Digital Commons Network^™

Assessment Of Passive Fire Protection On Steel-Girder Bridges, Michael Davidson

Masters Theses & Specialist Projects

Bridges in the US are severely damaged or suffer collapse from fires at significant rates, even when compared to other hazards such as earthquakes. Fire-induced bridge collapses are perpetuated by the general lack of installed fire protection systems. Therefore, new materials and applications are needed to mitigate structural damage that can be caused to civil infrastructure by severe fires. Accordingly, the objective of this study is to further the development of new fire protection applications in transportation structures. Specifically, the investigation centers on the development of new applications in passive fire protection materials, within the context of shielding steel-girder bridges …

Integrating Expert System And Geographic Information System For Spatial Decision Making, Sriharsha Shesham

Masters Theses & Specialist Projects

Spatial decision making is a process of providing an effective solution for a problem that encompasses semi-structured spatial data. It is a challenging task which involves various factors to consider. For example, in order to build a new industry, an appropriate site must be selected for which several factors have to be taken into consideration. Some of the factors, which can affect the decision in this particular case, are air pollution, noise pollution, and distance from living areas, which makes the decision difficult. The geographic information systems (GIS) and the expert systems (ES) have many advantages in solving problems in …

Contour Extraction Of Drosophila Embryos Using Active Contours In Scale Space, Soujanya Siddavaram Ananta

Masters Theses & Specialist Projects

Contour extraction of Drosophila embryos is an important step to build a computational system for pattern matching of embryonic images which aids in the discovery of genes. Automatic contour extraction of embryos is challenging due to several image variations such as size, shape, orientation and neigh- boring embryos such as touching and non-touching embryos. In this thesis, we introduce a framework for contour extraction based on the connected components in the gaussian scale space of an embryonic image. The active contour model is applied on the images to refine embryo contours. Data cleaning methods are applied to smooth the jaggy …

On Metal Synthesis Of Some Substituted Rhenium And Manganese Complexes, Jaron Michael Thomas

Masters Theses & Specialist Projects

Heterocyclic organic and organometallic compounds (i.e. polypyrrole), and their derivatives, have been of great interest for conductive polymers due to their novel properties and environmental stability as compared to their non-aromatic analogs (i.e. polyacetylene). Our current interest focus upon the potential role of metal ligand bound pyridazines as the next generation of electronic devices that utilize the metal ligands bound to organics as the semiconducting material. Pyridazine is a 6-membered aromatic ring with two adjacent nitrogen atoms. These are promising candidates for a variety of materials and commercial applications; but they are difficult to get a metal ligand to fuse …

Phosphorus Transport And Distribution In Kentucky Soils Prepared Using Various Biochar Types, Anvesh Reddy

Masters Theses & Specialist Projects

Conserving the environment is an issue that is gaining popularity day by day. Phosphorus transfer from agricultural soils is an important environmental issue that is being closely observed as the transport of phosphorous to water bodies is adversely affecting water quality due to accelerated eutrophication. It is important to establish phosphorous models that accurately account for soil test phosphorous. Standard models like SWAT (Soil and Water Assessment Tool) and EPIC (Environmental Policy Integrated Climate) were designed for serving this purpose. They are now used as the basis for developing new models that can more accurately account for the phosphorus transport, …

Nabla Fractional Calculus And Its Application In Analyzing Tumor Growth Of Cancer, Fang Wu

Masters Theses & Specialist Projects

This thesis consists of six chapters. In the first chapter, we review some basic definitions and concepts of fractional calculus. Then we introduce fractional difference equations involving the Riemann-Liouville operator of real number order between zero and one. In the second chapter, we apply the Brouwer fixed point and Contraction Mapping Theorems to prove that there exists a solution for up to the first order nabla fractional difference equation with an initial condition. In chapter three, we define a lower and an upper solution for up to the first order nabla fractional difference equation with an initial condition. Under certain …

