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183— Cannabis Sativa: Pretreatment And Fiber Content Analysis, Dina Bú, Arianna Soriano, Sofia Kostrinsky, Sarah Schmidlin, Barnabas Gikonyo 2020 SUNY Geneseo

183— Cannabis Sativa: Pretreatment And Fiber Content Analysis, Dina Bú, Arianna Soriano, Sofia Kostrinsky, Sarah Schmidlin, Barnabas Gikonyo

GREAT Day Posters

Cannabis Sativa commonly known as hemp, is one of the fastest growing plants whose refined products have immense commercial value. Refined hemp is included in various products: biofuels, biodegradable plastics, textiles, dietary supplements, paper, clothing and much more. Hemp fibers are also used in construction and manufacturing applications as a way to strengthen composite products. These qualities make hemp a high yielding, sustainable, and environmentally friendly crop with the potential to yield valuable raw materials for a large number of applications. Our research evaluates the pretreatment of hemp and the comparative analysis of the fiber content thereof. Our goal is …


385— Optimizing Nitrogen Concentrations To Maximize Lipid Yields For Biodiesel Production, Wady Jacoby, Daria Zhogina, Pavel Ananev, Lauren Saggese, Max Muller, Barnabas Gikonyo 2020 SUNY Geneseo

385— Optimizing Nitrogen Concentrations To Maximize Lipid Yields For Biodiesel Production, Wady Jacoby, Daria Zhogina, Pavel Ananev, Lauren Saggese, Max Muller, Barnabas Gikonyo

GREAT Day Posters

Select subspecies of microalgae are considered to be the most promising candidates for third generation renewable resources of biodiesel. Algae not only ingest excess carbon emissions from the atmosphere, they also convert it into energy-dense lipids which can be harvested, and then transformed into biodiesel. However, before the fuel industry can adopt algae farming as a realistic alternative to fossil fuels, the process of harvesting algal lipids must be optimized further. Our research aims to make algal lipid extraction more realistic by determining the ideal growing conditions of the algae species Chlorella Vulgaris. Our research this semester focused on two …


Analysis Of Petroleum Products For Forensic And Environmental Applications, Sarah Ghali, Sarah Porter 2020 Longwood University

Analysis Of Petroleum Products For Forensic And Environmental Applications, Sarah Ghali, Sarah Porter

Virtual 2020 Spring Student Showcase for Research and Creative Inquiry

In both forensic and environmental applications, it is often important to identify ignitable liquid (IL) residues, to find a suspect or to clean up an oil spill. The ASTM method is commonly used; the extraction methods vary, but the data collection is the same. The instrument used in the ASTM method is gas chromatography mass spectroscopy (GC-MS), which allows a visual identification of the IL contaminating the sample. In this study, the use of Fourier transform infrared spectrometry (FTIR) was used in conjunction with chemometric analysis. Samples were prepared were to simulate an oil spill in natural waters. Two chemometric …


Surveillance Of Microplastic Pollution In Central Virginia Freshwater Ecosystems, Alexandra Reddy 2020 Liberty University

Surveillance Of Microplastic Pollution In Central Virginia Freshwater Ecosystems, Alexandra Reddy

Senior Honors Theses

Aquatic organisms often mistake microplastic particulates (MP) as food and inadvertently ingest the particulates, which can biomagnify through the food chain. While MP ingestion is well-researched in the marine environment, little is known about microplastics in freshwater  ecosystems. This project explores MP occurrence in an ecologically significant freshwater invertebrate: crayfish. Crayfish from two Central Virginia streams are collected to identify MP in the digestive tracts and gill filaments, and characterize the MP using analytical chemistry techniques. It was determined that MP were present in the digestive tracts and gill filaments of crayfish collected from both streams, and that MP frequency …


Mercury And Other Trace Metal Analysis In Bat Guano, Amanda Lee Houchens 2020 Western Kentucky University

