Open Access. Powered by Scholars. Published by Universities.®

Catalysis and Reaction Engineering Commons™

Open Access. Powered by Scholars. Published by Universities.®

1,363 Full-Text Articles 3,866 Authors 808,599 Downloads 71 Institutions

All Articles in Catalysis and Reaction Engineering

Faceted Search

1,363 full-text articles. Page 1 of 51.

Voltage-Related Power Quality Issues And Impacts On Distribution Networks With Sensitive Loads - A Review, Godwin Elinazi Mnkeni, Jackson Justo, Aviti Thadei Mushi, Bakari M. M. Mwinyiwiwa 2026 Mbeya University of Science and Technology

Voltage-Related Power Quality Issues And Impacts On Distribution Networks With Sensitive Loads - A Review, Godwin Elinazi Mnkeni, Jackson Justo, Aviti Thadei Mushi, Bakari M. M. Mwinyiwiwa

Tanzania Journal of Engineering and Technology (TJET)

Voltage disturbances are the most important power quality (PQ) complications that customers and power utilities face in this smart era. The growing adoption of sophisticated electronic equipment and integration of renewable energy sources (RES) into power grids has increased the susceptibility of power distribution networks (PDNs) to voltage sags, swells, interruptions, flicker, and voltage imbalance. These disturbances, mainly caused by upstream faults, switching operations, and RES integration, compromise voltage PQ and system reliability. Consequently, they accelerate equipment degradation, increase electronic waste (e-waste), raise reactive power demand and maintenance costs, increase power losses, and impose substantial economic losses on customers and …


Catalytic Effect Of Metal Ions On The Oxidation Of Thiocyanate Ions With Hydrogen Peroxide, Sarvar B. RAJABOV, Salmon M. MUKHAMMADIEV, Berdakh T. DANIYAROV, Haci DEVECI, Shahlo Sh. DAMINOVA 2026 Uzbekistan-Japan Innovation Centre of Youth, Tashkent, Uzbekistan

Catalytic Effect Of Metal Ions On The Oxidation Of Thiocyanate Ions With Hydrogen Peroxide, Sarvar B. Rajabov, Salmon M. Mukhammadiev, Berdakh T. Daniyarov, Haci Deveci, Shahlo Sh. Daminova

CHEMISTRY AND CHEMICAL ENGINEERING

Thiocyanate (SCN⁻) ions, formed during the cyanidation of gold ores, pose a significant environmental problem when present in mine processing wastewater. In this study, the oxidation of potassium thiocyanate model solutions (10–1000 mg/L) with hydrogen peroxide, in the presence and absence of Cu2+ and Fe2+ ions, was investigated at room temperature. Residual SCN⁻ concentrations were determined by bromatometric titration and UV-spectroscopy. Without a catalyst, H2O2 showed the weakest effect at all concentrations, leaving 6–17% residual SCN⁻ even at the highest applied dose. The addition of Cu2+ and Fe2+ ions markedly accelerated oxidation via …


Efficient Acidic H2O2 Electrosynthesis Over Co Atoms Anchored On Nitrogen-Doped Hierarchical Porous Carbon, Xiao Huang, Zi-Hao Zhan, Hao-Xu Niu, Guan-Yu Luo, Jin-Tao Huang, Bo-Xuan Jin, De-Li Wang 2026 State Key Laboratory of Green and Efficient Development of Phosphorus Resources, School of Chemistry and Environmental Engineering, Wuhan Institute of Technology, Wuhan 430205, China; Hubei Key Laboratory of Processing and Application of Catalytic Materials, College of Chemistry and Chemical Engineering, Huanggang Normal University, Huanggang 438000, China

Efficient Acidic H2O2 Electrosynthesis Over Co Atoms Anchored On Nitrogen-Doped Hierarchical Porous Carbon, Xiao Huang, Zi-Hao Zhan, Hao-Xu Niu, Guan-Yu Luo, Jin-Tao Huang, Bo-Xuan Jin, De-Li Wang

