Atomic, Molecular and Optical Physics Commons^™

Direct Visualization Of 3-Dimensional Force And Energy Map Of A Single Molecular Switch, Abeykoon Mudiyanselage Shashika Darshani Wijerathna, Zaw Myo Win, K. Z. Latt, Yang Li, A. T. Ngo, L. Curtiss, R. Zhang, S. W. Hla, Y. Zhang

College of Sciences Posters

Mechanical properties of molecules adsorbed on materials surfaces are increasingly vital for the applications of molecular thin films. Here, we conduct a fundamental research to induce conformational change mechanically on a single molecule and quantify the driving force needed for such molecular shape switch via a low temperature (~ 5K) Scanning Tunneling Microscope (STM) and Qplus Atomic Force Microscope (Q+AFM). Our measurement maps a three-dimensional landscape for mechanical potential and force at single molecule level with high spatial resolution in all three dimensions of a few angstrom (10^-10 m).

Molecule TBrPP-Co (a cobalt porphyrin) deposited on an atomically clean …

Dipole Emission Characteristics Near A Topological Insulator Sphere Coated With A Metallic Nanoshell, Huai-Yi Xie, Railing Chang, P. T. Leung

Physics Faculty Publications and Presentations

Topological insulators (TI) are quantum states of (2D/3D) matter with an insulating interior but conducting edge/surface states, with these boundary conducting states being protected topologically by time-reversal symmetry. Composite materials of heavy atoms such as Bi₂Te₃ can be fabricated to show TI properties due to the strong intrinsic spin-orbit coupling of the electrons in these materials. Among the so many intriguing physical properties of these materials, their topological magneto-electric (TME) response is unique and has been studied intensively in the literature, leading to intriguing optical effects such as Faraday and Kerr rotations of incident polarized beams at …

Study Of Neon Collisional Negative Ion Compound Resonance Using A Trochoidal Electron Monochromator, Will Brunner

Honors Program: Senior Projects (Public)

This thesis describes the experimental apparatus and procedure used to measure the excitation function of the 2p⁵3p ³D₃ state of neon. First I describe the effect on this excitation of negative ion resonances and previous experiments to measure the excitation function, as well as suggestions for future applications of such studies. Then the experimental apparatus is described in three parts. The vacuum system uses a turbomolecular pump to decrease the pressure of the chamber to as low as 4*10^-9 Torr. The electron beam system incorporates a trochoidal electron monochromator to send a highly monochromatic beam …

Smart Quantum Technologies Using Photons, Narayan Bhusal

LSU Doctoral Dissertations

The technologies utilizing quantum states of light have been in the spotlight for the last two decades. In this regard, quantum metrology, quantum imaging, quantum-optical communication are some of the important applications that exploit fascinating quantum properties like quantum superposition, quantum correlations, and nonclassical photon statistics. However, the state-of-art technologies operating at the single-photon level are not robust enough to truly realize a reliable quantum-photonic technology.

In Chapter 1, I present a historical account of photon-based technologies. Furthermore, I discuss recent efforts and encouraging developments in the field of quantum-photonic technologies, and major challenges for the experimental realization of reliable …

Non-Adiabatic Quantum Interference In The Ultracold Li + Lina → Li2+ Na Reaction, Brian K. Kendrick, Hui Li, Ming Li, Svetlana Kotochigova, James F.E. Croft, Naduvalath Balakrishnan

Chemistry and Biochemistry Faculty Research

Electronically non-adiabatic effects play an important role in many chemical reactions. However, how these effects manifest in cold and ultracold chemistry remains largely unexplored. Here for the first time we present from first principles the non-adiabatic quantum dynamics of the reactive scattering between ultracold alkali-metal LiNa molecules and Li atoms. We show that non-adiabatic dynamics induces quantum interference effects that dramatically alter the ultracold rotationally resolved reaction rate coefficients. The interference effect arises from the conical intersection between the ground and an excited electronic state that is energetically accessible even for ultracold collisions. These unique interference effects might be exploited …

Implementing Inverse Design Tools For Plasmonic Digital Logic Devices, Krishna Narayan, Mark C. Harrison

Engineering Faculty Articles and Research

Despite the benefits that optics and photonics have brought to improving communications, there remains a lack of commercialized optical computing devices and systems, which reduces the benefits of using light as an information-carrying medium. We are developing architectures and designs of photonic logic gates for creating larger-scale functional photonic logic circuits. In contrast to other approaches, we are focusing on the development of logic devices which can be cascaded in arbitrary ways to allow for more complex photonic integrated circuit design. Additionally, optical computing often uses on-off keying, which fails to take advantage of denser encoding schemes often used to …

Correction To "Quantitative Study Of The Energy Changes In Voltage-Controlled Spin Crossover Molecular Thin Films" [The Journal Of Physical Chemistry Letters (2020) 11:19 (8231-8237) Doi: 10.1021/Acs.Jpclett.0c02209], Aaron Mosey, Ashley S. Dale, Guanhua Hao, Alpha N'Diaye, Peter Dowben, Ruihua Cheng

Peter Dowben Publications

In our recent publication, Figure 5 was published without adequate due diligence. The correct TOC Abstract graphic and Figure 5 are contained here in this correction. The correct on to off current ratios are in the range of 4 to 5, not 100 and the signal to noise ratios are far less than previously shown.

