Digital Commons Network^™

Developing And Applying An Integrated Spatial Karst Evaluation And Management Priority Tool: Case Study In Tongass National Forest, Alaska, Usa, Christian Decelle

Masters Theses & Specialist Projects

Karst terrains are complex landscapes that are sensitive to human disturbance. Human activities have polluted and impacted many of these terrains around the world. To preserve these unique landscapes, many karst regions are protected and designated as national parks, geologic special areas, or UNESCO Biosphere Reserves. Despite the widespread general protection of karst landscapes globally, a review of each area’s management plan reveals there is no standardized method of cave and karst management or evaluation of karst impacts.

The non-standardization of karst management strategies may be due to the gap that exists between the needs of karst land managers and …

Investigating Epikarst Recharge Dynamics Under Agricultural Landuse Using Hydrometeorological And Isotopic Tracers, Austin Shane Deering

Masters Theses & Specialist Projects

Epikarst systems have complex recharge – discharge processes in telogenetic karst systems, including highly variable storage, flowpaths, and mixing dynamics. This research aimed to characterize the epikarst zone using hydrogen and oxygen isotopic tracers of these processes within south-central Kentucky’s Crumps Cave system located in the Pennyroyal Sinkhole Plain. Data and statistical analyses were applied to highresolution rainfall (RF), lysimeter (10 cm, 20 cm, 30 cm depths), and an epikarst Waterfall 1 (WF1) isotope data collected on a weekly basis between 2011-2018. These data were coupled with WF1 discharge measurements and weather station data collected at Crumps Cave Preserve during …

Manufacturing: The Qualitative Study Of A Transition To A Green Facility, Brandon David Staves

Masters Theses & Specialist Projects

This qualitative study focused on answering three core questions: How have facilities reduce pollutions in regards to the quality of air, water, land, light and noise? Which Types of pollution reduction projects are more or less successful to implement? What types of pollution are facilities focusing on and why? The results of the 15 companies surveyed show a variety of projects that facilities have used to reduce pollution, it also shows that cost is a major factor in the unsuccessful projects, and that facilities are actively focused on reducing Air, Land, and Water pollution. While the data shows a variety …

An Adaptive Hazard Planning And Mitigation Framework For Responding To Urban Contamination In Karst Aquifer Systems, James Edward Troxell

Masters Theses & Specialist Projects

Environmental hazards in karst regions are damaging and often go unnoticed until an issue has escalated to a point of affecting life or property. The field of emergency and environmental contamination response lacks planning or preparedness focused on remediating groundwater contamination in karst systems. A lack of preplanning before an incident can lead to confusion, delayed response, and the inability to remediate the contaminant. Due to the rapid movement of contaminants through urban karst groundwater aquifers, an efficient response plan that leverages localized data in a GIS should be developed and maintained in order to adequately respond. The objective of …

Knot Theory In Virtual Reality, Donald Lee Price

Masters Theses & Specialist Projects

Throughout the study of Knot Theory, there have been several programmatic solutions to common problems or questions. These solutions have included software to draw knots, software to identify knots, or online databases to look up pre-computed data about knots. We introduce a novel prototype of software used to study knots and links by using Virtual Reality. This software can allow researchers to draw links in 3D, run physics simulations on them, and identify them. This technique has not yet been rigorously explored and we believe it will be of great interest to Knot Theory researchers. The computer code is written …

Functionalized Ionic Liquids For Improved Co2 Hydrogenation Catalysts, Amol Nanduji Jaybhaye

Masters Theses & Specialist Projects

Climate change is one of the biggest problems we are facing today, and anthropogenic greenhouse gases contribute significantly to it. Among greenhouse gasses, carbon dioxide emission is increased drastically and affecting majorly for increasing global temperature, and anything we can do to mitigate carbon dioxide emission will be helpful. A carbon dioxide hydrogenation reaction is a promising technique that can convert carbon dioxide into value-added chemicals, but the reaction rate is slow, and for that, we can use catalysts that will accelerate the reaction rate. Platinum-based nanoparticles have sparked research related to energy and environmental catalysts. Catalytic properties are depending …

Design Of Antioxidant Monomer, Augustine Osilamah Yusuf

Masters Theses & Specialist Projects

Reactive oxygen species such as hydrogen peroxide are present at the sites of inflammation in the body. Degradable polymeric nanoparticles have shown great promise in a range of biomedical applications which include preferential delivery of therapeutics to such inflamed sites. We are working towards a new class of materials expected to have tunable degradation rates in the presence of hydrogen peroxide. These new materials consist of three parts: degradable linkages, antioxidant groups, and unreactive filler monomers such as methylmethacrylate. We have synthesized a polymerization initiator with a degradable linkage, and we have shown that using this initiator to synthesize another …

Statistical Study Of The Effect Of Implementing An Airveyor System On The Warpage Of Injection Molded Closures, Charles Wesley Bozarth

Masters Theses & Specialist Projects

Berry Global in Bowling Green, Kentucky produces predominantly polypropylene container closures. One variant, the 83mm lined jar closure, is produced by first being injection molded, placed in work-in-progress (WIP) hold for 24 hours to cool, and then finished through the auxiliary liner operation into a final product. While this process is an effective method to produce a quality large-diameter closure and allows the polypropylene adequate time to cool without warping out of shape, the 24-hour WIP time and the manpower needed to accomplish this can negatively impact several business metrics as well as employee safety.