Journal of Electrochemistry

The two-electron oxygen reduction reaction (2e− ORR) presents a promising route for the on-site production of hydrogen peroxide (H2O2), offering a green alternative to energy-consuming anthraquinone process. However, the high selectivity toward the competing 4e− ORR over the desired 2e− pathway leads to low Faradaic efficiency for H2O2, posing a critical challenge in catalyst design. In this work, a nitrogen-doped hollow hierarchical porous carbon with anchored Co atoms (CoN/HPC) was constructed for high-performance H2O2 production. The as-prepared Co-N/HPC catalyst showed excellent 2e− ORR performance, achieving …


Engineering Small-Sized Cations With Strong Solvation For High-Voltage Supercapacitors, Tong Huo, Pan Liu, Hao Chen, Peng Zhang, Zhen-Lei Chen, Guo-Fu Sun, Zhi-Qiang Shi, Jing Wang 2026 College of Materials Science and Engineering, Tianjin Key Laboratory of Advanced Fibers and Energy Storage, Tiangong University, Tianjin 300387, China

Engineering Small-Sized Cations With Strong Solvation For High-Voltage Supercapacitors, Tong Huo, Pan Liu, Hao Chen, Peng Zhang, Zhen-Lei Chen, Guo-Fu Sun, Zhi-Qiang Shi, Jing Wang

Journal of Electrochemistry

Supercapacitors (SCs) have attracted much attention in the field of energy storage due to their high power density and long cycle life. However, their relatively low energy density limits their application in a wider range of fields. Methods to increase energy density include enhancing specific capacitance and extending operating voltage window. Herein, we report a novel electrolyte salt, tetramethylammonium bis(fluorosulfonyl)imide (TMA-FSI), the resulting electrolyte formed with propylene carbonate (PC), designated as TMF, exhibited a wide electrochemical stability window (ESW) of 5.09 V. On the one hand, we found that the small size of TMA+ enables it to enter the …


Dense Platinum Nanoparticles Confined In Mn-N-C Nanocages For Robust Heavy-Duty Pemfcs, Lei Zhao, Zhen-Min Cao, Jia-Yu Zuo, Ming-Liang Yang, Hong-Yan Qiao, Jun-Song Chen, Rui Wu 2026 School of Materials and Energy, University of Electronic Science and Technology of China, Chengdu 611731, P.R. China; School of Materials and Environmental Engineering, Chengdu Technological University, Chengdu 611730, P.R. China

Dense Platinum Nanoparticles Confined In Mn-N-C Nanocages For Robust Heavy-Duty Pemfcs, Lei Zhao, Zhen-Min Cao, Jia-Yu Zuo, Ming-Liang Yang, Hong-Yan Qiao, Jun-Song Chen, Rui Wu

Journal of Electrochemistry

High-loading Pt cathodes are essential for heavy-duty proton exchange membrane fuel cells but suffer from a critical tradeoff between ionomer sulfonate poisoning and nanoparticle instability. Herein, we report a spatial confinement strategy to encapsulate dense Pt nanoparticles (~51.8 wt%) within Mn/N-co-doped mesoporous carbon nanocages (denoted as Pt-MnNC). This architecture excludes bulky ionomers to create an ionomer-shielded environment against sulfonate poisoning, while Mn-Nx-mediated strong metal-support interactions anchor the Pt nanoparticles to prevent agglomeration and further boost durability. In the 5 × 5 cm2 membrane electrode assembly tests, the Pt-MnNC catalyst delivers an exceptional power density of 1.26 W·cm …


Recent Advances In Bioethanol Production From Water Hyacinth: A Critical Review, Umuamina A. Matola, Mahir Mohammed Said, Olga-Ioanna Kalantzi, Abraham K. Temu 2026 University of Dar es Salaam

Recent Advances In Bioethanol Production From Water Hyacinth: A Critical Review, Umuamina A. Matola, Mahir Mohammed Said, Olga-Ioanna Kalantzi, Abraham K. Temu

Tanzania Journal of Engineering and Technology (TJET)

