Digital Commons Network^™

Interactive Wireless Sensor For Remote Trace Detection And Recognition Of Hazardous Gases, Audrey Lama

Masters Theses & Specialist Projects

The interactive wireless sensor detects many hazardous gases such as Hexane, Propane, Carbon monoxide and Hydrogen. These gases are highly toxic and used in different kinds of manufacturing industries, domestic purpose and so on. So, building a sensor that can detect this kind of gases can save the environment; prevent the potential for explosion, and endangering human life. In long term, interactive wireless sensor can also prevent the financial losses that might occur due to the hazardous incident that might occur due to these toxic gases.

Hexane is a colorless, strong gas which inhaled in significant amounts by a person …

Sources Of Co2 Controlling The Carbonate Chemistry Of The Logsdon River, Mammoth Cave, Kentucky, Bruce Elliott Hatcher

Masters Theses & Specialist Projects

Logsdon River is a major, base-level stream within the Turnhole Bend Drainage basin of the Mammoth Cave System. The Logsdon River system has provided a unique opportunity to examine the geochemical evolution of a stream flowing through a major karst conduit that can be traversed for 10 km. This study examines CO₂ inputs at the upstream portion of the river, which provide major control for the river’s hydrochemistry. Samples were collected from the upstream portion of Logsdon River at what is referred to as the S-188 sump and also nearby at Crowbar Dome over the course of 44 weeks …

Eastern Deciduous Forest Phenology And Vegetative Vigor Trends From 2000 To 2013, Mammoth Cave National Park, Ky, Sean Taylor Hutchison

Masters Theses & Specialist Projects

Global climate change is predicted to affect environmental systems at the midlatitudes, but the scope, severity, and outcomes of these impacts are yet to be fully understood. This study focuses on the implications of short-term climate variability for forests in central Kentucky. Using a Normalized Difference Vegetation Index (NDVI) calculated from MODerate-Resolution Imaging Spectroradiometer (MODIS) instrument data, the photosynthetic activity of vegetation at Mammoth Cave National Park (MACA) is tracked from 2000 to 2013. Three methods were employed to examine the changes and climate influences in vegetation over the study period: 1) aggregating the NDVI of the Park by year …

Molecular Level Interaction Of Human Fibroblast Growth Factor-1 (Hfgf-1) With Phloridzin, Rammohan Paripelly

Masters Theses & Specialist Projects

Fibroblast growth factors (FGFs) are a family of growth factors which includes twenty three proteins. FGFs work as modulators for various cellular activities like mitosis, differentiation and survival. Among the FGF family, human fibroblast growth factor-1 (hFGF-1), which is also known as acidic fibroblast growth factor, is a potent angiogenic agent, involved in the formation of new blood vessels in various tissues. hFGF-1 is regarded as a prototype of the FGF family. It serves as one of the potential targets in tumor inhibition and obesity due to its involvement in new blood vessel formation in cancerous regions and adipose tissues. …

Solar Energy Conversion And Control Using Organic Photovoltaic Cells, Kurt Wade Woods

Masters Theses & Specialist Projects

Organic photovoltaic (OPV) cells are advanced, newly emerging technologies that are lightweight, mechanically flexible devices with highthroughput processes from low cost material in a variety of colors. Rathnayake et al. of Western Kentucky University have developed a nanostructure-based OPV cell. Presented in this thesis is a model and simulation of a generalized PV powered system that can predict the performance of solar arrays in various environmental conditions. The simulation has been carried out in Matlab/Simulink, and upon entering the cell’s parameters, it provides key electrical characteristics such as the cell’s I-V curve and efficiency information. The total system that is …

Synthesis And Structures Of New Three-Dimensional Copper Metal-Organic Frameworks, Nitin Kumar Pally

Masters Theses & Specialist Projects

Metal-organic frameworks (MOFs) are crystalline materials with metal ions covalently bonded to organic ligands. The ligands act as spacers often creating a porous structure with very high pore volume and surface area. MOFs are known for their robust structures, high porosity, and different chemical functionalities and are considered for applications in adsorptions, separations, catalysis and gas storage. This work focuses on the synthesis of new MOFs using copper compounds. Different types of carboxylate ligands were used for the synthesis. Two new copper-organic frameworks, [Cu₃(pyz)(btc)] (1), and [(Cu₃(btc))•xH₂O] (2) (btc= benzene-1,3,5-tricarboxylate, pyz= pyrazine) have been …

