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Western Kentucky University

Masters Theses & Specialist Projects

Physical Sciences and Mathematics

Carbon dioxide

Publication Year

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Functionalized Ionic Liquids For Improved Co2 Hydrogenation Catalysts, Amol Nanduji Jaybhaye Jul 2021

Functionalized Ionic Liquids For Improved Co2 Hydrogenation Catalysts, Amol Nanduji Jaybhaye

Masters Theses & Specialist Projects

Climate change is one of the biggest problems we are facing today, and anthropogenic greenhouse gases contribute significantly to it. Among greenhouse gasses, carbon dioxide emission is increased drastically and affecting majorly for increasing global temperature, and anything we can do to mitigate carbon dioxide emission will be helpful. A carbon dioxide hydrogenation reaction is a promising technique that can convert carbon dioxide into value-added chemicals, but the reaction rate is slow, and for that, we can use catalysts that will accelerate the reaction rate. Platinum-based nanoparticles have sparked research related to energy and environmental catalysts. Catalytic properties are depending …


Indirect Greenhouse Gas Dynamics In Karst Groundwater Systems Under Agricultural Land Use, Stacy Wayne Antle Oct 2018

Indirect Greenhouse Gas Dynamics In Karst Groundwater Systems Under Agricultural Land Use, Stacy Wayne Antle

Masters Theses & Specialist Projects

Greenhouse gases (GHGs) are a major global environmental concern, because their concentrations have continuously increased over the past few centuries, due to global population growth, fossil fuel dependency, and the Industrial Revolution. Since these gases are naturally occurring phenomena, they will never be completely eliminated. Efforts to reduce them span numerous scientific attempts, with minimal improvements in reducing their atmospheric concentrations. In agricultural land practices, greenhouse gases are common byproducts that affect the atmosphere and, potentially, the groundwater where livestock and fertilizers are key contributors. Little is known about the fate of such greenhouse gases in dissolved form, known as …


Epikarst Hydrogeochemical Changes In Telogenetic Karst Systems In South-Central Kentucky, Leah Jackson Jul 2017

Epikarst Hydrogeochemical Changes In Telogenetic Karst Systems In South-Central Kentucky, Leah Jackson

Masters Theses & Specialist Projects

Telogenetic epikarst carbon sourcing and transport processes and the associated hydrogeochemical responses are often complex and dynamic. Among the processes involved in epikarst development is a highly variable storage and flow relationship that is often influenced by the type, rate, and amount of dissolution kinetics involved. Diffusion rates of CO2 in the epikarst zone may drive hydrogeochemical changes that influence carbonate dissolution processes and conduit formation. Most epikarst examinations of these defining factors ignore regional-scale investigations in favor of characterizing more localized processes. This study aims to address that discrepancy through a comparative analysis of two telogenetic epikarst systems under …


Carbon Cycling Dynamics Inferred From Carbon Isotope Sourcing In A Mid-Latitude Karst-Influenced River, Kegan N. Mcclanahan Aug 2014

Carbon Cycling Dynamics Inferred From Carbon Isotope Sourcing In A Mid-Latitude Karst-Influenced River, Kegan N. Mcclanahan

Masters Theses & Specialist Projects

As ever-increasing levels of carbon dioxide alter the chemistry of the Earth’s atmosphere, understanding the global carbon cycle becomes increasingly important. A particularly important component is the riverine carbon cycle, as rivers are the primary conduits for dissolved inorganic carbon from terrestrial watersheds to ocean basins. Stable carbon isotopes (13C/12C) were collected weekly and input into the mixing model IsoSource to delineate seasonal carbon sourcing along two nested basins in the upper Green River System, Kentucky. In the more siliciclastic upstream catchment, dissolved inorganic carbon (DIC) was primarily derived from soil respiration (34%). Groundwater dissolving carbonate bedrock and carbonate dissolution/precipitation …