Water hyacinth (WH) is a highly invasive tropical aquatic weed with high holocellulose and low lignin content, making it a promising lignocellulosic feedstock for second-generation bioethanol production. Producing bioethanol from WH offers a sustainable approach to simultaneously managing invasive biomass and producing renewable energy. This review critically evaluates recent advancements in bioethanol production from WH by examining pretreatment, hydrolysis, and fermentation technologies reported between 2014 and 2024. A PRISMA-guided literature search was conducted using the Scopus and Web of Science databases, and fifty-nine original research articles were selected for analysis. The reviewed studies were comparatively assessed based on pretreatment strategies, …


Modeling Of A Two-Stage Extractive Distillation Process For The Separation Of 1,3-Butadiene From Pyrolysis-Derived C₄ Fractions, Muxriddin Xudoyor og‘li Ibodullayev, Jonibek Farxod o‘g‘li Norqulov, Olim Rustamovich Abduraxmonov, Orifjon Sharipovich Kodirov 2026 Karshi State Technical University. Address: 20, Shahrisabz street, Shahrisabz, Uzbekistan, 181306. E-mail: [email protected], Phone: +998 91 451 17 37;

Modeling Of A Two-Stage Extractive Distillation Process For The Separation Of 1,3-Butadiene From Pyrolysis-Derived C₄ Fractions, Muxriddin Xudoyor Og‘Li Ibodullayev, Jonibek Farxod O‘G‘Li Norqulov, Olim Rustamovich Abduraxmonov, Orifjon Sharipovich Kodirov

Chemical Technology, Control and Management

The separation of 1,3-butadiene from pyrolysis-derived C₄ fractions represents a challenging task due to the multicomponent nature of the feed and the close boiling points of accompanying hydrocarbons. In this study, a two-stage extractive distillation process was investigated using an acetonitrile–water solvent system to address these challenges. A semi-industrial experimental unit consisting of two extractive distillation columns connected in series was developed and analyzed, and the process configuration was supported by Aspen Plus simulation. The feedstock composition was characterized in detail, revealing that 1,3-butadiene constitutes approximately 40 wt.% of the C₄ fraction, accompanied by significant amounts of propylene, butanes, butanes, …


In Situ Electrochemical Characterization Techniques For Active Hydrogen In Electrocatalytic Nitrate Reduction To Ammonia, Hong-Mei Li, Mei Yi, Zhao-Yu Jin, Ming-Hao Xie, Khalid M. Omer, Yong Guo, Pan-Pan Li 2026 College of Chemistry, Sichuan University, Chengdu 610065, P. R. China

In Situ Electrochemical Characterization Techniques For Active Hydrogen In Electrocatalytic Nitrate Reduction To Ammonia, Hong-Mei Li, Mei Yi, Zhao-Yu Jin, Ming-Hao Xie, Khalid M. Omer, Yong Guo, Pan-Pan Li

Journal of Electrochemistry

Electrocatalytic nitrate reduction to ammonia (NitRR) represents a sustainable pathway that integrates environmental remediation with the production of high-value ammonia. However, the activity and selectivity of this process are limited by the generation, consumption, and dynamic equilibrium of the key transient intermediate—active hydrogen (*H). Precise modulation of *H necessitates a comprehensive understanding of its behavior, which relies fundamentally on advanced in situ electrochemical characterization techniques. However, a systematic review dedicated to the rational selection and application of in situ electrochemical techniques for the specific characterization of *H in NitRR, with clear definitions of each technique's "detectable targets, quantitative accuracy, and …


Neural Network Driven By Electrochemical Performance Data For Predicting The Discharge Termination Time Of Seawater Electrolyte-Based Metal-Air Batteries, Peng-Peng Shen, Yi-Chi Pan, Yu-Rong Liu, Lu-Dan Zhang, Ning Niu, Guan-Jun Wang, De-Kun Yang, Xin-Long Tian, Peng Rao 2026 State Key Laboratory of Tropic Ocean Engineering Materials and Materials Evaluation, School of Information and Communication Engineering, School of Electronic Science and Technology, Hainan University, Haikou 570228, Hainan, China

Neural Network Driven By Electrochemical Performance Data For Predicting The Discharge Termination Time Of Seawater Electrolyte-Based Metal-Air Batteries, Peng-Peng Shen, Yi-Chi Pan, Yu-Rong Liu, Lu-Dan Zhang, Ning Niu, Guan-Jun Wang, De-Kun Yang, Xin-Long Tian, Peng Rao