Electron Beam Dispersion Compensator Using A Wien Filter, Jackson Lederer

Honors Program: Senior Projects (Public)

When an electron beam travels through space, it spreads out over time which impedes the ability to work with short electron pulses in the lab. A Wien filter is a device consisting of perpendicular electric and magnetic fields which filters charged particles based on their velocities. For a specific velocity, the two forces from the two fields in the filter cancel each other out letting charges with that velocity travel straight through the filter. Charges moving at other speeds are deflected as they have a net force applied to them from the filter. If a particle is deflected from the …

Nonvolatile Voltage Controlled Molecular Spin‐State Switching For Memory Applications, Thilini K. Ekanayaka, Guanhua Hao, Aaron Mosey, Ashley S. Dale, Xuanyuan Jiang, Andrew J. Yost, Keshab R. Sapkota, George T. Wang, Jian Zhang, Alpha T. N’Diaye, Andrew Marshall, Ruihua Cheng, Azad Naeemi, Xiaoshan Xu, Peter Dowben

Peter Dowben Publications

Nonvolatile, molecular multiferroic devices have now been demonstrated, but it is worth giving some consideration to the issue of whether such devices could be a competitive alternative for solid-state nonvolatile memory. For the Fe (II) spin crossover complex [Fe{H₂B(pz)₂}₂(bipy)], where pz = tris(pyrazol-1-yl)-borohydride and bipy = 2,20-bipyridine, voltage-controlled isothermal changes in the electronic structure and spin state have been demonstrated and are accompanied by changes in conductance. Higher conductance is seen with [Fe{H₂B(pz)₂}₂(bipy)] in the high spin state, while lower conductance occurs for the low spin state. Plausibly, …

Lithium Compound Characterization Via Laser Induced Breakdown Spectroscopy And Raman Spectroscopy, James T. Stofel

Theses and Dissertations

Industries such as lithium-ion battery producers and the nuclear industry community seek to produce and store lithium in pure chemical forms. However, these lithium compounds are reactive with the atmosphere and quickly degrade into less desirable forms. Therefore, industry desires a fast and effective quality control approach to quantify the ingrowth of these secondary lithium chemical forms. This research presents a novel approach using Laser-Induced Breakdown Spectroscopy (LIBS) and Raman spectroscopy in tandem to enhance lithium compound characterization beyond what is achieved by either technique alone. The resulting spectral data are aggregated using data fusion and analyzed using chemometrics for …

Data Driven Investigation Into The Off-Axis Brdf To Develop An Algorithm To Classify Anisotropicity, Anne W. Werkley

Theses and Dissertations

The Bi-directional Reflectance Distribution Function (BRDF) is used to describe reflectances of materials by calculating the ratio of the reflected radiance to the incident irradiance. While it was found that isotropic BRDF microfacet models maintained symmetry about ɸ_s = π, such symmetry was not maintained about the θ_s = θ_i axis, except for close to the specular peak. This led to development of a novel data-driven metric for how isotropic a BRDF measurement is. Research efforts centered around developing an algorithm that could determine material anisotropy without having to fit to models. The algorithm developed here successfully …

Ab Initio Spectroscopy Of Natural And Artificial Fire Contaminants For V/W Band Frequency Signal Absorbance, Matthew B. Husk

Theses and Dissertations

The rotation and vibration spectral properties including frequencies and intensities for highly concentrated molecules present in wildland and artificial fires have been studied. These properties were used to determine absorption and its effect in a link budget analysis. Absorption in link budget analyses is commonly accounted for via line-by-line methodology aided by HITRAN documented intensities. Limited, if any, customization of spectral properties is available with HITRAN and other spectral databases. Ab initio calculations with different atomic basis sets were employed to obtain structures, dipole moments, rotational-vibrational frequencies and intensities, as well as various coupling parameters. Anharmonic corrections to the vibrational …

Error Reduction For The Determination Of Transverse Moduli Of Single-Strand Carbon Fibers Via Atomic Force Microscopy, Joshua D. Frey

Theses and Dissertations

The transverse modulus of single strand carbon fibers is measured using PeakForce Atomic Force Microscopy - Quantitative Nanomechanical Measurement to less than 5 percent error for 11 types of carbon fiber with longitudinal moduli between 924-231 GPA, including export-controlled fibers. Statistical methods are employed to improve the quality of data to exclude outliers within an measurement and within the sample set. A positive linear correlation between the longitudinal and transverse modulus with an R²=0.76 is found. Pitch-based fibers exhibit lower measurement error than PAN-based fibers, while PAN fibers exhibited no apparent modulus correlation when the Pitch fibers are …

Computational Electromagnetic Modeling Of Metasurface Optical Devices With Defect Study, Carlos D. Diaz

