Digital Commons Network^™

Farmers' Markets In Kentucky: A Geospatial, Statistical, And Cultural Analysis, Elizabeth Ann Schmitz

Masters Theses & Specialist Projects

To assess what factors are driving the exponential growth of farmers’ markets in Kentucky, geospatial and statistical analysis of a database of 121 farmers’ markets was conducted. A statewide survey of market leaders and a case study of a single farmers’ market both identified reasons for growing support of farmers’ markets in Kentucky.

Market distribution, vendor levels, and gross sales were mapped against a backdrop of county urban classification, median household income, and education levels. Kruskal-Wallace analysis was used to identify if Kentucky’s rural, micropolitan, and metropolitan markets differ significantly in terms of their age, number of vendors, and market …

The Hydrology Of The Carroll Cave-Toronto Springs System: Identifying And Examining Source Mixing Through Dye Tracing, Geochemical Monitoring, Seepage Runs, And Statistical Methods, Benjamin Verlinden Miller

Masters Theses & Specialist Projects

In karst areas relationships between activities occurring on the surface and the overall health of the subsurface environment are often highly interconnected. However, the complex nature of karst flow systems can often make identification of these connections difficult. Carroll Cave, a large stream cave system located in the central Missouri Ozarks, is known for its biological and speleological significance. A dye tracing project to delineate a Carroll Cave recharge area through dye tracing has identified an area of 18.5 km2 which contributes water to the cave. The water from Thunder River within Carroll Cave was positively traced to eight springs …

Two-Phase Partitioning System Using Elvax 40w Polymer For The Biodegradation Of Aqueous Phenols, Amit Suresh Ghode

Masters Theses & Specialist Projects

A solid-liquid two phase partitioning system (TPPS) is a new technology platform for destroying toxic organic compounds. TPPS have traditionally been operated by using an immiscible organic phase which partitions organic compounds into the aqueous phase. TPPS using an immiscible organic phase suffers from several limitations such as the organic phase could be biodegradable and hence only certain compatible microbial strains could be used. This therefore, eliminates the desired use of mixed microbial populations for efficient degradation. A solid-liquid two phase partitioning system, in which solid polymeric beads replace liquid organic phase, appears to have benefits over the traditional liquid-liquid …

Internet Gis As A Historic Place-Making Tool For Mammoth Cave National Park, Ann E. Epperson

Masters Theses & Specialist Projects

This project laid the groundwork for an Internet-delivered Public Participation Geographic Information System to facilitate exploration and discovery of the past communities of the Mammoth Cave Park area. The emergence of Internet Web 2.0 design along with distributed GIS services allows for anyone to interact with and add to the information found on central Internet sites. Historical geography often relies upon public participation from individuals outside the academic world to provide narrative descriptions, photographs and manuscripts of past places and events to augment information held by institutions and academia. A public-participation website for the Mammoth Cave Historic GIS (MCHGIS) created …

Investigation Of Volatile Products From Wood Pyrolysis, Prabhavathi Gade

Masters Theses & Specialist Projects

In this research we are following the thermo-chemical degradation of wood in the absence of oxygen. The objectives are to evaluate the influence of heating rates on pyrolysis products obtained from wood pyrolysis and to evaluate the influence of acid pre-treatment on pyrolysis products. Depending on the wood heating rates, pyrolysis can be categorized as Flash pyrolysis, Fast pyrolysis, and Slow pyrolysis. We have evaluated the volatile products obtained at different heating rates and the volatile products obtained from sulfuric acid pre-treatment by using gas chromatography- mass spectrometry (GC-MS). We have also performed thermo-gravimetric analysis (TGA) of raw wood samples …

Doppler-Broadening Of Light Nuclei Gamma-Ray Spectra, Melinda D. Whitfield

Masters Theses & Specialist Projects

Non-destructive methods of material interrogation are used to locate hidden explosives and thwart terrorism attempts. In one such method materials are bombarded with neutrons which react with the nuclei of the atoms within causing a de-excitation process emitting a gamma-ray. The spectrum displayed by the collection of these gamma-rays gives valuable information regarding the material’s elemental make-up. It has been hypothesized that gamma-rays from neutron-induced gamma-ray reactions on light elements with atomic numbers less than 20, including most of the gamma-rays of interest in explosives detection, are Doppler-broadened. This thesis focuses on the gamma ray spectra from the 4438 keV …

An Application And Refinement Of The Karst Disturbance Index Through Evaluating Variability In Island Karst Disturbance In Puerto Rico, Brandon Lee Porter

Masters Theses & Specialist Projects

Karst environments are unique landscapes that contain important resources, including freshwater aquifers and specialized ecosystems, which are easily disturbed due to the interconnected nature of the surface and subsurface. The anthropogenic impacts on karst are deleterious to the ecosystems that are dependent on the karst environment and also to groundwater supplies. The Karst Disturbance Index (KDI) is a holistic tool used to measure anthropogenic impacts associated with karst environments, which has been applied and refined through studies performed in Florida and Italy, yet still remains untested and susceptible to modification for other areas. Application of the KDI in Arecibo, Puerto …