Journal of Electrochemistry

Seawater electrolyte-based metal-air batteries exhibit great promise for marine energy supply systems. However, conventional statistical analysis methods, though applicable to seawater metal-air battery lifetime prediction, have inherent limitations of insufficient prediction accuracy and large error. Herein, a deep time-series regression framework based on InceptionTime and incorporating prior-biased attention pooling is proposed to construct a nonlinear mapping between electrochemical performance sequences and the discharge termination time of catalysts. Specifically, chronoamperometric profiles are employed to extract long-term stability features, while prior knowledge derived from linear sweep voltammetry is introduced to strengthen the attention weighting over critical potential regions. Under a nested leave-one-catalyst-out …


Microwave-Assisted Synthesis Of Core-Shell Structured Pd@Pdptcufe Recessed Truncated Octahedral Nanocrystals For Multifunctional Electrocatalysis, De-Zhong Hu, Wen-Dan Jiang, Wei Keat Ng, Jun Yang, Xiong-Wu Kang 2026 New Energy Research Institute, School of Environment and Energy, South China University of Technology, Guangzhou 510006, Guangdong, China

Microwave-Assisted Synthesis Of Core-Shell Structured Pd@Pdptcufe Recessed Truncated Octahedral Nanocrystals For Multifunctional Electrocatalysis, De-Zhong Hu, Wen-Dan Jiang, Wei Keat Ng, Jun Yang, Xiong-Wu Kang

Journal of Electrochemistry

Developing cost-efficient and durable multifunctional electrocatalysts of hydrogen evolution reaction, oxygen reduction reaction and oxygen evolution reaction is crucial for improving energy conversion efficiency in electrolytic water splitting electrolyzer and advancing rechargeable zinc-air batteries. Polyhedral shaped nanocrystals with well-defined crystal facets represent a type of model catalysts that enables the exploration of structure-activity relationships. However, it is still very challenging to prepare alloy nanocrystals with multiple metal components due to their complicated redox potentials and mixing enthalpy. Herein, we report a rapid microwave-assisted polyol reduction method for syntheses of core-shell Pd@PdPtCu, Pd@PdPtCuNi, Pd@PdPtCuCo and Pd@PdPtCuZn octahedral nanocrystals, and recessed truncated-octahedral …


Functionalized Loblolly Pine Derived Ultraporous Activated Hydrochars For Efficient Carbon Capture, Swarna Saha 2026 Florida Institute of Technology

Functionalized Loblolly Pine Derived Ultraporous Activated Hydrochars For Efficient Carbon Capture, Swarna Saha

Theses and Dissertations

The increasing concentration of anthropogenic carbon dioxide (CO₂) emissions has intensified the demand for efficient and sustainable carbon capture technologies. This dissertation investigates the development of functionalized ultraporous activated hydrochars derived from loblolly pine through hydrothermal carbonization (HTC) followed by chemical activation for enhanced CO₂ capture applications. Different functionalization strategies, including deep eutectic solvent (DES) modification, zeolite-assisted HTC, palladium-assisted HTC, and CO₂-assisted HTC, were systematically explored to evaluate the influence of pore structure, surface chemistry, and adsorption energetics on CO₂ capture performance. The synthesized materials were characterized using BET, FTIR, XRD, TGA, SEM, and adsorption isotherm modeling to establish the …


Dynamic Reconstruction Engineering Of Anti-Corrosion Ni-Based Anodes For Alkaline Seawater Electrolysis, Yi-Gang Zhang, Wen-Wen Xu, Tian-Yu Zhang, Zhi-Yi Lu 2026 Faculty of Maritime and Transportation, Ningbo University, Ningbo, 315211; Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Advanced Fuel Cells and Electrolyzers Technology, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, 315201

Dynamic Reconstruction Engineering Of Anti-Corrosion Ni-Based Anodes For Alkaline Seawater Electrolysis, Yi-Gang Zhang, Wen-Wen Xu, Tian-Yu Zhang, Zhi-Yi Lu