Mercury And Other Trace Metal Analysis In Bat Guano, Amanda Lee Houchens

Masters Theses & Specialist Projects

Heavy metal pollution in the environment pose risks to ecosystems and the populations that reside in them. Mercury, lead, and cadmium negatively impact humans by way of neurological disorders, various cancers, and damage the reproductive organs, kidneys, and lungs. Bats have been studied as a bioindicator species to identify possibly elevated levels of these metals in the environment. Previous studies have identified correlation between metal concentrations within bat tissues and fur. Many bat species are endangered or at risk due to white-nose syndrome so collection of tissues and fur for analysis can impose stress on bat colonies. This study investigates …


Using Electrocoagulation To Remove Perfluoroalkyl And Polyfluoroalkyl Substances (Pfas) From Contaminated Water, Amy Yanagida 2020 University of Nebraska-Lincoln

Using Electrocoagulation To Remove Perfluoroalkyl And Polyfluoroalkyl Substances (Pfas) From Contaminated Water, Amy Yanagida

UCARE: Research Products

Perfluoroalkyl and Polyfluoroalkyl substances (PFAS) are a family of manmade chemicals that are used to improve the quality of several commercial products by making them resistant to heat, oil, stains, grease and water. Unfortunately, the chemical properties that make PFAS useful from an industrial perspective also make them mobile and recalcitrant once released into the environment. We used electrocoagulation to run a direct current through contaminated water to generate a zinc floc to precipiate PFAS out of water.


Senior Project: An Investigative Study Into The Bacterial Contamination Of Little Black Creek, Margaret I. Brenneman 2020 Grand Valley State University

Senior Project: An Investigative Study Into The Bacterial Contamination Of Little Black Creek, Margaret I. Brenneman

Honors Projects

An investigation of Escherichia coli concentrations in a west Michigan stream was conducted to determine sources of fecal contamination that impact water quality. Little Black Creek (LBC) is located in Muskegon County and discharges into Lake Michigan at the P.J. Hoffmaster Campground Beach. Often referred to as an “indicator bacteria,” water contaminated with E. coli has a high probability to contain other enteric pathogens as well. Beach water testing in 2020 using Colilert-18 methods revealed E. coli levels of 579 cfu/100mL in the creek discharge area that exceeded total body contact criteria of 300 cfu/100mL. A follow-up study of the …


A Public Health Perspective On Gen X Contamination In Drinking Water, Allison Stevens 2020 Ohio Northern University

A Public Health Perspective On Gen X Contamination In Drinking Water, Allison Stevens

Honors Capstone Enhancement Presentations

No abstract provided.


Brown Carbon Production By Aqueous-Phase Interactions Of Glyoxal And So2, David O. De Haan, Kevin Jansen, Alec D. Rynaski, W. Ryan P. Sueme, Ashley K. Torkelson, Eric T. Czer, Alexander K. Kim, Michael A. Rafla, Audrey C. De Haan, Margaret A. Tolbert 2020 University of San Diego

Brown Carbon Production By Aqueous-Phase Interactions Of Glyoxal And So2, David O. De Haan, Kevin Jansen, Alec D. Rynaski, W. Ryan P. Sueme, Ashley K. Torkelson, Eric T. Czer, Alexander K. Kim, Michael A. Rafla, Audrey C. De Haan, Margaret A. Tolbert

Chemistry and Biochemistry: Faculty Scholarship

Oxalic acid and sulfate salts are major components of aerosol particles. Here, we explore the potential for their respective precursor species, glyoxal and SO2, to form atmospheric brown carbon via aqueous-phase reactions in a series of bulk aqueous and flow chamber aerosol experiments. In bulk aqueous solutions, UV- and visible-light-absorbing products are observed at pH 3–4 and 5–6, respectively, with small but detectable yields of hydroxyquinone and polyketone products formed, especially at pH 6. Hydroxymethanesulfonate (HMS), C2, and C3 sulfonates are major products detected by electrospray ionization mass spectrometry (ESI-MS) at pH 5. Past studies …


