Series Reports From Professor Wei’S Group Of Chongqing University: Advancements In Electrochemical Energy Conversions (2/4): Report 2: High-Performance Water Splitting Electrocatalysts,
2025
National Key Laboratory of Special Power Supplies, National-Municipal Joint Engineering Laboratory for Chemical Process Intensification and Reaction, School of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044, China
Series Reports From Professor Wei’S Group Of Chongqing University: Advancements In Electrochemical Energy Conversions (2/4): Report 2: High-Performance Water Splitting Electrocatalysts, Ling Zhang, Wang-Yang Wu, Qiu-Yue Hu, Shi-Dan Yang, Li Li, Rui-Jin Liao, Zi-Dong Wei
Journal of Electrochemistry
The unavailability of high-performance and cost-effective electrocatalysts has impeded the large-scale deployment of alkaline water electrolyzers. Professor Zidong Wei’s group has focused on resolving critical challenges in industrial alkaline electrolysis, particularly elucidating hydrogen and oxygen evolution reaction (HER/OER) mechanisms while addressing the persistent activity-stability trade-off. This review summarizes their decade-long progress in developing advanced electrodes, analyzing the origins of sluggish alkaline HER kinetics and OER stability limitations. Professor Wei proposes a unifying “12345 Principle” as an optimization framework. For HER electrocatalysts, they have identified that metal/metal oxide interfaces create synergistic “chimney effect” and “local electric field enhancement effect”, enhancing selective …
Local Electric Fields Coupled With Cl− Fixation Strategy For Improving Seawater Oxygen Reduction Reaction Performance,
2025
School of Marine Science and Engineering, Hainan University, Haikou 570228, Hainan, China
Local Electric Fields Coupled With Cl− Fixation Strategy For Improving Seawater Oxygen Reduction Reaction Performance, Yu-Rong Liu, Miao Zhang, Yan-Hui Yu, Ya-Lin Liu, Jing Li, Xiao-Dong Shi, Zhen-Ye Kang, Dao-Xiong Wu, Peng Rao, Ying Liang, Xin-Long Tian
Journal of Electrochemistry
Development of robust electrocatalyst for oxygen reduction reaction (ORR) in a seawater electrolyte is the key to realize seawater electrolyte-based zinc-air batteries (SZABs). Herein, constructing a local electric field coupled with chloride ions (Cl−) fixation strategy in dual single-atom catalysts (DSACs) was proposed, and the resultant catalyst delivered considerable ORR performance in a seawater electrolyte, with a high half-wave potential (E1/2) of 0.868 V and a good maximum power density (Pmax) of 182 mW·cm−2 in the assembled SZABs, much higher than those of the Pt/C catalyst (E1/2: 0.846 V; Pmax: 150 mW·cm−2 …
Bridging Materials And Energy Storage Mechanisms In Zn-I2 Batteries,
2025
Key Laboratory for Colloid and Interface Chemistry Ministry of Education, School of Chemistry and Chemical Engineering Department, Shandong University, Jinan 250100, China
Bridging Materials And Energy Storage Mechanisms In Zn-I2 Batteries, Rong-Qi Liu, Wen-Shuo Shang, Jin-Tao Zhang
Journal of Electrochemistry
Zinc-iodine (Zn-I2) batteries have emerged as a compelling candidate for large-scale energy storage, driven by the growing demand for safe, cost-effective, and sustainable alternatives to conventional systems. Benefiting from the inherent advantages of aqueous electrolytes and zinc metal anodes, including high ionic conductivity, low flammability, natural abundance, and high volumetric capacity, Zn-I2 batteries offer significant potential for grid-level deployment. This review provides a comprehensive overview of recent progress in three critical domains: positive-electrode engineering, zinc anode stabilization, and in situ characterization methods. On the cathode side, anchoring iodine to conductive matrices effectively mitigates polyiodide shuttling and enhances …
Significantly Enhanced Oxygen Reduction Reaction Activity In Co-N-C Catalysts Through Synergistic Boron Doping,
2025
Laboratory of Advanced Power Source, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, China; School of Applied Chemistry and Engineering, University of Science and Technology of China, Hefei, 230026, China; Jilin Province Key Laboratory of Low Carbon Chemical Power Sources, Changchun 130022, China; State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese, Academy of Sciences, Changchun 130022, China
Significantly Enhanced Oxygen Reduction Reaction Activity In Co-N-C Catalysts Through Synergistic Boron Doping, Chang Lan, Jing-Sen Bai, Xin Guan, Shuo Wang, Nan-Shu Zhang, Yu-Qing Cheng, Jin-Jing Tao, Yu-Yi Chu, Mei-Ling Xiao, Chang-Peng Liu, Wei Xing
Journal of Electrochemistry
