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Monitoring And Evaluating The Influences Of Class V Injection Wells On Urban Karst Hydrology, James Adam Shelley

Masters Theses & Specialist Projects

The response of a karst aquifer to storm events is often faster and more severe than that of a non-karst aquifer. This distinction is often problematic for planners and municipalities, because karst flooding does not typically occur along perennial water courses; thus, traditional flood management strategies are usually ineffective. The City of Bowling Green (CoBG), Kentucky is a representative example of an area plagued by karst flooding. The CoBG, is an urban karst area (UKA), that uses Class V Injection Wells to lessen the severity of flooding. The overall effectiveness, siting, and flooding impact of Injection Wells in UKA’s is …

Developing A New Sensing Technology For Double-Stranded Dna Detection Utilizing Engineered Zinc Finger Proteins And Nanomaterials, Dat Thinh Ha

Masters Theses & Specialist Projects

A specific double-stranded DNA sensing system is of great interest for diagnostic and other biomedical applications. Zinc finger domains, which recognize double-stranded DNA, can be engineered to form custom DNA-binding proteins for recognition of specific DNA sequences. As a proof of concept, a sequence-enabled reassembly of TEM-1 β- lactamase system (SEER-LAC) was previously demonstrated to develop zinc finger protein (ZFP) arrays for the detection of a double-stranded bacterial DNA sequence. Here, we implemented the SEER-LAC system to demonstrate the direct detection of pathogenspecific DNA sequences present in E. coli O157:H7 on the lab-on-a chip. ZFPs customdesigned to detect shiga toxin …

Indirect Greenhouse Gas Dynamics In Karst Groundwater Systems Under Agricultural Land Use, Stacy Wayne Antle

Masters Theses & Specialist Projects

Greenhouse gases (GHGs) are a major global environmental concern, because their concentrations have continuously increased over the past few centuries, due to global population growth, fossil fuel dependency, and the Industrial Revolution. Since these gases are naturally occurring phenomena, they will never be completely eliminated. Efforts to reduce them span numerous scientific attempts, with minimal improvements in reducing their atmospheric concentrations. In agricultural land practices, greenhouse gases are common byproducts that affect the atmosphere and, potentially, the groundwater where livestock and fertilizers are key contributors. Little is known about the fate of such greenhouse gases in dissolved form, known as …

Controls On Speleogenesis In The Upper-Mississippian Pennington Formation On The Western Cumberland Plateau Escarpment, Hali Steinmann

Masters Theses & Specialist Projects

Much of the pioneering work on caves of the Cumberland Plateau (province spanning Tennessee, Kentucky, Alabama, and Georgia) has been stratigraphically located within the Mississippian Bangor and Monteagle Limestones, wherein some of the region’s largest and most spectacular caves occur. Of interest to the understanding of this karst landscape, but severely underrepresented in the literature thereof, are caves and karst features in a heterogeneous sequence of clastics and carbonates known collectively as the Pennington Formation (Upper Mississippian). This work consisted of a regional study of Pennington caves on the western Cumberland Plateau escarpment (Alabama and Tennessee), and a case study …

Mass-Transport Deposits In The Northern Gulf Of Mexico And Their Implications For Hydrocarbon Exploration, Michael Raymond Arthur

Masters Theses & Specialist Projects

This study investigates Mio-Pliocene mass-transport deposits (MTDs) in an understudied, hydrocarbon-rich region of the northeastern Gulf of Mexico. The research utilizes a high-quality 3D seismic dataset with an area of 635 km2, along with wireline logs and biostratigraphic data. With the help of quantitative seismic geomorphology techniques, detailed mapping of MTDs suggests a complex erosional and depositional history. Deposition of a MTD unit resulted in a 180 m topographic high that substantially influenced the distribution and morphology of subsequent MTDs, specifically the bifurcation of later mass-transport flows. This bifurcation contributed to the generation of a non-shielded erosional remnant with an …

Land-Use Impacts On The Hydrology Of The Hidden River Groundwater Subbasin, Horse Cave, Hart County, Kentucky, Cesalea N. Osborne

Masters Theses & Specialist Projects

No abstract provided.