Application Of The Weather Research And Forecasting (Wrf) Model To Simulate A Squall Line: Implications Of Choosing Parameterization Scheme Combinations And Model Initialization Data Sets, Mitchell Gaines

Masters Theses & Specialist Projects

On January 29-30, 2008 a squall line of thunderstorms moved through the Ohio Valley resulting in four deaths and one injury. Such events highlight the importance of accurate forecasting for public safety. Mesoscale Modeling plays an important role in any forecast of a potential squall line. The focus of this study was to examine the performance of several parameterization scheme combinations in the Weather Research and Forecasting Model version three (WRF) as they related to this event. These examinations included cloud microphysics (WRF Single-Moment 3-class, 6-class, and Goddard), cumulus parameterization (Kain-Fritsch and Bets-Miller-Janjic) and planetary boundary layer schemes (Yonsei-University and …

Preparation Of Copper-Based Oxygen Carrier Supported On Titanium Dioxide, Yaowen Cui

Masters Theses & Specialist Projects

Chemical-looping combustion is an indirect oxygen combustion strategy, considered to be the most cost-effective power generation technology with the CO2 inherently concentrated. In this process, a solid oxygen carrier is used to transfer oxygen from the air reactor to the fuel reactor, which completely isolates nitrogen in air to meet with fuels. The oxygen carriers in the combustion process are subjected to the severe environments, such as high temperatures, multi-cycle operations, and thermodynamic limitations. Thus, the preparation of an oxygen carrier with high durability and better kinetics under harsh environment could be an essential part of Chemical-looping combustion development. In …

Photochemical Oxidation Studies Of Porphyrin Ruthenium Complexes, Eric Vanover

Masters Theses & Specialist Projects

In nature, transition metal containing enzymes display many biologically important, attractive and efficient catalytic oxidation reactions. Many transition metal catalysts have been designed to mimic the predominant oxidation catalysts in nature, namely, the cytochrome P450 enzymes. Ruthenium porphyrin complexes have been the center of this research and have successfully been utilized, as catalysts, in major oxidation reactions, such as the hydroxylation of alkanes. The present work focuses on photocatalytic studies of aerobic oxidation reactions with well characterized ruthenium porphyrin complexes.

The photocatalytic studies of aerobic oxidation reactions of hydrocarbons The photocatalytic studies of aerobic oxidation reactions of hydrocarbons catalyzed by …

Modeling Daily Power Demand In Southern Kentucky: A Single Household Approach, Craig M. Dickson

Masters Theses & Specialist Projects

In this study, we use a nonparametric technique, locally weighted robust least squares regression (LOESS), to forecast a 24 hour demand profile at the household level and compare it to existing aggregate demand models discussed in literature. Of these aggregate demand models, a quadratic autoregressive model was selected to be used as a basis for comparison with the LOESS forecasts. It was our goal to automate the forecasting process by using the goodness of fit metric, AICCI, for smoothing parameter selection. The statistical workflow was executed using SAS and data was provided by the Glasgow Electric Plant Board of Barren …

Making Music Sustainable: The Case Of Marketing Summer Jamband Festivals In The U.S., 2010, Melissa A. Cary

Masters Theses & Specialist Projects

Commercial music festivals in the United States have been growing in popularity since the 1960s. Today, many weekend-long music festivals are annual events spanning a variety of genres and often occur at the same locations each year. My research compares and contrasts how jamband music festivals are marketed as sustainable events and attempts to determine how the advertised sustainable practices are implemented and utilized at selected jamband music venues. The jamband genre of music emphasizes musical improvisation and borrows from other styles of music: rock, electronic, jazz, blues, folk, and bluegrass.

