Double Resonance Spectroscopy Of The D1Πu+ And B''B-Bar 1Σu+ States Near The Third Dissociation Threshold Of H2,
2013
Bryn Mawr College
Double Resonance Spectroscopy Of The D1Πu+ And B''B-Bar 1Σu+ States Near The Third Dissociation Threshold Of H2, R. C. Ekey, A. E. Cordova, W. Duan, Alexander M. Chartrand, Elizabeth Mccormack
Physics Faculty Research and Scholarship
Double-resonance laser spectroscopy via the E, F 1Σg+, v' = 6, J' state was used to probe the energy region below the third dissociation limit of molecular hydrogen. Resonantly enhanced multi-photon ionization spectra were recorded by detecting ion production as a function of energy using a time-of-flight mass spectrometer. Energies and line widths for the v = 14–17 levels of the D1Πu+ state of H2 are reported and compared to experimental data obtained by using VUV synchrotron light excitation (Dickenson et al. 2010 J. Chem. Phys. 133 144317) and fully ab …
Above-Threshold Ionization As Temporal Multi-Slit Interference,
2013
Southern Adventist University
Above-Threshold Ionization As Temporal Multi-Slit Interference, William B. Laing Iii, B.D. Esry
Faculty Works
When atoms are subjected to a laser pulse of sufficiently high intensity, electrons are ionized by absorbing multiple photons in excess of the ionization potential. The resulting sequence of peaks in the photoelectron spectrum separated by the energy of one photon is called ``above-threshold ionization'' (ATI). This time-independent description of ATI invokes the language of photons, even though calculations are performed using the time-dependent Schrodinger equation with a classical electric field. We demonstrate that the energy-periodic structure of ATI can be understood from the interference of ionized electron wavepackets produced periodically each half-cycle of the laser field. Using this simple …
Above-Threshold Ionization As Temporal Multi-Slit Interference,
2013
Southern Adventist University
Above-Threshold Ionization As Temporal Multi-Slit Interference, William B. Laing Iii
Faculty Works
When atoms are subjected to a laser pulse of sufficiently high intensity, electrons are ionized by absorbing multiple photons in excess of the ionization potential. The resulting sequence of peaks in the photoelectron spectrum separated by the energy of one photon is called “above-threshold ionization” (ATI). This time-independent description of ATI invokes the language of photons, even though calculations are performed using the time-dependent Schrodinger equation with a classical electric field. We demonstrate that the energy-periodic structure of ATI can be understood from the interference of ionized electron wavepackets produced periodically each half-cycle of the laser field. Using this simple …
Resonant Enhancement Of The Harmonic-Generation Spectrum Of Beryllium,
2013
University of Nebraska-Lincoln
Resonant Enhancement Of The Harmonic-Generation Spectrum Of Beryllium, Jean Marcel Ngoko Djiokap, Anthony F. Starace
Anthony F. Starace Publications
The high-order harmonic-generation (HHG) spectrum of Be is investigated in the multiphoton regime by solving the full-dimensional, two-active-electron, time-dependent Schr¨odinger equation in an intense (≈1013 W/cm2), 30-cycle laser field. As the laser frequency ωL varies from 1.7 to 1.8 eV (which is in the tunable range of a Ti:sapphire laser), the seventh harmonic becomes resonant sequentially with the transition between the ground state and two doubly excited autoionizing states, 2p4s(1P) (at ωL = 1.734 eV) and 2p5s …
Carrier-Envelope-Phase-Induced Asymmetries In Double Ionization Of Helium By An Intense Few-Cycle Xuv Pulse,
2013
University of Nebraska-Lincoln
Carrier-Envelope-Phase-Induced Asymmetries In Double Ionization Of Helium By An Intense Few-Cycle Xuv Pulse, Jean Marcel Ngoko Djiokap, N. L. Manakov, A. V. Meremianin, Anthony F. Starace
Anthony F. Starace Publications
The carrier-envelope-phase (CEP) dependence of electron angular distributions in double ionization of He by an arbitrarily polarized, few-cycle, intense XUV pulse is formulated using perturbation theory (PT) in the pulse amplitude. Owing to the broad pulse bandwidth, interference of first- and second-order PT amplitudes produces asymmetric angular distributions sensitive to the CEP. The PT parametrization is shown to be valid by comparing with results of solutions of the full-dimensional, two-electron time-dependent Schrödinger equation for the case of linear polarization.
