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Magnetism Of Cluster-Deposited Y–Co Nanoparticles, Balamuruga Balamurugan, Ralph Skomski, Xingzhong Li, V. R. Shah, George C. Hadjipanayis, Jeffrey E. Shield, David J. Sellmyer 2011 University of Nebraska-Lincoln

Magnetism Of Cluster-Deposited Y–Co Nanoparticles, Balamuruga Balamurugan, Ralph Skomski, Xingzhong Li, V. R. Shah, George C. Hadjipanayis, Jeffrey E. Shield, David J. Sellmyer

Nebraska Center for Materials and Nanoscience: Faculty Publications

Nanoparticles of YCo2, YCo3, and YCo5 are produced by cluster-deposition and investigated both structurally and magnetically. The nanoparticles have sizes of less than 10 nm and are superparamagnetic at 300 K, irrespective of stoichiometry. As-produced nanoparticles exhibit disordered structures with magnetic properties differing from those of the bulk particles. The temperature-dependent magnetization curves of the nanoparticles reveal blocking temperatures from 110 to 250 K, depending on stoichiometry. The magnetic anisotropy constant K1 of disordered YCo5 nanoparticles of 7.8 nm in size is 3.5×106ergs/cm3, higher than those of the disordered YCo …


Optical Cell For Combinatorial In Situ Raman Spectroscopic Measurements Of Hydrogen Storage Materials At High Pressures And Temperatures, Jason R. Hattrick-Simpers, Wilbur S. Hurst, Sesha S. Srinivasan, James E. Maslar 2011 University of South Carolina - Columbia

Optical Cell For Combinatorial In Situ Raman Spectroscopic Measurements Of Hydrogen Storage Materials At High Pressures And Temperatures, Jason R. Hattrick-Simpers, Wilbur S. Hurst, Sesha S. Srinivasan, James E. Maslar

Faculty Publications

An optical cell is described for high-throughput backscattering Raman spectroscopic measurements of hydrogen storagematerials at pressures up to 10 MPa and temperatures up to 823 K. High throughput is obtained by employing a 60 mm diameter × 9 mm thick sapphire window, with a corresponding 50 mm diameter unobstructed optical aperture. To reproducibly seal this relatively large window to the cell body at elevated temperatures and pressures, a gold o-ring is employed. The sample holder-to-window distance is adjustable, making this cell design compatible with optical measurement systems incorporating lenses of significantly different focal lengths, e.g., microscope objectives and single element …


Density Functional Theory Study On The Electronic Structure Of N- And P-Type Doped Srtio3 At Anodic Solid Oxide Fuel Cell Conditions, S. Suthirakun, Salai Cheettu Ammal, G. Xiao, Fanglin Chen, Hans-Conrad zur Loye, Andreas Heyden 2011 University of South Carolina - Columbia

Density Functional Theory Study On The Electronic Structure Of N- And P-Type Doped Srtio3 At Anodic Solid Oxide Fuel Cell Conditions, S. Suthirakun, Salai Cheettu Ammal, G. Xiao, Fanglin Chen, Hans-Conrad Zur Loye, Andreas Heyden

Faculty Publications

The electronic conductivity and thermodynamic stability of mixed n-type and p-type doped SrTiO3 have been investigated at anodic solid oxide fuel cell (SOFC) conditions using density functional theory (DFT) calculations. In particular, constrained ab initio thermodynamic calculations have been performed to evaluate the phase stability and reducibility of various Nb- and Ga-doped SrTiO3 at synthesized and anodic SOFC conditions. The density of states (DOS) of these materials was analyzed to study the effects of n- and p-doping on the electronic conductivity. In agreement with experimental observations, we find that the transformation from 20% Nb-doped Sr-deficient SrTiO3 to a non-Sr-deficient phase …


Design Of Superconducting Parallel Bar Deflecting/Crabbing Cavities, Jean R. Delayen, Subashini De Silva 2011 Old Dominion University

Design Of Superconducting Parallel Bar Deflecting/Crabbing Cavities, Jean R. Delayen, Subashini De Silva

Physics Faculty Publications

The superconducting parallel-bar cavity is a deflecting/crabbing cavity with attractive properties, compared to other conventional designs, that is being considered for a number of applications. We present an analysis of several designs of parallel-bar cavities and their electromagnetic properties.


