Materials Chemistry Commons^™

Preparation And Performance Investigation Of Li-Sgo Doped Semi-Ipns Porous Single Ion Conducting Polymer Electrolyte, Yun-Feng Zhang, Jia-Ming Dong, Chang Tan, Shi-Kang Huo, Jia-Ying Wang, Yang He, Ya-Ying Wang

Journal of Electrochemistry

Herein, the lithiated sulfonated graphene oxide (Li-SGO) was successfully prepared via three steps by sulfonation of graphene oxide with 3-merraptnpropylt rimethnxysilane, oxidation of thiol into sulfonate with hydrogen peroxide and lithiation of sulfonate with aqueous lithium hydroxide. The as-prepared Li-SGO was then introduced into the semi-interpenetrating networks of single ion conducting polymer electrolyte (Li-SGO-FPAS) and poly vinylidenefluoride-hexafluoro propylene (PVDF-HFP) binder by in-situ polymerization to fabricate the porous single ion conducting polymer electrolyte membrane (Li-SGO-po-FPAS) generated from the poor compatibility between aromatic Li-SGO-FPAS and aliphatic PVDF-HFP binder. The key properties such as morphology, porosity, solvent uptake, mechanical …

Combined Applications Of Photocurrent Spectroscopy, Photoluminescence Spectroscopy And Uv-Vis Spectroscopy For Nano-Semiconductor Based Photoelectric Devices, Si-Da Bian, Jian-Zhang Zhou, Zhong-Hua Lin

Journal of Electrochemistry

The electronic structures and properties of nano-semiconductors are quite different from those of bulk semiconductors due to the nano-size effect (such as quantum size effect). Moreover, when the nano-semiconductor materials are deposited onto the substrate to construct a device, their electronic properties are also affected by the substrate or other components, which may lead to different performances of nano-semiconductors based photoelectric devices, and consequently, different corresponding characterization methods are needed. The combination of photocurrent spectroscopy, photoluminescence spectroscopy with UV-Vis absorption spectroscopy can provide a more comprehensive characterization for the electronic properties and photoelectrochemical performances of nano-semiconductors in photoelectric devices. Our …

Preparations And Electrochemical Properties Of Bc/Coni2S4@Ppy Flexible Composites For Supercapacitors, Si-Yuan Peng, Shi-Run Yang, Jing-Hong Zhou, Zhi-Jun Sui, Tao Zhang, Yi Shi, Xing-Gui Zhou

Journal of Electrochemistry

Flexible supercapacitor is one of the most promising energy storage devices for portable and wearable electronic products due to its advantages of high power density, fast charging and long cycle life. Therefore, self-supporting flexible electrode materials with high performance have attained more and more attention both in academia and in industry recently. In this work, using bacterial cellulose (BC) as a flexible substrate, the bacterial cellulose/nickel-cobalt sulfide@polypyrrole (BC/CoNi₂S₄@PPy) flexible composites with three-dimensional porous network and good conductivity were prepared by a combined solvothermal-in-situ polymerization-vacuum filtration method. The samples were characterized by X-ray diffraction, …

Study On Li3Bo3 Interface Modification Of Garnet Solid Electrolyte, Gui-Wei Chen, Zheng-Liang Gong

Journal of Electrochemistry

Garnet solid-state electrolytes have become the research hotspot due to their high ionic conductivity, wide electrochemical stability window and good air stability. However, there are still a series of problems to be solved. The poor contact between the lithium (Li) metal and garnet pellet make it difficult to build stable ion diffusion channels, resulting in large interfacial resistance. The continuous growth of lithium dendrites can penetrate the electrolyte pellet and cause a short circuit in the solid-state battery. Herein, a novel strategy is proposed to improve the wettability of LLZTO electrolyte with Li metal, via interfacial modification of LLZTO electrolyte …

Research Progress On Transition State Of Organic Electrode Materials, Xue-Qian Zhang, Zhou-Guang Lu, Wei-Wei Huang