Journal of Electrochemistry

Green hydrogen production via alkaline seawater electrolysis offers an environmentally sustainable and potentially cost-effective route to address both energy and climate challenges. Achieving long-term anode stability under complex ionic environments and industrial current densities remains a central bottleneck. Specifically, Ni-based anodes exhibit intense surface reconstruction during the oxygen evolution reaction, necessitating dynamic anti-corrosion strategies. This mini review systematically summarizes reconstruction engineering approaches to develop anti-corrosion Ni-based anodes of alkaline seawater electrolysis across increasingly complex ionic environments from simulated seawater to real seawater: (i) Cl– dominated; (ii) Cl– with co-existing oxyanions, and (iii) Cl–  with co-existing Br– …


Preparation And Performance Study Of In-Situ Self-Assembled Biphasic Smmn2O5-Nimn2O4 Composite Cathode, Neng-Chu Xia, Yu Zhou, Qin Wang, Jia-You Zhang, Chun Yu, Yang Zhang, Wan-Bing Guan, Jian-Xin Wang 2026 School of Materials Science and Chemical Engineering, Ningbo University, Ningbo, Zhejiang, 315211, P.R. China; Key Laboratory of Advanced Fuel Cells and Electrolyzers Technology of Zhejiang Province, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, Zhejiang, 315201, P.R. China

Preparation And Performance Study Of In-Situ Self-Assembled Biphasic Smmn2O5-Nimn2O4 Composite Cathode, Neng-Chu Xia, Yu Zhou, Qin Wang, Jia-You Zhang, Chun Yu, Yang Zhang, Wan-Bing Guan, Jian-Xin Wang

Journal of Electrochemistry

Mullite-structured oxides exhibit excellent oxygen reduction reaction activity, possess a low thermal expansion coefficient due to their unique crystal structure, and can eliminate the need for a barrier layer and simplify the preparation process as they contain no alkaline earth elements. Thus, they hold great promise as novel cathode materials for solid oxide fuel cells. In this work, a mullite-spinel-structured SmMn2O5-NiMn2O4 (SMO-NMO) composite cathode was one-step synthesized via a solid-liquid composite route, and its in-situ self-assembly enabled good compatibility with the electrolyte without any barrier layer. Characterization results showed that the SMO:NMO = …


In-Situ Stm Visualization Of Molecular Structural Evolution During Electrochemical Oxidation Coupling Of Para-Aminothiophenol On Au(111), Zi-Wei Ma, Tai-Rui Wu, An-Ni Zheng, Lai-Ke Chen, Yuan-Hui Xiao, Zhao-Bin Chen, Qing-Na Zheng, Jian-Zhang Zhou, Jia-Wei Yan, De-Yin Wu 2026 State Key Laboratory of Physical Chemistry of Solid Surface, and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, PR China

In-Situ Stm Visualization Of Molecular Structural Evolution During Electrochemical Oxidation Coupling Of Para-Aminothiophenol On Au(111), Zi-Wei Ma, Tai-Rui Wu, An-Ni Zheng, Lai-Ke Chen, Yuan-Hui Xiao, Zhao-Bin Chen, Qing-Na Zheng, Jian-Zhang Zhou, Jia-Wei Yan, De-Yin Wu

Journal of Electrochemistry

Para-aminothiophenol (PATP) is not only a widely-used probe molecule in the field of surface-enhanced Raman spectroscopy (SERS), but also an important model molecule for interfacial reactions, exhibiting distinct photo- and electro-oxidation pathways, so that PATP is selectively activated under different external fields. The evolution of products and intermediates during electrochemical oxidative coupling remains unknown. In this study, we have investigated the dynamic electrochemical oxidation process of PATP on the Au(111) surface using cyclic voltammetry, electrochemical (EC)-SERS, and in situ electrochemical scanning tunneling microscopy (EC-STM). The results showed that PATP forms an unsaturated adsorption coverage on Au(111) in an acidic solution. …


Effect Of Concentration And Temperature Of Tio2-Al2o3 Hybrid Nanofluid On The Corrosion Rate Of Aluminum Radiator, Ratna Monasari, Rizky Maulana Ramadhan, Nike Nur Farida, Ahmad Hanif Firdaus, Supa Kusuma Aji, Yuniarto Agus Winoko, Rizkyansyah Alif Hidayatullah 2026 Politeknik Negeri Malang, Malang, East Java, Indonesia

