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Thermal Effects On The Voc-Sensitive Polydimethylsiloxane Holographic Gratings, Aleksandra Hernik, Faolan Radford McGovern, Patrick Iftime, Izabela Naydenova 2024 Technological University Dublin, Ireland

Thermal Effects On The Voc-Sensitive Polydimethylsiloxane Holographic Gratings, Aleksandra Hernik, Faolan Radford Mcgovern, Patrick Iftime, Izabela Naydenova

Conference Papers

The imperative for monitoring volatile organic compounds (VOCs) emerges from their harmful impact on human health when inhaled excessively over a long term. Polydimethylsiloxane (PDMS), valued for its transparency and excellent flexibility, has already been demonstrated as a promising biocompatible and cost-effective transducer for optical VOCs sensing. Moreover, it facilitates further functionalisation with adsorbing materials to enhance sensitivity and selectivity for specific VOCs detection. We fabricated and examined PDMS-based surface diffraction gratings after exposure to selected VOCs, demonstrating different response for polar and non-polar molecules. Investigated gratings were prepared by replicating sinusoidal surface relief structures inscribed in acrylamide photopolymer using …


Investigation Of The Uv-Resistance Of Photopolymerisable Glass For Space Applications, Luca Sorridente, Tatsiana Mikulchyk, Izabela Naydenova, Kevin Murphy 2024 Technological University Dublin

Investigation Of The Uv-Resistance Of Photopolymerisable Glass For Space Applications, Luca Sorridente, Tatsiana Mikulchyk, Izabela Naydenova, Kevin Murphy

Articles

The progress of space based scientific research leads to an increasing demand for more efficient and less bulky instruments. Conventional refractive elements make up a critical part of many optical instruments launched into space; however, they can be bulky and heavy. Holographic optical elements are an efficient alternative to replace the conventional optical elements as they are lightweight and can be miniaturized. Current materials typically used for volume holographic optical elements are not robust enough for use in space environment. Recently a promising photopolymerisable glass has been developed using a sol-gel technique, which can provide dry layers suitable for holographic …


Photopolymer Material Durability And Safety In Holographic Diffusers For Visual Applications, Matthew Hellis, Alan Casey, Edoardo Splendi, Suzanne Martin, Matthew Sheehan, Kevin Murphy 2024 Technological University Dublin

Photopolymer Material Durability And Safety In Holographic Diffusers For Visual Applications, Matthew Hellis, Alan Casey, Edoardo Splendi, Suzanne Martin, Matthew Sheehan, Kevin Murphy

Articles

This study introduces novel holographic diffuser applications employing acrylamide- or diacetone acrylamide-based photopolymers, patterned within the volume on a micron scale by a single-beam holographic recording process. These diffusers have previously been presented as potential treatments for amblyopia and diplopia. This work has now been extended to spectrometric analysis to determine their properties under broadband light. Diffusive elements with higher diffusion efficiencies exhibited a marginal reduction (< 5%) in diffusion efficiency across most of the visible spectrum. Given the intended application of these holographic diffusers, cytotoxicity assessments were also performed. This is significant as there is a difference in toxicity between the crystalline acrylamide (classified as a category 3 material) and diacetone acrylamide (classified as a category 4 material). The findings indicated substantially lower toxicity in holograms produced with diacetone acrylamide-based photopolymer. The accelerated ageing of both formulations of holographic diffusers indicated that the acrylamide-based holographic diffusers did not reduce efficacy in the 292 days of ageing. The diacetone acrylamide-based holographic diffusers exhibited reduced efficacy by day 182. Despite this, both formulations have been shown to perform for prolonged periods as the treatment modality would require. These results emphasise that holographic diffusers exhibit minimal spectral impact, and longevity on the scale of treatment regimes which are crucial considerations for their prospective use case as treatments for amblyopia and diplopia.


Bridging The Geometric And Quantum Information Of Structured Light, Andrew Alexander Voitiv 2024 University of Denver

Bridging The Geometric And Quantum Information Of Structured Light, Andrew Alexander Voitiv

Electronic Theses and Dissertations

In this Dissertation, we review the several advances we have developed for preparing and measuring the geometric and quantum information of structured light. The geometric phase acts as a memory of transformations undertaken by physical processes; quantum entanglement underpins quantum information science which explores the theoretical and technological applications of nonclassical correlations. Beginning with classical light, we demonstrate novel experiments and measurements of geometric phase that are enabled by spatially structuring laser beams. We then extend those concepts to complement the richer possibilities within quantum optics. Our work covers new abilities in tailoring and measuring the phase content of spatially-structured …


Single-Molecule Orientation Imaging Reveals The Nano-Architecture Of Amyloid Fibrils Undergoing Growth And Decay, Brian Sun, Tianben Ding, Weiyan Zhou, Tara S. Porter, Matthew D. Lew 2024 Washington University in St. Louis