Synthesis And Characterization Of Manganese Pyridazyl Complexes, Sana Shah

Masters Theses & Specialist Projects

Heterocyclic’s and their fused-ring derivatives have been of interest for their use in electronic materials due to their ease of production, synthetic versatility, and low cost compared to traditional inorganic materials like silicon. Pyridazines have been found to be useful in catalysis gas storage, polymeric sensors and biological mimetics. When a transition-metal is fused into a synthesized pyridazine, unique properties such as conductivity and optics are allowed. In this work, synthesized pyridazine complexes will be analyzed by mass spectroscopy, elemental analysis, nuclear magnetic resonance, imaging, x-ray crystallography, and infrared spectroscopy. We are interested in synthesizing organometallic pyridazines and manganese pyridazyl …

Global Digital Elevation Model Accuracy Assessment In The Himalaya, Nepal, Luke G. Miles

Masters Theses & Specialist Projects

Digital Elevation Models (DEMs) are digital representations of surface topography or terrain. Collection of DEM data can be done directly through surveying and taking ground control point (GCP) data in the field or indirectly with remote sensing using a variety of techniques. The accuracies of DEM data can be problematic, especially in rugged terrain or when differing data acquisition techniques are combined. For the present study, ground data were taken in various protected areas in the mountainous regions of Nepal. Elevation, slope, and aspect were measured at nearly 2000 locations. These ground data were imported into a Geographic Information System …

The Use Of The Ostracode Cyprideis Americana (Sharpe) As A Proxy For Salinity In Bahamian Lake Systems, Rachel E. Bowles

Masters Theses & Specialist Projects

Ostracodes, bi-valved crustaceans, are potentially excellent proxies for salinity.They are abundant, react to changes in salinity, and secrete low-magnesium calcite shells that preserve information about their host water chemistry. Changes in valve trace element concentration, stable isotope composition, and sieve pore shape values have been linked to changes in salinity. This study analyzed the response of the euryhaline ostracode, Cyprideis americana, to salinity in six lakes from two Bahamian islands across two seasons. The purpose of this work was to determine which compositional and morphological variables in C. americana are the most useful for paleosalinity reconstructions.Ostracode and water samples were …

Has Safeer Improved Sacm's Work And Helped Saudi Students In The Usa Resolve Their Needs Quickly, Faisal M. Alzomily

Masters Theses & Specialist Projects

This study examined efficiency of the Safeer by gathering and analyzing the perception of 131 Saudi students from Bowling Green, KY. The purpose of the study was to ensure that the system is able to perform its function as the bridge between different institutions and Saudi students studying in the US who require assistance in processing their academic requirements. A self-administered survey using five scale points was employed. Results were summarized using descriptive statistics at 95% confidence level. The result confirmed the hypothesis that the use of the Safeer program provides quality service delivery within SACM, which in turn benefits …

Experimental Studies Of Android App Development For Smart Chess Board System, Srujan Gopu

Masters Theses & Specialist Projects

Playing chess on a smart phone has gained popularity in the last few years, offering the convenience of correspondence play, automatic recording of a game, etc. Although a good number of players love playing chess on a tablet/smart phone, it doesn't come close to the experience of playing over the traditional board. The feel and pleasure are more real when playing face down with the opponent sitting across each other rather than playing in mobile devices. This is especially true during chess tournaments. It would be ideal to enhance the experience of playing chess on board with the features of …

Single Step Synthesis Of Antibiotic Kanamycin Embedded Gold Nanoparticles For Efficient Antibacterial Activity, Shravan Gavva

Masters Theses & Specialist Projects

Nanotechnology has become the most advanced type of drug delivery system within the last decade. This advancement shifted the focus on small carriers to increase the efficiency of the drugs. Among these, gold nanoparticles (GNPs) were found to have profound biomedical applications. In current research, kanamycin embedded GNPs were prepared in a single step, single phase, and bio-friendly (green synthesis) procedure. The synthesized Kanamycin-GNPs (Kan-GNPs) were spherical in shape and had a size range of 15 ± 3 nm. The chosen kanamycin is an aminoglycosidic antibiotic that is isolated from Streptomyces kanamyceticus. These special antibiotic GNPs are further characterized using …