Dissipation Of Benzobicyclon And Benzobicyclon Hydrolysate In A Louisiana Rice Field, Xavier Poole 2020 Louisiana State University

Dissipation Of Benzobicyclon And Benzobicyclon Hydrolysate In A Louisiana Rice Field, Xavier Poole

LSU Master's Theses

Pesticide resistance in rice fields is an ongoing issue that has resulted in the development and use of pesticides with new modes of action. Benzobicyclon is the first registered hydroxyphenylpyruvate(HPPD)-inhibiting pesticide in the United States and has gained attention as a resistance management strategy to control weed pests in rice fields. Understanding the environmental fate and dissipation mechanisms of benzobicyclon is important due to the unique rotation of rice and crayfish in Louisiana on the same fields. Benzobicyclon persistence into the crayfish growing seasons may lead to unintended consequences for crayfish growth and production, assuming there is toxicity to crawfish. …


Methanethiol, Dimethyl Sulfide And Acetone Over Biologically Productive Waters In The Southwest Pacific Ocean, Sarah J. Lawson, Cliff S. Law, Mike J. Harvey, Thomas G. Bell, Carolyn F. Walker, Warren J. De Bruyn, Eric S. Saltzman 2020 ommonwealth Scientific and Industrial Research Organisation (CSIRO), Australia

Methanethiol, Dimethyl Sulfide And Acetone Over Biologically Productive Waters In The Southwest Pacific Ocean, Sarah J. Lawson, Cliff S. Law, Mike J. Harvey, Thomas G. Bell, Carolyn F. Walker, Warren J. De Bruyn, Eric S. Saltzman

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Atmospheric methanethiol (MeSHa), dimethyl sulfide (DMSa) and acetone (acetonea) were measured over biologically productive frontal waters in the remote southwest Pacific Ocean in summertime 2012 during the Surface Ocean Aerosol Production (SOAP) voyage. MeSHa mixing ratios varied from below the detection limit (< 10 ppt) up to 65 ppt and were 3 %–36 % of parallel DMSa mixing ratios. MeSHa and DMSa were correlated over the voyage (R2=0.3, slope = 0.07) with a stronger correlation over a coccolithophore-dominated phytoplankton bloom (R2=0.5, slope 0.13). The diurnal cycle for MeSHa shows similar behaviour to DMSa with mixing ratios …


Assessing The Ecological Risk Of Heavy Metal Sediment Contamination From Port Everglades Florida, Dimitri G. Giarikos, Laura White, Amy C. Hirons 2020 Nova Southeastern University

Assessing The Ecological Risk Of Heavy Metal Sediment Contamination From Port Everglades Florida, Dimitri G. Giarikos, Laura White, Amy C. Hirons

SECLER Data

Port sediments are often contaminated with metals and organic compounds from anthropogenic sources. Port dredging can remobilize contaminated sediments, resulting in harmful impacts to the benthic community. Twelve sediment cores were collected from four Port Everglades, Florida sites and a control site; surface sediment was collected at two nearby coral reef sites. Sediment cores, sampled every 5 cm, were quantified for 14 heavy metals using induced coupled plasma mass spectrometry (ICPMS). Geo-accumulation index shows moderate-to-strong contamination of As and Mo in port sediments, and potential ecological risk indicates moderate-to-significantly high overall metal contamination. Arsenic port sediment concentrations exceed threshold effect …


Synthesis And Fabrication Of Trimetallic (Ru-Mn Co) Catalyst Supported On Tio2 And Ni(Oh)2 Thin Films For Photoelectrochemical Applications, Che Mat Ahmad Nazeer 2020 Universiti Malaya

Synthesis And Fabrication Of Trimetallic (Ru-Mn Co) Catalyst Supported On Tio2 And Ni(Oh)2 Thin Films For Photoelectrochemical Applications, Che Mat Ahmad Nazeer

Student Works (2020-2029)