In addition, any impacts these festivals have upon the …

Removal Of Heavy Metals From Drinking Water By Adsorption Onto Limestone With A Focus On Copper And Aluminum Applications, Swarna Latha Somasani

Masters Theses & Specialist Projects

Elevated levels of arsenic and other heavy metals like copper, aluminum, zinc, and selenium in drinking water are found to have deleterious effects on human health. Hence, finding methods for reducing their levels is critical. Iron-coated limestone is used as an adsorption material for the removal of heavy metals from drinking water. Removal of heavy metals by native or uncoated limestone was also observed and used for comparison to and evaluation of the improvement in removal efficiency from the ironcoated material. The removal efficiency with limestone was studied for different concentrations of heavy metals. Kinetic studies were done to determine …

An Examination Of White-Nose Syndrome Occurrence And Dispersal Patterns: Utilizing Global And Local Moran's I Analysis To Evaluate An Emerging Pathogen, Celia M. Davis

Masters Theses & Specialist Projects

In this research, a novel approach that utilizes Moran’s I statistical analyses to examine the spatio-temporal dispersal patterns of the White-Nose Syndrome currently affecting North American bat species is undertaken to further understand the disease transmission mechanism(s) of this emerging wildlife epidemic. White-Nose Syndrome has been responsible for in excess of five million bat deaths to date and has the potential to alter the ecological landscape significantly; however, due to a variety of factors, little research has been conducted into the patterns of infection on a national scale. Global and Local Moran’s I analyses were performed on the spatial-temporal variable …

Mercury Transportation In Soil Using Gypsum From Flue Gas Desulphurization Unit In Coal-Fired Power Plant, Kelin Wang

Masters Theses & Specialist Projects

This work investigates mercury flux in soil amended by gypsum from flue gas desulphurization (FGD) units of coal-fired power plants. There are two phases of this research, including field and greenhouse studies. Previous studies indicate that FGD gypsum could increase corn yield, but may lead to more mercury uptake by corn.

Recent studies have been carried out in greenhouses to investigate mercury transport in FGD gypsum treated soil. Major aspects include uptake of mercury by plants and emission of mercury into the atmosphere based on application rates of FGD gypsum. Additional aspects include rainfall, temperature, soil, and plants types. Higher …

Remainders And Connectedness Of Ordered Compactifications, Sinem Ayse Karatas

Masters Theses & Specialist Projects

The aim of this thesis is to establish the principal properties for the theory of ordered compactifications relating to connectedness and to provide particular examples. The initial idea of this subject is based on the notion of the Stone-Cech compactification.
The ordered Stone-Cech compactification oX of an ordered topological space X is constructed analogously to the Stone-Cech compactification X of a topological space X, and has similar properties. This technique requires a conceptual understanding of the Stone-Cech compactification and how its product applies to the construction of ordered topological spaces with continuous increasing functions. Chapter 1 introduces background information.

Chapter …

Size Dependent Antimicrobial Properties Of Sugar Encapsulated Gold Nanoparticles, Lakshmisri Manisha Vangala

Masters Theses & Specialist Projects

The antimicrobial properties of dextrose encapsulated gold nanoparticles (dGNPs) with average diameters of 25 nm, 60 nm, and 120 nm (± 5 nm) synthesized by green chemistry principles were investigated against both Gram-negative and Gram-positive bacteria. Studies were performed involving the effect of the dGNPs on the growth, morphology and the ultrastructural properties of bacteria. dGNPs were found to have significant dose dependent antibacterial activity which was directly proportional to their size and also their concentration. The microbial assays revealed the dGNPs to be bacteriostatic as well as bactericidal. The dGNPs exhibited their bactericidal action through the disruption of the …

Monitoring Photocatalytic Degradation Of X-Ray Contrast Media With Raman Spectroscopy, Sabina Salkic

Masters Theses & Specialist Projects

X-ray contrast media such as diatrizoate and iohexol have been found in wastewater and drinking water and are difficult to remove because they are resistant to water treatment processes. A removal process can be started with ultraviolet photocatalytic degradation of X-ray contrast media in the presence of titanium dioxide or other catalysts. Raman spectra of diatrizoate and iohexol were taken in an aqueous solution in the presence and absence of titanium dioxide during exposure to ultraviolet radiation. Raman intensity is directly proportional to concentration; therefore, we can measure the rate of the reaction based on changes in the Raman spectrum. …