Late Holocene Paleoenvironmental Reconstruction In Barbados, Gilman Reno Ouellette

Masters Theses & Specialist Projects

Barbados is the easternmost island in the Caribbean region, and is uniquely situated between the Atlantic Ocean and Caribbean Sea. Being an isolated island with a karstified aquifer providing the majority of the nation’s water resources, Barbados has found itself in water scarce situations in recent years. In order to better understand natural shifts in groundwater recharge (which is determined by shifts in precipitation), longer records of precipitation are needed than are available from modern measurements. This study presents a paleoclimate reconstruction for the late Holocene on Barbados using stable and radiogenic isotope ratios in speleothem lamina as proxies. In …

Development Of Colloid Displacement Lithography Platforms For Sensor Applications, Mahesh Thugu

Masters Theses & Specialist Projects

In this work, Poly (diallyldimethylammonium) chloride - (PDDA) was used as a base layer for developing colloid displacement lithography platforms for sensor applications. Previous work shows that glass coated with PDDA and exposed to gold acts as a good platform for colloid displacement lithography. However, for actual sensor applications, electrical isolation of individual sensor sections must be achieved. This is attempted by laying down a 40 μm stripe of PDDA on a cleaned substrate and coating that stripe with gold colloid. The size of 40 μm or less in width is set as the target to fit within the scan …

Reinventing Aromatic Substitution: A Novel Look, Quang Nguyen

Masters Theses & Specialist Projects

Electrophilic aromatic substitution (EAS) and directed ortho-metalation (DoM) involve the direct substitution of an arene hydrogen. A major drawback involving EAS is the necessity for harsh forcing conditions for the reaction to proceed. Catalysts such as Lewis acids FeBr₃ and AICI₃ for the introduction of halogens and acyl groups, respectively, are each highly toxic and corrosive. Textbook preparations of aryl iodides classicaly involved the use of iodine and nitric acid. This approach affords only modest yields and does not provide regiospecific substitution of most substituted aromatics because most contain ortho/para directors which afford mixtures of …

Synthesis And Computational Studies Of A New Class Of Lanthanide Niobate Cluster : [Ln4(H2O)8(So4)5(Nbo3)2]+3h2O; Ln= Dy, Tb, Brady D. Garabato

Masters Theses & Specialist Projects

Polyoxoniobates (PONbs) are a small family of highly electron-rich clusters. The development of new solids composed of these clusters have applications in green energy and electronics. However, the high charge environment of PONbs typically requires alkaline synthetic conditions that are unsuitable for introducing other metals and organic molecules, making synthesis of new systems difficult. To date, very few transition metals and organic ligands have been incorporated into these PONb solids, and lanthanide metal inclusion, which generally improves photoconductivity due to longlived f-orbital excitations, has not yet been fully realized. Here, the synthesis of a new class of lanthanide niobate cluster …

Ionic Conductivity In Non-Ionic Compounds, Usha Kranthi Avala

Masters Theses & Specialist Projects

The main objective of this work is to investigate the ionic conductivity of the drugs under certain conditions and also to compare the ionic conductivities of drugs determined by single surface sensors and parallel plate sensors. The ionic conductivity of various materials at their pre-melt and melt states are studied in order to further study a recently discovered phenomenon. Polar solids like Lidocaine, Ketoconazole, Procainamide and Nifedipine were examined in this study. Experimental studies show an increase in ionic conductivity in both pre-melt (20 -30 °C below melting temperature) and melt transition regions. Results of ionic conductivity of both parallel …

Analysis Of Kyrock For Leaching Of Impurities In Synthetic Rainwater, Santhosh Kumar Kasulavada