Harmonic Generation Spectroscopy With A
Two-Colour Laser Field Having Orthogonal
Linear Polarizations,
2013
Voronezh State University
Harmonic Generation Spectroscopy With A Two-Colour Laser Field Having Orthogonal Linear Polarizations, T. S. Sarantseva, M. V. Frolov, N. L. Manakov, M. Yu. Ivanov, Anthony F. Starace
Anthony F. Starace Publications
The interpretation of many high-order harmonic generation (HHG) experiments is based on the assumption that the HHG yield of an atom can be factorized into (i) a laser-dependent ‘electron wave packet’ with rather simple properties, including a nearly universal shape, and (ii) an atomic photorecombination cross section. We show that this factorization is restricted to linearly polarized laser fields and fails in two-colour laser fields with orthogonal polarizations. At the same time, we show how two-colour HHG spectroscopy using orthogonally polarized intense fundamental and relatively weak second harmonic fields makes a complete experiment possible that enables the retrieval of the …
Imaging Molecular Structures With Atomic Force Microscopy,
2013
Clark University
Imaging Molecular Structures With Atomic Force Microscopy, Unurbat Erdenemunkh, Tyler Flanagan
Student Works
As part of the LEEP project we repaired the Atomic Force Microscopy (AFM), and wrote a user manual on using AFM. Then we scanned Self Assembly of Copolymer Films collaboration with Prof. Sergio Granados –Focil and Copper Oxide Nanocubes with Professor Prof.Luis Smith.
Dynamics Underlying The Gaussian Distribution Of The Classical Harmonic Oscillator In Zero-Point Radiation,
2013
University of Nebraska-Lincoln
Dynamics Underlying The Gaussian Distribution Of The Classical Harmonic Oscillator In Zero-Point Radiation, Wayne Cheng-Wei Huang, Herman Batelaan
Department of Physics and Astronomy: Faculty Publications
Stochastic electrodynamics (SED) predicts a Gaussian probability distribution for a classical harmonic oscillator in the vacuum field. This probability distribution is identical to that of the ground state quantum harmonic oscillator. Thus, the Heisenberg minimum uncertainty relation is recovered in SED. To understand the dynamics that give rise to the uncertainty relation and the Gaussian probability distribution, we perform a numerical simulation and follow the motion of the oscillator. The dynamical information obtained through the simulation provides insight to the connection between the classic double-peak probability distribution and the Gaussian probability distribution. A main objective for SED research is to …
Measurement Of A Weak Transition Moment Using Coherent Control,
2013
Purdue University
Measurement Of A Weak Transition Moment Using Coherent Control, Dionysios Antypas
Open Access Dissertations
We have developed a two-pathway Coherent Control technique for measurements of weak optical transition moments. We demonstrate this technique through a measurement of the transition moment of the highly-forbidden magnetic dipole transition between the 6s2S1/21/2 and 7s2S1/21/2 states in atomic Cesium. The experimental principle is based on a two-pathway excitation, using two phase-coherent laser fields, a fundamental field at 1079 nm and its second harmonic at 539.5 nm. The IR field induces a strong two-photon transition, while the 539.5 nm field drives a pair of weak one-photon transitions: a Stark-induced transition of …
Experimental Studies Of Lirb: Spectroscopy And Ultracold Molecule Formation By Photoassociation,
2013
Purdue University
Experimental Studies Of Lirb: Spectroscopy And Ultracold Molecule Formation By Photoassociation, Sourav Dutta
Open Access Dissertations
Heteronuclear polar molecules have recently attracted enormous attention owing to their ground state having a large electric dipole moment. The long range anisotropic dipole-dipole interaction in such systems is the basis for a variety of applications including quantum computing, precision measurements, ultracold chemistry and quantum simulations. Heteronuclear bi-alkali molecules, only a small subset of polar molecules, have received special attention mainly because the constituent alkali atoms are easy to laser cool and can be relatively easily associated to form molecules at ultracold temperatures. Our choice, the LiRb molecule, is motivated by the relatively high dipole moment (4.1 Debye) of the …
Applicability Of Continuum Fracture Mechanics In Atomistic Systems,
2013
Purdue University
Applicability Of Continuum Fracture Mechanics In Atomistic Systems, Shao-Huan Cheng