Dynamic Scoping For Browser Based Access Control System, Vinaykumar Nadipelly

Masters Theses & Specialist Projects

We have inorganically increased the use of web applications to the point of using them for almost everything and making them an essential part of our everyday lives. As a result, the enhancement of privacy and security policies for the web applications is becoming increasingly essential. The importance and stateless nature of the web infrastructure made the web a preferred target of attacks. The current web access control system is a reason behind the victory of attacks. The current web consists of two major components, the browser and the server, where the effective access control system needs to be implemented. …

Creation Of A Spatial Decision Support System As A Risk Assessment Tool Based On Kentucky Tornado Climatology, Christopher Michael Blinn

Masters Theses & Specialist Projects

Tornadoes are one of Mother Nature’s deadliest phenomena. They affect a large region of the United States. The risk of tornadoes is contingent on dynamic atmospheric conditions that are most likely during spring but which can occur anytime of the year, making the storms challenging to forecast. Using geographical information systems (GIS), a web-based spatial decision support system (SDSS) was created to help understand the spatial dimension of tornado risk assessment. The risk values are calculated using Tornado Days rather than taking a crude density measurement. The SDSS hosts GIS web services that are displayed on an Adobe Flex application. …

Development Of Nabla Fractional Calculus And A New Approach To Data Fitting In Time Dependent Cancer Therapeutic Study, Nihan Acar

Masters Theses & Specialist Projects

The aim of this thesis is to develop discrete fractional models of tumor growth for a given data and to estimate parameters of these models in order to have better data tting. We use discrete nabla fractional calculus because we believe the discrete counterpart of this mathematical theory will give us a better and more accurate outcome.

This thesis consists of ve chapters. In the rst chapter, we give the history of the fractional calculus, and we present some basic de nitions and properties that are used in this theory. We de ne nabla fractional exponential and then nabla fractional …

The Effects Of Goal Setting In A Developmental Algebra Course, Richard Leo Hunt

Masters Theses & Specialist Projects

The purpose of this study was to study the effects of goal setting on students in a developmental algebra course. This study examined the effects on test scores for students that were prescribed a test score goal, students that created their own test score goal, and then compared to a control group. Three classes of developmental algebra were chosen with a total of 25 participants with reported results. Results showed that students with a goal on a test did not score significantly better than students without a goal, but did score significantly better on a test after the goal than …

Racemization Of Amino Acids In Teeth For The Determination Of Age, Andrea Lee Toll

Masters Theses & Specialist Projects

Instrumental to forensic investigations is the ability to identify unknown human remains providing key evidence to criminal cases, resolution to missing persons, and assistance in mass or natural disasters. Identification of remains in an effort to determine age is an area of forensics that has received considerable attention. Traditional methods in age determination such as morphology are often biased, antiquated, and frequently result in a large margin of error. Conversely, the emergence of new forensic techniques provide promise to reduce the margin of error in determining age. One such technique has focused on relating the extent of amino acid racemization …

Continued Radicals And Cantor Sets, Thomas Tyler Clark

Masters Theses & Specialist Projects

We examine the formation of sets homeomorphic to the ternary Cantor set by continued radicals. We determine properties of bridges and gaps and calculate the thickness of the Cantor set. From this we apply information from continued fractions to continued radicals to obtain new results. We also consider the measure of several Cantor sets.

