Digital Commons Network^™

A Monte Carlo Analysis Of Seven Dichotomous Variable Confidence Interval Equations, Morgan Juanita Dubose

Masters Theses & Specialist Projects

Department of Psychological Sciences Western Kentucky University There are two options to estimate a range of likely values for the population mean of a continuous variable: one for when the population standard deviation is known and another for when the population standard deviation is unknown. There are seven proposed equations to calculate the confidence interval for the population mean of a dichotomous variable: normal approximation interval, Wilson interval, Jeffreys interval, Clopper-Pearson, Agresti-Coull, arcsine transformation, and logit transformation. In this study, I compared the percent effectiveness of each equation using a Monte Carlo analysis and the interval range over a range …

Reinforcement Learning With Deep Q-Networks, Caleb Cassady

Masters Theses & Specialist Projects

In the past decade, machine learning strategies centered on the use of Deep Neural Networks (DNNs) have caught the interest of researchers due to their success in complicated classification and prediction problems. More recently, these DNNs have been applied to reinforcement learning tasks with state of- the-art results using Deep Q-Networks (DQNs) based on the Q-Learning algorithm. However, the DQN training process is different from standard DNNs and poses significant challenges for certain reinforcement learning environments. This paper examines some of these challenges, compares proposed solutions, and offers novel solutions based on previous research. Experiment implementation available at https://github.com/caleb98/dqlearning.

K-Means Clustering Using Gravity Distance, Ajinkya Vishwas Indulkar

Masters Theses & Specialist Projects

Clustering is an important topic in data modeling. K-means Clustering is a well-known partitional clustering algorithm, where a dataset is separated into groups sharing similar properties. Clustering an unbalanced dataset is a challenging problem in data modeling, where some group has a much larger number of data points than others. When a K-means clustering algorithm with Euclidean distance is applied to such data, the algorithm fails to form good clusters. The standard K-means tends to split data into smaller clusters during a clustering process evenly.

We propose a new K-means clustering algorithm to overcome the disadvantage by introducing a different …

Synthetic, Photophysical, And Catalytic Studies Of Light-Harvesting Macrocyclic Complexes, Fox Bratcher

Masters Theses & Specialist Projects

Chromophores are an important class of compounds in Nature and industry, with several hundred thousand tons produced annually as dyes and pigments. Alone, these compounds absorb light unto themselves; however, several of these compounds can be combined to produce a beneficial cascading transfer of energy to a core chromophore.

In this study, photophysical properties of several covalent and axially borondipyrromethene (BODIPY)-conjugated complexes of porphyrin and salphen scaffolds have been evaluated in a series of emission and catalytic studies. In the porphyrin systems, a beneficial excited energy transfer (EET) from the BODIPY moieties to the porphyrin core was observed; however, only …

Developing And Applying An Integrated Spatial Karst Evaluation And Management Priority Tool: Case Study In Tongass National Forest, Alaska, Usa, Christian Decelle

Masters Theses & Specialist Projects

Karst terrains are complex landscapes that are sensitive to human disturbance. Human activities have polluted and impacted many of these terrains around the world. To preserve these unique landscapes, many karst regions are protected and designated as national parks, geologic special areas, or UNESCO Biosphere Reserves. Despite the widespread general protection of karst landscapes globally, a review of each area’s management plan reveals there is no standardized method of cave and karst management or evaluation of karst impacts.

The non-standardization of karst management strategies may be due to the gap that exists between the needs of karst land managers and …

Investigating Epikarst Recharge Dynamics Under Agricultural Landuse Using Hydrometeorological And Isotopic Tracers, Austin Shane Deering

Masters Theses & Specialist Projects

Epikarst systems have complex recharge – discharge processes in telogenetic karst systems, including highly variable storage, flowpaths, and mixing dynamics. This research aimed to characterize the epikarst zone using hydrogen and oxygen isotopic tracers of these processes within south-central Kentucky’s Crumps Cave system located in the Pennyroyal Sinkhole Plain. Data and statistical analyses were applied to highresolution rainfall (RF), lysimeter (10 cm, 20 cm, 30 cm depths), and an epikarst Waterfall 1 (WF1) isotope data collected on a weekly basis between 2011-2018. These data were coupled with WF1 discharge measurements and weather station data collected at Crumps Cave Preserve during …