Anatase supported heterogeneous photocatalyst consisting of RuO2, MnO2 and Co3O4 (1:13:13 ratio) was synthesized by precipitation method. The film of the prepared catalyst was fabricated by electrophoretic deposition technique in an aqueous solution of 0.1 mM ammonia and tested for photoelectrocatalytic (PEC) oxidation of methanol in 0.1M KOH under visible light irradiation. The as-prepared photocatalyst was characterized by FTIR, UV–Vis, XRD, Raman spectroscopy, FESEM/EDX, TEM, BET, XPS and TPR. The PEC study by cyclic voltammetry indicates that the oxidation of methanol to CO2 and H2O upon exposure to visible light occurs between 400 and 800 nm. The smaller value of …


Surface Reservoirs Dominate Dynamic Gas-Surface Partitioning Of Many Indoor Air Constituents, Chen Wang, Douglas B. Collins, Caleb Arata, Allen H. Goldstein, James M. Mattila, Delphine K. Farmer, Laura Ampollini, Peter F. DeCarlo, Atila Novoselac, Marina E. Vance, William W. Nazaroff, Jonathan P.D. Abbatt 2020 University of Toronto

Surface Reservoirs Dominate Dynamic Gas-Surface Partitioning Of Many Indoor Air Constituents, Chen Wang, Douglas B. Collins, Caleb Arata, Allen H. Goldstein, James M. Mattila, Delphine K. Farmer, Laura Ampollini, Peter F. Decarlo, Atila Novoselac, Marina E. Vance, William W. Nazaroff, Jonathan P.D. Abbatt

Faculty Journal Articles

Human health is affected by indoor air quality. One distinctive aspect of the indoor environment is its very large surface area that acts as a poorly characterized sink and source of gas-phase chemicals. In this work, air-surface interactions of 19 common indoor air contaminants with diverse properties and sources were monitored in a house using fast-response, on-line mass spectrometric and spectroscopic methods. Enhanced-ventilation experiments demonstrate that most of the contaminants reside in the surface reservoirs and not, as expected, in the gas phase. They participate in rapid air-surface partitioning that is much faster than air exchange. Phase distribution calculations are …


Assessment Of Soil Protein And Refractory Soil Organic Matter Across Two Chronosequences Of Newly Developing Marshes In Coastal Louisiana, Usa, Stuart Alexander McClellan 2020 Louisiana State University and Agricultural and Mechanical College

Assessment Of Soil Protein And Refractory Soil Organic Matter Across Two Chronosequences Of Newly Developing Marshes In Coastal Louisiana, Usa, Stuart Alexander Mcclellan

LSU Doctoral Dissertations

The impacts of sea-level rise and hydrologic manipulation are threatening the stability of coastal marshes throughout the world, thereby increasing the potential for re-mineralization of soil organic matter (SOM) in these systems. Such threats have prompted marsh restoration efforts, particularly in coastal Louisiana, yet it is unclear how the slowly decomposing (refractory) and quickly decomposing (labile) fractions of SOM may be differentially affected by different approaches to marsh restoration. Additionally, otherwise labile compounds may accumulate in the soil via a range of protective mechanisms, including rapid burial and association with organic compounds that are thought to enhance soil aggregation, such …


Analysis Of Organochlorine Pesticides Levels In Irrigation Water From Various Water Sources Across Egypt, Omar Tarek Khairy 2020 The American University in Cairo AUC

Analysis Of Organochlorine Pesticides Levels In Irrigation Water From Various Water Sources Across Egypt, Omar Tarek Khairy

Theses and Dissertations

Organochlorine pesticides are extensively used in agriculture to cope with the world’s increasing population and demands for nutrition. This class of pesticides poses a serious risk to human health upon chronic exposure to elevated levels. Determination of organochlorine pesticides levels in water has been extensively covered in literature in Egypt and other parts of the world. The need for up-to date data and statistical information regarding the levels of organochlorine pesticides in water is ever increasing. These compounds, although a lot have been prohibited from use decades ago, can still be detected in trace levels in water due to their …