Theses and Dissertations

One of the first fabricated metasurface optical devices, the in-plane V-antenna lenses, were plagued by a fundamental transmission limit (<25 >). Two distinct sets of Out-of-Plane phase elements were designed with improved transmission (~60 ). These were fabricated as beamsteerers and characterized in terms of their Bidirectional Transmittance Distribution Function measured as a function of scatter angle. Experimental data from the beamsteerers was analyzed via simulations using a finite element method (FEM). The measurements showed the designed beamsteering, but also a strong zero-order diffraction not present in the simulations, which motivated this study to understand what was causing these differences. …

Development Of 3d In Vitro Tissue Models For The Analysis Of Solar Radiation Damage Of Skin, Ulises Lopez Gonzalez

Doctoral

The aim of this work was to investigate changes to the molecular composition and conformation of HaCaT cells as a result of simulated solar radiation in a 3D in vitro skin model by Raman spectroscopy. The process to achieve this goal was performed in three main stages: (1) optimisation of the working concentration and volume of two 3D membranes, used as a structural support in the skin model; (2) the construction of the 3D in vitro skin model and; (3) the investigation of the dose-dependent effects of solar radiation on HaCaT cells in the skin model in comparison with the …

Electronic Transitions In Rb2+ Dimers Solvated In Helium, Simon Albertini, Paul Martini, Arne Schiller, Harald Schöbel, Elham Ghavidel, Milan Ončák, Olof E. Echt, Paul Scheier

Faculty Publications

We have measured depletion spectra of the heteronuclear (⁸⁵Rb⁸⁷Rb⁺) dimer cation complexed with up to 10 He atoms. Two absorption bands are observed between 920 and 250 nm. The transition into the repulsive 1²Sigma_u⁺ state of HeRb₂⁺ gives rise to a broad feature at 790 nm (12650 cm^–1); it exhibits a blueshift of 98 cm^–1 per added He atom. The transition into the bound 1 ²Pi_u state of HeRb₂⁺ reveals vibrational structure with a band head at < 15522 cm^–1, a harmonic …

Remote Mesoscopic Signatures Of Induced Magnetic Texture In Graphene, N. Arabchigavkani, R. Somphonsane, H. Ramamoorthy, G. He, J. Nathawat, S. Yin, B. Barut, K. He, M. D. Randle, R. Dixit, K. Sakanashi, N. Aoki, K. Zhang, L. Wang, W. N. Mei, Peter Dowben, J. Fransson, J. P. Bird

Peter Dowben Publications

Mesoscopic conductance fluctuations are a ubiquitous signature of phase-coherent transport in small conductors, exhibiting universal character independent of system details. In this Letter, however, we demonstrate a pronounced breakdown of this universality, due to the interplay of local and remote phenomena in transport. Our experiments are performed in a graphene-based interaction-detection geometry, in which an artificial magnetic texture is induced in the graphene layer by covering a portion of it with a micromagnet. When probing conduction at some distance from this region, the strong influence of remote factors is manifested through the appearance of giant conductance fluctuations, with amplitude much …

Triplet 23S State Of A Quantum Dot In A Magnetic Field: A 'Quantal Newtonian' First Law Study, Marlina Slamet, Viraht Sahni

Publications and Research

The triplet 2³S state of a 2-electron 2-dimensional quantum dot in a magnetic field is studied via a complementary perspective of Schrödinger-Pauli theory. The perspective is that of the individual electron via its equation of motion or ‘Quantal Newtonian’ first law. According to the law, each electron experiences an external and internal field, the sum of which vanishes. The external field is the sum of the binding and Lorentz fields. The internal field is a sum of the electron-interaction, kinetic, differential density, and internal magnetic fields. The energy is expressed in integral virial form in terms of these …

Determination Of The Rydberg Constant From The Emission Spectra Of H And He+, Kyle D. Shaffer

Ramifications

Abstract

In this experiment, the Rydberg constants for the hydrogen atom and He⁺ were determined by analysis of the emission spectra of Hand He, respectively, in comparison to the principal quantum numbers of each transition. Using both a hydrogen and then a helium atomic lamp attached to a 0.5 m grating spectrometer and a photomultiplier detector (PMT), a change in voltage detected by the PMT can be paired with a corresponding wavelength passing through the spectrometer from each emission peak in the visible to ultraviolet range. The peaks acquired from this change in voltage were analyzed to find their …

Plasmonic Waveguides To Enhance Quantum Electrodynamic Phenomena At The Nanoscale, Ying Li, Christos Argyropoulos

Department of Electrical and Computer Engineering: Faculty Publications

The emerging field of plasmonics can lead to enhanced light-matter interactions at extremely nanoscale regions. Plasmonic (metallic) devices promise to efficiently control both classical and quantum properties of light. Plasmonic waveguides are usually used to excite confined electromagnetic modes at the nanoscale that can strongly interact with matter. The analysis of these nanowaveguides exhibits similarities with their low frequency microwave counterparts. In this article, we review ways to study plasmonic nanostructures coupled to quantum optical emitters from a classical electromagnetic perspective. These quantum emitters are mainly used to generate single-photon quantum light that can be employed as a quantum bit …