Manufacturing: The Qualitative Study Of A Transition To A Green Facility, Brandon David Staves

Masters Theses & Specialist Projects

This qualitative study focused on answering three core questions: How have facilities reduce pollutions in regards to the quality of air, water, land, light and noise? Which Types of pollution reduction projects are more or less successful to implement? What types of pollution are facilities focusing on and why? The results of the 15 companies surveyed show a variety of projects that facilities have used to reduce pollution, it also shows that cost is a major factor in the unsuccessful projects, and that facilities are actively focused on reducing Air, Land, and Water pollution. While the data shows a variety …

An Adaptive Hazard Planning And Mitigation Framework For Responding To Urban Contamination In Karst Aquifer Systems, James Edward Troxell

Masters Theses & Specialist Projects

Environmental hazards in karst regions are damaging and often go unnoticed until an issue has escalated to a point of affecting life or property. The field of emergency and environmental contamination response lacks planning or preparedness focused on remediating groundwater contamination in karst systems. A lack of preplanning before an incident can lead to confusion, delayed response, and the inability to remediate the contaminant. Due to the rapid movement of contaminants through urban karst groundwater aquifers, an efficient response plan that leverages localized data in a GIS should be developed and maintained in order to adequately respond. The objective of …

Knot Theory In Virtual Reality, Donald Lee Price

Masters Theses & Specialist Projects

Throughout the study of Knot Theory, there have been several programmatic solutions to common problems or questions. These solutions have included software to draw knots, software to identify knots, or online databases to look up pre-computed data about knots. We introduce a novel prototype of software used to study knots and links by using Virtual Reality. This software can allow researchers to draw links in 3D, run physics simulations on them, and identify them. This technique has not yet been rigorously explored and we believe it will be of great interest to Knot Theory researchers. The computer code is written …

Functionalized Ionic Liquids For Improved Co2 Hydrogenation Catalysts, Amol Nanduji Jaybhaye

Masters Theses & Specialist Projects

Climate change is one of the biggest problems we are facing today, and anthropogenic greenhouse gases contribute significantly to it. Among greenhouse gasses, carbon dioxide emission is increased drastically and affecting majorly for increasing global temperature, and anything we can do to mitigate carbon dioxide emission will be helpful. A carbon dioxide hydrogenation reaction is a promising technique that can convert carbon dioxide into value-added chemicals, but the reaction rate is slow, and for that, we can use catalysts that will accelerate the reaction rate. Platinum-based nanoparticles have sparked research related to energy and environmental catalysts. Catalytic properties are depending …

Design Of Antioxidant Monomer, Augustine Osilamah Yusuf

Masters Theses & Specialist Projects

Reactive oxygen species such as hydrogen peroxide are present at the sites of inflammation in the body. Degradable polymeric nanoparticles have shown great promise in a range of biomedical applications which include preferential delivery of therapeutics to such inflamed sites. We are working towards a new class of materials expected to have tunable degradation rates in the presence of hydrogen peroxide. These new materials consist of three parts: degradable linkages, antioxidant groups, and unreactive filler monomers such as methylmethacrylate. We have synthesized a polymerization initiator with a degradable linkage, and we have shown that using this initiator to synthesize another …

Statistical Study Of The Effect Of Implementing An Airveyor System On The Warpage Of Injection Molded Closures, Charles Wesley Bozarth

Masters Theses & Specialist Projects

Berry Global in Bowling Green, Kentucky produces predominantly polypropylene container closures. One variant, the 83mm lined jar closure, is produced by first being injection molded, placed in work-in-progress (WIP) hold for 24 hours to cool, and then finished through the auxiliary liner operation into a final product. While this process is an effective method to produce a quality large-diameter closure and allows the polypropylene adequate time to cool without warping out of shape, the 24-hour WIP time and the manpower needed to accomplish this can negatively impact several business metrics as well as employee safety.

