularian method with kinetic theory of granular flow is used to solve the gas-solids two-phase flow in the CFB riser. The simulation results are compared with experimental data, with the reaction rate modified using an empirical coefficient to provide better simulation results than the original reaction rate. Moreover, the particle size has great effects on the reaction rate. Studies on …

Sustainability Analysis Of Personal Transportation For Near Urban Commuting, Theodore Ansink, Matthew Atchley, Virginia Browning, Yue Cao, Michelle Everett, James Hall Jr, William R. Henson, Eugene Ng, Michael Picklesimer, Justin Ridenour, Scott Teeters, James Wilson

Chancellor’s Honors Program Projects

No abstract provided.

Oxidation Of Borides And Carbides With Y2o3 And Ta Additions, Salvador Manuel Rodriguez

Open Access Theses & Dissertations

The study presented here describes an investigation of an oxidation scale of a fully-sintered Y2O3-ZrB2-TiC composite exposed in air at 1173K. Upon oxidation of the boride/carbide, a ZrO2-TiO2 was expected to form similar to the ZrO2-SiO2 dual scale of an oxidized ZrB2-SiC. The 47wt% Y2O3-38wt%ZrB2-16wt%TiC composite formed a dual scale consisting primarily of an Y2O3-ZrO2-TiC inner scale with an outer scale of ZrO2-TiO2-Y2O3.

The samples oxidized with a parabolic layer growth allowing the calculation of the effective diffusion coefficient indicating that the oxidation was controlled by oxygen ingress through primarily the ZrO2-Y2O3 phase. The oxygen potential between the inner layer …

Analysis Of Biomass/Coal Co-Gasification For Integrated Gasification Combined Cycle (Igcc) Systems With Carbon Capture, Henry A. Long Iii

University of New Orleans Theses and Dissertations

In recent years, Integrated Gasification Combined Cycle Technology (IGCC) has become more common in clean coal power operations with carbon capture and sequestration (CCS). Great efforts have been spent on investigating ways to improve the efficiency, reduce costs, and further reduce greenhouse gas emissions. This study focuses on investigating two approaches to achieve these goals. First, replace the subcritical Rankine steam cycle with a supercritical steam cycle. Second, add different amounts of biomass as feedstock to reduce emissions. Finally, implement several types of CCS, including sweet- and sour-shift pre-combustion and post-combustion.

Using the software, Thermoflow®, this study shows that utilizing …

Evaluation Of Cathode Materials For Low Temperature (500-700c) Solid Oxide Fuel Cells, Alexander M. Lassman

Master's Theses

Solid oxide fuel cells (SOFC) have gained a great deal of interest, due to their potential for high efficiency power generation and ability to utilize hydrogen fuel, as well as various hydrocarbon-based fuels. A recent trend in SOFC development has been towards lower operating temperatures (500-700°C), which can substantially reduce the cost and complexity of the system. This thesis presents an investigation into state of the art Ba- and La- based cathode materials for use in low temperature (500-700°C) solid oxide fuel cells.

Synthesis of A-site deficient [A=0.97] Ba_0.5Sr_0.5Co_0.8Fe_0.2O₃ (BSCF) was …

Applied Control Strategies At A Cogeneration Plant, Joseph William Burns

Master's Theses

The purpose of this paper is to demonstrate the effectiveness of “classical strategies for dynamic control” on authentic cogeneration processes. These strategies are applied to several processes at the University of Connecticut’s cogeneration plant. Case studies of their applications are presented in this paper. Strategies that are applied include the following:

1) The classical SISO feedback structure

2) The First Order Plus Dead Time (FOPDT) process model

3) The Internal Model Control (IMC) correlations for PI controller tuning

4) Static feed forward with feedback trim

5) Cascade Control

Rayleigh Test Apparatus Design Report, Josef Duller, Owen Raybould, James Nicovich

Mechanical Engineering

The Rayleigh Test Apparatus is a device that will be used to test the thermodynamic properties of Nitrous Oxide to assess the feasibility of using this fluid as a coolant for a hybrid rocket aero spike. The aero spike is intended to redirect the propulsion flow as it leaves the engine to create a more efficient flow pattern at low and high altitudes. However, there are issues of overheating which leads to melting of the aero spike. For this reason, the use of nitrous oxide (N2O) as a coolant is being explored. N20 is being considered because it is already …

Comparison Of Horizontal Ground Source (Geothermal) Heat Pump Layouts For Optimal Performance And Thermal Efficiency, Elizabeth M. Bocchino

Honors Theses

This study investigates the difference in thermal efficiencies of horizontal ground source heat pump layouts through computer simulation and experimental modeling. The main objective of this project was to determine if the shape of the layout affects the total heat exchange in a horizontal geothermal system. Geothermal energy is power extracted from the Earth and studies have been focused on increasing the efficiency of the heat transfer from the Earth to the system. Steady state and transient thermal analyses were conducted on two horizontal layout shapes, a U-loop and a coil, in ANSYS Fluent. This system was not full size, …

An Adaptive Nonparametric Modeling Technique For Expanded Condition Monitoring Of Processes, Matthew John Humberstone

Doctoral Dissertations

New reactor designs and the license extensions of the current reactors has created new condition monitoring challenges. A major challenge is the creation of a data-based model for a reactor that has never been built or operated and has no historical data. This is the motivation behind the creation of a hybrid modeling technique based on first principle models that adapts to include operating reactor data as it becomes available.