Synthesis Of A Platinum Triamine Complex And Its Interactions With Guanosine 5’- Monophosphate And N-Acetylmethionine, Manal El Masri

Masters Theses & Specialist Projects

Cisplatin (cis-diamminedichloroplatinum(II)) and its analogs are known to form 1,2-intrastrand cross-links with guanine bases that lead to DNA distortion and are responsible for cytotoxicity. Reaction with proteins, especially at methionine residues, could also be responsible for cytotoxicity (Sandlin, R. D. et al. 2010). A new tridentate platinum(II) complex with a piperazine ring was successfully designed and synthesized. In this complex, the platinum is coordinating to all three nitrogens of (1,2- dimethylaminoethylpiperazine), which makes it a Platinum triamine compound. A series of chemical reactions of this compound with guanosine 5’-monophosphate (5’-GMP) and N-acetylmethionine (N-AcMet) were conducted under different conditions. Reactions with …

Unroofing History Of The Northwestern Ethiopian Plateau: Insights From Low-Temperature Apatite Thermochronology, Shelby Bowden

Masters Theses & Specialist Projects

The geology of Ethiopia is dominated by the Ethiopian Plateau that is similar in elevation to, but aerially larger than, the Colorado Plateau. Several rivers have incised through the plateau, creating gorges that reach up to 1.5 km in depth. The plateau uplifted to its current elevation and was subsequently incised sometime after the Oligocene flood basalt event that signaled the arrival of the African Superplume below Kenya and Ethiopia. Due to its size and extent, published climate modeling has indicated that Late Cenozoic plateau formation could have been a driving force in the East African Cenozoic climate changes. Although …

Exploring The Effect Of Different Numbers Of Convolutional Filters And Training Loops On The Performance Of Alphazero, Jared Prince

Masters Theses & Specialist Projects

In this work, the algorithm used by AlphaZero is adapted for dots and boxes, a two-player game. This algorithm is explored using different numbers of convolutional filters and training loops, in order to better understand the effect these parameters have on the learning of the player. Different board sizes are also tested to compare these parameters in relation to game complexity. AlphaZero originated as a Go player using an algorithm which combines Monte Carlo tree search and convolutional neural networks. This novel approach, integrating a reinforcement learning method previously applied to Go (MCTS) with a supervised learning method (neural networks) …

Synthesis And Characterization Of Graphene-Family Mesoporous Nanomaterials For Themal Energy Harvesting And Sensing Applications, Romney Meek

Masters Theses & Specialist Projects

Graphene-family nanomaterials (GFNs) have attracted a great deal of attention both in academia and in industry for a range of applications relevant for homeland security. In this thesis, an array of graphene-based hybrid materials and aerogels are synthesized for use as novel thermo-electrochemical energy harvesters and for ascorbic acid biosensing devices. The graphene-family nanomaterials include graphene oxide-GO, thermally reduced GO-rGOth, nitrogenated functionalized graphene-NFG, graphene aerogel-GA, nitrogen-doped graphene aerogel-NGA, multi-walled carbon nanotube aerogel-MWCNT, single-walled carbon nanotube aerogel-SWCNT, graphene and nanotube combined ‘hybrid’ aerogels-Gr:(SW/MW)CNT of various ratios, along with multilayered nanostructured architectures such as gold (AuNP) and silver nanoparticles (AgNP) decorated NFG …

Photochemical Investigation Of High-Valent Metal-Oxo Intermediates Containing Corrole And Light-Harvesting Porphyrin Ligands, Jonathan Malone

Masters Theses & Specialist Projects

In enzymatic and synthetic catalytic oxidations, high-valent iron-oxo intermediates play a vital role as the active oxidant. In this regard, many synthetic metal catalysts are designed as biomimetic models to resemble the active site of Cytochrome P450 enzymes (P450) which are the predominant oxidation catalysts in nature. Vitamin B12 cofactors, with a corrole-like structure corrin, are also utilized in some of the more difficult reactions in nature such as rearrangement and reductase reactions.

In this work, application of the promising photochemical method to corrolecontaining ligands systems showed much success in the generation of manganese(V)-oxo corrole intermediates using two electron-deficient corrole …

Characterization Of Eight Potentially Hazardous Near Earth Asteroids: Rotation Period Analysis And Structure Modeling Via Light Curve Inversion Techniques, Stacy Jo Hicks

Masters Theses & Specialist Projects

The term “homeland security”, seems to have become synonymous with terrorism in the minds of the general public. However, there are other threats to the security of the United States homeland that can be just as, if not more, devastating than terrorism. Included among these other threats is the potential of an asteroid collision with Earth. Historically, asteroid impact events have been responsible for the devastation of our planet and many of the mass extinction events encountered throughout the geologic record. Knowledge of physical parameters such as structure and rotational dynamics of the asteroid are critical parameters in developing interception …

Molecular Assembly Of Monolayer-Protected Gold Nanoparticles And Their Chemical, Thermal, And Ultrasonic Stabilities, Steven Ray Isaacs