Appearance Based Stage Recognition Of Drosophila Embryos, Gopi Chand Nutakki

Masters Theses & Specialist Projects

Stages in Drosophila development denote the time after fertilization at which certain specific events occur in the developmental cycle. Stage information of a host embryo, as well as spatial information of a gene expression region is indispensable input for the discovery of the pattern of gene-gene interaction. Manual labeling of stages is becoming a bottleneck under the circumstance of high throughput embryo images. Automatic recognition based on the appearances of embryos is becoming a more desirable scheme. This problem, however, is very challenging due to severe variations of illumination and gene expressions. In this research thesis, we propose an appearance …

Geographic Factors Of Residential Burglaries - A Case Study In Nashville, Tennessee, Jonathan A. Hall

Masters Theses & Specialist Projects

This study examines geographic patterns and geographic factors of residential burglary at the Nashville, TN area for a twenty year period at five year interval starting in 1988. The purpose of this study is to identify what geographic factors have impacted on residential burglary rates, and if there were changes in the geographic patterns of residential burglary over the study period. Several criminological theories guide this study, with the most prominent being Social Disorganization Theory and Routine Activities Theory. Both of these theories focus on the relationships of place and crime. A number of spatial analysis methods are hence adopted …

Synthesis, Kinetic And Photocatalytic Studies Of Porphyrin-Ruthenium-Oxo Complexes, Yan Huang

Masters Theses & Specialist Projects

Macrocyclic ligand-complexed transition metal-oxo intermediates are the active oxidizing species in a variety of important biological and catalytic oxidation reactions. Many transition metal catalysts have been designed to mimic the predominant oxidation catalysts in Nature, namely the cytochrome P450 enzymes. Ruthenium porphyrin complexes have been the center of the research and have successfully been utilized, as catalysts, in major oxidation reactions such as the hydroxylation of alkanes. This study focuses on kinetic and photocatalytic studies of oxidation reactions with wellcharacterized high-valent ruthenium-oxo porphyrin complexes.
The trans-dioxoruthenium(VI) porphyrins have been among the best characterized metal-oxo intermediates and their involvement as …

High Pressure Liquid Chromatography Studies Of The Reaction Of Platinum Complexes With Peptides, Khaja Muneeruddin

Masters Theses & Specialist Projects

Platinum complexes (cisplatin, carboplatin and oxaliplatin) are effective anticancer agents. However the major drawbacks of platinum chemotherapy are toxic side effects and resistance. The affinity of platinum complexes to sulfur donor ligands of side chains of methionine and cysteine amino acids was assumed to be responsible for toxicity and resistance. Recently, it was found that the reaction of platinum complex with proteins containing sulfur donor ligands could actually favor its anticancer activity. Copper transporter 1 (Ctr 1), a protein involved in the transport of copper into the cell, also helps in the influx of cisplatin by binding to N-terminal domain …

On-Metal Synthesis Of Some Aryl Substituted Rhenium Η5 Cyclopenta[C] Pyridazyl Complexes, Phenahas Gandu Sriramulu

Masters Theses & Specialist Projects

Heterocyclic organic and organometallic compounds (e.g. polypyrrole) and their derivatives have been of great interest for conductive polymers due to their novel properties and environmental stability as compared to non-aromatic analogs (e.g. polyacetylene). We are interested in synthesizing organometallic pyridazines and rhenium pyridazyl complexes for polymer research. SeveraI5,6-fused ring pyridazines (1,2-CsH3(CRNH)(CRN) have been synthesized and characterized. Additionally, pyridazyl complexes of rhenium were synthesized in three steps beginning from fulvenes 1,2-CsH3(COHR)(COR). On-Metal synthesis and characterization of (Re(CO)3 {1,2- CSH3(CRN)(CRN)}] (R=C6RtOMe, C6RtCI, C4H30) and some off-metal pyridazines are reported here. Our research is focused on synthesis of a variety of 5,6- fused …

Exploring Zirconia As A Column Packing Material, Tushar Ghugare

Masters Theses & Specialist Projects

Zirconia is one of the most promising column packing materials for High Performance Liquid Chromatography (HPLC). The perfect HPLC support material should be energetically homogenous, have a high surface area on which different chemical species can reversibly attach and be physically and chemically stable over a wide range of pH, temperature and solvent conditions. Most existing supports do not have all of these properties. This project is also focused on a proteomics study. Zirconia, hafnium oxide and titanium oxide which are some of the more promising materials currently available, can be used for the separation and analysis of phosphorylated proteins. …

Algal Biomass Accrual In Relation To Nutrient Availability Along A Longitudinal Gradient In The Upper Green River, Kentucky, Mary Douglas Penick

Masters Theses & Specialist Projects

Nutrient limitation in aquatic ecosystems results from a deficiency in nitrogen or phosphorus levels relative to cellular growth needs. Nutrient limitation of freshwater systems is a function of biotic and abiotic factors. Biotic factors include vascular and nonvascular plant community composition. Abiotic factors include underlying bedrock and land-use activities (e.g. agriculture, septic systems). Nutrient availability directly affects growth, productivity, and community structure of primary producers. The purpose of this study was two-fold: (1) to assess the relationship between ambient algal biomass. and in-stream nutrient levels along the longitudinal course of a river through a transition from weak to well-developed underlying …

Degradation Of Chlorophenols In Swine Waste, Srilatha Gangula

Masters Theses & Specialist Projects

Naturally occurring plant derived phenols can be degraded through bacteria in swine waste. Chlorinated phenols, which are not naturally present in the environment, are toxic and generated from industrial activities as such petrochemical, pharmaceutical, plastic, rubber, pesticide, iron, steel, paper production, coal conversion, wood preserving, and cellulose bleaching. Large scale coal gasification and carbonization plants are another source of chlorinated phenols. Although not normally present in the environment, chlorinated phenols are structurally similar to many plant derived phenolics.

