Digital Commons Network^™

Chemistry Of Zirconia And Its Bioanalytical Applications, Oge Anazia

Masters Theses & Specialist Projects

This research studies the chemical nature of zirconia and the complex surface chemistry of zirconia in order to better comprehend its behavior under chromatographic conditions. This research shows how the physical and chemical properties of zirconia depend strongly on the thermal treatment during synthesis. The morphology of the samples was also studied. The absorption capability of Adenosine Triphosphate (ATP) on zirconia was also monitored and spectrally characterized.

The results of this research showed how the properties of zirconia vary with thermal treatment. It was observed that the zirconia prepared at a higher temperature had lower surface area, lower pore size …

A Characterization Of Caffeine Imprinted Polypyrrole Electrode, Deepika Mandadi

Masters Theses & Specialist Projects

Nanotechnology holds great potential for improving our lives by creating many new materials and devices in medical sciences, electronics and also in energy production. Molecularly imprinted polymers (MIPs) are highly stable synthetic polymers that possess molecular recognition properties due to cavities created in the polymer matrix that are complementary to an analyte both in shape and in positioning of functional groups. These MIPs have been widely employed for diverse applications (e.g., in chromatographic separation, drug screening, chemosensors, catalysis, immunoassays etc) due to their specificity towards the target molecules and high stability against physicochemical perturbations. Conductive polymers, (CPs) such as polypyrrole, …

Random Walks With Elastic And Reflective Lower Boundaries, Lucas Clay Devore

Masters Theses & Specialist Projects

No abstract provided.

Heirloom And Hybrid Tomato Yield And Quality In Organic And Conventional Production Systems, Diana J. Edlin

Masters Theses & Specialist Projects

Due to the recent changes in the economy of Kentucky tobacco production, some producers are seeking an alternative crop that will provide similar economic gains to tobacco without needing more acreage. Tomatoes are an existing crop in Kentucky that have been declining in acreage over the last five years. There is evidence to suggest that, through niche and local marketing, tomatoes may be able to fill the void left by tobacco. However, there is concern among producers that they will lose yield and/or quality if they switch to one of these niche production systems or cultivars.

A two year study …

Using Conservative And Biological Tracers To Better Understand The Transport Of Agricultural Contaminants From Soil Water Through The Epikarstic Zone, Brian Ham

Masters Theses & Specialist Projects

Agriculture contamination is very common in karst systems due to the vulnerability of these aquifers. Animal waste is often spread across crop land to enrich the soil with nitrates and phosphates. Herbicides and pesticides are also applied to the crops. The transport of these pollutants through the soil and epikarst is a difficult process to monitor due to the complex, heterogeneous behavior of the groundwater as it makes its way down to the aquifer below.

An experimental site at Crumps Cave lended a unique opportunity to monitor the vadose zone at a waterfall in the cave below. A previous dye …

Kinetic Studies Of The Sulfoxidation Of Aryl Methyl Sulfides By Trans-Dioxoruthenium(Vi) Porphyrin Complexes, Chris Abebrese

Masters Theses & Specialist Projects

The development of an efficient, catalytically active, biomimetic model for cytochrome P-450 enzymes has been an area of intense research activity. Ruthenium porphyrin complexes have been the center of this research and have successfully been utilized, as catalysts, in major oxidation reactions such as the hydroxylation of alkanes, the epoxidation of alkenes and aromatic rings, and the N-oxidation of amines, among others. In this project, the kinetics of two-electron sulfoxidation of para-substituted phenyl methyl sulfides to the corresponding sulfoxides with well-characterized trans-dioxoruthenium(VI) porphyrin complexes were studied by rapid stopped-flow spectroscopy. The substituent effect in sulfides and in dioxoruthenium(VI) complexes were …

"All The Crises Reached A Concerted Crescendo" - The Arab Oil Embargo And Why The United States Was Unprepared For It, Jonathan D. Chilcote

Masters Theses & Specialist Projects

During the 2008 spike in oil prices, oil companies and government officials were brought under close scrutiny as many Americans began to question why prices were able to rise so quickly. Americans had become accustomed to living in an economy where cheap oil was the norm, and demanded answers when that situation changed. What most of them did not know is that they were repeating history and mimicking the response to the 1973 oil embargo. Just as in 2008, the United States faced a crisis in 1973 with which it was unprepared to effectively cope. This thesis analyzes the reasons …

Analysis Of Mammoth Cave Pre-Park Communities, Matthew Brunt

Masters Theses & Specialist Projects

Before the creation of Mammoth Cave National Park, this area was home to numerous communities, each with a sense of identity. To prepare for the creation of the National Park, all residents living within these communities were relocated, and many of these communities were lost to the passage of time. Today, public memory of these lost communities is being fostered by the descendents of the pre-park area.