The purpose of this thesis …

Analysis Of Boundary Observability Of Strongly Coupled One-Dimensional Wave Equations With Mixed Boundary Conditions, Wilson Dennis Horner

Masters Theses & Specialist Projects

*see note below

In control theory, the time it takes to receive a signal after it is sent is referred to as the observation time. For certain types of materials, the observation time to receive a wave signal differs depending on a variety of factors, such as material density, flexibility, speed of the wave propagation, etc. Suppose we have a strongly coupled system of two wave equations describing the longitudinal vibrations on a piezoelectric beam of length L. These two wave equations have non-identical wave propagation speeds c1 and c2. First, we prove the exact observability inequality with the optimal …

Revisiting Hudson County Water Co. V. Mccarter: Realism, The Public Trust Doctrine, And Environmental Conservation In The Lochner Era, Steven Huffman

Masters Theses & Specialist Projects

Legal histories of the Gilded Age and Progressive Era tend to focus inordinately on economic regulation within a doctrinal framework in which private rights, equal protection, and “substantive” due process guided judicial decision-making. Consequently, the overarching economic context in prevailing legal historiography obscures an important yet oft-overlooked development in the linkage between public rights, natural resource trusteeship, and the early-twentieth-century environmental conservation movement. This development is inextricably tied to the evolution of water law in the late nineteenth century and the expansion of the American commercial republic. A normative understanding of public water rights during this period is confined to …

The Effect Of Environmental Context Upon Visual Distance Perception, Jessica M. Dukes

Masters Theses & Specialist Projects

The ability of 16 younger adults to visually perceive distances in depth was evaluated within three environmental contexts (indoors in the dark, indoors in the light, and outdoors). The observers' task was to bisect an 8m distance interval in all contexts using both monocular and binocular vision. In the outdoor environment (a natural grassy field), the observers' judgments indicated perceptual compression of farther distances similar to that obtained in many previous studies. In the indoor lighted environment (a 10.2 x 9.6m laboratory room), the observers' judgments were consistent with perceptual expansion of farther distances. Finally, there was a beneficial effect …

Reimagining The Duck Stamp, Hunting Licensure And Public Land Preservation, Alec Wayne Boyd-Devine

Masters Theses & Specialist Projects

The American Migratory Bird Hunting and Conservation Stamp, or Duck Stamp, is a form of licensure issued by the Federal Government for waterfowl hunters. Why do physical stamps act as licensure to hunt waterfowl on both public and private land in the United States? How did the stamp become the key that grants access to resources that supposedly should be owned by the public? The duck stamp has been well-documented in conservation communities as a resource which has made significant positive impacts on the environment. The increase of anti-hunting sentiments in our society combined with fewer hunters per capita may …

Visible Light Generation And Mechanistic Investigation Of High-Valent Metal-Oxo Species Supported By Different Ligands, Seth Ellis Klaine

Masters Theses & Specialist Projects

Numerous transition metal catalysts have been designed as biomimetic model compounds for the active site of metalloenzymes found throughout Nature, most notably cytochrome P450 monooxygenases that carry out the oxidative transformations of organic substrates with near-perfect chemo-, regio-, and stereo-selectivity. The primary active oxidants in catalytic and enzymatic cycles are fleeting high-valent metal-oxo intermediates where the oxo ligand can transfer to an organic substrate in a process known as oxygen atom transfer (OAT).

In the present work, porphyrin-manganese(III), salen-chromium(III), and salenmanganese( III) derivatives were successfully synthesized and spectroscopically characterized using 1H NMR and UV-Vis spectroscopies. A facile photochemical approach was …

Buffer Overflow And Sql Injection In C++, Noah Warren Kapley

Masters Theses & Specialist Projects

Buffer overflows and SQL Injection have plagued programmers for many years. A successful buffer overflow, innocuous or not, damages a computer’s permanent memory. Safer buffer overflow programs are presented in this thesis for the C programs characterizing string concatenation, string copy, and format get string, a C program which takes input and output from a keyboard, in most cases. Safer string concatenation and string copy programs presented in this thesis require the programmer to specify the amount of storage space necessary for the program’s execution. This safety mechanism is designed to help programmers avoid over specifying the amount of storage …

Synthesis And Catalytic Oxidation Of Organic Substrates By Light-Harvesting Metalloporphyrins, Christian Alcantar

Masters Theses & Specialist Projects

note: Some notation in this abstract may not appear exactly as formatted in the thesis.

In this work, ruthenium, iron, and manganese light-harvesting metalloporphyrins have been successfully synthesized to serve as biomimetic models of the active site of Cytochrome P450 for the development of a green and efficient oxidation catalyst. The covalent introduction of light-harvesting boron-dipyrrin (BODIPY) fluorophores on the porphyrin macrocycle allows for the absorption of a broader range of visible light in addition to that captured by the porphyrin aromatic system alone. It is expected that this core-antenna system will increase the absorbed light energy and transfer it …