Biological Degradation Of Acetaldehyde In Southern California Coastal Waters,
2015
Chapman University
Biological Degradation Of Acetaldehyde In Southern California Coastal Waters, Mary Senstad, Sovanndara Hok, Ori Barashy, Catherine D. Clark, Warren J. De Bruyn
Student Scholar Symposium Abstracts and Posters
Oxygenated hydrocarbons are ubiquitous in the atmosphere with levels ranging from low ppt (acetaldehyde) to low ppb (methanol). As an OH sink and an atmospheric HOx and ozone source, oxygenated hydrocarbons have a direct impact on the oxidative capacity of the atmosphere. The oceans are one of the largest sources of uncertainty in current atmospheric budget estimates of these species. A better understanding of the processes that produce and destroy these species in seawater would improve our understanding of the role of the oceans in cycling these species into or out of the atmosphere. We have measured the degradation rate …
Effects Of Ecologically Realistic Heating Profiles On Feeding In The Intertidal Hermit Crab, Pagurus Sameulis,
2015
Chapman University
Effects Of Ecologically Realistic Heating Profiles On Feeding In The Intertidal Hermit Crab, Pagurus Sameulis, Paige Davis
Student Scholar Symposium Abstracts and Posters
The intertidal zone is an ideal habitat to investigate effects of global warming because species living in it are very close to their physiological limits. Initial studies of invertebrate physiological responses to heat stress have employed relatively abrupt increases in temperature. My research investigates effects of ecologically more realistic temperature profiles on feeding in the intertidal hermit crab, Pagurus sameulis. Recent work in the Wright lab showed that feeding in this species is inhibited by an abrupt increase in temperature. Because temperature change in the natural environment of Pagurus is much more gradual, I hypothesize that such a gradual temperature …
Biological Degredation Of Acetaldehyde In Southern California Wetlands,
2015
Chapman University
Biological Degredation Of Acetaldehyde In Southern California Wetlands, Anthony Castagnola, Brandon Lamb, Mary Senstad, Sovandara Hok
Student Scholar Symposium Abstracts and Posters
Oxygenated hydrocarbons are ubiquitous in the atmosphere with levels ranging from low ppt (acetaldehyde) to low ppb(methanol). As an OH sink and an atmospheric HOx source, oxygenated hydrocarbons have a direct impact on the oxidative capacity of the atmosphere. A better understanding of the processes that produce and destroy these species in natural water would improve our understanding of the role that these systems play in cycling these species into or out of the atmosphere. These species can be lost to chemical, photochemical, and partical mediated (abiotic and biotic) processes in natural waters. Chemical loss and photochemical loss are believed …
Analysis Of Secondary Wastewater Treatment,
2015
Chapman University
Analysis Of Secondary Wastewater Treatment, Jennifer Magana
Student Scholar Symposium Abstracts and Posters
At the Irvine Ranch Water District, two types of secondary treatment are utilized: a sludge and Dual Media Filters (DMF) process and Membrane Bioreactor (MBR) process. This study was proposed to analyze the electrical conductivity (EC) of each secondary effluent and possible reasons for differences. After testing the two effluents using an electrical conductivity probe and ion chromatography, it was discovered that there is no significant difference between the two, though secondary treatment raises the nitrate levels in general.