Hybrid Nanostructures For Artificial Machine Olfaction, Landon Joseph Oakes

Masters Theses & Specialist Projects

The detection of low level concentrations of particles in a gaseous environment is of importance to many fields, especially Homeland Security. The ability to identify ppb concentrations of explosives and their degradation products can aid in the detection of improvised explosive devices (IEDs), ammunition dumps, or hidden explosives. One method of accomplishing this task is through the use of an array of chemiresistors in an electronic nose device. For this study, chemiresistors were constructed using 3-D silica nanospring mats with a contiguous film of ZnO nanocrystals and ZnO nanocrystals decorated by metallic nanoparticles. Samples with an average grain size of …

On Nullification Of Knots And Links, Anthony Montemayor

Masters Theses & Specialist Projects

Motivated by the action of XER site-specific recombinase on DNA, this thesis will study the topological properties of a type of local crossing change on oriented knots and links called nullification.

One can define a distance between types of knots and links based on the minimum number of nullification moves necessary to change one to the other. Nullification distances form a class of isotopy invariants for oriented knots and links which may help inform potential reaction pathways for enzyme action on DNA. The minimal number of nullification moves to reach a è-component unlink will be called the è-nullification number.

This …

Dynamic Data Extraction And Data Visualization With Application To The Kentucky Mesonet, Anoop Rao Paidipally

Masters Theses & Specialist Projects

There is a need to integrate large-scale database, high-performance computing engines and geographical information system technologies into a user-friendly web interface as a platform for data visualization and customized statistical analysis. We present some concepts and design ideas regarding dynamic data storage and extraction by making use of open-source computing and mapping technologies. We implemented our methods to the Kentucky Mesonet automated weather mapping workflow. The main components of the work flow includes a web based interface, a robust database and computing infrastructure designed for both general users and power users such as modelers and researchers.

Organizational Search In Email Systems, Sruthi Bhushan Pitla

Masters Theses & Specialist Projects

The storage space for emails has been increasing at a rapid pace day by day. Email systems still serve as very important data repositories for many users to store different kinds of information which they use in their daily activities. Due to the rapidly increasing volume of email data, there is a need to maintain the data in a most efficient way. It is also very important to provide intuitive and flexible search utilities to provide better access to the information in the email repositories, especially in an enterprise or organizational setting. In order to implement the functionality, we are …

Manipulation Of 3d Knotted Polygons, Sairaj Rachamadugu

Masters Theses & Specialist Projects

This thesis discusses the development of software architecture to support the computational investigation of random polygons in 3 space. The random polygons themselves are a simple model of long polymer chains. (A DNA molecule is one example of a polymer.)

This software architecture includes "building blocks" which specify the actual manipulations and computations to be performed, and a structural framework which allows the user to specify which manipulations/computations to perform, in which order and with how many repetitions. The overall framework is designed in such a way that new building blocks can easily be added in the future. The development …

Synthesis, Structure, And Characterization Of Hybrid Solids Containing Polyoxometalates And Ruthenium Polypyridyl Complexes, Yanfen Ll

Masters Theses & Specialist Projects

Polyoxometalates (POMs), which are inorganic metal oxide cluster anions with discrete structures, have been extensively studied in recent years due to their large variety of applications such as medicine, biology, catalysis, material sciences and chemical analysis. Ruthenium polypyridyl complexes have been extensively studied for their applications as photosensitizers in solar energy conversion and photoelectronic materials. Recently, ruthenium heterocyclic ligand complex-based building blocks have been used for the synthesis of hybrid organic-inorganic solids through the self-assembly. We are interested in the synthesis of ruthenium polypyridyl complexes and polyoxometalate anions through different ways such as coordination bonds, hydrogen bonds and ionic bonds …

Ensemble Of Feature Selection Techniques For High Dimensional Data, Sri Harsha Vege

Masters Theses & Specialist Projects

Data mining involves the use of data analysis tools to discover previously unknown, valid patterns and relationships from large amounts of data stored in databases, data warehouses, or other information repositories. Feature selection is an important preprocessing step of data mining that helps increase the predictive performance of a model. The main aim of feature selection is to choose a subset of features with high predictive information and eliminate irrelevant features with little or no predictive information. Using a single feature selection technique may generate local optima.

In this thesis we propose an ensemble approach for feature selection, where multiple …