Through the use of a Historical Geographic Information System, 1920 Edmonson County manuscript census data, and statistical analysis, the demographic composition of these lost communities was explored. This project not only brought to …

Off-Metal Synthesis Of Some Aryl Substituted Rhenium N5-Cyclopenta [C] Pyridazyl Complexes, James Leif Neathery

Masters Theses & Specialist Projects

Heterocyclic organic and organometallic compounds (e.g. polypyrrole), and their derivatives, have been of great interest for conductive polymers due to their novel properties and environmental stability as compared to non-aromatic analogs (e.g. polyacetylene). Our current interests focus upon the potential role of pyridazines in next generation electronic devices that utilize organics as the semiconducting material. Pyridazines, 6-membered aromatic rings with two adjacent nitrogens, are promising candidates for a variety of materials and commercial applications. These molecular electronic materials posses several advantages over traditional inorganic semiconducting materials including lower cost of production, higher processibility, and the ability to function on flexible …

Green Employees: Organizational Identification In An Environmentally Friendly Company, Jenna Haugen

Masters Theses & Specialist Projects

Environmental sustainability is an issue facing our global society and one that must be addressed through communication in order to encourage change amongst individuals. The current research focuses on the organization, in this instance a “Green” printing company, and its role in building identification amongst employees. This study focuses on environmental sustainable practices initiated or continued by employees through the use of a directed mission statement and organizational rhetoric. Utilizing individual interviews, the findings suggest that by building organizational identification, more environmentally-friendly practices amongst organizational members may be achieved.

Increased Control Over Gold Colloid Adsorption On Substrates For Colloid Displacement Lithography, Vara Prasad Reddy Sakampally

Masters Theses & Specialist Projects

Colloid displacement lithography is proving to be very effective in the designing of nanometer scale electronic devices. Precise control of the structure of matter at the nanometer scale has brought a revolutionary change in science and technology. The use of these nanometer scale devices ranges from the diagnosis of various diseases to cell repair to ultra strong materials. This research focused on optimizing the conditions for gold colloid particle adsorption for colloid displacement lithography, an expansion on gold colloid particle manipulation techniques using a scanned probe microscope. The system consists of a scrupulously cleaned glass surface that is coated with …

Near-Surface Atmospheric Response To Simulated Changes In Land-Cover Vegetation Fraction, And Soil Moisture Over Western Kentucky, Ronnie Leeper

Masters Theses & Specialist Projects

A series of land-use-land-cover-change (LULCC) based sensitivity experiments, including changes in vegetation type, fractional vegetation (FV), and soil moisture (SM), over Western Kentucky were conducted to investigate atmospheric response to land-use. The choice of land-use for this study was chosen in the context of Western Kentucky’s historical LULCC. For this study, vegetation types considered were grassland, forest, and bare soil with further variations in FV for grassland and forest at 25, 50, 75, and 100 % and systematic increases and decreases in volumetric SM of 0.05, 0.10, and 0.15 m3 m-3. To the author’s knowledge, this is the first assessment …

Synthesis And Characterization Of Some Rhenium Complexes, Joseph Brian Scott

Masters Theses & Specialist Projects

Plastics or polymers are thought to behave oppositely from metals. Ideally, polymers behave as insulators while metals conduct electricity. Shirakawa and coworkers discovered conductive polymers in 1977.1 These conductor polymers have been extensively studied, discovering that charge transfer oxidative doping of polyacteylene could increase its conductivity by 12 orders of magnitude. Polyacetylene, although showing promise as an organic conductor, because it is highly air-sensitive and oxidizes when exposed to molecular oxygen, therefore making this an unattractive use for commercial products. Attention has been focused on heterocylic aromatic polymers such as polythiophene and polypyrrole, in efforts to produce conductive polymers that …

A Survey Of Drought Impacts And Mitigation Planning In Kentucky, Crystal Jane Bergman