Masters Theses & Specialist Projects

Gold monolayer-protected nanoclusters (MPCs) with average diameters of 1-5 nm protected by alkane- and arenethiolates were synthesized. Mixed-monolayer protected nanoparticles (MMPCs) were prepared by functionalizing hexanethiolate-protected MPCs with either 11-mercaptoundecanoic acid (MUA-MMPC), 11-mercaptoundecanol (MUO-MMPC), or 4-aminothiophenol (ATP-MMPC) using ligand place exchange. Presentation of various chemical reagents such as nucleophile, acid, or base and change in physical environment through ultrasonic and thermal irradiation resulted in changes to particles and their physical properties. Thermogravimetric analysis (TGA) was used to measure maximum temperature of the derivated thermogravimetric peaks (Tmax,DTG) as a means of comparing temperature dependence of mass loss. The absorption spectrum within …

Investigations Of Biotremors In The Veiled Chameleon (Chamaeleo Calyptratus), Kathryn C. Laslie

Masters Theses & Specialist Projects

While substrate-borne vibrations are utilized by different reptile species, true conspecific communication via biotremors has not yet been demonstrated in reptiles. This study follows a preliminary report that the veiled chameleon (Chamaeleo calyptratus) could produce biotremors in communicative contexts. I tested chameleon behavioral sensitivity to vibrations by placing them on a dowel attached to a shaker emitting vibrations of 25, 50, 150, 300, and 600 Hz and then measured their changes in velocity before and after the stimulus. I then paired chameleons in various social contexts [anthropogenic disturbance (human disruption of animal); dominance (malemale; female-female C. calyptratus); courtship (male-female C. …

Laser-Induced Recoverable Surface Patterning On Ni50ti50 Shape Memory Alloys, Saidjafarzoda Ilhom

Masters Theses & Specialist Projects

Shape memory alloys (SMAs) are a unique class of smart materials exhibiting extraordinary properties with a wide range of applications in engineering, biomedical, and aerospace technologies. In this study, an advanced, efficient, low-cost, and highly scalable laser-assisted imprinting method with low environmental impact to create thermally controllable surface patterns is reported. Two different imprinting methods were carried out mainly on Ni50Ti50 (at. %) SMAs by using a nanosecond pulsed Nd:YAG laser operating at 1064 nm wavelength and 10 Hz frequency. First, laser pulses at selected fluences were directly focused on the NiTi surface, which generated pressure pulses of up to …

Using Mobile Eye-Tracking To Inform The Development Of Mass Tourism In Iceland Towards The Principles Of Ecotourism, James Tyler Graham

Masters Theses & Specialist Projects

Since the late 20th century, nature-based tourism, an alternative to mass tourism with a focus on natural environments, has steadily grown in popularity. Nature-based tourism areas are considered a platform for informal education and exemplify principles of environmental stewardship and conservation. Iceland, an island nation in the North Atlantic, is one area of the world that has seen dramatic growth in its nature-based tourism industry in recent years; tourists are drawn to Iceland in numbers five times the total population of the Country. The pressures of economic development have resulted in the continued promotion of Icelandic tourism, and, subsequently, the …

Visible Light Generation Of High-Valent Corrole-Manganese(V)-Oxo Intermediates And Biomimetic Studies Of The Oxidation Of Organic Sulfides Catalyzed By Manganese Corroles With Iodobenzene Diacetate, Davis Ray Ranburger

Masters Theses & Specialist Projects

High-valent transition metal-oxo intermediates play essential roles as active oxidizing species in enzymatic and biomimetic catalytic systems. Extensive research has been conducted on a variety of transition metal catalysts being studied as models for the ubiquitous cytochrome P450 enzymes. In doing so, the production of enzyme-like oxidation catalysts and probing studies on the sophisticated oxygen atom transfer mechanism are taking place.

In this work, visible-light irradiation of highly-photo-labile corrole-manganese(IV) bromates and chlorates was studied in two corrole systems with differing electronic environments, i.e. 5,10,15-trisphenylcorrole (H3TPC) and 5,10,15- tris(pentafluorophenyl)corrole (H3TPFC). In both systems, homolytic cleavage of the O- …

A Climatology Of Convective And Non-Convective High-Wind Events Across The Eastern United States During 1973-2015, Victoria Murley

Masters Theses & Specialist Projects

High-wind events (HWE) occur across every region of the United States (U.S.) and result in hundreds of fatalities, as well as thousands of dollars in damages annually. HWEs are classified as sustained high-winds or high-wind gusts and can be generated from convective or non-convective weather systems. This study investigates high-wind observations across the eastern U.S. during a 43-year climatological period (1973-2015) for spatial and temporal variations in wind speed and direction. Hourly surface wind observations were gathered from the National Centers for Environmental Information Data Center Integrated Surface Database (NCEI-ISD). This dataset includes qualitycontrolled wind observations from 391 first-order weather …