Journal of Electrochemistry

With the increasing requirements for high energy density, long lifetime, high safety, environmentally friendly fabrication, and sustainable development of large energy storage devices, the society calls for new electrode materials in rechargeable batteries beyond traditional inorganic materials which are limited by specific capacity. Organic electrode materials have been widely used in rechargeable batteries due to their advantages of large theoretical capacity, designable structures and environmentally friendly fabrications. In this review, the radical intermediates of organic electrode materials produced in the charging-discharging process (redox reaction) and their types are systematically reviewed. The stability of radical intermediates controlled by changing the structure …

Research Progress In Electrodeposition Technology Of Titanium-Based Iridium Oxide Electrode, Dan-Dan Wu, Xu Wu

Journal of Electrochemistry

Titanium-based iridium oxide electrode has been widely used in various fields, such as electrocatalytic oxidation, biomedical applications, hydrometallurgical metal recovery, electro-osmotic dewatering, etc. At present, it is mainly prepared by traditional thermal decomposition method, however, which has high cost, cumbersome process, mainly relying on manual labor and cannot be mass-produced yet. It is, therefore, urgently necessary to explore new preparation technologies by focusing on electrodeposition technology, with technological characteristics such as eco-friendly and sustainable development. This article systematically discusses the research progress in iridium oxide electrodeposition preparation technology from the aspects of deposition solution formulation, base material selection and treatment, …

Preparations And Electrocatalytic Ethanol Properties Of Palladium Intercalated Hydrotalcite, Shou-Xun Hu, Liang Li, Jun-Hao Yang, Liu-Qiang Li, Zhi-Hao Jin

Journal of Electrochemistry

High-performance electrocatalysts play a vital role in the commercial application of direct fuel cells. Current anode materials still have such problems as low activity, easy poisoning and high cost. In this study, a new type of nano- palladium (Pd) catalyst was prepared by dipping method using layered double hydroxides (LDHs) as the carrier. X-ray diffractometer, scanning electron microscope (SEM), inductively coupled plasma mass spectrometer (ICP-MS), energy spectrometer, transmission electron microscope (TEM), cyclic voltammetry, chronoamperometry and electrochemical impedance spectroscope were used to analyze the structure and electrocatalytic performance of the catalyst. The results showed that the newly prepared Pd/Mg-Al-LDHs still maintained …

Research Progress Of Sio2 Regrowth During Selective Etching Process In 3d Nand Manufacture Procedure, Zi-Han Zhou, Yun-Wen Wu, Ming Li, Su Wang

Journal of Electrochemistry

As one of the most significant memory chips in semiconductor market, NAND has been developed from two-dimension (2D) to three-dimension (3D). Due to the three-dimensional memory structure of 3D NAND, the capacity density, read-write speed and reliability of memory chips have been greatly improved, as well as the reduction of power dissipation. It is by nitride-oxide selective etching process in the alternate stacked structure of 3D NAND that the inter-dielectric layers can be obtained. The more stack layers, the better performance of chips will be. Meanwhile, however, silicon dioxide (SiO₂) would regrow on the corner of oxide layers, …

Influence Of Resveratrol On Performance Of Long-Term Storage’S Lithium-Ion Battery Electrolyte, Lei Zhang, Xu-Ping Zhang, Si-Wei Zhang, Quan-Chao Zhuang

Journal of Electrochemistry

Electrolyte of lithium-ion battery usually goes through processes of filling, transportation and storage from the completion of manufacture to the use. Understanding the influence of long-term storage process on performance of lithium-ion battery electrolyte is of theoretical significance for production of lithium-ion battery. Scanning electron microscope (SEM) images showed that the solid electrolyte interface (SEI) film formed on the surface of the graphite electrode was thicker in the base electrolyte after 6 months of storage. The charge/discharge test results showed that the reversible cycle capacity and cycle stability (capacity retention rate) of graphite electrode decreased significantly after 6 months of …

Syntheses Of Na3V2(Po4)2O2F As A Cathode For Sodium Ion Battery Application, Kai Wu