Masters Theses & Specialist Projects

Drought is a well-known and costly climate-related natural hazard. Unlike other climate-related natural hazards, droughts are usually long in duration and may cover a large region, the physical boundaries of areas affected by drought are sometimes arbitrary, and the impacts are sometimes difficult to identify. Climate records since 1895 show that drought has occurred periodically in Kentucky. The drought of 2007 was the most recent drought to affect Kentucky and is the primary focus of this research. The purpose of this research is to identify impacts of drought and potential vulnerabilities to various drought impact sectors in Kentucky so that …

The Study Of Variations In The Properties Of Biodiesel On Addition Of Antioxidants, Hiranmayee Kandala

Masters Theses & Specialist Projects

This research studies variations in biodiesel upon addition of different concentrations of antioxidant and petrodiesel additives. Oxidation onset temperature, oxidation induction time, oxidative stability, thermal stability, crystallization onset temperature and moisture retention properties of the biodiesel, with and without antioxidants have been studied. Antioxidants like BHT, BHA, PrG, Vit E and Vit C were added to the biodiesel during the study. These samples were analyzed using the PDSC, TGA, DSC and TGA-SA instrumentation.

The results of this research show an improvement in the OOT, OIT and Oxidative stability of biodiesel with the addition of antioxidants and by blending the biodiesel …

Geometric Build-Up Solutions For Protein Determination Via Distance Geometry, Robert Tucker Davis

Masters Theses & Specialist Projects

Proteins carry out an almost innumerable amount of biological processes that are absolutely necessary to life and as a result proteins and their structures are very often the objects of study in research. As such, this thesis will begin with a description of protein function and structure, followed by brief discussions of the two major experimental structure determination methods. Another problem that often arises in molecular modeling is referred to as the Molecular Distance Geometry Problem (MDGP). This problem seeks to find coordinates for the atoms of a protein or molecule when given only a set of pair-wise distances between …

Synthesis And Characterization Of Bis-Phosphine Complexes With Transition Metals, Alicia L. Mcdaniel

Masters Theses & Specialist Projects

Extractants and extraction methodologies play a vital role in many industrial processes, from the concentration of precious metals from ores to the separation of longlived nuclei from radioactive waste as well as the removal of heavy metals from soils and water for remediation. The vast majority of extractants rely on the use of nitrogen, oxygen, sulfur or selenium as Lewis base donor atoms to form coordination complexes with the metal ions of interest. These extractants often make use of the chelate effect and/or the macrocyclic effect in order to form stable complexes. Some of the best known types of chelate …

Assessing Organic Matter Breakdown And Associated Macroinvertebrate Community Structure In Headwater Streams: Effects Of Hydrologic Gradients And Upland Timber Harvesting, Miller Scott Jarrell

Masters Theses & Specialist Projects

I examined the effects of hydrologic gradients and upland timber harvesting with different streamside management zone widths on yellow-poplar (Liriodendron tulipifera) processing and the associated macroinvertebrate community structure in the Cumberland Plateau ecophysic region, U.S.A. Prior to upland timber harvesting, 5.0 ± 0.1 g yellow-poplar leaf packs were constructed, zip-tied to gutter nails, and placed into 7 perennial and 6 temporary stream reaches with similar physiochemical and geomorphic characteristics. From December 2007 to May 2008, 3–5 leaf packs were collected per reach monthly. I found significant differences in the functional feeding group composition. Temporary reaches contained higher shredder, gathering-collector, predator, …

Modeling Stormwater Pollutant Transport In A Karst Region--Bowling Green, Kentucky, Allison H. Ross

Masters Theses & Specialist Projects

The management of stormwater runoff is a particular challenge for communities in karst regions. Most guidelines for compliance with regulations for stormwater monitoring and mapping pertain to non-karst environments. It can be argued that effective stormwater management is even more essential to karst regions because stormwater receives little or no natural filtration as it is transferred through conduits in the subsurface and the buildup of pollutants underneath can be detrimental to community and environmental health if not effectively mitigated. Because of the limited resources available to determine how stormwater runoff carries potential pollutants across the surface before being transferred to …

Arsenic And Selenium Distribution In Coal-Fired Plant Samples, Pauline Rose Hack Norris

Masters Theses & Specialist Projects

Arsenic and selenium distributions in coal-fired plant samples are studied. This research includes arsenic and selenium concentrations in samples of coal, fly ash, bottom ash, economizer ash, Flue Gas Desulfurization (FGD) slurry and flue gas taken from four power plants with the goal being to examine the distribution of these metals in these materials and calculate a materials balance for the system. All samples were analyzed using ICP-ES.