An Adaptive Non-Parametric Model (ANPM) was developed for adaptive monitoring of small to medium size reactors (SMR) but would be applicable to all designs. Ideally, an adaptive model should have …

Simulation, Synthesis, And Characterization Of Hydrogels And Nanocomposite Gels., Kamleshkumar J. Suthar

Dissertations

Stimuli-responsive gels are three-dimensional, cross-linked polymeric materials that undergo large physical change in response to the environmental stimuli, like temperature, pH, electrical potential, and irradiation. Ferrogels are colloidaldispersion of magnetic nanoparticles in the hydrogel network. The magnetic nanoparticles are attached to the polymeric network by different adhesive forces; as a result, it becomes sensitive to the applied magnetic field.

The main objective of this research is the simulation, synthesis, and characterization of the hydrogel and ferrogel. Simulation of the hydrogel response was performed for various environmental stimuli using a multiphysics finite element analysis software, COMSOL. The pH and electrical response …

Temperature Influence And Heat Management Requirements Of Microalgae Cultivation In Photobioreactors, Thomas Hagen Mehlitz

Master's Theses

Microalgae are considered one of the most promising feedstocks for biofuel production for the future. The most efficient way to produce vast amounts of algal biomass is the use of closed tubular photobioreactors (PBR). The heat requirement for a given system is a major concern since the best algae growth rates are obtained between 25-30 °C, depending on the specific strain. A procedure to determine temperature influence on algal growth rates was developed for a lab-scale PBR system using the species Chlorella. A maximum growth rate of 1.44 doublings per day at 29 °C (optimal temperature) was determined. In addition, …

Treatment Of Aqueous Waste Streams At Eli Lilly - Alternatives To Incineration, Barry Hennessy

Theses

The aim of this project was to investigate the potential to treat liquid waste (secondary) from production processes at Eli Lilly with the emphasis on minimising the volume of waste sent for thermal oxidation. In addition, the project aimed to investigate if the chosen technology was diverse and potentially capable of handling waste streams from different processes. Membrane technology was identified as one of the most suitable technologies and trials were carried out on secondary waste from three production processes. The literature review and practical thrials aswell as assessment of trial results ran from October 2003 to June 2005.

All …

Development Of A Novel Microreactor For Improved Chemical Reaction Conversion, Yu Liang

Doctoral Dissertations

Microreactors have been widely studied over the past two decades for different chemical reactions, to develop new analytical capabilities, and to obtain high mixing performance in the reactors. The main objectives of this work are to investigate the effect of different microchannel structures on the fluid properties and mixing behavior in microreactors, and to design, fabricate, and test a novel microreactor for higher conversion in a chemical reaction. The development of this novel microreactor is intended to provide a valuable guideline in achieving enhanced chemical mixing and to make available a solid research base for optimization of the yield of …

A Finite Element Simulation Of Temperature And Material Flow In Fricton Stir Welding, Mark J. Lasley

Theses and Dissertations

The purpose of this research was to use the Transvalor S.A. product, Forge3, to develop a finite element simulation of the friction stir welding process that improves the predictability of temperature evolution and material flow within the plunge portion of the process. Previous modeling created more heating within the billet than experimental results, probably due to the simplification of the simulation with adiabatic boundary conditions. More realistic tooling temperatures were included in this model as these affect heat evolution which is a determining factor in microcrystalline growth. These results were validated by experimental efforts using a billet and tooling instrumented …

Layer-By-Layer Nanoassembly Combined With Microfabrication Techniques For Microelectronics And Microelectromechanical Systems, Jingshi Shi

Doctoral Dissertations

The objective of this work is to investigate the combination of layer-by-layer self-assembly with microfabrication technology and its applications in microelectronics and MEMS.

One can assemble, on a standard silicon wafer, needed multilayers containing different nanoparticles and polymers and then apply various micromanufacturing techniques to form microdevices with nanostructured elements.