Journal of Electrochemistry

High-temperature solid-state method, hydro-thermal method and solvo-thermal method have been mainly employed to synthesize Na₃V₂(PO₄)₂O₂F (NVPF) cathode materials. However, these methods are energy consuming and complicated, which is not applicable for a large scale industrial production. In this study, a rather low-temperature (70℃) co-precipitation strategy was proposed to synthesize NVPF cathode materials. The as-prepared NVPF cathode materials showed a spherical shape with a diameter of 400 ~ 500 nm, and exhibited a sodium storage of 105.6 mAh·g^-1 and an efficiency of 90.06%. After a simple thermal process, the specific …

Doped-Magnesium Manganese Oxide Cathode For Rechargeable Magnesium Batteries, Nurhidayu Harudin

Student Works (2020-2029)

Magnesium has numerous good characteristics that make it attractive as an electrode material for rechargeable batteries. There are many advantages of Magnesium (Mg) such as available in abundance, ease of handling, low toxicity and environmental friendly. Due to its benefits, magnesium ion battery can be considered as an alternative to lithium in future. In the present work, the improvement electrochemical properties of magnesium-based cathode material, MgMn2O4 was done by adding calcium (Ca) and strontium (Sr) as dopant i.e MgMn2-xCaxO4 and MgMn2-xSrxO4. These materials with compositions of x=0.1,0.2,0.3,0.4,0.5 were synthesized by self-propagating combustion method using citric acid as a reducing agent. …

Exploring The Silent Aspect Of Carbon Nanopores, Teresa J. Bandosz

Publications and Research

Recently, owing to the discovery of graphene, porous carbons experienced a revitalization in their explorations. However, nowadays, the focus is more on search for suitable energy advancing catalysts sensing, energy storage or thermal/light absorbing features than on separations. In many of these processes, adsorption, although not emphasized sufficiently, can be a significant step. It can just provide a surface accumulation of molecules used in other application-driving chemical or physical phenomena or can be even an additional mechanism adding to the efficiency of the overall performance. However, that aspect of confined molecules in pores and their involvement in the overall performance …

Piezomagnetic Switching And Complex Phase Equilibria In Uranium Dioxide, Daniel J. Antonio, Joel T. Weiss, Katherine S. Shanks, Jacob P.C. Ruff, Marcelo Jaime, Andres Saul, Thomas Swinburne, Myron Salamon, Keshav Shrestha, Barbara Lavina, Daniel Koury, Sol M. Gruner, David A. Andersson, Christopher R. Stanek, Tomasz Durakiewicz, James L. Smith, Zahirul Islam, Krzysztof Gofryk

Physics & Astronomy Faculty Research

Actinide materials exhibit strong spin-lattice coupling and electronic correlations, and are predicted to host new emerging ground states. One example is piezomagnetism and magneto-elastic memory effect in the antiferromagnetic Mott-Hubbard insulator uranium dioxide, though its microscopic nature is under debate. Here, we report X-ray diffraction studies of oriented uranium dioxide crystals under strong pulsed magnetic fields. In the antiferromagnetic state a [888] Bragg diffraction peak follows the bulk magnetostriction that expands under magnetic fields. Upon reversal of the field the expansion turns to contraction, before the [888] peak follows the switching effect and piezomagnetic 'butterfly' behaviour, characteristic of two structures …

Interactions Of Organic Fluorophores With Plasmonic Surface Lattice Resonances, Robert J. Collison

Dissertations, Theses, and Capstone Projects

It is common knowledge that metals, alloys and pure elements alike, are lustrous and reflective, the more so when a metal surface is flat, polished, and free from oxidation and surface fouling. However, some metals reflect visible light, in the 380 nm to 740 nm range of wavelengths, much more strongly than others. In particular, some metals reflect wavelengths in certain portions of the ultraviolet (UV), visible, and near-infrared (NIR) regime, let us say 200 nm to 2000 nm, while absorbing light strongly in other segments of this range. There are several factors that account for this difference between various …

Experimental And Computational Design Of Nanostructured Materials For High Performance Supercapacitor Devices, Basant A. Ali