Analysis Of Nitrogen And Phosphorus Nutrients In Lake Sediment,
2015
James Madison University
Analysis Of Nitrogen And Phosphorus Nutrients In Lake Sediment, Kelsey L. Berrier
Senior Honors Projects, 2010-2019
Analytical methods for the determination of nitrogen and phosphorus nutrients (NO3-N, NH4-N and PO4-P) in sediment were studied with the goal of developing extraction steps compatible with analysis by ion chromatography (IC). Research focused on extractant solution composition, Dionex OnGuard® sample pretreatment cartridges for salt removal, and chromatographic resolution. Aqueous test samples, lake sediment samples and spiked lake sediment samples were analyzed. Dionex Ag, Ag/H, and H cartridges were studied for the pretreatment step. Silver (Ag) cartridges were found effective in removing >99% of interfering chloride ion to allow NO3-N determination …
Green Chemistry As A Tool For Understanding The Toxic Substances Control Act: A Lecture Module For Undergraduate Students,
2015
University of Connecticut - Storrs
Green Chemistry As A Tool For Understanding The Toxic Substances Control Act: A Lecture Module For Undergraduate Students, Molly R. Blessing
Honors Scholar Theses
The Toxic Substances Control Act (TSCA) is the central form of chemical regulation existent in the United States today, yet scientists are often unaware or uncertain of its provisions. Violations of TSCA by unknowing chemists set industry and government unnecessarily at odds. A lecture on TSCA was developed for undergraduate students that uses the concept of green chemistry to promote interest and incentivize learning. Green chemistry methods are cleaner and less wasteful than traditional chemical ones, and many companies using them are at the forefront of technological innovation. The lecture explains both green chemistry and TSCA, includes company case studies, …
Investigation Of The Chemical Protection Capacity Of Common Shoe Materials In Undergraduate Laboratories,
2015
East Tennessee State University
Investigation Of The Chemical Protection Capacity Of Common Shoe Materials In Undergraduate Laboratories, Sarah E. Lawson
Undergraduate Honors Theses
The objective of this study was to evaluate the chemical resistance of common shoe materials regularly worn in undergraduate chemistry laboratories by subjecting the materials to hydrochloric acid and sodium hydroxide. The materials tested were leather, canvas cotton, and polyester. Due to the lack of restriction on undergraduate laboratory footwear, the research discussed in this thesis is important to undergraduate universities. Currently, many universities across the nation only require undergraduate students to wear close-toed, close-heeled shoes in chemistry laboratories, and often the resistance of the shoe material to acids and bases may not be taken into careful consideration. Overall, the …
Applications Of Pure And Recycled Polymeric Micronanofiber For The Removal Of Oil Spills,
2015
United Arab Emirates University
Applications Of Pure And Recycled Polymeric Micronanofiber For The Removal Of Oil Spills, Afra Gharib Khamis Al-Blooshi Al-Blooshi
Theses
Cleaning oil spills is a universal concern due to its environmental impact. The aim of this study is to study the effectiveness and applications of pure and recycled polymers in clean-up and the recovery of crude oil from oil spills. In this study, micro-nanofibers of analytical-grade and commercial polystyrene samples were prepared by electrospinning technique. Fiber size distribution was shown to vary with the electrospinning parameters and type of polymer. Fibrous sorbents prepare hereafter were investigated for their efficiency in removing oil spills. Results showed a variation in the sorption capacities of the fibers to various types of crude oils …
Assessment Of Silk Degradation Using Pyrolysis,
2015
Bryant University
Assessment Of Silk Degradation Using Pyrolysis, Conor Makepeace
Honors Projects in Science and Technology
The purpose of this research is to investigate the molecular constitution of silk and the specific causes of post-production degradation in silk material. This capstone project focused specifically on the conditions and degradation of ancient Chinese silk products provided by the Chinese National Silk Museum. Modern silk products were artificially degraded and compared to the ancient silk using Py-GC-MS and comparative analytic techniques. This investigation revealed that the ancient silk products most likely underwent degradation in elevated temperatures while in the presence of moisture and the absence of sunlight or UV radiation during long term burial.
Impact Of Biogenic Volatile Organic Compounds On Peroxyacetyl Nitrate Production In The Southeast United States,
2015
Purdue University
Impact Of Biogenic Volatile Organic Compounds On Peroxyacetyl Nitrate Production In The Southeast United States, Christopher John Groff
Open Access Theses
Our atmosphere is arguably the fundamental entity that has made life on Earth possible. Knowledge of the delicate nature of our atmosphere continues to spread as "green" initiatives promote awareness of human influence on the environment. However, many climate scientists fear that unless immediate mitigation occurs, the reversal of human impact on our planet will be impossible, leading to unknown consequence. Perturbations to natural processes are likely to cause drastic change to the planet as we know it and ultimately result in significant health issues. It is important to push the boundaries of our understanding of atmospheric processes with intent …
Spectroscopic Characterization And Photochemistry Of Nitrogen-Containing Molecules Relevant To Titan's Atmosphere,
2015
Purdue University