Metastability Of Free Cobalt And Iron Clusters: A Possible Precursor To Bulk Ferromagnetism, Xiaoshan Xu, Shuangye Yin, Ramiro Moro, Anthony Liang, John Bowlan, Walt A. de Heer 2011 University of Nebraska-Lincoln

Metastability Of Free Cobalt And Iron Clusters: A Possible Precursor To Bulk Ferromagnetism, Xiaoshan Xu, Shuangye Yin, Ramiro Moro, Anthony Liang, John Bowlan, Walt A. De Heer

Xiaoshan Xu Papers

Homonuclear cobalt and iron clusters CoN and FeN measured in a cryogenic molecular beam exist in two states with distinct magnetic moments (μ), polarizabilities, and ionization potentials, indicating distinct valences. The μ is approximately quantized: μN ~ 2NμB in the ground states and μN* ~ NμB in the excited states for Co; μN ~ 3N μB and μN * ~ NμB for Fe. At a large size, the average μ of the two states converges to the bulk value with diminishing ionization potential differences. …


Mesoscale Flux-Closure Domain Formation In Single-Crystal Batio3, R. G.P. McQuaid, L. J. McGilly, Pankaj Sharma, Alexei Gruverman, J. M. Gregg 2011 Queen’s University Belfast

Mesoscale Flux-Closure Domain Formation In Single-Crystal Batio3, R. G.P. Mcquaid, L. J. Mcgilly, Pankaj Sharma, Alexei Gruverman, J. M. Gregg

Alexei Gruverman Publications

Over 60 years ago, Charles Kittel predicted that quadrant domains should spontaneously form in small ferromagnetic platelets. He expected that the direction of magnetization within each quadrant should lie parallel to the platelet surface, minimizing demagnetizing fields, and that magnetic moments should be configured into an overall closed loop, or flux-closure arrangement. Although now a ubiquitous observation in ferromagnets, obvious flux-closure patterns have been somewhat elusive in ferroelectric materials. This is despite the analogous behaviour between these two ferroic subgroups and the recent prediction of dipole closure states by atomistic simulations research. Here we show Piezoresponse Force Microscopy images of …


Resonant Photoemission Of Rare Earth Doped Gan Thin Films, S. R. McHale, J. W. McClory, J. C. Petrosky, J. Wu, R. Palai, Yaroslav B. Losovyj, Peter A. Dowben 2011 Air Force Institute of Technology

Resonant Photoemission Of Rare Earth Doped Gan Thin Films, S. R. Mchale, J. W. Mcclory, J. C. Petrosky, J. Wu, R. Palai, Yaroslav B. Losovyj, Peter A. Dowben

Peter Dowben Publications

The 4d → 4f Fano resonances for various rare earth doped GaN thin films (RE = Gd, Er, Yb) were investigated using synchrotron photoemission spectroscopy. The resonant photoemission Fano profiles show that the major Gd and Er rare earth 4f weight is at about 5–6 eV below the valence band maximum, similar to the 4f weights in the valence band of many other rare earth doped semiconductors. For Yb, there is very little resonant enhancement of the valence band of Yb doped GaN, consistent with a largely 4f14 occupancy.


Parametric Study On Instabilities In A Two-Layer Electromagnetohydrodynamic Channel Flow Confined Between Two Parallel Electrodes, P. Dinesh Sankar Reddy, Dipankar Bandyopadhyay, Sang Woo Joo, Ashutosh Sharma, Shizhi Qian 2011 Old Dominion University

Parametric Study On Instabilities In A Two-Layer Electromagnetohydrodynamic Channel Flow Confined Between Two Parallel Electrodes, P. Dinesh Sankar Reddy, Dipankar Bandyopadhyay, Sang Woo Joo, Ashutosh Sharma, Shizhi Qian