Theses and Dissertations

Both energy conversion and storage technologies need to be developed hand-to-hand simultaneously to overcome the energy crises. To this end, supercapacitors (SCs) have the potential to be the energy storage platform due to their fast charging capability and long cycling stability. However, their low energy is the bottleneck towards their wide implementation compared to batteries. Also, current research is based on guess and check methods to modify electrode materials with limited properties prediction. In this thesis, density functional theory (DFT) has been employed as a tool to identify potential SC electrode materials. Then, the gained knowledge was used to develop …

Nanoengineered Materials For Energy Conversion & Storage Applications: A Density Functional Theory Study, Ahmed Biby

Theses and Dissertations

The conventional approach for the development of novel materials has become long relative to the desired product development cycle. Thus, the sluggish pace of the development of materials within the conventional approach hinders the rapid transformation of the scientific outcomes into useful technological products. To this end, the field of hierarchical materials informatics evolved to bridge this gap. In this field, the multiscale material internal structure is considered the starting point and the core of this approach. This being said, the density functional theory (DFT) was used to generate useful materials data for the advancement of the hierarchical materials data-bases …

Synthesis And Characterization Of Perovskite-Based Materials For Memory Device Application, Gregory Thien Soon How

Student Works (2020-2029)

This project aims to study the resistive switching behaviour in memory devices using perovskites-based structures. A hybrid organic-inorganic lead halide perovskite was studied in this project, specifically methylammonium lead triiodide, CH3NH3PbI3 or MAPbI3 perovskite. The effect of the various counter electrodes in MAPbI3 perovskite was investigated by fabricating MAPbI3 perovskite on Indium Tin Oxide (ITO). Three commonly used electrodes which are Aluminium (Al), Silver (Ag), and Gold (Au) were thermally evaporated on top of the MAPbI3 perovskite layer. It was found that the ITO/MAPbI3/Al exhibits Resistive Random Access Memory (ReRAM) behaviour with SET voltage (VSET) of 4.5 V and RESET …

Development Of Engineered Soil Surrogates For Modeling Natural Soil Sorption Behavior, Ghada Yehia Abdalla

LSU Doctoral Dissertations

The land produces more than 95% of the global food supply, and with a continuously growing population, we need to optimize the use of the available agricultural land. Soil organic matter (SOM) is an essential component of soils, especially concerning their fertility and sorption behavior. The chemical composition of the SOM consists of lipids, lignin, and cellulose. However, the heterogeneous and complex nature of SOM, and real soils, makes their study challenging and introduces uncontrollable factors.

Therefore, structural mimics of natural soils with increasing complexity representing the real soil functionality were synthesized and evaluated for bulk properties related to their …

Synthesis Of New Anilinoquinazoline Derivatives As Potential Anticancer Agents: Antiproliferative Activity, Molecular Docking And Molecular Dynamics Studies, Muhammad Kumayl Abdul Wahab

Student Works (2020-2029)

Current reversible epidermal growth factor (EGFR) tyrosine kinase inhibitors of the non-small cell lung cancer (NSCLC) have been resisted by T790M mutation, while irreversible inhibitors introduced to overcome the mutation have faced resistance from C797S mutation. In the effort to discover potential reversible EGFR inhibitors, two series of anilinoquinazoline derivatives were synthesized and characterized, studied for their in vitro antiproliferative activity against NSCLC cell lines, namely A549, H1650 and H1975, and studied for the plausible binding mode in epidermal growth factor receptor kinases with different mutations through molecular docking. In the first series, the anilinoquinazoline scaffold was derivatized through the …

Numerical Reconstruction Of Spalled Particle Trajectories In An Arc-Jet Environment, Raghava S. C. Davuluri, Sean C. C. Bailey, Kaveh A. Tagavi, Alexandre Martin

Mechanical Engineering Faculty Publications

To evaluate the effects of spallation on ablative material, it is necessary to evaluate the mass loss. To do so, a Lagrangian particle trajectory code is used to reconstruct trajectories that match the experimental data for all kinematic parameters. The results from spallation experiments conducted at the NASA HYMETS facility over a wedge sample were used. A data-driven adaptive methodology was used to adapts the ejection parameters until the numerical trajectory matches the experimental data. The preliminary reconstruction results show that the size of the particles seemed to be correlated with the location of the ejection event. The size of …