Spectroscopic Characterization And Photochemistry Of Nitrogen-Containing Molecules Relevant To Titan's Atmosphere, Deepali N. Mehta-Hurt
Open Access Dissertations
Titan's atmospheric chemistry has been the source of intrigue since the planetary body's discovery. Though there is a growing understanding of the atmospheric chemistry of small molecules on Titan, much less is known about larger molecule formation, and particularly about nitrile chemistry. This dissertation characterizes nitrile/isonitrile intermediates that are postulated to be important in Titan's atmosphere, adding to the necessary foundation for understanding Titan's atmospheric chemistry. The vibronic spectroscopy of para-diisocyanobenzene (pDIB, C≡N-Ph-N≡C) has been characterized as a first step towards photochemical studies that can test the transformation of the isonitrile group to other nitrogen-based functionalities.p …
Blue Carbon In Freshwater / Brackish Marshes On The Barrier Islands Of Virginia Aboveground Net Primary Productivity And Carbon Pools,
2015
Old Dominion University
Blue Carbon In Freshwater / Brackish Marshes On The Barrier Islands Of Virginia Aboveground Net Primary Productivity And Carbon Pools, Emily Caitlin Adams
Biological Sciences Theses & Dissertations
"Blue carbon" is a relatively new concept describing carbon distributed tidally and sequestered via net production within coastal ecosystems, including seagrass beds, mangrove forests, and salt-water marshes. These systems sequester carbon at least 10 times faster than terrestrial systems. Fresh to brackish wetlands that receive irregular tidal influence due to overwash and storm events have not been typically studied as blue carbon systems. My objective was to quantify carbon pools within four interdunal fresh to brackish marshes on Hog Island, Virginia to determine their blue carbon potential. Marshes 1 and 2 were farthest from the ocean, below and above a …
Blue Carbon In Coastal Freshwater/Brackish Marshes On The Barrier Islands Of Virginia: Belowground Carbon Dynamics,
2015
Old Dominion University
Blue Carbon In Coastal Freshwater/Brackish Marshes On The Barrier Islands Of Virginia: Belowground Carbon Dynamics, Nathan M. Sedghi
Biological Sciences Theses & Dissertations
Some coastal ecosystems sequester substantially more carbon (blue carbon) than land locked systems due to high net primary production and deposition associated with oceanic influences. Most blue carbon research has focused on mangroves, seagrass beds, and salt marshes. Studies on blue carbon potential of coastal freshwater marshes are less common. Barrier islands frequently flood, with seawater reaching interior ecosystems. I examined brackish/freshwater marshes on Virginia barrier islands for possible roles as blue carbon systems. I studied four interior marshes on Hog Island, which varied in proximity to a direct overwash path and protection by a trail berm that divides northern …
Polycyclic Aromatic Hydrocarbon Determination In Liver Of Menhaden Exposed To The Deep Water Horizon Oil Spill,
2015
Seton Hall University
Polycyclic Aromatic Hydrocarbon Determination In Liver Of Menhaden Exposed To The Deep Water Horizon Oil Spill, Rebecca Hawke
Seton Hall University Dissertations and Theses (ETDs)
The April 2010 BP® oil spill has caused great concern for ecological impacts in the Gulf of Mexico. Crude oil contains polycyclic aromatic hydrocarbon (PAHs) and oil spills increase the exposure of aquatic organisms to this class of chemicals. The overall detrimental health effects associated with PAH exposure depend on the exposure period, the concentration of PAHs, and the toxicity of the PAHs in the mixture. Brevoortia tyrannus and Brevoortia patronus are filter feeding fish commonly known as menhaden and account for over 40% of the commercial industry fisheries catch. As primary consumers, they are a major link in the …
On-Road Heavy-Duty Vehicle Emissions Monitoring System,
2015
University of Denver
On-Road Heavy-Duty Vehicle Emissions Monitoring System, Gary A. Bishop, Rachel Hottor-Raguindin, Donald H. Stedman, Peter Mcclintock, Ed Theobald, Jeremy D. Johnson, Doh-Won Lee, Josias Zietsman, Chandan Misra
Fuel Efficiency Automobile Test Publications
The introduction of particulate and oxides of nitrogen (NOx) after-treatment controls on heavy-duty vehicles has spurred the need for fleet emissions data to monitor their reliability and effectiveness. The University of Denver has developed a new method for rapidly measuring heavy-duty vehicles for gaseous and particulate fuel specific emissions. The method was recently used to collect 3,088 measurements at a Port of Los Angeles location and a weigh station on I-5 in northern California. The weigh station NOx emissions for 2014 models are 73% lower than 2010 models (3.8 vs. 13.9 gNOx/kg of fuel) and …
Comparing Three Methods For Estimating Ozone Depleting Substance Substitute Greenhouse Gases: Case Study Of The New York City Region,
2015
Hunter College
Comparing Three Methods For Estimating Ozone Depleting Substance Substitute Greenhouse Gases: Case Study Of The New York City Region, Wallace A. Murray Iii
Theses and Dissertations
This thesis evaluates the United States Environmental Protection Agency (EPA) method for estimating emissions from one source, Ozone Depleting Substances Substitutes (ODS substitutes) by comparing results for the New York City Metropolitan Statistical Area (NYC-MSA) with results from two other methodologies. The EPA’s method utilizes population data and GDP data to estimate and geographically allocate emissions, with little regard for the geographies of industrial activity. The two alternative methods use data for industrial employment and activity to provide results for comparison and perhaps a more accurate accounting and allocation of emissions throughout the NYC-MSA.