Mechanical & Aerospace Engineering Faculty Publications

Instabilities in a two-phase electromagnetohydrodynamic (EMHD) flow between a pair of parallel electrodes are explored. A linear stability analysis has been performed based on a coupled Orr-Sommerfeld system generated from the conservation laws. The study shows the presence of a finite-wave-number EMHD mode of instability in addition to the two commonly observed instability modes in the pressure-driven two-layer flows, namely, the long-wave interfacial mode arising from the viscosity or density stratification and the finite-wave-number shear flow mode engendered by the Reynolds stresses. This extra EMHD mode originates from the additional stresses generated by the Lorenz force acting at the liquid …


Breaking And Moving Hotspots In A Large Grain Nb Cavity With A Laser Beam, G. Ciovati, A. Gurevich, C. Baldwin, K. Jordan, P. Kneisel, S. Zhang, G. Nemes, M. Morrone, S. Anlage, L. Turlington, K. Wilson, G. Cheng 2011 Thomas Jefferson National Accelerator Facility

Breaking And Moving Hotspots In A Large Grain Nb Cavity With A Laser Beam, G. Ciovati, A. Gurevich, C. Baldwin, K. Jordan, P. Kneisel, S. Zhang, G. Nemes, M. Morrone, S. Anlage, L. Turlington, K. Wilson, G. Cheng

Physics Faculty Publications

Magnetic vortices pinned near the inner surface of SRF Nb cavities are a possible source of RF hotspots, frequently observed by temperature mapping of the cavities outer surface at RF surface magnetic fields of about 100 mT. Theoretically, we expect that the thermal gradient provided by a 10 W green laser shining on the inner cavity surface at the RF hotspot locations can move pinned vortices to different pinning locations. The experimental apparatus to send the beam onto the inner surface of a photoinjector-type large-grain Nb cavity is described. Preliminary results on the changes in thermal maps observed after applying …


Tof-Sims Analysis Of Hydrogen In Niobium, From 160°K To 475°K, P. Maheshwari, G. R. Myneni, G. Ciovati, C. Zhou, F. A. Stevie, J. M. Rigsbee, D. P. Griffis, A. D. Batchelor 2011 North Carolina State University

Tof-Sims Analysis Of Hydrogen In Niobium, From 160°K To 475°K, P. Maheshwari, G. R. Myneni, G. Ciovati, C. Zhou, F. A. Stevie, J. M. Rigsbee, D. P. Griffis, A. D. Batchelor

Physics Faculty Publications

Niobium (Nb) is the material of choice for superconducting radio frequency (SRF) cavities due to its high critical temperature and critical magnetic field. Interstitial impurity elements such as H directly influence the efficiency of these cavities. Quantification of H in Nb is difficult since H is extremely mobile in Nb with a very high diffusion coefficient even at room temperature. In the presented work, Time of Flight Secondary Ion Mass Spectrometry (TOF-SIMS) was used to characterize H in Nb over a wide temperature range (160°K to 475°K) in situ to check for changes in mobility. Multiple experiments showed that as …


Significant Enhancement Of Upper Critical Fields By Doping And Strain In Iron-Based Superconductors, C. Tarantini, A. Gurevich, J. Jaroszynski, F. Balakirev, E. Bellingeri, I Pallecchi, C. Ferdeghini, B. Shen, H. H. Wen 2011 Florida State University

Significant Enhancement Of Upper Critical Fields By Doping And Strain In Iron-Based Superconductors, C. Tarantini, A. Gurevich, J. Jaroszynski, F. Balakirev, E. Bellingeri, I Pallecchi, C. Ferdeghini, B. Shen, H. H. Wen

Physics Faculty Publications

We report measurements of 85 Tesla of the upper critical fields Hc2(T) on Ba1-xKxAs2Fe2 single crystals and FeSe1-xTex films tuned by doping and strain. We observed an Hc2 enhancement by more than 25 T at low temperatures for the optimally doped Ba1-xKxAs2Fe2 as compared to the previous measurements and extraordinarily high slopes of dHc2/dT = 250-500 T/K near Tc in FeSe 1-xTex, indicating almost-complete suppression of orbital pair breaking. Theoretical analysis of Hc2 …