Single-Molecule Orientation Imaging Reveals The Nano-Architecture Of Amyloid Fibrils Undergoing Growth And Decay, Brian Sun, Tianben Ding, Weiyan Zhou, Tara S. Porter, Matthew D. Lew

Electrical & Systems Engineering Publications and Presentations

Amyloid-beta (Aβ42) aggregates are characteristic Alzheimer’s disease signatures, but probing how their nanoscale architectures influence their growth and decay remains challenging using current technologies. Here, we apply time-lapse single-molecule orientation-localization microscopy (SMOLM) to measure the orientations and rotational “wobble” of Nile blue (NB) molecules transiently binding to Aβ42 fibrils. We correlate fibril architectures measured by SMOLM with their growth and decay over the course of 5 to 20 min visualized by single-molecule localization microscopy (SMLM). We discover that stable Aβ42 fibrils tend to be well-ordered and signified by well-aligned NB orientations and small wobble. SMOLM also shows that increasing order …


Modeling Redistribution Of Nanozeolites In Holographic Recording, Dana Mackey, Jack Lyons Dr, Izabela Naydenova 2024 Technological University Dublin

Modeling Redistribution Of Nanozeolites In Holographic Recording, Dana Mackey, Jack Lyons Dr, Izabela Naydenova

Articles

Zeolite doped photopolymers have been studied experimentally due to their potential application in the develop- ment of optical sensors. It has been shown that dopant redistribution can be achieved by holographic recording and has a direct influence on the sensitivity of the recorded grating. To achieve better theoretical understanding of these processes, this paper proposes an extended photopolymerization-diffusion mathematical model for describing the dynamics of nanozeolite redistribution during recording in an acrylamide-based photopolymer. Using numerical simulations of this model, we investigate how recording conditions, dopant transport parameters, and initial load affect the refractive index modulation of the resulting photonic structure.


Focused Led Sintering, Dylan DeFazio, Nilav Maulik, Branden Majors, Michael Fontillas 2024 California Polytechnic State University, San Luis Obispo

Focused Led Sintering, Dylan Defazio, Nilav Maulik, Branden Majors, Michael Fontillas

Mechanical Engineering

This report provides a detailed overview of the final design of our light-emitting diode (LED) focusing system. Our system incorporates a converging lens and a specially designed "glass funnel," which acts as a thick fiber optic that narrows the light to a fine point through internal reflection. The glass components of our system are precisely housed in a part made using advanced computer-numeric controlled (CNC) Mill and CNC Lathe manufacturing processes. This ensures high precision and durability of the overall system. Our LED focusing system is designed with a 60-watt stage light. The decision to use a glass funnel as …


Phase Error Scaling Law In Two-Wavelength Adaptive Optics, Milo W. Hyde IV, Matthew Kalensky, Michael J. Spencer 2024 Air Force Institute of Technology

Phase Error Scaling Law In Two-Wavelength Adaptive Optics, Milo W. Hyde Iv, Matthew Kalensky, Michael J. Spencer

Faculty Publications

We derive a simple, physical, closed-form expression for the optical-path difference (OPD) of a two-wavelength adaptive-optics (AO) system. Starting from Hogge and Butts’ classic OPD variance integral expression, we apply Mellin transform techniques to obtain series and asymptotic solutions to the integral. For realistic two-wavelength AO systems, the former converges slowly and has limited utility. The latter, on the other hand, is a simple formula in terms of the separation between the AO sensing (i.e., the beacon) and compensation (or observation) wavelengths. We validate this formula by comparing it to the OPD variances obtained from the aforementioned series and direct …


Development And Application Of Magnus Expansion Based Propagators For Problems In Spectroscopy And Quantum Dynamics, Taner M. Ture 2024 CUNY Graduate Center

Development And Application Of Magnus Expansion Based Propagators For Problems In Spectroscopy And Quantum Dynamics, Taner M. Ture

Dissertations, Theses, and Capstone Projects

Stable and accurate numerical propagators of time-evolution equations in quantum mechanics are required to capture correct dynamical behavior, especially in the long time limit. Magnus expansion (ME) provides a general way to expand the real time propagator of a time dependent Hamiltonian within the exponential such that the unitarity is satisfied at any order. Integrators are developed by truncating the ME and using explicit integration of Lagrange interpolation formulas for the time dependent Hamiltonian within each time interval. The derived approximations are studied in a numerical test and compared to other available expressions. The sixth order expression is applied to …


Unconventional Computing With Photonic Oscillator Networks, Mostafa Honari Latifpour 2024 CUNY Graduate Center

Unconventional Computing With Photonic Oscillator Networks, Mostafa Honari Latifpour

Dissertations, Theses, and Capstone Projects

The ever-increasing demand for data processing and the challenges in scaling traditional computing architectures are driving intensive research into alternative computing paradigms. Optical computing has garnered renewed attention since the 2010s, driven by its potential to accelerate specialized computational tasks such as combinatorial optimization and neural networks.