The weak adsorption energy of oxygen-containing intermediates on Co center leads to a considerable performance disparity between Co-N-C and costly Pt benchmark in catalyzing oxygen reduction reaction (ORR). In this work, we strategically engineer the active site structure of Co-N-C via B substitution, which is accomplished by the pyrolysis of ammonium borate. During this process, the in-situ generated NH3 gas plays a critical role in creating surface defects and boron atoms substituting nitrogen atoms in the carbon structure. The well-designed CoB1N3 active site endows Co with higher charge density and stronger adsorption energy toward oxygen species, …
The Effect Of Ozone Treatment On The Quality Of Biodiesel From Waste Cooking Oil,
2025
Quality Assurance of Food Industry, Polytechnic of AKA Bogor, Bogor 16154, Indonesia
The Effect Of Ozone Treatment On The Quality Of Biodiesel From Waste Cooking Oil, Sri Redjeki Setyawati, Singgih Wibowo
Makara Journal of Science
This research demonstrates the successful production of biodiesel from waste cooking oil (WCO) using the transesterification method. A methoxide solution, formed by employing a base catalyst and alcohol, facilitated the conversion of triglycerides into methyl esters and glycerol as the byproduct. The conversion process yielded 74% biodiesel and 13.5% glycerol content, with the remaining proportion consisting of water and contaminants. The application of ozone (O3) aeration proved effective in reducing contaminants—such as alcohol, unreacted catalysts, food residues and water—by approximately 60%. Furthermore, Fourier transform infrared (FTIR) testing affirmed that the biodiesel product—treated with O3 aeration—maintained its original …
Design And Optimization Of Anode Catalysts For Direct Ethanol Fuel Cells: Advances And Challenges In C-C Bond Activation And Selective Modulation Of The C1 Pathway,
2025
Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education Faculty of Chemistry, Northeast Normal University, 5268 Renmin Street, Changchun 130024, PR China
Design And Optimization Of Anode Catalysts For Direct Ethanol Fuel Cells: Advances And Challenges In C-C Bond Activation And Selective Modulation Of The C1 Pathway, Kai-Chi Qin, Meng-Tian Huo, Yu Liang, Si-Yuan Zhu, Zi-Hao Xing, Jin-Fa Chang
Journal of Electrochemistry
Direct ethanol fuel cells (DEFCs) are a promising alternative to conventional energy sources, offering high energy density, environmental sustainability, and operational safety. Compared to methanol fuel cells, DEFCs exhibit lower toxicity and a more mature preparation process. Unlike hydrogen fuel cells, DEFCs provide superior storage and transport feasibility, as well as cost-effectiveness, significantly enhancing their commercial viability. However, the stable C–C bond in ethanol creates a high activation energy barrier, often resulting in incomplete electrooxidation. Current commercial platinum (Pt)- and palladium (Pd)-based catalysts demonstrate low C–C bond cleavage efficiency (
Superhydrophilic Porous Coooh Nano-Architecture With Abundant Oxygen Vacancies For Enhanced Urea Electrooxidation At Ampere-Level Current Densities,
2025
Faculty of Chemical Engineering, Yunnan Provincial Key Laboratory of Energy Saving in Phosphorus Chemical Engineering and New Phosphorus Materials, Kunming University of Science and Technology, Kunming 650500, Yunnan, China
Superhydrophilic Porous Coooh Nano-Architecture With Abundant Oxygen Vacancies For Enhanced Urea Electrooxidation At Ampere-Level Current Densities, Wen-Jing Lv, Xiao-Man Tang, Xue-Tong Wang, Wen-Cai Liu, Jian-Wen Zhu, Guo-Jing Wang, Yuan-Zhi Zhu
Journal of Electrochemistry
The conversion of urea-containing wastewater into clean hydrogen energy has gained increasing attention. However, challenges remain, particularly with sluggish catalytic kinetics and limited long-term stability of urea oxidation reaction (UOR). Herein, we report the loosely porous CoOOH nano-architecture (CoOOH LPNAs) with hydrophilic surface and abundant oxygen vacancies (Ov) on carbon fiber paper (CFP) by electrochemical reconstruction of the CoP nanoneedles precursor. The resulting three-dimensional electrode exhibited an impressively low potential of 1.38 V at 1000 mA·cm−2 and excellent durability for UOR. Furthermore, when tested in an anion exchange membrane (AEM) electrolyzer, it required only 1.53 V at …
Methane Partial Oxidation With Ni-Mg-Al Hydrotalcites: Impact Of Magnesium On Catalyst Performance,
2025
The British University in Egypt
Methane Partial Oxidation With Ni-Mg-Al Hydrotalcites: Impact Of Magnesium On Catalyst Performance, Dalia A. Ali Dr.
