Other Chemical Engineering Commons^™

Study Level Design Of Thorium Oxide Production, Dylan G. Chitwood, Drake Crawford, Chase Toth

Chancellor’s Honors Program Projects

No abstract provided.

Extraction Of Thorium Oxide From Monazite Ore, Makalee Ruch, Chloe Frame, Molly Landon, Ralph Laurel, Annabelle Large

Chancellor’s Honors Program Projects

No abstract provided.

Using Green Emitting Ph-Responsive Nanogels To Report Environmental Changes Within Hydrogels: A Nanoprobe For Versatile Sensing, Mingning Zhu, Dongdong Lu, Shanglin Wu, Qing Lian, Wenkai Wang, L. Andrew Lyon, Weiguang Wang, Paulo Bártolo, Brian R. Saunders

Engineering Faculty Articles and Research

Remotely reporting the local environment within hydrogels using inexpensive laboratory techniques has excellent potential to improve our understanding of the nanometer-scale changes that cause macroscopic swelling or deswelling. Whilst photoluminescence (PL) spectroscopy is a popular method for such studies this approach commonly requires bespoke and time-consuming synthesis to attach fluorophores which may leave toxic residues. A promising and more versatile alternative is to use a pre-formed nanogel probe that contains a donor/acceptor pair and then “dope” that into the gel during gel assembly. Here, we introduce green-emitting methacrylic acid-based nanogel probe particles and use them to report the local environment …

Effect Of Coagulant Recycling On Chemically Enhanced Primary Treatment Performance, Tulip Chakraborty

Electronic Thesis and Dissertation Repository

Chemically enhanced primary treatment (CEPT) process is a promising method for carbon redirection and improving the performance and efficiency of wastewater treatment processes. CEPT is employed to precipitate colloidal and suspended matter from wastewater; however, this requires a significant amount of coagulant and produces large volumes of sludge. Coagulant recovery (CR) from the precipitated sludge has the potential to reduce sludge quantities, associated costs for disposal of sludge, cost of dosing fresh coagulant by regenerating and purifying the coagulant before reuse. This research was conducted to understand the feasibility and implications of CR in municipal wastewater.

In order to evaluate …

Nanogels And Microgels: From Model Colloids To Applications, Recent Developments, And Future Trends, Mattias Karg, Andrij Pich, Thomas Hellweg, Todd Hoare, L. Andrew Lyon, J. J. Crassous, Daisuke Suzuki, Rustam A. Gumerov, Stefanie Schneider, Igor I. Potemkin, Walter Richtering

Engineering Faculty Articles and Research

Nanogels and microgels are soft, deformable, and penetrable objects with an internal gel-like structure that is swollen by the dispersing solvent. Their softness and the potential to respond to external stimuli like temperature, pressure, pH, ionic strength, and different analytes make them interesting as soft model systems in fundamental research as well as for a broad range of applications, in particular in the field of biological applications. Recent tremendous developments in their synthesis open access to systems with complex architectures and compositions allowing for tailoring microgels with specific properties. At the same time state-of-the-art theoretical and simulation approaches offer deeper …

Iron-Containing Nanoparticles For The Treatment Of Chrionic Biofilm Infections In Cystic Fibrosis, Leisha M. A. Martin

Nanoscience and Microsystems ETDs

Cystic fibrosis (CF) is the most common genetic disease resulting in the morbidity and mortality of Caucasian children and adults worldwide. Due to a genetic mutation resulting in malfunction of the Cystic Fibrosis Transmembrane Conductance Regulator (CFTR) protein, CF patients produce highly viscous mucus in their respiratory tract. This leads to impairment of the mucociliary clearance of inhaled microbes. In addition to reduced microbial clearance, anoxic environmental conditions in the lungs promote biofilm-mode growth of the pathogenic bacterial species Pseudomonas aeruginosa. Chronic infections of P. aeruginosa begin in early childhood and typically persist until respiratory failure and death result. The …

Hazard And Operability Analysis Of An Ethylene Oxide Production Plant, Samantha Ciricillo

Senior Theses

The purpose of this work was to evaluate potential hazards and failures as part of the design and economic analysis for a chemical plant that would produce 150,000 tons of ethylene oxide per year. The Hazard and Operability (HAZOP) method of analysis was used to accomplish this goal. This method of hazard analysis involves brainstorming potential errors in a system by examining each element of each process unit in full detail. This project was focused on the reactor unit because the reactor has several important parameters that could fail, resulting in safety issues within the system. Input for this analysis …

Improving The Distribution And Use Of Biogas By Conversion To Methanol, Zachary Christman

Department of Agronomy and Horticulture: Dissertations, Theses, and Student Research

In this technology review, the process of turning an average biogas into methanol will be presented. The purpose is to find a better method of transporting the energy contained within biogas so that it may be used in industry as a value added product. The first step is removal of hydrogen sulfide, a corrosive chemical that can breakdown mechanical parts. The second step is carbon capture and conversion of the biogas into hydrogen. The final step is the hydrogenation of carbon dioxide into methanol using a copper catalyst and an alcohol co-catalyst.