Structural Characterization Of Nb Films Deposited By Ecr Plasma Energetic Deposition On Crystalline Insulators, Xin Zhao, A. -M. Valente-Feliciano, J. K. Spradlin, H. L. Phillips, C. E. Reece, D. Gu, H. Baumgart, K. Seo 2011 Jefferson Lab

Structural Characterization Of Nb Films Deposited By Ecr Plasma Energetic Deposition On Crystalline Insulators, Xin Zhao, A. -M. Valente-Feliciano, J. K. Spradlin, H. L. Phillips, C. E. Reece, D. Gu, H. Baumgart, K. Seo

Physics Faculty Publications

An energetic condensation thin film coating technique with an electron cyclotron resonance (ECR) induced Niobium (Nb) plasma ion source is used to deposit Nb thin films on crystalline insulating substrates, such as a-plane and c-plane sapphire (Al₂O₃) and on magnesium oxide, MgO (100), (110), and (111).

Hetero-epitaxial Nb films were produced by ECR deposition with regulated substrate temperature. The residual resistivity ratio (RRR) of about 1 micron thick films on a-plane (1,1,-2,0) sapphire substrates reach values (350 - 450) comparable to high RRR bulk NB commonly used for SRF cavities.

The epitaxial relationship of Nb/crystalline substrate is found to be …


Ignition Of A Large Volume Plasma With A Plasma Jet, M. Laroussi, M. A. Akman 2011 Old Dominion University

Ignition Of A Large Volume Plasma With A Plasma Jet, M. Laroussi, M. A. Akman

Electrical & Computer Engineering Faculty Publications

Here we report on a method to generate a long plasma plume and to ignite a large volume plasma by means of the jet. The plasma plume is generated by our tube reactor and then introduced into a chamber where the pressure is controlled. We discovered there are three operating phases:Aphasewhere the plume length remains approximately constant, followed by a second phase where the jet increases in length as the pressure decreases. Then at pressures below 70 Torr a mode transition occurs where the plume length decreases and the plasma expands until the entire chamber is filled.


Measurement System For High Pressure Characterizations Of Materials, Matthew K. Jacobsen 2010 University of Nevada, Las Vegas

Measurement System For High Pressure Characterizations Of Materials, Matthew K. Jacobsen

UNLV Theses, Dissertations, Professional Papers, and Capstones

Thermoelectric materials have long been investigated for possible use as power sources. This application was recently put to use in the Voyager space program, powering the deep space probes. Despite the usefulness of these materials, the use of pressure to investigate the material properties has only recently become interesting. As such, the work in this document was to developing a system for concurrently measuring the necessary properties. This system is capable of measuring the electrical resistivity, thermal conductivity, and Seebeck coefficient in the pressure range from 0 - 10 GPa. The results for zinc, almandine garnet, and nickel are presented …


Development Of Acrylamide Based Photopolymer For Full Colour Display Holography, Chakrapani Meka 2010 Technological University Dublin

Development Of Acrylamide Based Photopolymer For Full Colour Display Holography, Chakrapani Meka

Doctoral

Holography is a firmly established discipline that can be used as a tool for scientific and engineering studies and as a display medium as well. Until now both silver halide photographic emulsions (SHPE) and dichromated gelatine (DCG) have been the most common materials used for high efficiency full colour reflection hologram recording. However, these materials require wet chemical processing for developing the holograms which is laborious and costly from the point of view of commercial applications. Self-developing photopolymers such as acrylamide based photopolymer (ABP) which do not require development are the ideal choice for real-time recording and reconstruction of holograms. …


Pulsed Laser Deposition Of Graphite Counter Electrodes For Dye-Sensitized Solar Cells, Krishna P. Acharya, Himal Khatri, Sylvain Marsillac, Bruno Ullrich, Pavel Anzenbacher, Mikhail Zamkov 2010 Old Dominion University