Chemical Engineering
The partial oxidation of methane (POM) is a promising route for hydrogen-rich syngas production with lower energy requirements compared to steam reforming. Herein, Ni-incorporated Mg-Al hydrotalcite- derived mixed oxide catalysts (5Ni-HT-x, x = 60, 65, 70, 75 wt.% Mg) were synthesized via co-precipitation and evaluated for CH₄ conversion and H₂ yield. Characterization techniques, including X-ray Diffraction (XRD), X-ray Photoelectron Spectroscopy (XPS), BET, H₂-TPR, TEM, FTIR, TGA, and Raman spectroscopy, were employed to investigate catalyst structure, active site stability, and carbon deposition. As a constituent of hydrotalcite-derived mixed oxides (HT), Ni2+ is strongly bound within the hydrotalcite- derived mixed oxides structure, …
Upcycling Waste To Wealth: Cuo-Sio₂/Reduced Graphene Nanocomposite From Pomegranate Peels For One-Pot Low-Temperature Conversion Of Waste Oils Into Valuable Fatty Acid Monomers,
2025
The British University in Egypt
Upcycling Waste To Wealth: Cuo-Sio₂/Reduced Graphene Nanocomposite From Pomegranate Peels For One-Pot Low-Temperature Conversion Of Waste Oils Into Valuable Fatty Acid Monomers, Attia Attia, Shahenda Mahran Dr., Maria Centeno Prof., Basudeb Saha
Petroleum Engineering and Gas
and hence reduce the price of the fatty acid monomers. This study reports for the first time a novel, environmentally benign, highly active copper oxide-silica oxide/reduced graphene oxide (CuO-SiO2/RGO), heterogeneous nano-catalyst derived from waste pomegranate peels, for the one-pot, low-temperature synthesis of fatty acid monomers from high-acid-value waste vegetable oil (WVO). The synthesised nano-catalyst was extensively characterised using XRD, FT-IR, TEM, SEM, EDX and TGA-DTA. Further, it was utilised to synthesise fatty acidrich oleic phenoxypropyl acrylate (OPA) monomer from high acid value WVO via a single-step reaction.
Boosted Electrochemical Oxidation Of Methanol At Feox/Pd/Au Ternary Nanocatalyst,
2025
The British University in Egypt
Boosted Electrochemical Oxidation Of Methanol At Feox/Pd/Au Ternary Nanocatalyst, Ghada El-Nowihy
Chemical Engineering
In this paper, a highly effective catalyst for methanol electrochemical oxidation (MEO) was developed by the sequential deposition of spherical gold nanoparticles (nano-Au) on a glassy carbon (GC) rod’s surface followed by palladium nanoparticles (nano-Pd), then, iron oxide nanoparticles (nano-FeOx) to form FeOx/Pd/Au/GC catalyst. The sequence of catalyst’s layers proved crucial in optimizing its performance towards MEO. Notably, FeOx/Pd/Au/GC electrode produced a remarkable enhancements in the catalytic activity (by 7 times) and stability (approximately 16 fold) when compared to those produced at Pd/GC rod. Additionally, the onset potential for MEO was significantly reduced by approximately 40 mV. Through material and …
Cultivation Of Botryococcus Braunii For The Production Of Hydrocarbons Suitable For Fuel Use,
2025
Clemson University
Cultivation Of Botryococcus Braunii For The Production Of Hydrocarbons Suitable For Fuel Use, Bryan C. Carroll
All Theses
Energy security, rural poverty, and climate change are pressing issues of our time. Biofuels provide a solution to these issues, with a focus on sustainable aviation fuel, SAF, due to compatibility with aircraft infrastructure and energy density. This research aims to review and produce knowledge about a specific microalga, Botryococcus braunii, for its potential for SAF. First a literature review on the process was conducted followed by an experimental study on the impact of aqueous media and inorganic carbon its growth and hydrocarbon content. The literature review found the process consists of cultivation followed by lipid extraction or hydrothermal …
Numerical Simulation Of The Pitting Corrosion Behavior Of Stainless Steel Bellows Influenced By Varying Liquid Film Thicknesses,
2025
School of Mechanical and Power Engineering, East China University of Science and Technology, Shanghai 200237, China
Numerical Simulation Of The Pitting Corrosion Behavior Of Stainless Steel Bellows Influenced By Varying Liquid Film Thicknesses, Lu-Jun Ren, Guo-Min Li, Zhen-Xiao Zhu, Hai-Yan Xiong, Bing Li
Journal of Electrochemistry