Effect Of Concentration And Temperature Of Tio2-Al2o3 Hybrid Nanofluid On The Corrosion Rate Of Aluminum Radiator, Ratna Monasari, Rizky Maulana Ramadhan, Nike Nur Farida, Ahmad Hanif Firdaus, Supa Kusuma Aji, Yuniarto Agus Winoko, Rizkyansyah Alif Hidayatullah

Journal of Mechanical Engineering Science and Technology (JMEST)

Corrosion of aluminum radiators can reduce cooling system reliability and shorten service life in automotive applications. This study examines the effect of TiO2-Al2O3 hybrid nanofluid concentration and temperature on the corrosion rate of commercially available aluminum radiator material. Hybrid nanoparticles with a TiO2-Al2O3 mass ratio of 50:50 were dispersed in distilled water at concentrations of 0.6 wt.%, 0.8 wt.%, and 1.0 wt.%. Corrosion behavior was evaluated using a 14-day accelerated immersion test at 60°C and 80°C, and the corrosion rate was determined using the gravimetric mass loss method. The results …


Li+/Na+ Hybrid Ion Conduction Mechanism In The Superionic Conductor Li3–XNaXZr2Si2Po12, Yi-Hong Wu, Xia Xie, Lei Zhu, Mu-Ran Yu, Guo-Tai Zhang, Jun-Chao Chen, Shu-Ying Sun, You-Wei Wang, Wei-Ping Tang 2026 School of Resources and Environmental Engineering, East China University of Science and Technology, Shanghai, 200237, China

Li+/Na+ Hybrid Ion Conduction Mechanism In The Superionic Conductor Li3–XNaXZr2Si2Po12, Yi-Hong Wu, Xia Xie, Lei Zhu, Mu-Ran Yu, Guo-Tai Zhang, Jun-Chao Chen, Shu-Ying Sun, You-Wei Wang, Wei-Ping Tang

Journal of Electrochemistry

Hybrid ion conductors that transport multiple ionic conductive species provide a useful platform for understanding how mixed-ion transport governs ionic conductivity within a single phase. However, the controlled introduction of multiple mobile ions into solid-state electrolytes and a mechanistic understanding of their migration within the framework remain challenging. Herein, a skeleton-retained Li+↔Na+ cationic exchange was used to simultaneously induce Li+ and Na+ cations into the NASICON-type framework of Li3–xNaxZr2Si2PO12 (0 < x < 3). We show that the interpenetration of NaO6 and NaO8 coordination polyhedra significantly influences the ionic conductivity of hybrid ion conductors. Computational …


Distribution And Transport Of Lithium Ions At Interfaces Between Graphite And Carboxymethyl Celluloses, Zi-Jun Huang, Zhen-Ying Zheng, Hua-Wei Cao, Jian Wang, Qing-Feng Zhang, Sheng-Li Chen 2026 College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, China

Distribution And Transport Of Lithium Ions At Interfaces Between Graphite And Carboxymethyl Celluloses, Zi-Jun Huang, Zhen-Ying Zheng, Hua-Wei Cao, Jian Wang, Qing-Feng Zhang, Sheng-Li Chen

Journal of Electrochemistry

Carboxymethyl cellulose (CMC) is a water-processable binder widely used for graphite anodes. However, a microscopic understanding of why the identity of CMC counterions (Li+/Na+/K+) strongly affects electrode performance remains limited. Here, molecular dynamics (MD) simulations are used to track Li+ transport accessibility across electrolyte/CMC/graphite three-phase interfaces, comparing pure CMC-Li, CMC-Na, CMC-K, and mixed-counterion CMC binders. We find that CMC-Li sustains a continuous Li+ transport pathway from the electrolyte through the binder phase toward graphite. In contrast, in CMC-Na and CMC-K, Na+/K+ ions preferentially enrich at the graphite/binder interface, forming …


