Mechanical Engineering Commons^™

The Role Of Transport Phenomena In The Direct Oxidation Of Solid Fuels, Charles J. Banas

Master's Theses

Direct carbon fuel cells have shown promise for stationary power generation by utilizing the direct oxidation of a solid carbon fuel source at the anode. In laboratory settings, researchers have reported up to 300mA/cm2 of current density from these cells types which suffer from mass transport losses. This paper studies the surface properties of the solid fuel source, and describes the process of CO2 evolution through an analogy to pool boiling. In nucleate boiling (a subset of pool boiling) vapor bubbles grow from nucleation sites where gas are trapped in micro-cavities on the surface. Carbon surfaces possess these same features, …

Improved Non-Linear Solution Of Dip Coating Flow, Omar Bin Yusuf

Electronic Thesis and Dissertation Repository

A thin layer of film is developed on the surface of a substrate in the dip coating process where the substrate is initially immersed into the coating fluid and then withdrawn continuously from the coating fluid bath. In this study a two dimensional flow of the thin film for a Newtonian fluid is examined theoretically by dividing the film into three separate regions. A general formulation is developed for a thin film flow, which then simplifies for each region upon considering appropriate assumptions to each region. The influence of inertia and surface tension in the presence of gravity is investigated …

Numerical Simulation Of Catalytic Ozone Decomposition Reaction In A Gas-Solids Circulating Fluidized Bed Riser, Lei Kong

Electronic Thesis and Dissertation Repository

Computational fluid dynamics (CFD) modeling of catalytic ozone decomposition reaction in a circulating fluidized bed (CFB) riser using iron impregnated FCC particles as catalyst is carried out. The catalytic reaction is defined as a one-step reaction with an empirical coefficient. Eularian-Eularian method with kinetic theory of granular flow is used to solve the gas-solids two-phase flow in the CFB riser. The simulation results are compared with experimental data, with the reaction rate modified using an empirical coefficient to provide better simulation results than the original reaction rate. Moreover, the particle size has great effects on the reaction rate. Studies on …

Sustainability Analysis Of Personal Transportation For Near Urban Commuting, Theodore Ansink, Matthew Atchley, Virginia Browning, Yue Cao, Michelle Everett, James Hall Jr, William R. Henson, Eugene Ng, Michael Picklesimer, Justin Ridenour, Scott Teeters, James Wilson

Chancellor’s Honors Program Projects

No abstract provided.

Oxidation Of Borides And Carbides With Y2o3 And Ta Additions, Salvador Manuel Rodriguez

Open Access Theses & Dissertations

The study presented here describes an investigation of an oxidation scale of a fully-sintered Y2O3-ZrB2-TiC composite exposed in air at 1173K. Upon oxidation of the boride/carbide, a ZrO2-TiO2 was expected to form similar to the ZrO2-SiO2 dual scale of an oxidized ZrB2-SiC. The 47wt% Y2O3-38wt%ZrB2-16wt%TiC composite formed a dual scale consisting primarily of an Y2O3-ZrO2-TiC inner scale with an outer scale of ZrO2-TiO2-Y2O3.

The samples oxidized with a parabolic layer growth allowing the calculation of the effective diffusion coefficient indicating that the oxidation was controlled by oxygen ingress through primarily the ZrO2-Y2O3 phase. The oxygen potential between the inner layer …