Masters Theses & Specialist Projects

Kyrock is a coarse grained sandstone with a complex mixture of organic and inorganic compounds. Mining of Kyrock is for use in road construction and roofing. Kyrock samples were analyzed using scanning electron microscopy to obtain elemental analysis. High levels of carbon indicate the presence of organic compounds. Analysis of an acid digestion of the samples using inductively coupled plasma spectroscopy showed inorganic compounds such as titanium oxide, vanadium oxide along with traces of arsenic. Elemental analysis of samples indicates a percent of carbon, and sulfur with no notable traces of nitrogen. Pyrolysis of the samples was done using gas …

Effects Of Xanthan/Locust Bean Gum Mixtures On The Physicochemical Properties And Oxidative Stability Of Whey Protein Stabilized Oil-In-Water Emulsions, Goutham Puli

Masters Theses & Specialist Projects

Scientific evidence shows that dietary intake of the omega-3 polyunsaturated fatty acids is beneficial to human health. Fish oil is a rich source of omega-3 fatty acids. However, fish oil with high levels of omega-3 PUFA is very susceptible to oxidative deterioration during storage. The objective of this study was to investigate the effect of xanthan gum (XG)-locust bean gum (LBG) mixtures on the physicochemical properties of whey protein isolate (WPI) stabilized oil-in-water (O/W) emulsions containing 20% v/v menhaden oil. The O/W emulsions containing XG/LBG mixtures were compared to emulsions with either XG or LBG alone. The emulsions were prepared …

Selective Catalytic Oxidation Of Organic Sulfides By Iron (Iii) Porphryin Catalysts And Generation Of Iron (Iv)-Oxo Prophyrin Radical Cations, Nawras A. Asiri

Masters Theses & Specialist Projects

Macrocyclic ligand-complexed transition metal-oxo intermediates are the active oxidizing species in a variety of important biological and catalytic oxidation reactions. Many transition metal catalysts have been designed to mimic the predominant oxidation catalysts in nature, namely the cytochrome P450 enzymes. Iron porphyrin complexes have been the center of research as catalysts. In this study 5,10,15,20- tetramesitylporphyrin (H₂TMP) and its corresponding iron complexes Fe^III(X)TMP (X= Cl, ClO₄, ClO₃, NO₃, NO₂, and BrO₃) have been successfully synthesized and fully characterized by UV-vis and NMR spectroscopies. For the catalytic …

Floquet Theory On Banach Space, Fatimah Hassan Albasrawi

Masters Theses & Specialist Projects

In this thesis we study Floquet theory on a Banach space. We are concerned about the linear differential equation of the form: y'(t) = A(t)y(t), where t ∈ R, y(t) is a function with values in a Banach space X, and A(t) are linear, bounded operators on X. If the system is periodic, meaning A(t+ω) = A(t) for some period ω, then it is called a Floquet system. We will investigate the existence …

Analyzing And Solving Non-Linear Stochastic Dynamic Models On Non-Periodic Discrete Time Domains, Gang Cheng

Masters Theses & Specialist Projects

Stochastic dynamic programming is a recursive method for solving sequential or multistage decision problems. It helps economists and mathematicians construct and solve a huge variety of sequential decision making problems in stochastic cases. Research on stochastic dynamic programming is important and meaningful because stochastic dynamic programming reflects the behavior of the decision maker without risk aversion; i.e., decision making under uncertainty. In the solution process, it is extremely difficult to represent the existing or future state precisely since uncertainty is a state of having limited knowledge. Indeed, compared to the deterministic case, which is decision making under certainty, the stochastic …

Forensic Investigation Of Stamped Markings Using A Large-Chamber Scanning Electron Microscope And Computer Analysis For Depth Determination, Eric Douglas Jones

Masters Theses & Specialist Projects

All firearms within the United States are required by the Gun Control Act to be physically marked with a serial number; which is at least 0.003” in depth and 1/16” in height. The purpose of a serial number is to make each firearm uniquely identifiable and traceable. Intentional removal of a serial number is a criminal offense and is used to hide the identity and movements of the involved criminal parties. The current standard for firearm serial number restoration is by chemical etching; which is time & labor intensive as well as destructive to the physical evidence (firearm). It is …

