Atomic, Molecular and Optical Physics Commons^™

Experimental Analyses Of Emission Lines In The Uv/Vis/Nir Range For Astrophysically-Important Elements: From The Iron Group To R-Process Elements, Brynna Neff

All Dissertations

Analysis of astrophysical phenomena requires an understanding of the electronic

structure and transition probabilities of the elements present in that environment,

yet there are still many charge states of heavy elements whose electronic

structures and spectroscopic properties are not yet well understood. To address this,

we investigated the spectroscopic properties of three different elements through an

analysis of spectra collected from three different experimental apparatuses.

In order to better understand the spectroscopic properties of Ni I and II, we

analyzed spectra collected from the Compact Toroidal Hybrid (CTH) apparatus at

Auburn University. In this experiment, a nickel sample was inserted …

Development Of A High-Resolution Mid-Infrared Spectroscopy Apparatus For The Study Of Methane And Other Astrochemical Molecules., S M Shah Riyadh

Electronic Theses and Dissertations

This research documents steps towards building a novel spectroscopic technique, namely, cavity-enhanced double-resonance (CEDR) spectroscopy, for investigating methane (CH₄) and other molecules with significance in astrochemistry. These efforts focus on tackling the complexities of their ro-vibrational energy levels and the inefficiencies in analyzing vibrational spectra, particularly for molecules with high symmetry and strong intramolecular interactions. In the CEDR spectroscopy, the first photon, generated by a continuous-wave optical parametric oscillator (CW-OPO) locked to a Doppler-free saturation absorption line, excites the molecule from its ground level to a selected excited ro-vibrational (rotational-vibrational) level, e.g., that of the asymmetric CH-stretch mode. …

Investigations Of Physical Properties Of Novel Magnetic And Non- Magnetic Two-Dimensional (2d) Alloys., Mohammed Ameen Irziqat

Electronic Theses and Dissertations

This research work reports investigations of structural and physical properties of novel magnetic and non-magnetic 2D alloys. Three techniques were utilized in this investigation: Angle-resolved polarized Raman spectroscopy (ARPRS), Electrical &Thermoelectric power measurements, Magneto-optic Kerr effect (MOKE) spectroscopy. ARPRS and MOKE experiments were constructed during the course of this work. ARPRS was used to study the anisotropy of 2-dimensional black-arsenic phosphors (b-AsxP1-x) as a function of arsenic concentration (x). It was observed experimentally that all Raman modes of the studied samples with x=0, 0.4, 0.8 exhibit polarization dependence. More interestingly, the polarization dependence of Raman modes due to the vibrations …

Electrochemical Modulation Of Surface Plasmon Wave To Investigate Dna-Based Sensing Platforms And Detection Of Sars-Cov2., Anil Sharma

Electronic Theses and Dissertations

This study offers a thorough comparative analysis of optical and electrical signaling strategies for assessing the electrochemical properties of different redox-labeled DNA-based biosensing platforms. In addition, it illustrates the development of an optical interrogation technique with electrochemical modulation of surface plasmon waves (ECM-SPW) as a route for analyzing and implementing DNA-based hybridization sensors. For those quantitative analyses, we chose a model sensing platform composed of a methylene blue (MB)-modified single-stranded DNA (ssDNA) signaling probe and an unlabeled capture ssDNA probe that complements the signaling probe. Two types of signaling probes were employed in this work: one with MB attached to …

Generalizations Of The Hardy Spaces And The Schwarz Boundary Value Problem, William L. Blair

Graduate Theses and Dissertations

We prove that many of the boundary properties associated with functions in the classic holomorphic Hardy spaces on the complex unit disk are present in Hardy classes of solutions to certain nonhomogeneous Cauchy-Riemann equations and higher-order generalizations of these equations. Also, we explicitly solve generalizations of the Schwarz boundary value problem on the complex unit disk and the upper-half plane when the boundary condition is in terms of boundary values in the sense of distributions.

Plasma Diagnostics For Anode Cathode Plasmas And High Energy Density Physics On A Linear Transformer Driver, Robert Beattie-Rossberg

Electrical and Computer Engineering ETDs

A twelve-brick air insulated linear transformer driver (LTD) was characterized by charging to voltages ranging from 30 to 70 kV and delivering energy to two separate resistive loads. Various plasma diagnostics were built and fielded with an emphasis on the design, implementation and analysis of a Mach Zehnder interferometer, a moiré deflectometer and a spectroscopy system providing information on the temporal evolution of plasma electron density and atomic composition. Rogowski coils, XRD radiation detectors, framing camera images and time integrated DSLR images are used to further understand load conditions where current data, x ray radiation data, velocity data and instability …

Implementation Of Python Based High Voltage Tests For Gem Detectors, John Paul Hernandez

Aerospace, Physics, and Space Science Student Publications

The Compact Muon Solenoid, CMS, and other detectors at LHC are in the process of being upgraded for the HL-LHC (High-Luminosity Large Hadron Collider) which will produce more than 5 times the particle interactions than of the current LHC. One upgrade to CMS is the introduction of new GEM detectors (Gaseous Electron Multiplier), GE2/1 and ME0 shown at right are new detectors to CMS and therefore must be tested thoroughly prior to being installed.