It is our hypothesis that bacteria located in swine wastes may also have the ability to degrade chlorinated phenols. Identifying situations (and …

Discrete Fractional Calculus And Its Applications To Tumor Growth, Sevgi Sengul

Masters Theses & Specialist Projects

Almost every theory of mathematics has its discrete counterpart that makes it conceptually easier to understand and practically easier to use in the modeling process of real world problems. For instance, one can take the "difference" of any function, from 1st order up to the n-th order with discrete calculus. However, it is also possible to extend this theory by means of discrete fractional calculus and make n- any real number such that the ½-th order difference is well defined. This thesis is comprised of five chapters that demonstrate some basic definitions and properties of discrete fractional calculus …

An Algorithm To Generate Two-Dimensional Drawings Of Conway Algebraic Knots, Jen-Fu Tung

Masters Theses & Specialist Projects

The problem of finding an efficient algorithm to create a two-dimensional embedding of a knot diagram is not an easy one. Typically, knots with a large number of crossings will not nicely generate two-dimensional drawings. This thesis presents an efficient algorithm to generate a knot and to create a nice two-dimensional embedding of the knot. For the purpose of this thesis a drawing is “nice” if the number of tangles in the diagram consisting of half-twists is minimal. More specifically, the algorithm generates prime, alternating Conway algebraic knots in O(n) time where n is the number of crossings …

A Novel Pervious Cement Reaction Barrier (Pcrb) In Situ Arsenic Remediation System, Morgan Liane Jones

Masters Theses & Specialist Projects

No abstract provided.

Analysis Of Fresh Water Resources At The Line Hole Well Field, San Salvador Island, The Bahamas, Scot Allan Russell Jr.

Masters Theses & Specialist Projects

A major economic constraint in the Bahamas, and other small carbonates islands world-wide, is the lack of fresh water resources. To combat these socio-economic problems on San Salvador Island I sought to gain a more detailed understanding of the extent, behavior, and controls on the island’s fresh-water lens. DC electrical resistivity tomography and time-series geochemical data are used to study the fresh water lens at the Line Hole well field. Electrical Resistivity profiles are used to image the extent of fresh water resources. Time-series geochemical data provide information on the behavior of the fresh water resources as a function of …

The Reaction Of A Water Soluble Platinum Compound With Methionine And Derivatives, Yueh Ying Liao

Masters Theses & Specialist Projects

Water soluble platinum complexes are a recent area of emphasis of cisplatin chemistry. The water soluble complexes could have a reduced toxicity compared with cisplatin. Oxaliplatin, which has an oxalate leaving group, has previously been shown to have less nephro-toxicity and higher water solubility than cisplatin. [Pt(en)(oxalate)] (en = ethylenediamine) has been prepared from Pt(en)Cl2 and silver oxalate. This complex has been reacted with methionine and N-acetylmethionine at different molar ratios. At high Pt: methionine ratios, chelates with the sulfur and nitrogen atoms of the methionine are dominant; at lower Pt: methionine ratios, a bis-methionine product is formed. The en …

Information Technology Implementation Decisions To Support The Kentucky Mesonet, D. Michael Grogan

Masters Theses & Specialist Projects

The Kentucky Mesonet is a high-density, mesoscale network of automated meteorological and climatological sensing platforms being developed across the commonwealth. Data communications, collection, processing, and delivery mechanisms play a critical role in such networks, and the World Meteorological Organization recognizes that “an observing system is not complete unless it is connected to other systems that deliver the data to the users.” This document reviews the implementation steps, decisions, and rationale surrounding communications and computing infrastructure development to support the Mesonet. A general overview of the network and technology-related research is provided followed by a review of pertinent literature related to …

Suspended Sediment Transport Dynamics And Sediment Yields In Relation To Watershed Characteristics, Upper Green River Basin, Kentucky, James Nii Aboh Otoo

Masters Theses & Specialist Projects

Sediment delivery is a major problem in the Green River, Kentucky, home of 71 of the state’s 103 known mussel species and 151 fish species. The river also provides water for many of its surrounding counties. This research focuses on how suspended sediment loads, grain size, and sediment concentration during runoff events are related to watershed characteristics.

The research characterized suspended sediment loads, grain size, and sediment concentration during runoff events and how they were related to watershed characteristics such as hydro-climatic regime, watershed size, geology and soils, topography and landuse conditions and land cover conditions. The study focused on …