Open Access Dissertations
By quantitating the amplitude of the unbounded stress, the continuum fracture mechanics defines the stress intensity factor K to characterize the stress and displacement fields in the vicinity of the crack tip, thereby developing the relation between the stress singularity and surface energy (energy release rate G). This G-K relation, assigning physical meaning to the stress intensity factor, makes these two fracture parameters widely used in predicting the onset of crack propagation. However, due to the discrete nature of the atomistic structures without stress singularity, there might be discrepancy between the failure prediction and the reality of nanostructured materials. Defining …
On The Origin Of Mode- And Bond-Selectivity In Vibrationally Mediated Reactions On Surfaces,
2013
Tufts University
On The Origin Of Mode- And Bond-Selectivity In Vibrationally Mediated Reactions On Surfaces, Daniel Killelea, Arthur L. Utz
Chemistry: Faculty Publications and Other Works
The experimental observations of vibrational mode- and bond-selective chemistry at the gas–surface interface indicate that energy redistribution within the reaction complex is not statistical on the timescale of reaction. Such behavior is a key prerequisite for efforts to use selective vibrational excitation to control chemistry at the technologically important gas–surface interface. This paper outlines a framework for understanding the origin of non-statistical reactivity on surfaces. The model focuses on the kinetic competition between intramolecular vibrational energy redistribution (IVR) within the reaction complex, which in the long-time limit leads to statistical behavior, and quenching, scattering, or desorption processes that restrict the …
Wave Function For Time-Dependent Harmonically Confined Electrons In A Time-Dependent Electric Field,
2013
Ningbo University
Wave Function For Time-Dependent Harmonically Confined Electrons In A Time-Dependent Electric Field, Yu-Qi Li, Xiao-Yin Pan, Viraht Sahni
Publications and Research
The many-body wave function of a system of interacting particles confined by a time-dependent harmonic potential and perturbed by a time-dependent spatially homogeneous electric field is derived via the Feynman path-integral method. The wave function is comprised of a phase factor times the solution to the unperturbed time-dependent Schrödinger equation with the latter being translated by a time-dependent value that satisfies the classical driven equation of motion. The wave function reduces to that of the Harmonic Potential Theorem wave function for the case of the time-independent harmonic confining potential.
Ground State Of The Singly Ionized Oxygen Vacancy In Rutile Tio2,
2013
West Virginia University
Ground State Of The Singly Ionized Oxygen Vacancy In Rutile Tio2, A. T. Brant, Nancy C. Giles, Shan Yang (杨山), M. A. R. Sarker, S. Watauchi, M. Nagao, I. Tanaka, D. A. Tryk, A. Manivannan, Larry E. Halliburton
Faculty Publications
Results from electron paramagnetic resonance (EPR) and electron-nuclear double resonance (ENDOR) experiments are used to establish the model for the ground state of the singly ionized oxygen vacancy in the interior of bulk rutile TiO2 crystals. Hyperfine from 47Ti and 49Ti nuclei show that the unpaired electron in this S = 1/2 defect is localized on one titanium ion adjacent to the oxygen vacancy (i.e., the spin is not shared by two titanium ions). These defects are formed at low temperature (∼35 K) in as-grown oxidized crystals when sub-band-gap 442 nm laser light converts doubly ionized nonparamagnetic …
Dynamic Electron Control Using Light And Nanostructure,
2013
University of Nebraska-Lincoln
Dynamic Electron Control Using Light And Nanostructure, Wayne Cheng-Wei Huang
Department of Physics and Astronomy: Dissertations, Theses, and Student Research
The advent of nano-technology has made possible the manipulation of electron or light through nanostructures. For example, a nano-tip in near-field optical microscopy allows imaging beyond the diffraction limit, and a nano-fabricated hologram is used to produce electron vortex beam. While most schemes of electron control utilize only static components, dynamic electron beam control using both light and nanostructures has not yet been realized. In this dissertation, we explore this possibility and study the interplay between electron, light, and nanostructures. A understanding of such a system may facilitate dynamic electron beam control or even bring new insights to fundamental quantum …