Float Like A Butterfly, Sting Like A Bee!, Kobe D. Rome

SACAD: Scholarly Activities

By injecting an electron into the empty pie* molecular orbital (LUMO) of Amino Acids in gas phase, we measure the Vertical Attachment Energies (VAEs) for the formation of short-lived anion states of these species using electron transmission spectroscopy (ETS). Our ETS study, a first of its kind to measure the VAE for the simplest of proteins, Glycine-Glycine (Gly-Gly), is currently in progress. Based on our previous measurements for several Amino Acids including Glycine, we expect a common range of attachment energy (1.50 – 2.00 eV) for Gly-Gly.

All-Optical Probes Of Particle-Like Charge Migration Dynamics, Kyle A. Hamer

LSU Doctoral Dissertations

Particle-like charge migration (CM) is the coherent, back-and-forth motion of a positively-charged electron hole along the backbone of a molecule following a sudden ionization. CM in small molecules generally occurs on an Angstrom (10^-10 m) spatial scale and an attosecond (10^-18 s) timescale. I use time-dependent density-functional theory (TDDFT) to simulate CM modes in organic molecules, and to explore all-optical probes of this attosecond electron dynamics using high-harmonic spectroscopy (HHS). By leveraging my results from previous studies of two-center interferences in carbon dichalcogens, in which I separated the harmonic signal into contributions from individual Kohn-Sham orbitals, I first …

Nowcasting Solar Euv Irradiance With Photospheric Magnetic Fields And The Mg Ii Index, Kara L. Kniezewski, Samuel J. Schonfeld, Carl J. Henney

Student Publications

A new method to nowcast spectral irradiance in extreme ultraviolet (EUV) and far ultraviolet (FUV) bands is presented here, utilizing only solar photospheric magnetograms and the Mg II index (i.e., the core-to-wing ratio). The EUV and FUV modeling outlined here is a direct extension of the SIFT (Solar Indices Forecasting Tool) model, based on Henney et al. (2015, https://doi.org/10.1002/2014sw001118). SIFT estimates solar activity indices using the earth-side solar photospheric magnetic field sums from global magnetic maps generated by the ADAPT (Air Force Data Assimilative Photospheric Flux Transport) model. Utilizing strong and weak magnetic field sums from ADAPT maps, Henney …

Group Iv Topological Quantum Alloy And The Role Of Short-Range Order: The Case Of Ge-Rich Ge1–XPbX, Yunfan Liang, Shunda Chen, Xiaochen Jin, Damien West, Shui-Qing Yu, Tianshu Li, Shengbai Zhang

Electrical Engineering and Computer Science Faculty Publications and Presentations

Despite the explosion of interest in topological materials over the last decades, their applications remain limited due to challenges in growth and incorporation with today’s microelectronics. As a potential bridge to close this gap, we investigate the group-IV alloy Ge_1–xPb_x, in the Ge-rich condition using density functional theory and show that relatively low concentrations of Pb (~9.4%) can lead to a topological phase transition. Furthermore, the calculation of the Z₂ invariant for both the random alloy and the alloy with short-range order (SRO) indicate that the topological phase of the material can be directly modified …

Modeling And Numerical Analysis Of The Cholesteric Landau-De Gennes Model, Andrew L. Hicks

LSU Doctoral Dissertations

This thesis gives an analysis of modeling and numerical issues in the Landau-de Gennes (LdG) model of nematic liquid crystals (LCs) with cholesteric effects. We derive various time-step restrictions for a (weighted) $L^2$ gradient flow scheme to be energy decreasing. Furthermore, we prove a mesh size restriction, for finite element discretizations, that is critical to avoid spurious numerical artifacts in discrete minimizers that is not well-known in the LC literature, particularly when simulating cholesteric LCs that exhibit ``twist''. Furthermore, we perform a computational exploration of the model and present several numerical simulations in 3-D, on both slab geometries and spherical …

Advancements In Characterization Of Ancient Potteries From Southeast Asia: A Review Of Analytical Techniques, Chitnarong Sirisathitkul

Makara Journal of Science

Ancient potteries offer valuable information regarding technological advancements, life dynamics, cultural diversity, and trade routes in the past. Earthenware, stoneware, and porcelain from Southeast Asia have been characterized using several analytical techniques, as reviewed in this article. Fluorescent and diffracted X-rays give rise to elemental and phase compositions, respectively. Examination of molecular bonds requires vibrational spectroscopy, which is useful for the identification of organic materials in ancient potteries. With the advent of portable X-ray fluorescence and Raman spectrometry, on-site analysis of archeological ceramics is now possible. For in-depth analysis, synchrotron light sources can provide new insights into artifacts through X-ray …

Size Limits And Fission Channels Of Doubly Charged Noble Gas Clusters, Ianessa Stromberg, Stefan Bergmeister, Lisa Ganner, Fabio Zappa, Paul Scheier, Olof Echt, Elisabeth Gruber