Coherent light sources including lasers and parametric oscillators have been around for decades and become indispensable tools in modern technology, but these photonic oscillators are also nonlinear dynamical systems that can exhibit emergent, complex phenomena, especially when coupled in arrays. These nonlinear optical systems have recently been shown to be capable of doing …


Pt-Symmetry And Eigenmodes, Tamara Gratcheva 2024 Portland State University

Pt-Symmetry And Eigenmodes, Tamara Gratcheva

University Honors Theses

Spectra of systems with balanced gain and loss, described by Hamiltonians with parity and time-reversal (PT) symmetry is a rich area of research. This work studies by means of numerical techniques, how eigenvalues and eigenfunctions of a Schrodinger operator change as a gain-loss parameter changes. Two cases on a disk with zero boundary conditions are considered. In the first case, within the enclosing disk, we place a parity (P) symmetric configuration of three smaller disks containing gain and loss media, which does not have PT-symmetry. In the second case, we study a PT-symmetric configuration …


Computational Microscopy For Biomedical Imaging With Deep Learning Assisted Image Analysis, Yuwei Liu 2024 New Jersey Institute of Technology

Computational Microscopy For Biomedical Imaging With Deep Learning Assisted Image Analysis, Yuwei Liu

Dissertations

Microscopy plays a crucial role across various scientific fields by enabling structural and functional imaging with microscopic resolution. In biomedicine, microscopy contributes to basic research and clinical diagnosis. Conventionally, optical microscopy derives its contrast from the amplitude of the optical wave and provides visualization of the physical structure of the sample qualitatively. To understand the function at the cellular or tissue level, there is a need to characterize the sample quantitatively and explore contrast mechanisms other than light intensity. Image enhancement or reconstruction from microscopic imaging systems is known as computational microscopy, and it involves the application of computational techniques …


Holographic Multiplexing In A Photopolymerisable Hybrid Sol-Gel, Pamela Stoeva, Tatsiana Mikulchyk, Izabela Naydenova, Kevin Murphy 2024 Technological University Dublin

Holographic Multiplexing In A Photopolymerisable Hybrid Sol-Gel, Pamela Stoeva, Tatsiana Mikulchyk, Izabela Naydenova, Kevin Murphy

Articles

Holographic multiplexing techniques enhance functionality and information storage by leveraging the inherent selectivity of holograms. This is crucial for advancing holographic sensors, which excel in simultaneously detecting multiple parameters from a single input signal. This study explores the potential of the recent photopolymerisable hybrid sol-gel (PHSG) material for application in Space sensing systems through the investigation of its holographic angular multiplexing capabilities. For the first time, to the best of our knowledge, we report the successful recording of up to five angularly multiplexed gratings with diffraction efficiencies (DE) ≥ 15% in 187 ± 18 µm PHSG layers. A 3 mW/cm2 …


Optical Transport Of Ultracold Atoms, David Vera 2024 University of San Diego

Optical Transport Of Ultracold Atoms, David Vera

Undergraduate Honors Theses

At temperatures near absolute zero, bosons form a macroscopic quantum state that can be manipulated and imaged in a very controlled and tunable way. To reach these extreme temperatures near absolute zero, advanced methods in cooling, including laser and evaporative cooling, must be used. In addition to these techniques for cooling, atoms must also be held up against the constant pull of gravity, so additional trapping techniques using lasers and magnets are used. In our lab at University of San Diego, we are implementing a tunable lens system (TLS) to optically transfer atoms to a more optically accessible location. A …


Optimization And Applications Of Whispering Gallery Mode Microbubble Resonator, Maxwell Adolphson 2024 Washington University in St. Louis

Optimization And Applications Of Whispering Gallery Mode Microbubble Resonator, Maxwell Adolphson

McKelvey School of Engineering Graduate Student Theses & Dissertations

Optical biosensors are frontrunners for rapid and real-time detection of analytes, particularly for low concentrations. Among them, whispering gallery mode (WGM) resonators have recently attracted a growing focus due to their robust optomechanical and optofluidic features and high sensitivity, measuring down to single binding events in small volumes. With their unique advantages and their compatibility with different sensing modalities, these sensors have the potential to become major game changers for biomedical and environmental monitoring, among many other relevant target applications. In this dissertation we focus on one geometry of whispering gallery mode resonators, the microbubble resonator. This platform is unique, …