An Evaluation Of Deterrent Methods Utilized To Prevent Crop Raiding By African Elephants (Loxodonta Africana) In The Kasigau Wildlife Corridor, Kenya, Rebecca Lynn Von Hagen

Masters Theses & Specialist Projects

Escalating human elephant conflict (HEC) continues to be a contributing factor

towards elephant decline, and crop raiding is the most common form of negative

human-elephant interactions. For communities that cannot reverse or prevent crop

raiding, it is necessary to contain HEC events through deterrent measures. Few

deterrent measures exist that combine practicality and affordability while also

preventing habituation by elephants. This project focused on comparing the efficacy of

deterrent methods to assess which was the most successful at preventing elephants

from entering crops in the farming community of Sasenyi, Kenya. In this paired-control

study, four deterrent methods were evaluated: acacia …

Application Of Huffman Data Compression Algorithm In Hashing Computation, Lakshmi Narasimha Devulapalli Venkata,

Masters Theses & Specialist Projects

Cryptography is the art of protecting information by encrypting the original message into an unreadable format. A cryptographic hash function is a hash function which takes an arbitrary length of the text message as input and converts that text into a fixed length of encrypted characters which is infeasible to invert. The values returned by the hash function are called as the message digest or simply hash values. Because of its versatility, hash functions are used in many applications such as message authentication, digital signatures, and password hashing [Thomsen and Knudsen, 2005].

The purpose of this study is to apply …

An Integration Setup If The In-Situ Mass And Spectroscopic Analysis For Volatile Liquids Or Solids, Kolton K. Jones

Masters Theses & Specialist Projects

To help address the growing need for more and better sensors, an attempt was made to produce an in-situ mass and spectroscopic analysis of liquid and solid samples, to characterize samples and sensors. Spectroscopic analysis consisted of Raman and FTIR where mass measurements were carried out. The sample or sensor’s holder would allow for spectroscopic analysis as well as expose the sample to high temperatures and various chemicals. While Raman and FTIR were successful in producing reliable and consistent data, the constructed watt balance was not. This failure was a result of eliminate vibrational noise.

Policy Communication And The Influence Of Agricultural Communities On Karst Landscapes: A Case Study In Phong Nha-Kẻ Bàng National Park, Vietnam, Elizabeth Willenbrink

Masters Theses & Specialist Projects

Karst landscapes are vulnerable to human influence, especially agricultural practices. The interconnectedness between surface activities and subsurface environments make karst landscapes particularly susceptible to soil erosion and water contamination. The likelihood of these two phenomena happening increases when agricultural intensification, irrigation, or fertilizer application occurs. This situation arises frequently in Vietnam, where 18% of the country is karst terrain and 60% of the population depends on agriculture for their livelihoods (Farming First 2009). In order to mitigate the negative consequences of agriculture on karst landscapes, effective implementation of policy to regulate human activities and increased communication of these policies to …

Biomimetic Studies Of Oxidation Reactions By Metalloporphyrins Through Ligand Effect And Kinetic Studies Of Photo-Generated Porphyrin-Iron(Iv)- Oxocompound Ii Models, Dharmesh J. Patel

Masters Theses & Specialist Projects

High-valent iron(IV)-oxo porphyrins are the central oxidizing species in hemecontaining enzymes and synthetic oxidation catalysts. Many transition metal complexes have been extensively studied as models of the ubiquitous cytochrome P450 enzymes to probe the sophisticated oxygen atom transfer (OAT) mechanism as well as to invent enzyme-like oxidation catalysts. In this work, two metalloporphyrin complexes have been successfully synthesized, and spectroscopically characterized. A new photochemical entry to porphyrin-iron(IV)-oxo derivatives, commonly referred to as compound II models, was also investigated in two porphyrin ligands that differ in electronic and steric environments. As determined by their distinct UV-vis spectra and kinetic behaviors, iron(IV)-oxo …

Cayley Graphs Of Psl(2) Over Finite Commutative Rings, Kathleen Bell

Masters Theses & Specialist Projects

Hadwiger's conjecture is one of the deepest open questions in graph theory, and Cayley graphs are an applicable and useful subtopic of algebra.