The Standard New Astronomy Cryostat For Sofia: A Design For Cryogen-Free Infrared Astronomy,
2013
CSU Chico
The Standard New Astronomy Cryostat For Sofia: A Design For Cryogen-Free Infrared Astronomy, Carey F. Scott, Jeffrey Van Cleve, Eric Burgh, Earl T. Daley, Ali Kashani, Zaheer Ali
STAR Program Research Presentations
Astronomy at infrared wavelengths requires optical instruments that operate at low temperatures, which is typically done using liquid cryogens such as nitrogen and helium. These cryogens are costly and limit the operational time of the science instrument. The Standard New Astronomy Cryostat for SOFIA (SNACS) will provide a design for a helium cryocooler-cooled cryostat that meets the stringent airworthiness requirements of the Stratospheric Observatory for Infrared Astronomy (SOFIA) and can be used by future instrument builders to reduce the cost and risk of their instrument design and development. The SNACS dewar will provide approximately 3.4 x 10-1 cubic meters …
Breaking Peroxy Bonds In H20 Ice Doped With H202 To Create Positive Hole Charge Carriers.,
2013
Middle Tennessee State University
Breaking Peroxy Bonds In H20 Ice Doped With H202 To Create Positive Hole Charge Carriers., Corey C. Stockburger
STAR Program Research Presentations
Using stress-activated electric conductivity in water ice doped with hydrogen peroxide as a model for stress-activated electric conductivity of igneous and high-grade metamorphic rocks due to the presence of peroxy defects, which when broken, createpositive-hole charge carriers. Blocks of pure H2O ice and H2O2–doped H2O ices, frozen at –20°C, will be stressed with piezo electric transducers(pzt) at one end to generate stress-activated electric currents flowing down the stress gradient. Pure H2O ice should produce no current or a small insignificant amount during rapid deformation or fracture. Stressing H2O2-doped H2O ices, however, should lead to 100-1000 times higher currents. These stress-activated …
Use Of Zwitterionic Molecules For Forming A Hole Or Electron Transport Layer,
2013
University of Strasbourg, Institute of Physics and Chemistry of Materials of Strasbourg
Use Of Zwitterionic Molecules For Forming A Hole Or Electron Transport Layer, Bernard Doudin, Pierre Braunstein, Lucie Routaboul, Guillaume Dalmas, Zhengzheng Zhang, Peter Dowben
Peter Dowben Publications
The invention relates to the use of zwitterionic molecules for forming a hole or electron transport layer. The preferred zwitterionic molecules of the invention are derivatives of p-benzoquinonemonoimines. The invention is useful in the field of electronic devices in particular.
Optical And Thermal Properties Of Spinel With Revised (Increased) Absorption At 4 To 5 Μm Wavelengths And Comparison With Sapphire,
2013
Naval Air Warfare Center
Optical And Thermal Properties Of Spinel With Revised (Increased) Absorption At 4 To 5 Μm Wavelengths And Comparison With Sapphire, Daniel C. Harris, Giorgio Turri
Publications
Infrared absorption of high-quality, commercial, polycrystalline MgAl2O4 spinel is ∼40% greater in the range of 3.8 to 5.0 μm than the value predicted by the computer code OPTIMATR®, which has been used for window and dome design for more than 20 years. As a result, spinel and a-plane sapphire windows designed to support the same external pressure with the same probability of survival have approximately the same infrared absorptance in the range 3.8 to 5.0 μm. c-Plane sapphire has greater absorptance than spinel in the range 3.8 to 5.0 μm. Spinel has two weak absorption bands near 1.8 and 3.0 …
Electron Matter Optics Of The Aharonov–Bohm And Stern–Gerlach Effects,
2013
University of Nebraska-Lincoln
Electron Matter Optics Of The Aharonov–Bohm And Stern–Gerlach Effects, Scot Mcgregor
Department of Physics and Astronomy: Dissertations, Theses, and Student Research
Since the advent of quantum mechanics and the idea that massive particles exhibit wave properties, physicists have made efforts to make use of the short deBroglie wave length of matter waves for fundamental as well as practical studies. Among these are the precise measurements allowed by interference, diffraction, and microscopy as well as the study of more fundamental aspects of quantum theory such as the Aharonov-Bohm effects or the Stern-Gerlach effect, which are described below. However, in order to use matter waves to observe any of these effects it is necessary to produce and maintain coherence in the waves which …