The purpose of this thesis …

Analysis Of Boundary Observability Of Strongly Coupled One-Dimensional Wave Equations With Mixed Boundary Conditions, Wilson Dennis Horner

Masters Theses & Specialist Projects

*see note below

In control theory, the time it takes to receive a signal after it is sent is referred to as the observation time. For certain types of materials, the observation time to receive a wave signal differs depending on a variety of factors, such as material density, flexibility, speed of the wave propagation, etc. Suppose we have a strongly coupled system of two wave equations describing the longitudinal vibrations on a piezoelectric beam of length L. These two wave equations have non-identical wave propagation speeds c1 and c2. First, we prove the exact observability inequality with the optimal …

Revisiting Hudson County Water Co. V. Mccarter: Realism, The Public Trust Doctrine, And Environmental Conservation In The Lochner Era, Steven Huffman

Masters Theses & Specialist Projects

Legal histories of the Gilded Age and Progressive Era tend to focus inordinately on economic regulation within a doctrinal framework in which private rights, equal protection, and “substantive” due process guided judicial decision-making. Consequently, the overarching economic context in prevailing legal historiography obscures an important yet oft-overlooked development in the linkage between public rights, natural resource trusteeship, and the early-twentieth-century environmental conservation movement. This development is inextricably tied to the evolution of water law in the late nineteenth century and the expansion of the American commercial republic. A normative understanding of public water rights during this period is confined to …

The Effect Of Environmental Context Upon Visual Distance Perception, Jessica M. Dukes

Masters Theses & Specialist Projects

The ability of 16 younger adults to visually perceive distances in depth was evaluated within three environmental contexts (indoors in the dark, indoors in the light, and outdoors). The observers' task was to bisect an 8m distance interval in all contexts using both monocular and binocular vision. In the outdoor environment (a natural grassy field), the observers' judgments indicated perceptual compression of farther distances similar to that obtained in many previous studies. In the indoor lighted environment (a 10.2 x 9.6m laboratory room), the observers' judgments were consistent with perceptual expansion of farther distances. Finally, there was a beneficial effect …

Reimagining The Duck Stamp, Hunting Licensure And Public Land Preservation, Alec Wayne Boyd-Devine

Masters Theses & Specialist Projects

The American Migratory Bird Hunting and Conservation Stamp, or Duck Stamp, is a form of licensure issued by the Federal Government for waterfowl hunters. Why do physical stamps act as licensure to hunt waterfowl on both public and private land in the United States? How did the stamp become the key that grants access to resources that supposedly should be owned by the public? The duck stamp has been well-documented in conservation communities as a resource which has made significant positive impacts on the environment. The increase of anti-hunting sentiments in our society combined with fewer hunters per capita may …

Visible Light Generation And Mechanistic Investigation Of High-Valent Metal-Oxo Species Supported By Different Ligands, Seth Ellis Klaine

Masters Theses & Specialist Projects

Numerous transition metal catalysts have been designed as biomimetic model compounds for the active site of metalloenzymes found throughout Nature, most notably cytochrome P450 monooxygenases that carry out the oxidative transformations of organic substrates with near-perfect chemo-, regio-, and stereo-selectivity. The primary active oxidants in catalytic and enzymatic cycles are fleeting high-valent metal-oxo intermediates where the oxo ligand can transfer to an organic substrate in a process known as oxygen atom transfer (OAT).

In the present work, porphyrin-manganese(III), salen-chromium(III), and salenmanganese( III) derivatives were successfully synthesized and spectroscopically characterized using 1H NMR and UV-Vis spectroscopies. A facile photochemical approach was …

Buffer Overflow And Sql Injection In C++, Noah Warren Kapley

Masters Theses & Specialist Projects

Buffer overflows and SQL Injection have plagued programmers for many years. A successful buffer overflow, innocuous or not, damages a computer’s permanent memory. Safer buffer overflow programs are presented in this thesis for the C programs characterizing string concatenation, string copy, and format get string, a C program which takes input and output from a keyboard, in most cases. Safer string concatenation and string copy programs presented in this thesis require the programmer to specify the amount of storage space necessary for the program’s execution. This safety mechanism is designed to help programmers avoid over specifying the amount of storage …

Synthesis And Catalytic Oxidation Of Organic Substrates By Light-Harvesting Metalloporphyrins, Christian Alcantar

Masters Theses & Specialist Projects

note: Some notation in this abstract may not appear exactly as formatted in the thesis.