Chapter 1 will introduce Hadwiger's conjecture and Cayley graphs, providing a summary of background information on those topics, and continuing by introducing our problem. Chapter 2 will provide necessary definitions. Chapter 3 will give a brief survey of background information and of the existing literature on Hadwiger's conjecture, Hamiltonicity, and the isoperimetric number; in this chapter we will explore what cases are already shown and what the most recent results are. Chapter 4 will give our decomposition …

Imidazolium Ionic Liquids As Multifunctional Solvents, Ligands, And Reducing Agents For Noble Metal Deposition Onto Well-Defined Heterostructures And The Effect Of Synthetic History On Catalytic Performance, Michael Drake Ballentine

Masters Theses & Specialist Projects

1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([BMIM]Tf2N) was investigated as a multifunctional solvent, ligand, and reducing agent for platinum deposition onto well-defined CdSe@CdS nanorods. Platinum deposition was carried out thermally and photochemically using Pt(acac)2 as the metal precursor. Thermal deposition was investigated in [BMIM]Tf2N with and without addition of a sacrificial reducing agent, and product topology was compared with the products obtained from polyol reduction using 1,2-hexadecanediol, oleic acid, and oleylamine in diphenyl ether. Photochemically induced platinum deposition was carried out at room temperature in [BMIM]Tf2N, and product topology was compared with the photodeposition products obtained from a toluene dispersion. Thermal deposition of platinum …

The Influence Of A Proposed Margin Criterion On The Accuracy Of Parallel Analysis In Conditions Engendering Underextraction, Justin M. Jones

Masters Theses & Specialist Projects

One of the most important decisions to make when performing an exploratory factor or principal component analysis regards the number of factors to retain. Parallel analysis is considered to be the best course of action in these circumstances as it consistently outperforms other factor extraction methods (Zwick & Velicer, 1986). Even so, parallel analysis could benefit from further research and refinement to improve its accuracy. Characteristics such as factor loadings, correlations between factors, and number of variables per factor all have been shown to adversely impact the effectiveness of parallel analysis as a means of identifying the number of factors …

Score Test And Likelihood Ratio Test For Zero-Inflated Binomial Distribution And Geometric Distribution, Xiaogang Dai

Masters Theses & Specialist Projects

The main purpose of this thesis is to compare the performance of the score test and the likelihood ratio test by computing type I errors and type II errors when the tests are applied to the geometric distribution and inflated binomial distribution. We first derive test statistics of the score test and the likelihood ratio test for both distributions. We then use the software package R to perform a simulation to study the behavior of the two tests. We derive the R codes to calculate the two types of error for each distribution. We create lots of samples to approximate …

Carbon Flux And Weathering Processes In Icelandic Glacial-Fed Rivers, Allison Quiroga

Masters Theses & Specialist Projects

An investigation into the carbon dynamics and weathering processes occurring in Icelandic glacial-fed streams was conducted during the spring to summer seasonal transition in June of 2017. Four major outlet rives were sampled from the glaciers of Gígjökull, Steinsholtsjökull, Sólheimajökull, and Falljökull. Markarfljót, the major river that Gígjökull, Steinsholtsjökull, and many other glaciers drain into, was also sampled. Longitudinal sampling occurred at all sites to capture downstream trends in the hydrogeochemistry and carbon dynamics. Distinct differences in geochemistry between glacier surface meltwater, sub-glacial waters, pro-glacial lake water, and post-mixed downstream samples were evident in the data. Glacier surface streams were …

Investigating The Influence Of Esri Story Map Design On Partcipation In Sustainability-Related Activities, Brittany Grace Austin

Masters Theses & Specialist Projects

Decades of scientific inquiry have conveyed evidence in support of sustainability efforts to mitigate some of the greatest challenges and dilemmas facing modern and future societies. The solutions to these dilemmas may not be achievable in the short-term, yet, through increased public participation in sustainable community development, smallscale, localized solutions can be obtained. This preliminary research explored the influence of Environmental Systems Research Institute (Esri) story map designs on participation in sustainability-related activities among individuals who expressed interest in sustainable lifestyles. Specifically, this exploratory study was designed to demonstrate the applicability of interactive web geographic information systems (GIS) applications as …

Foutier Transform Infrared Spectroscopy Instrumentation And Integration With Thermogravimetry, Junjie Xiang

Masters Theses & Specialist Projects

To discover the potential of IR spectroscopy and explore the details of FTIR instrumentation, a FTIR was built from most basic parts to provide access to every aspect of a IR spectrometer including the hardware and software. The optical system followed the most widely used double-interferometer design. The software control system was developed with LabVIEW to perform data acquisition of the detectors, data processing and controls of the actuators. The FTIR built will be able to provide a full optical IR spectroscopy platform which has a complete control and data acquisition system and can be continuously improved in accuracy and …