This research shows that 60-80% of the arsenic in coal-fired plant samples will be associated with the fly ash. Approximately 35-55% of the selenium will be associated with the fly ash and …

Qualitative Behavior Of Solutions To Differential Equations In RN And In Hilbert Space, Qian Dong

Masters Theses & Specialist Projects

The qualitative behavior of solutions of differential equations mainly addresses the various questions arising in the study of the long run behavior of solutions. The contents of this thesis are related to three of the major problems of the qualitative theory, namely the stability, the boundedness and the periodicity of the solution. Learning the qualitative behavior of such solutions is crucial part of the theory of differential equations. It is important to know if a solution is bounded or unbounded or if a solution is stable. Moreover, the periodicity of a solution is also of great significance for practical purposes.

A Framework For Consistency Based Feature Selection, Pengpeng Lin

Masters Theses & Specialist Projects

Feature selection is an effective technique in reducing the dimensionality of features in many applications where datasets involve hundreds or thousands of features. The objective of feature selection is to find an optimal subset of relevant features such that the feature size is reduced and understandability of a learning process is improved without significantly decreasing the overall accuracy and applicability. This thesis focuses on the consistency measure where a feature subset is consistent if there exists a set of instances of length more than two with the same feature values and the same class labels. This thesis introduces a new …

Real Time Driver Safety System, Gyuchoon Cho

Masters Theses & Specialist Projects

The technology for driver safety has been developed in many fields such as airbag system, Anti-lock Braking System or ABS, ultrasonic warning system, and others. Recently, some of the automobile companies have introduced a new feature of driver safety systems. This new system is to make the car slower if it finds a driver’s drowsy eyes. For instance, Toyota Motor Corporation announced that it has given its pre-crash safety system the ability to determine whether a driver’s eyes are properly open with an eye monitor. This paper is focusing on finding a driver’s drowsy eyes by using face detection technology. …

Generalized Probabilistic Bowling Distributions, Jennifer Lynn Hohn

Masters Theses & Specialist Projects

Have you ever wondered if you are better than the average bowler? If so, there are a variety of ways to compute the average score of a bowling game, including methods that account for a bowler’s skill level. In this thesis, we discuss several different ways to generate bowling scores randomly. For each distribution, we give results for the expected value and standard deviation of each frame's score, the expected value of the game’s final score, and the correlation coefficient between the score of the first and second roll of a single frame. Furthermore, we shall generalize the results in …

Vadose Zone Hydrology Near The Vicinity Of Edna's Dome, Mammoth Cave, Kentucky, Johnny Merideth

Masters Theses & Specialist Projects

This study examines the differences in key physical aqueous parameters at two different cave sites separated by only a few tens of meters. One site (FF) has a freefalling water component where water descends nearly 30 meters from the ceiling of a vertical shaft. The other location (WW) appears to have continuous water to rock contact as it descends to near the same level in the cave.

Water samples were collected at the two sites in two week intervals from May to August 2002. While both sites were proximal, they demonstrated very different behaviors, particularly during storm events. Differences in …

Multi-Walled Carbon Nanotubes-Modified Polymer Organic Photovoltaics, Tzu-Fan Chen

Masters Theses & Specialist Projects

Since the carbon nanotubes were first discovered by Iijima in 1991, CNTs have been the focus of intense research by many groups. Nearly 7000 papers and 700 theses on carbon nanotubes can be found from the eminent journals such as Nature and Science in the last decade. Since carbon nanotubes show impressive mechanical, physical and electronic properties such as high stiffness, high strength, low density, and excellent thermal conductivity, suggesting its role in light-weight high strength material application. A great quantity of important research has evidently been done in this field. The purpose of this thesis research is to investigate …

On The Breadth Of The Jones Polynomial For Certain Classes Of Knots And Links, Cody Lorton

Masters Theses & Specialist Projects

The problem of finding the crossing number of an arbitrary knot or link is a hard problem in general. Only for very special classes of knots and links can we solve this problem. Often we can only hope to find a lower bound on the crossing number Cr(K) of a knot or a link K by computing the Jones polynomial of K, V(K). The crossing number Cr(K) is bounded from below by the difference between the greatest degree and the smallest degree of the polynomial V(K). However the computation of the Jones polynomial of an arbitrary knot or link is …

Fractional Calculus: Definitions And Applications, Joseph M. Kimeu

Masters Theses & Specialist Projects

No abstract provided.