In this work, ruthenium, iron, and manganese light-harvesting metalloporphyrins have been successfully synthesized to serve as biomimetic models of the active site of Cytochrome P450 for the development of a green and efficient oxidation catalyst. The covalent introduction of light-harvesting boron-dipyrrin (BODIPY) fluorophores on the porphyrin macrocycle allows for the absorption of a broader range of visible light in addition to that captured by the porphyrin aromatic system alone. It is expected that this core-antenna system will increase the absorbed light energy and transfer it …

Some Generalizations Of Classical Integer Sequences Arising In Combinatorial Representation Theory, Sasha Verona Malone

Masters Theses & Specialist Projects

There exists a natural correspondence between the bases for a given finite-dimensional representation of a complex semisimple Lie algebra and a certain collection of finite edge-colored ranked posets, laid out by Donnelly, et al. in, for instance, [Don03]. In this correspondence, the Serre relations on the Chevalley generators of the given Lie algebra are realized as conditions on coefficients assigned to poset edges. These conditions are the so-called diamond, crossing, and structure relations (hereinafter DCS relations.) New representation constructions of Lie algebras may thus be obtained by utilizing edge-colored ranked posets. Of particular combinatorial interest are those representations whose corresponding …

Application Of Excitation-Emission Matrices To Fluorescent Dye Tracing Of Groundwater Flow, Cayla M. Baughn

Masters Theses & Specialist Projects

Fluorescent dye tracing of groundwater is a technique employed particularly in carbonate rock karst regions to examine karst hydrology by mapping underground flow paths. It is important to understand the hydrology of karst environments because solutionally-enlarged conduits may allow the rapid influx of contaminants into the groundwater system. Fluorescent dye tracing involves the injection of a fluorescent dye into an appropriate injection site (sinking streams, sinkholes, or even through soil flushed with water) and is followed by sampling at sites where the dye may be recovered (typically springs). Various methods exist by which sampling may occur, but all methods ultimately …

Developing Novel Tale-Based Rapid Detection Of Pathogenic Dna Utilizing 2d Graphene Oxide Nanosheets And Quantum Dots, Narayan Neupane

Masters Theses & Specialist Projects

A faster method of quantitative detection of specific dsDNA of pathogenic bacteria such as the Shiga toxin 2 gene (stx2) present in E. coli O157:H7 is of great importance. There is a need for a simple and facile method for sensitive detection of pathogenic gene which is crucial for the prevention and earlier treatment of any infectious diseases. A Transcriptional Activator-Like Effector (TALE) is a novel class of DNA-binding proteins with the unique modularity, flexibility and easy programmability compared to previously discovered DNA- binding proteins. TALEs can bind to any DNA sequences through its unique variable di- residues …

A Monte Carlo Analysis Of Ordinary Least Squares Versus Equal Weights, James Brewer Ayres

Masters Theses & Specialist Projects

Equal weights are an alternative weighting procedure to the optimal weights offered by ordinary least squares regression analysis. Also called units weights, equal weights are formed by standardizing scores on the predictor variables and averaging these standardized scores to create a composite score. Research is limited regarding the conditions under which equal weights result in cross-validated 𝑅𝑅2 values that meet or exceed optimal weights. In this study, I explored the effect of various predictor-criterion correlations, predictor intercorrelations, and sample sizes to determine the relative performance of equal and optimal weighting schemes upon cross-validation. Results indicated that optimally weighted predictors explained …

Video Game Genre Classification Based On Deep Learning, Yuhang Jiang

Masters Theses & Specialist Projects

Video games have played a more and more important role in our life. While the genre classification is a deeply explored research subject by leveraging the strength of deep learning, the automatic video game genre classification has drawn little attention in academia. In this study, we compiled a large dataset of 50,000 video games, consisting of the video game covers, game descriptions and the genre information. We explored three approaches for genre classification using deep learning techniques. First, we developed five image-based models utilizing pre-trained computer vision models such as MobileNet, ResNet50 and Inception, based on the game covers. Second, …