To advance the understanding of the corrosion behavior of stainless steel bellows in marine atmospheric environments and enhance the precision of service life predictions, this study employs finite element simulations to investigate the pitting corrosion rates and pit morphologies of bellows peaks and troughs under varying electrolyte film thicknesses. The model incorporates localized electrochemical reactions, oxygen concentration, and homogeneous solution reactions. For improved computational accuracy, the fitted polarization curve data were directly applied as nonlinear boundary conditions on the electrode surface via interpolation functions. Simulation results reveal that the peak regions exhibit faster corrosion rates than the trough regions. With …
Ionic Liquid Enhanced Proton Transfer For Neutral Oxygen Evolution Reaction,
2025
Henan Engineering Research Center of Design and Recycle for Advanced Electrochemical Energy Storage Materials, School of Materials Science and Engineering, Henan Normal University, Xinxiang 453007, China
Ionic Liquid Enhanced Proton Transfer For Neutral Oxygen Evolution Reaction, Ming-Xing Chen, Nian Liu, Zi-He Dua, Jing Qi, Rui Cao
Journal of Electrochemistry
The development of highly active catalyst in pH-neutral media for oxygen evolution reaction (OER) is critical in the field of renewable energy storage and conversion. Nevertheless, the slow kinetics of proton-coupled electron transfer (PCET) hinders the overall OER efficiency. Herein, we report an ionic liquid (IL) modified CoSn(OH)6 nanocubes (denoted as CoSn(OH)6-IL), which could be prepared through a facile strategy. The modified IL would not change the structural characteristics of CoSn(OH)6, but could effectively regulate the local proton activity near the active sites. The CoSn(OH)6-IL exhibited higher intrinsic OER performances than the pristine …
Regulating The Amount Of Graphene Oxide For Enhanced Capacitive Energy Storage Of Mof Derived Materials,
2025
ShenSi Lab, Shenzhen Institute for Advanced Study, University of Electronic Science and Technology of China, Longhua, Shenzhen 518110, China
Regulating The Amount Of Graphene Oxide For Enhanced Capacitive Energy Storage Of Mof Derived Materials, Yong-Ji Qin, Jing-Quan Yang, Hao Wang, Mei-Ling Lian, Pei-Pei Jia, Jun Luo, Xi-Jun Liu, Jun-Feng Liu
Journal of Electrochemistry
In pursuit of more efficient and stable electrochemical energy storage materials, composite materials consisting of metal oxides and graphene oxide have garnered significant attention due to their unique structures and exceptional properties. Graphene oxide (GO), a two-dimensional material with an extremely high specific surface area and excellent conductivity, offers new possibilities for enhancing the electrochemical performance of metal oxides. In this work, we synthesized metal- organic framework (MOF) and GO composites by regulating the amount of GO, and successfully prepared composites of metal oxides supported by nitrogen-doped carbon frameworks and GO through a simple one-step calcination process. Based on the …
Anion Exchange Membrane Transport And Accelerated Testing Methods For Co2 Electrolyzers With Cu-Based Electrocatalyst,
2025
Louisiana State University and Agricultural and Mechanical College
Anion Exchange Membrane Transport And Accelerated Testing Methods For Co2 Electrolyzers With Cu-Based Electrocatalyst, John C. Hendershot
LSU Doctoral Dissertations
Electrocatalytic carbon dioxide (CO2) reduction to C2+ products holds promise for low carbon intensity fuels, chemicals, and food; however, durability challenges, particularly bicarbonate (HCO3-)and carbonate (CO32-) salt precipitation, hinder their commercialization. This report considers water (H2O) and ion transport properties of conventional anion exchange membranes (AEMs) in zero-gap membrane electrode assembly (MEA) configurations using Cu electrocatalysts. Transport characterization includes H2O diffusion, permeability, potassium (K+) diffusion, and transference numbers using three commercial AEMs, including piperidinium-based (Versogen), quaternary ammonium-based (Fumasep), and imidazolium-based (Dioxide Materials) membranes. Accelerated lifetime …
Pd-Based Hydrogen Separation Membranes Synthesized Via A Liquid-Phase Route,
2025
University of New Mexico - Main Campus
Pd-Based Hydrogen Separation Membranes Synthesized Via A Liquid-Phase Route, Chase W. Thompson
Chemical and Biological Engineering ETDs
Palladium (Pd) membranes have gained significant attention for their ability to selectively separate hydrogen, a critical process for clean energy applications such as fuel cells and hydrogen storage. However, challenges such as grain growth, sintering, hydrogen embrittlement, and film uniformity limit their scalability and long-term stability. This thesis focuses on the controlled synthesis, deposition, and stability of Pd nanoparticles to optimize membrane performance for hydrogen separation. This work investigates solution-phase synthesis of Pd nanoparticles, focusing on temperature, precursor concentration, and solvent composition as key variables influencing particle growth and dispersion. Pd membranes were fabricated using nanoparticle deposition onto porous supports, …