Anoxic Conditions Maintained High Phosphorus Sorption In Humid Tropical Forest Soils, Yang Lin, Avner Gross, Christine S. O'Connell, Whendee L. Silver 2020 University of California - Berkeley

Anoxic Conditions Maintained High Phosphorus Sorption In Humid Tropical Forest Soils, Yang Lin, Avner Gross, Christine S. O'Connell, Whendee L. Silver

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

The strong phosphorus (P) sorption capacity of iron (Fe) and aluminum (Al) minerals in highly weathered, acidic soils of humid tropical forests is generally assumed to be an important driver of P limitation to plants and microbial activity in these ecosystems. Humid tropical forest soils often experience fluctuating redox conditions that reduce Fe and raise pH. It is commonly thought that Fe reduction generally decreases the capacity and strength of P sorption. Here we examined the effects of 14 d oxic and anoxic incubations on soil P sorption dynamics in humid tropical forest soils from Puerto Rico. Contrary to the …


Air/Sea Transfer Of Highly Soluble Gases Over Coastal Waters, J. G. Porter, Warren J. de Bruyn, S. D. Miller, E. S. Saltzman 2020 University of California, Irvine

Air/Sea Transfer Of Highly Soluble Gases Over Coastal Waters, J. G. Porter, Warren J. De Bruyn, S. D. Miller, E. S. Saltzman

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

The deposition of soluble trace gases to the sea surface is not well studied due to a lack of flux measurements over the ocean. Here we report simultaneous air/sea eddy covariance flux measurements of water vapor, sulfur dioxide (SO2), and momentum from a coastal North Atlantic pier. Gas transfer velocities were on average about 20% lower for SO2 than for H2O. This difference is attributed to the difference in molecular diffusivity between the two molecules (D SO 2/D H 2O = 0.5), in reasonable agreement with bulk parameterizations in air/sea gas …


Correlation Between Ocean Acidification And Zooplankton In The South Pacific Gyre, Samuel Noonan, Rachel Scudder 2020 University of Denver

Correlation Between Ocean Acidification And Zooplankton In The South Pacific Gyre, Samuel Noonan, Rachel Scudder

DU Undergraduate Research Journal Archive

The South Pacific Gyre is a naturally occurring carbon sink, meaning that it absorbs atmospheric carbon dioxide by dissolving it into the moving surface water. The dissolution of CO2 level will dictate the water’s acidic levels a larger the concentration of dissolved CO2 is known to increase the salt water’s acidity. A great amount of the ocean’s biomass is composed of calcifying organisms, which produce tests or shells made from calcium carbonate CaCO3.The goal of our project is to determine if there is a correlation between the water acidity across various locations, as we sailed through the South Pacific gyre …


Data On Gc/Ms Elution Profile, 1h And 13c Nmr Spectra Of 1-, 3-, And 6-Nitrobenzo[A]Pyrenes, Kefa Karimu Onchoke 2020 Stephen f. Austin state univetsity

Data On Gc/Ms Elution Profile, 1h And 13c Nmr Spectra Of 1-, 3-, And 6-Nitrobenzo[A]Pyrenes, Kefa Karimu Onchoke

Faculty Publications

The data presented in this article is related to the research article entitled, “13C NMR Chemical Shift Assignments of Nitrated Benzo[a]pyrenes based on Two-dimensional Techniques and DFT/GIAO Calculations”, Kefa K. Onchoke, PeerJ., . The NMR spectral profiles of nitrated benzo[a]pyrenes is presented. Further, the article describes elution profiles of 1-, 3- and 6-NBaP, the acquisition of 1H and 13C NMR data and the J-Coupling constants (which are useful for the assignment of peaks via 2D HMQC and HMBC techniques). The data presented is useful for developing structure-activity relationships for other nitrated polycyclic aromatic hydrocarbons (NPAHs)


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