Alternate layer-by-layer self-assembly of linear polyions and colloidal silica at elevated temperatures have been firstly studied by QCM and SEM. LbL self-assembly and photolithography were combined to fabricate an indium resistor. The RTA method was employed in the fabrication. Hot-embossing technique as a reasonably fast and moderately expensive technique was …

Design And Simulation Of An Induction Skull Melting System, Taide Tan

UNLV Theses, Dissertations, Professional Papers, and Capstones

Incorporating volatile actinides, mainly americium into a metallic fuel pin (MFP) has been a serious problem due to americium’s high vapor pressure. An Induction Skull Melting (ISM) system was identified by Argonne National Laboratory (ANL) as a potential furnace design to cast MFPs. Through the development of the ISM system, the nuclear waste feedstock can be melted and injected into the mold for fabricating MFPs in the advanced nuclear fuel cycles. The main phenomena in this system include: induction melting process, casting process and mass transfer process of americium. Issues related to ISM system design for casting MFPs are discussed …

Fatigue Of Drill Pipes Used In Horizontal Directional Drilling, Feibai Ma

Doctoral Dissertations

Fatigue is the most common cause of mini-HDD drill rod failure. It can occur at stress levels far below the normal operating stress in most drill stem components. Fatigue failures occur because the drill rod, after it has been forced into a curved path, undergoes a cyclic bending stress oscillating from tension to compression in concert with the other stress components caused by torque, thrust, or pullback.

When a rod breaks underground, there is considerable extra cost caused by the delay in “fishing” out the broken rod as well as the cost of replacing the rod. On the other hand, …

Design And Analysis For Melt Casting Metallic Fuel Pins Incorporating Volatile Actinides, Xiaolong Wu

UNLV Theses, Dissertations, Professional Papers, and Capstones

Fundamental issues related to the selection of a metallic fuel casting furnace design are presented and discussed including heating mechanisms, casting issues, crucible design, and issues related to the mass transport of americium. The process of evaluating all of these different criteria is undertaken to select a concept that would have the greatest chance of success for casting americium in a metallic fuel rod. Based on this evaluation process, a concept for the casting of metallic fuel pins containing high vapor pressure materials is selected and discussed. The important physics of this concept include mass transport of americium from the …

Modeling And Simulation Of The Chemical Etching Process In Niobium Cavities, Qin Xue

UNLV Theses, Dissertations, Professional Papers, and Capstones

Niobium Cavities are important parts of the integrated NC/SC high-power linear accelerator (linac) that can accelerate over 100 mA of protons to several GeV. Surface finish of the niobium cavity plays an important role of achieving the best performance of niobium cavity. The chemical etching techniques have been widely used.

Chemical etching of the inner surface of the cavity is achieved by circulating acid through it. The acid interacts with the surface and eliminates imperfections. During the etching process, a pipe with baffles is inserted within the cavity to direct the flow along the surfaces.

A 2-D, axisymmetric, steady state, …

Mathematical Modeling For Fabricating A Microstructure With A Pre-Specified Geometry Using Laser -Induced Chemical Vapor Deposition, Chaoyang Zhang

Doctoral Dissertations

Laser-induced chemical vapor deposition (LCVD) is an emerging new technique with many practical applications. To optimize the system for fabricating a microstructure with a pre-specified geometry in pyrolytic LCVD, a three-dimensional mathematical model is developed for predicting temperature distributions and laser dwell times across the substrate scanned by the laser beam. A microstructure is fabricated layer by layer, and for each layer the laser beam moves from one pixel to the next. The complicated correlations among temperature distribution, deposit growth rate, and laser dwell time are investigated. A purely heterogeneous reaction is assumed and any gas-phase transport is ignored.

A …

Studies Of Mixing Processes In Gases And Effects On Combustion And Stability, Frank Paul Kozusko Jr.

Mathematics & Statistics Theses & Dissertations

Three physical models of laminar mixing of initially separated gases are studied. Two models study the effects of the mixing dynamics on the chemical reactions between the gases. The third model studies the structure and stability of a laminar mixing layer in a binary gas. The three models are:

1. Two ideal and incompressible gases representing fuel and oxidizer are initially at rest and separated across an infinite linear interface in a two dimensional system. Combustion, expected as the gases mix, will lead to a rapid rise in temperature in a localized area, i.e. ignition. The mixing of the gases …

Fabrication Of Thermoplastic Polymer Composite Ribbon, Donald Allan Sandusky

Dissertations, Theses, and Masters Projects

The goal of this research was to develop a controllable process to convert a thermoplastic powder-coated carbon-fiber towpreg into uniform and consolidated ribbon. The approach comprised four primary activities. (1) The patent and processing literature was studied to evaluate the state of the art. (2) A functional ribbon fabrication technique was developed by scaling-up, in a novel configuration, hardware components found in the literature. (3) The ex parte ribbonizing process was characterized by calibrating equipment, determining steady state and studying cause and effect between process parameters and ribbon quality. (4) Process design and control methods were derived from heat transfer …