Impacts Of Forest Management And Timber Harvest Practices On Karst Critical Zone Processes In Tongass National Forest, Alaska, Anna Gwendolyn Harris

Masters Theses & Specialist Projects

This study characterizes the throughfall, hydrogeochemistry, dissolution rates, and carbon sources of two proximate temperate rainforest cave systems within the Tongass National Forest in Southeast Alaska (Tongass). Study sites include: an old-growth forest, characterized by having never been logged (containing Walkabout Cave system); and a previously logged – within thirty years, second-growth forest (containing Zina Cave system). Precipitation data were recorded over a five-month period at 10-minute intervals, to understand the effects of throughfall between the altering old and second-growth canopies. At each major spring for the two cave systems, high-resolution data were collected from June 29 through November 21, …

The Language Of Breathing, Brian Wallace Baker

Masters Theses & Specialist Projects

The Language of Breathing is an eclectic collection of 18 creative nonfiction essays that capture moments from the author’s life and attempt to give them meaning through narrative and metaphor. They deal with relationships, nature, faith, and often rely on background research to pair art, mythology, current events, and science with personal experience.

Improved Antimicrobial Properties Of Silver Nanoparticles With Methylene Blue, Ermek Belekov

Masters Theses & Specialist Projects

Photosensitizing agents are the cornerstone of photodynamic therapy (PDT) that play essential role in deactivation process of multidrug resistant pathogens and tumor treatments. In this work we studied a photosensitizing agent made from mixture of silver nanoparticles (Ag NPs) and methylene blue (MB) which possess improved important characteristics like high photostability and high singlet oxygen yield. Ag NPs were synthesized by pulsed laser ablation technique in different aqueous solutions like Polyvinylpyrrolidone (PVP), citrate and Deionized (DI) water. The synthesized Ag NPs were characterized in depth using with transmission electron microscopy (TEM), UVVisible (UV-Vis), and photoluminescence (PL) spectra. Ag NPs were …

Hydrogeochemical Characterization And Speleogenesis Of Sistema Huautla In Oaxaca, Mexico, Fernando Hernandez

Masters Theses & Specialist Projects

Sierra Mazateca, Mexico is home to Sistema Huautla, the deepest cave in the Western hemisphere with 1,560 meters of depth and 90 kilometers of passage, including 26 entrances distributed in a high-relief, karstified terrain, within the Sistema Huautla Karst Groundwater Basin. Exploration of the cave has generated research questions about its evolution and geomorphology given the different vadose and phreatic zones impacted by tectonic and incision processes. Dye traces during this study of Cueva de La Peña Colorada confirmed it is a fossil resurgence of the cave system. An additional cave, Cueva Elysium, was connected hydrologically in 2019, expanding the …

Solvent-Free Synthesis Of Metal Coordination Compounds Using Ball Mills, Jenna Cantway

Masters Theses & Specialist Projects

Mechanochemistry utilizes mechanical energy to promote chemical reactions to completion. Samples ground with a ball mill are placed under consistent pressure and temperature, which allows for increased surface area, shorter reaction times and overall better control of reaction conditions compared to the use of a mortar and pestle. Many synthetic techniques to prepare metal coordination compounds use a solvent. The solvent promotes the reactions by providing a route for reagents to interact. While solvents facilitate reactions, there is interest in reducing or eliminating solvents altogether during the synthesis process due to potential instability of a solvent under certain experimental conditions …

Synthesis Of Cds/Zns Core/Shell Semiconductor Nanoparticles, Austin Skyler Antle

Masters Theses & Specialist Projects

Core/shell semiconductor nanoparticles are of great interest as photocatalysts due to their large surface area per volume and tunable band gaps. The synthesis of core/shell semiconductor nanoparticles has traditionally involved the use of binding ligands to ensure the particles do not aggregate. These binding ligands lower the surface area of the nanoparticles though, reducing their overall efficiency. Ionic liquids have been found to be capable of acting as both solvents and stabilizing agents for synthesis of catalysts with highly active surfaces. Our experiments focus on the synthesis of CdS/ZnS core/shell nanoparticles with the ionic liquid 1-butyl-3-methylimidazolium methyl sulfate, [BMIM][MeSO4], acting …