Analysis And Control Of Aluminum Concentration In Groundwater: Mathematical Modelling And Laboratory Study, Daria Popugaeva

Electronic Thesis and Dissertation Repository

The remediation of metal-contaminated natural water bodies is prioritized due to metals toxicity, non-biodegradable properties, and accumulative behaviours leading to the increased incidence of adverse health effects. Current investigation is driven by the existing problem of elevated aluminum concentrations in the groundwater of Khibiny alkaline massif (Kola Peninsula). The prohibitive aluminum level exceeding the accepted standard of 0.20 mg L⁻¹ is described as a serious health concern when the groundwater used for the local water supply. The results of comprehensive field data analysis based on chemometric methods applied to the available monitoring data including 12 groundwater quality parameters are …

Using Fluorescence Spectroscopy To Determine Concentrations Of Quantum Dot Solutions, Cameron Sawyer

Summer Community of Scholars Posters (RCEU and HCR Combined Programs)

No abstract provided.

Electrochemical Properties Of Crystalline Polymorphs Of Mno2 In Aluminum And Zinc Metal Batteries, Subhadip Pal

Dissertations and Theses

The widespread use of non-renewable fossil fuels has led to societal problems like global warming and climate change. Electrochemical energy storage can enable the integration of renewable energy sources that are inherently intermittent (solar, wind, etc.) into the electric grid, though major advances in cost, cycle life, and safety are necessary to have a global impact on the energy landscape. Both aluminium (Al) and zinc (Zn) metals are earth abundant, low-cost, safe, and exhibit high coulombic capacities, which make them promising electrode materials for “beyond lithium-ion” battery chemistries. However, the electrochemical feasibility and charge storage mechanisms of alternative Al and …

Prevention Of Harmful Algal Blooms By The Mitigation Of Phosphorus Nutrient Loading Via Filtration By Steel Wool And Activated Carbon, Ronald Simpson, Sara Kidd, Samantha Zidd

Williams Honors College, Honors Research Projects

Harmful Algal Blooms (HABs) are a devastating ecological and economic consequence of the abundance of nutrient-rich agricultural runoff entering aquatic ecosystems (Baker et al. 2014). Bio-available phosphorus from synthetic fertilizers is one of the major nutrients contributing to this global issue. Previous studies indicated that dissolved phosphorus can be removed from an aqueous environment when passed through a composite mixture of granular steel wool particles and activated carbon (Erickson, Gulliver, and Weiss, 2007). In this project, we conducted experiments using higher quality concentration measurements to determine what grades of steel wool (SW-0000, SW-000, SW-00) and types of activated carbon (granulated …

Investigation Of The Synthesis And Optoelectronic Properties Of Ultrasmall Cdse Quantum Dots, Megan Webster

Dissertations and Theses

Traditional, or 1^st generation, solar cells have a theoretical upper limit of 33% power conversion efficiency based on the thermodynamic limitation of the single p-n junction cell design. This limitation is known as the Shockley-Queisser limit and methods to design solar cells to circumvent it have been creative, with a significant part of the field focused on quantum dot (QD) based systems. With theoretical efficiencies ranging between 44 and 67% for one sun concentration, QD solar cell designs are clearly superior to the limits of 1^st generation solar cells. However, maximum achieved efficiencies for QD-based designs are far …

Novel Adsorbent For Industrial Wastewater Treatment Applications, Islam M. Al-Akraa, Ahmed Y. Zakaria Eng, Dalia A. Ali Eng, Hany A. Elazab Dr, Hoda A. Elsawy Dr

Chemical Engineering

In this study, the hydroxyapatite powder is investigated for both of methylene blue and thymol blue in aqueous solution. The physical and chemical properties of the adsorbent were evaluated systematically using the different techniques including Microsoft Excel programming, linear regression model and also the coefficient of determination. Batch adsorption experiments were conducted to determine the effect of contact time, solution pH, initial dye concentrations, and also the adsorbent dosage on adsorption. The adsorption kinetic parameters confirmed the better fitting of pseudo-second order kinetic model for both of methylene blue and thymol blue. The isotherm data of methylene blue and thymol …