Distinct Co2 Electroreduction Behaviors Over Planar And Non-Planar Cobalt Molecular Catalysts, Ru Jia, Cheng-Biao Zhu, Zi-Mo Zhang, Tuo Wang, Kai-Cong Yang, Guang-Zhe Wang, Yang Hu, Ting-Ting Zhang, Zhen-Wei Wei, Li Xiao, Gong-Wei Wang, Lin Zhuang 2026 College of Chemistry and Molecular Sciences, Hubei Key Lab of Electrochemical Power Sources, Wuhan University, Wuhan 430072, China

Distinct Co2 Electroreduction Behaviors Over Planar And Non-Planar Cobalt Molecular Catalysts, Ru Jia, Cheng-Biao Zhu, Zi-Mo Zhang, Tuo Wang, Kai-Cong Yang, Guang-Zhe Wang, Yang Hu, Ting-Ting Zhang, Zhen-Wei Wei, Li Xiao, Gong-Wei Wang, Lin Zhuang

Journal of Electrochemistry

Molecular catalysts serve as ideal platforms for studying electrocatalytic reaction mechanisms. While current research mainly focuses on modulating central metals or surrounding ligands, the influence of molecular spatial configuration remains largely unexplored. Herein, we synthesized two cobalt complexes with similar ligand environments but distinct spatial geometries, a planar cobalt hexaazamacrocyclic complex (CoHAM) and a non-planar acyclic Co(phen)2Cl2, and evaluated their performance in CO2 reduction reaction (CO2RR). The planar CoHAM exhibited dramatically superior CO2RR performance compared to the non-planar Co(phen)2Cl2. Through a series of combined analyses using in-situ …


Physicochemical Properties And Chemical Compositions Of Cashew Nut Shell Liquid Extracted With Carbon Dioxide–Expanded Hexane, Neema Msuya, Joseph YN Philip, Frank Jacob, Kando K. Janga 2026 Department of Chemical and Process Engineering, University of Dar es Salaam, Dar es Salaam, Tanzania

Physicochemical Properties And Chemical Compositions Of Cashew Nut Shell Liquid Extracted With Carbon Dioxide–Expanded Hexane, Neema Msuya, Joseph Yn Philip, Frank Jacob, Kando K. Janga

Tanzania Journal of Engineering and Technology (TJET)

Cashew nut shell liquid (CNSL) is a mixture of phenolic compounds that can effectively replace commercially available phenols in various applications. This study investigated the physicochemical properties and chemical composition of CNSL extracted using CO2–expanded hexane (CXH) and compared to the traditional Soxhlet extraction method. Steamed cashew nut shells (sCNS) were used in both cases.  The CXH was carried under varying CO2-mole fractions (0.468-0.892) and temperatures (20-36 °C) whereas Soxhlet extraction was performed at atmospheric pressure and hexane boiling point. Response Surface Methodology (RSM) with Central Composite Face-Centred Design (CCFD) was employed to evaluate the effect …


Photocatalysts Based On Titanium Dioxide And Zinc Phthalocyanine Composites For Photodegradation Of Methylene Blue, Albert R. KOLDAROV, Mastura Kh. ARIPOVA, Odilzhon E. ABDURAKHMONOV, Zuhra Ch. KADIROVA, Abror O. TASHPULATOV 2026 Tashkent Institute of Chemical Technology, Tashkent, Uzbekistan

Photocatalysts Based On Titanium Dioxide And Zinc Phthalocyanine Composites For Photodegradation Of Methylene Blue, Albert R. Koldarov, Mastura Kh. Aripova, Odilzhon E. Abdurakhmonov, Zuhra Ch. Kadirova, Abror O. Tashpulatov

CHEMISTRY AND CHEMICAL ENGINEERING

The aim of this work is to analyze the photocatalytic degradation of a model methylene blue solution using titanium dioxide composites with zinc phthalocyanine as the sensitizing photocatalyst under sunlight. The objects of the study are TiO2-based photocatalysts derived from the spent catalyst of the Shurtan GCC after heat treatment at 650°C (T-650), as well as a composite containing zinc phthalocyanine (T-650/PcZn). It has been established that the photodegradation reaction follows a pseudo-first-order model, while the rate constant for the TiO2/PcZn composite is significantly higher than that of pure TiO2, indicating greater efficiency. The …


Digital Commons powered by bepress