Synthesis Of Rhenium And Manganese Pyridazoal Complexes, Jesse Evans

Masters Theses & Specialist Projects

Pyridazines are a heterocyclic aromatic compound containing a characteristic N-N bond that are utilized in many fields, including medicine and electronics. It is this latter field that Dr. Snyder's research group is focused upon. Organometallic compounds are a better conducting material than the current inorganic compounds used in electronics due to better conductance of electricity, lower production cost, and the ability to be formed into thin films. With this in mind, Dr. Snyder's research group has set out to synthesize organometallic compounds for this purpose. Following procedures set forth by Snyder etc, and altered to form an off-metal route, we …

Hybrid Methods For Feature Selection, Iunniang Cheng

Masters Theses & Specialist Projects

Feature selection is one of the important data preprocessing steps in data mining. The feature selection problem involves finding a feature subset such that a classification model built only with this subset would have better predictive accuracy than model built with a complete set of features. In this study, we propose two hybrid methods for feature selection. The best features are selected through either the hybrid methods or existing feature selection methods. Next, the reduced dataset is used to build classification models using five classifiers. The classification accuracy was evaluated in terms of the area under the Receiver Operating Characteristic …

Minimizing Travel Time Through Multiple Media With Various Borders, Tonja Miick

Masters Theses & Specialist Projects

This thesis consists of two main chapters along with an introduction and
conclusion. In the introduction, we address the inspiration for the thesis, which
originates in a common calculus problem wherein travel time is minimized across two media separated by a single, straight boundary line. We then discuss the correlation of this problem with physics via Snells Law. The first core chapter takes this idea and develops it to include the concept of two media with a circular border. To make the problem easier to discuss, we talk about it in terms of running and swimming speeds. We first address …

Ikriya: Simulating Software Quality Enhancement With Selected Replacement Policies, Sindhu Dharani Murthy

Masters Theses & Specialist Projects

The quality of information systems in any organization helps to determine the
efficiency of the organization. Many organizations maintain a custom software portfolio, whose quality is important to the organization. Management would like to optimize the portfolio’s quality. Decisions about software replacement or enhancement are made based on organizational needs and priorities. The development resources allocated help in determining the quality of new software, and should be put to optimal use. Enhancing existing software might sound cheap and easy but it is not always efficient. This thesis proposes a simulation model - iKriya - for this problem. It explores the …

Efficient Architectures For Retrieving Mixed Data With Rest Architecture Style And Html5 Support, Koushik Maddipudi

Masters Theses & Specialist Projects

Software as a service is an emerging but important aspect of the web. Web
Services play a vital role in providing it. Web Services are commonly provided in one of two architectural styles: a "REpresentational State Transfer" (REST), or using the "Simple Object Access Protocol" (SOAP.) Originally most web content was text and small images. But more recent services involve complex data structures including text, images, audio, and video. The task of optimizing data to provide delivery of these structures is a complex one, involving both theoretical and practical aspects. In this thesis work, I have considered two architectures developed …

Fused Arenes-Based Molecular And Polymeric Materials For Organic Field Effect Transistors, Harista Irugulapati

Masters Theses & Specialist Projects

In the past decade, tremendous progress has been made in organic field effect
transistors. Fused oligothiophenes and anthracene molecules are fascinating
macromolecules having unique optoelectronic properties. These compounds are successfully employed as active components in optoelectronic devices including field effect transistors. Our goal is to design and synthesize conjugated molecular materials, which are highly functionalized through structural modifications in order to enhance their electronic, photonic, and morphological properties. The main desire is to synthesize novel organic fused-arenes having efficient charge carrier mobilities, as well as to optimize optical properties for organic field effect transistors (OFETs). Novel series of fused arene …

Effects Of Cisplatin Analog Size On The Reaction With Dna Bases, Swathi Nandala

Masters Theses & Specialist Projects

Cancer is the second leading cause of death in the United States. Cisplatin is one of the well-known anti-cancer agents used to treat testicular and ovarian cancers. It mainly binds to the DNA bases, which leads to cell death. The cytotoxic activity of the cisplatin analogs is due to the interaction of platinum with nucleotides like adenine at N₇ or N₁ position and guanine at N₇ position. Guanine is the primary target for cisplatin analogs whereas adenine is the secondary target. Cisplatin analogs, [Pt(Me₅dien)(D₂O)]²⁺[Me₅dien = N,N,N’,N’,N’’-pentamethyl diethylene triamine] and …