Chloroamino Acids As A Chemical Explanation For Viking Labeled Release Soil Activity On Mars,
2015
California Polytechnic State University, San Luis Obispo
Chloroamino Acids As A Chemical Explanation For Viking Labeled Release Soil Activity On Mars, John C. Hironimus
STAR Program Research Presentations
The Viking missions to Mars, which took place in the 1970’s, performed several experiments on martian soil in an attempt to discern if there was microbial life present. In one set of experiments, a nutrient solution containing amino acids and organic substrates tagged with carbon-14 was injected into sample cells containing martian soil, and the evolution of labeled CO2 was monitored. The evolution of labeled CO2 indicated that there was a process occurring that broke down the nutrients in solution and released CO2 as a byproduct. Cellular metabolism releases CO2, so this result supported the idea of microbial life on …
Determination Of Total Peroxide Content In Secondary Organic Aerosol Particles,
2015
Concordia University - Portland
Determination Of Total Peroxide Content In Secondary Organic Aerosol Particles, Matthew E. Wise, John Shilling, Ryan Caylor
CUP Faculty Research
Secondary organic aerosol particles (SOA) formed from the oxidation of monoterpenes can impact the Earth’s radiation balance, act as cloud condensation nuclei and negatively affect human health. In the initial Visiting Faculty Program application, we proposed the use of an ultraviolet-visible spectrometer equipped with a liquid waveguide capillary flow cell to determine the extent to which SOA absorb visible light. The inclusion of Concordia University in the Secondary Organic Aerosol From Forest Emissions Experiment (SOAFFEE) laboratory campaign at PNNL necessitated a change in the proposed experiments. An iodometric-spectrophotometric (IS) technique was developed to quantify the total peroxide content in SOA. …
Determination Of The Optical Properties Of Secondary Organic Aerosol Particles,
2015
Concordia University - Portland
Determination Of The Optical Properties Of Secondary Organic Aerosol Particles, Matthew E. Wise, John Shilling, Felisha Imholt, Ryan Caylor
CUP Faculty Research
The enhanced greenhouse effect is currently considered to be our most important global environmental problem. While the magnitude of radiation absorbed by greenhouse gases is known to a high certainty, the absorption of radiation by atmospheric aerosol particles is not. In the initial Visiting Faculty Program application, we proposed the use of an ultraviolet-visible (UV/Vis) spectrometer equipped with a liquid waveguide capillary flow cell to determine the extent to which secondary organic aerosol particles (SOA) absorb visible light. Early in the research period, the UV/Vis technique was optimized for three solvent systems (methanol, water and 0.1 M hydrochloric acid). Using …
Pyrolysis-Gc-Ms For The Rapid Environmental Forensic Screening Of Contaminated Brownfield Soil,
2015
University of Oviedo
Pyrolysis-Gc-Ms For The Rapid Environmental Forensic Screening Of Contaminated Brownfield Soil, Azucena Lara-Gonzalo, Michael A. Kruge, I Lores, B Gutiérrez, José Luis Gallego
Department of Earth and Environmental Studies Faculty Scholarship and Creative Works
An abandoned chemical plant in Asturias (Spain) was studied using a multi-faceted molecular fingerprinting approach, demonstrating that it is possible to: (1) carefully unravel tangled evidence resulting from multiple pollution sources, and (2) recognize major contaminants largely ignored by conventional analyses. This methodology employed a battery of GC-MS analyses of liquid chromatographic fractions of soil extracts, plus the pyrolysis products of the soil extract's asphaltene fraction and the whole soil itself. In this example, coal tar distillation and the subsequent production of naphthalene, phenols and polymer resins are responsible for most of the soil contamination. Styrene, naphthalene, indene, and their …