New Method Of Manufacturing Carbon Foam, Matthew D. Artimez

Graduate Theses, Dissertations, and Problem Reports

Carbon foam is a product that has some unique features. Carbon foam is a light weight material that has a high crush strength. It is electrically conductive, but because it is composed of air space between the tendrils, it is not a thermal conductor. Since it contains no volatile content, it is noncombustible. All these features allow carbon foam to have many modern applications. Currently, there are only three methods of producing carbon foam, and all three are not cost- efficient enough to meet the demand of potential new markets.

In this thesis, a new procedure of producing carbon foam …

Design Of Geothermal District Heating And Cooling System For The West Virginia University, Oluwasogo Bolaji Alonge

Graduate Theses, Dissertations, and Problem Reports

Recent Appalachian Basin Geothermal Play Fairway Analysis estimated elevated heat flows in north-central West Virginia. This region provides an optimal and unique combination of elevated temperatures and flow necessary for geothermal development along with year-round surface demand for heating and cooling on the campus. Therefore, West Virginia University’s (WVU’s) Morgantown campus has been identified as a prime location in the eastern United States for the development of a geothermal direct-use heating and cooling application. The objective of this study was to perform a feasibility analysis for the development of a geothermal district heating and cooling (GDHC) system for WVU campus …

Improving The Delivered Specific Impulse Of Composite Rocket Propellant Through Alteration Of Chemical Composition: Methodology And Parameters For Characterization Of Propellant And Validation Of Simulation Software Common To The Amateur Rocketry Community, Isaac O'Brien, Austin Ryan

Williams Honors College, Honors Research Projects

In this study, two solid composite rocket propellants were designed utilizing ProPEP, a rocket propellant formulation software common in the amateur and hobby rocketry communities. The two propellants were designed to optimize specific impulse relative to a literature propellant designed by 1020 Research Labs. The literature propellant was also tested in order to validate the design of experiment as well as the mixing and testing procedures. All three propellants, which includes the literature propellant RCS-P, and the two novel propellants AKR-P1 and AKR-P2 were characterized with static tests. The results of the static tests provide data on propellant performance and …

Cataloging The Degree Of Sensitization Via Electrochemical Reactivation For Studying The Corrosion Behavior Of Inconel 718, Austenitic, And Duplex Stainless Steels, Bradley Lynes

Williams Honors College, Honors Research Projects

Corrosion resistant materials can be expensive, but usually reduce the life cycle cost of metallic assets. However, negligent sensitization of these materials can lead to aggressive, intergranular corrosion. Using the methodology of the double loop electrochemical potentiokinetic reactivation (DL-EPR), this project investigates different steel reinforced bars and Inconel to determine the degree of sensitization after a heat treatment of 900°C for 2 hours. The purpose of this research is to validate and determine the appropriate test parameters for performing further DL-EPR test in the future. Additionally, the kinetics observed for each sample during the DL-EPR test will be analyzed and …

Understanding Effects Of Engineering Outreach On Elementary Students, Thomas Cobb

Williams Honors College, Honors Research Projects

Currently, there is a desire to increase engineering understanding held by elementary students. As such, there needs to be a way to stimulate not only engineering, but other science, technology, engineering, and mathematics (STEM) topics in a young student’s lifestyle. One way to emphasize the importance of STEM while also showing how fun it can be is through different hands on activities led by individuals partaking in undergraduate studies or the industry. While having the students participate in the activities, it is important to understand what the students are learning and how the activity overall is viewed. With the help …

Form Stable Phase-Change Materials, Russell Dent, Marjan Kashfipour, Nitin Mehra, Jiahua Zhu

Williams Honors College, Honors Research Projects

This work investigates the use of two different polyols, xylitol (Xyl) and erythritol (Ery), in conjunction with boron nitride (BN) aerogels, for the purpose of creating thermally conductive composites. While the BN filler in Xyl composites achieved a high anisotropic thermal conductivity of up to 4.53 W/m-K at 18.2 weight percent filler loading, they do not exhibit good phase-change material qualities due to a low solidification enthalpy even at low cooling rates. Alternatively, the BN-Ery composites have shown promising results with a solidification enthalpy of 225.14 J/g and a melting enthalpy of 385.84 J/g at a heat rate of 5 …