Pulsed Laser Deposition Of Graphite Counter Electrodes For Dye-Sensitized Solar Cells, Krishna P. Acharya, Himal Khatri, Sylvain Marsillac, Bruno Ullrich, Pavel Anzenbacher, Mikhail Zamkov

Electrical & Computer Engineering Faculty Publications

We report on pulsed laser deposition of graphite onto flexible plastic and conductive glass substrates for use as a counter electrode in dye-sensitized solar cells. The efficiency of as-prepared graphite electrodes was tested using CdS-sensitized solar cell architecture resulting in external quantum efficiency comparable to that of conventional platinum counter electrodes. This work highlights the possibility of using pulsed laser deposited graphite as a low-cost alternative to platinum, which could be fabricated both on flexible and rigid substrates.


Doping Dependence Of Electronic And Mechanical Properties Of Gase1−XTeX And Ga1−XInXSe From First Principles, Zs. Rak, S. D. Mahanti, K. C. Mandal, N. C. Fernelius 2010 University of South Carolina - Columbia

Doping Dependence Of Electronic And Mechanical Properties Of Gase1−XTeX And Ga1−XInXSe From First Principles, Zs. Rak, S. D. Mahanti, K. C. Mandal, N. C. Fernelius

Faculty Publications

No abstract provided.


Nonlinear Observers For Human-In-The-Loop Control Systems, Samuel Kitchen McKinley 2010 Embry-Riddle Aeronautical University

Nonlinear Observers For Human-In-The-Loop Control Systems, Samuel Kitchen Mckinley

Master's Theses - Daytona Beach

The development of models for a human-in-the-loop with hardware is an area of ongoing research. The ability to simulate a human-in-the-loop with hardware provides a platform for better understanding the dynamics of human and machine cognition. A human-in-the-loop model provides information that can be used to design more efficient human interfaces and smarter autonomous assistant controllers. This can make a complex task such as flying an aircraft safer and more accessible. This thesis explores different possibilities for human operator models to be modeled in the loop with a vehicle. A human is modeled as a linear state feedback controller in …


An Inverse Kinematic Mathematical Model Using Groebner Basis Theory For Arm Swing Movement In The Gait Cycle, Kimberly D. Kendricks, Adam M. Fullenkamp, Robert McGrellis, Jonathan Juhl, Ronald F. Tuttle 2010 Center for MASINT Studies and Research, Air Force Institute of Technology

An Inverse Kinematic Mathematical Model Using Groebner Basis Theory For Arm Swing Movement In The Gait Cycle, Kimberly D. Kendricks, Adam M. Fullenkamp, Robert Mcgrellis, Jonathan Juhl, Ronald F. Tuttle

Faculty Publications

Two important indicators in the gait cycle: arm swing and foot placement, when isolated, provide key information about future behaviors in the gait cycle. Through video captured data, the INSPIRE (Integration of a Sensor Package for Identifying Radical Extremists) project seeks to identify gait characteristics in arm and leg swing movement to recognize threatening individuals. In particular, one approach discussed in this paper uses Groebner Basis Theory to model arm swing movement in the gait cycle. Through inverse kinematics, joint configurations of the shoulder and elbow are found to place the wrist at a specific position and orientation in the …


Simulation Of Temperature Distributions In Tissue Upon Laser Pulse Irradiation Including Water Mass Transfer, Deepthi Nagulapally 2010 Old Dominion University

Simulation Of Temperature Distributions In Tissue Upon Laser Pulse Irradiation Including Water Mass Transfer, Deepthi Nagulapally

Electrical & Computer Engineering Theses & Dissertations

Lasers, due to their unique characteristics, have tremendous applications in the medical field. Generally all laser applications in hie-medicine involve the propagation of laser energy through tissue. Energy is deposited giving rise to many physical, hie-chemical, and mechanical effects. Among these are dynamical changes in the local temperature distributions within the tissue. Analysis of the temperature changes requires the creation of an appropriate optical transmission and heat flow model that incorporates user specified laser parameters. Here, a numerical simulation model was developed to study both steady state and time dependent temperature distributions due to pulsed laser radiation within user specified …


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