Supercontinuum Generation With A Ti: Sapphire Laser And Photonic Crystal Fiber, Joseph Lange 2024 College of Saint Benedict/Saint John's University

Supercontinuum Generation With A Ti: Sapphire Laser And Photonic Crystal Fiber, Joseph Lange

Celebrating Scholarship and Creativity Day (2018-)

A broad spectrum of visible light was produced by focusing the 50-fs, 800-nm, 5-nJ pulses from an unamplified Ti:sapphire laser into a 20-cm-long photonic crystal fiber. A prism pair was used to compensate for material dispersion of the system. Different focusing methods were investigated including beam telescopes and lenses of various focal lengths. A 3X beam expander telescope near the laser output and a 3-cm focal length achromatic lens after the prism pair were found to work best for coupling the light into the fiber which has a core diameter of 1.7 μm.


Optical Tweezers Explorations: Dna-Mitoxantrone Interactions At 20pn, Heléna Kathryn Beeloo 2024 Bridgewater State University

Optical Tweezers Explorations: Dna-Mitoxantrone Interactions At 20pn, Heléna Kathryn Beeloo

Honors Program Theses and Projects

Mitoxantrone is a chemotherapy drug that treats a variety of cancers by inhibiting cancer cell replication through intercalation with DNA. Intercalation is the process by which certain small molecules slide flat planar regions in their structure between the base pairs of DNA. This increases the stacking force in the DNA double helix, preventing DNA replication by increasing the force required to separate the two strands that compose the helix. In this study, dual-beam optical tweezers were used to determine the binding kinetics and dissociation constant of Mitoxantrone to single molecules of DNA at 20 pN of force. This study utilized …


Multiphoton Quantum Sensing, Fatemeh Mostafavikhatam 2024 Louisiana State University and Agricultural and Mechanical College

Multiphoton Quantum Sensing, Fatemeh Mostafavikhatam

LSU Doctoral Dissertations

While the fundamental principles of light-matter interaction are well-understood and drive countless technologies, the world of multiphoton processes remains a fascinating puzzle, holding the potential to drastically alter our understanding of how light interacts with matter at its most basic level [1–4]. This rich interplay of light and matter unveils novel phenomena that can be harnessed for sensing with exceptional precision, as exemplified by multiphoton quantum sensing. This thesis delves into the applications of multiphoton quantum protocols, particularly in imaging, communication, and plasmonic sensing, to surpass classical limitations and achieve enhanced sensitivity. We explore the potential of multiphoton quantum processes, …


Comparison Of The Fluorescence Of Bulk Cadmium Sulfide And Cadmium Sulfide Nanoparticles, Jacob Goranson 2024 College of Saint Benedict/Saint John's University

Comparison Of The Fluorescence Of Bulk Cadmium Sulfide And Cadmium Sulfide Nanoparticles, Jacob Goranson

Celebrating Scholarship and Creativity Day (2018-)

The fluorescence of bulk cadmium sulfide and cadmium sulfide nanoparticles were compared. This was done using an 800-nm, unamplified Ti:sapphire laser producing 50-fs pulses. The pulses were frequency doubled using a beta barium borate (BBO) crystal. The 400-nm beam was used to induce fluorescence in the nanoparticles, while the original 800-nm beam was used to induce fluorescence in the bulk CdS by two-photon absorption. The bulk CdS showed a single fluorescent peak at 523 nm. The nanoparticles showed fluorescence at various wavelengths across the visible spectrum. In general, the nanoparticles showed a broad fluorescent spectrum between 500 nm and 750 …


Quantification Of Surface Layer Turbulence Using Sensible Heat Values From Energy Balance Versus Aerodynamic Methods, Steven T. Fiorino, Yogendra Raut, Jaclyn Schmidt, Laura Slabaugh, Blaine Fourman, Jack E. McCrae, Benjamin C. Wilson, Santasri R. Bose-Pillai 2024 Air Force Institute of Technology

Quantification Of Surface Layer Turbulence Using Sensible Heat Values From Energy Balance Versus Aerodynamic Methods, Steven T. Fiorino, Yogendra Raut, Jaclyn Schmidt, Laura Slabaugh, Blaine Fourman, Jack E. Mccrae, Benjamin C. Wilson, Santasri R. Bose-Pillai

Faculty Publications

Surface layer optical turbulence values in the form of the refractive index structure function C_n^2 are often calculated from surface layer temperature, moisture, and wind characteristics and compared to measurements from sonic anemometers, differential temperature sensors, and imaging systems. A key derived component needed in the surface layer turbulence calculations is the sensible heat value. Typically, the sensible heat is calculated using the bulk aerodynamic method that assumes a certain surface roughness and a friction velocity that approximates the turbulence drag on temperature and moisture mixing from the change in the average surface layer vertical wind velocity. These assumptions/approximations generally …


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