Faculty Publications

Small, highly charged liquid droplets are unstable with respect to spontaneous charge separation when their size drops below the Rayleigh limit or, in other words, their fissility parameter X exceeds the value 1. The absence of small doubly charged atomic cluster ions in mass spectra below an element-specific appearance size n_a has sometimes been attributed to the onset of barrierless fission at X = 1. However, more realistic models suggest that n_a marks the size below which the rate of fission surpasses that of competing dissociative channels, and the Rayleigh limit of doubly charged van der Waals clusters …

Spectroscopic End Point Detection With An Electron Beam Evaporator, Ryan Mcgraw

University Honors Theses

Spectroscopic end point detection is a common tool used for measuring slope changes in wavelength intensity. Using algorithms able to apply this concept, coatings will be able to be dynamically measured in real time and stopped at the appropriate level to ensure process uniformity. It is currently applied to reductive processes such as etching, where the surface will start to be eaten away, creating a plasma. When the entire amount of a material on a substrate has been eaten away, the plasma will change color as it is beginning to etch a different material. Using a spectrometer, this point where …

Doubly Charged Dimers And Trimers Of Heavy Noble Gases, Gabriel Schöpfer, Stefan Bergmeister, Milan Ončák, Ianessa Stromberg, Masoomeh Mahmoodi-Darian, Paul Scheier, Olof Echt, Elisabeth Gruber

Faculty Publications

Many doubly charged heteronuclear dimers are metastable or even thermodynamically stable with respect to charge separation. Homonuclear dicationic dimers, however, are more difficult to form. He₂²⁺ was the first noble gas dimer predicted to be metastable and, decades later, observed. Ne₂²⁺ is the only other dicationic noble gas dimer that has been detected so far. Here, we present a novel approach to form fragile dicationic species, by post-ionization of singly charged ions that are embedded in helium nanodroplets (HNDs). Bare ions are then extracted by colliding the HNDs with helium gas. We detect homonuclear doubly charged …

Stoner Instability-Mediated Large Magnetoelectric Effects In 2d Stacking Electrides, Zhigang Gui, Haiyan Zhu, Zhe Wang, M. Umar Farooq, Laurent Bellaiche, Li Huang

Physics Faculty Publications and Presentations

Strong magnetoelectric effects in single-phase two-dimensional (2D) materials are extremely rare in nature. Here by first-principles calculations, we find a strong magnetoelectric coupling in polar stacking bilayer Hf₂S that allows the reversal of net magnetic moments with the reversal of electric dipoles. Further analysis shows that such strong magnetoelectric effects benefit from the Stoner instability of surface Hf atoms triggered by polar stacking. Moreover, an unexpectedly large out-of-plane electric polarization (which is at least two times larger than that of bilayer BN) survives in the material, despite its metallicity. The large electric polarization is ascribed to the delocalized …

Global Empirical Model Of Sporadic-E Occurrence Rates, Eli V. Parsch

Theses and Dissertations

Encompassing the Earth, the ionosphere presents unique challenges to modern communication, navigation, and surveillance technologies. Intense ionization enhancements known as sporadic-E (Es), can degrade and disrupt signals in unpredictable ways. Much work has been done to understand this phenomenon and more recent efforts have attempted to model its behavior and impacts. However, there have been limited efforts at modeling global Es occurrence rates (OR) at high time resolutions. This study develops a global empirical model of blanketing sporadic-E (fbEs) occurrence rates using a Karhunen-Lo´eve Expansion (KLE) of global fbEs OR climatologies built with Global Positioning System radio occultations (GPS-RO) and …

Neutron Spectrum Unfolding From Activation Foils Irradiated In Gamble Ii Using Deuterated Polyethylene Anodes, Christopher J. Smith

Theses and Dissertations

Neutrons can cause irreparable harm to electronics, and experiments are needed to understand their effects fully. This work explores using pulsed power, which is low-cost compared to other sources, to create a useful neutron-rich environment. Deuterated polyethylene was used as anode and catcher material to generate the neutrons from the Deuterium-Deuterium (DD) fusion reaction. A simple, effective, and repeatable method was employed to directly cast deuterated polyethylene onto polyethylene sheets to fabricate the anode and catcher. The DD reactions were made by an ion beam-driven pulsed power generator, Gamble II, with the catcher located in the cathode. Zinc, copper, aluminum, …

Analyzing The Effects Of Atmospheric Turbulence On Polarization-Entangled Photon Pairs Using Quantum State Tomography, Noah S. Everett

Theses and Dissertations

To help in building a quantum-based communication link, we experimentally designed a system to simulate atmospheric turbulence and characterize its effects on a polarization-entangled photon-pair source. The simulated turbulence is constructed using two afocal optical systems with a phase plate inserted in each to mimic both weak and strong atmospheric turbulence respectively. After propagation, quantum state tomography (QST) is performed on each pair to reconstruct the density matrix of the pair’s overall polarization state. In characterization of the simulated turbulence, we were able to reach strengths up to a D/r0 of 18.2, which begins to approach the strong turbulent regime. …