Low Temperature Methane Coupling With Co And Co2,
2025
Louisiana State University and Agricultural and Mechanical College
Low Temperature Methane Coupling With Co And Co2, A K M Kazi F.M. Aurnob
LSU Doctoral Dissertations
Methane is the smallest hydrocarbon and the most abundant component in natural gas. Despite its availability, its chemical utilization has remained limited due to the challenges associated with direct methane activation and conversion. Most of the methane oxidation and oxidative carbonylation reactions in literature have been carried out at high-pressure using batch reactors or at ambient pressure using flow reactors. While batch reactors have been shown to have higher product yields, they are limited in their capability to provide real-time kinetic insights and comprehensive mechanistic understanding of the reactions involved due to the long residence time. This limits rationalization of …
Anion Exchange Membrane Durability For Electrochemical Co2 Reduction In Membrane Electrode Assembly Cells,
2025
Louisiana State University and Agricultural and Mechanical College
Anion Exchange Membrane Durability For Electrochemical Co2 Reduction In Membrane Electrode Assembly Cells, Soundarzo Tasnim
LSU Master's Theses
The electrochemical reduction of CO₂ using membrane electrode assembly (MEA) cells has emerged as a promising approach for carbon capture and conversion into valuable products. This study investigates the degradation mechanisms of anion exchange membranes (AEMs) in CO₂ reduction applications, focusing on Sustainion X37-50, PiperION, and FAA-3-50. The research analyzes the impact of chemical and mechanical degradation on membrane performance, highlighting key stability challenges in long-term operation. Fourier transform infrared spectroscopy (FTIR) and electrochemical impedance spectroscopy (EIS) were employed to monitor functional group stability and ionic conductivity loss over extended operation. The results indicate that hydroxide-induced degradation leads to nucleophilic …
Experimentally Driven Numerical Model Of Carbon/Polyaniline-Based Glucose Monitoring Sensors: An Evaluation Using A New Figure Of Merit,
2025
University
Experimentally Driven Numerical Model Of Carbon/Polyaniline-Based Glucose Monitoring Sensors: An Evaluation Using A New Figure Of Merit, Ziad Khalifa, Kyrillos Selim, Amira Ali, Sameh Abdellatif
Chemical Engineering
This study presents an experimentally driven numerical model for evaluating carbon/polyaniline (PANI)- based glucose monitoring sensors (GMSs), focusing on innovative configurations using graphene-PANI and carbon nanotube (CNT)-PANI composites. We performed a thorough analysis of the morphological, electrophysical, and electrical properties of these materials, ultimately leading to the extraction of key electrical parameters for integration into a finite element model (FEM). This model simulates the entire sensor, enabling the estimation of critical performance metrics such as sensitivity, limit of detection (LOD), linearity, and power consumption. Our findings demonstrate that the CNT-PANI configuration significantly outperforms the laser-induced graphene (LIG)-PANI electrode, achieving a …
Comprehensive Review Of Sensible Thermal Storage Systems For Cooking Applications,
2025
Department of Energy and Process Engineering, Norwegian University of Science and Technology, Norway
Comprehensive Review Of Sensible Thermal Storage Systems For Cooking Applications, Anna K. Shariishoy
Tanzania Journal of Engineering and Technology (TJET)
This paper reviewed the sensible thermal storage systems specifically designed for cooking applications. The review focuses on the characteristics of storage materials, their practical applications, and the overall performance of the systems. The review consolidated an array of experimental and numerical research published across various sources such as journals, conferences, books, online resources, and professional reports. A systematic review is used to reach the conclusion of this paper. Significant findings from this study include the wide range of storage capacities attained from small-scale systems that can store ~1–5 MJ of energy for a single meal to bigger systems that can …
