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Articles 3301 - 3330 of 3581

Full-Text Articles in Materials Chemistry

Study Of The Effect Of Rare Earth Ions On Dna Using Cyclic Voltammetry And Spectroscopy, Hei-Bai Shen, Yu-Zhuan Kang, Hai-Feng Yang, Lin Yu, Zong-Rang Zhang Nov 1998

Study Of The Effect Of Rare Earth Ions On Dna Using Cyclic Voltammetry And Spectroscopy, Hei-Bai Shen, Yu-Zhuan Kang, Hai-Feng Yang, Lin Yu, Zong-Rang Zhang

Journal of Electrochemistry

The interaction between rare earth ions(e.g. Eu3+ ,Ce3+, Er3+, Sm3+, Tb3+, La3+ and Nd3+) and DNA had been investigated by using Cyclic Voltammetry, Ultraviolet and Raman Spectroscopy. After the adding of Ce3+ ion to DNA solution, the cathodic peak current of Ce3+ ion reduction was found to decrease obviously, and the anodic peak current to decrease even more significantly. Differential UV spectra of Ce3+ ion depicted hyperchromic effect after the reaction of these two species and a new peak of 272 nm was found. Differential …

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Direct Electro-Oxidation Synthesis Of D-Arabinose On Spectroscopic Graphite Electrode, Hei Wei, Huang Ying Nov 1998

Direct Electro-Oxidation Synthesis Of D-Arabinose On Spectroscopic Graphite Electrode, Hei Wei, Huang Ying

Journal of Electrochemistry

D Arabinose synthesized by direct electro-oxidative decarboxylation of D gluconate on graphite electrode from aqueous solutions. The effects of D gluconate concentration, electrolysis potential, temperature and electrolyte composition on the current efficiency and product yield of electrosynthsis are discussed. The laboratory scale electrosynthesis was achieved with flow through cell. The optimum technology conditions for electrosynthesis were obtained with orthogonal design method. Both galvanostatic and potentionstatic conditions have been exploited, the later was found to be more effective.

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The Study Of Poly [N-(3-Ferrocene Acetamino Propyl- Pyrrole] Film Modified Glucose Electrode, Cheng-Yun Tian, Jing Chen, Li Zhang Nov 1998

The Study Of Poly [N-(3-Ferrocene Acetamino Propyl- Pyrrole] Film Modified Glucose Electrode, Cheng-Yun Tian, Jing Chen, Li Zhang

Journal of Electrochemistry

A poly [N-(3-ferrocene-acetamino-propyl-pyrrole)] film modified electrode was fabricated and studied by cyclic voltammetric method. The result shows that the modified electrode can give stable redox peaks of ferrocene, and an obvious catalytic peak due to glucose. This modified electrode was used to tabricate a glucose sensor which operates at +0.2 V, so that the ascorbic acid or uric acid doesn't affect the accuracy detection of glucose concentration. The sensor has a linear range of 0.1～10 mmol/L glucose, which the period of long term stability and response time of the sensor are about ten days and 2 min.

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Study On The Ti/Sno2/Pbo2 Anode In Sulphuric Acid Solution, Yao-Gang Li, Yan-Pin Shun, Wen-Lin Xu Nov 1998

Study On The Ti/Sno2/Pbo2 Anode In Sulphuric Acid Solution, Yao-Gang Li, Yan-Pin Shun, Wen-Lin Xu

Journal of Electrochemistry

The Ti/SnO2/PbO2 electrode, prepared by the electrodeposition method, was tested as the anode for the oxygen evolution reaction in 1 mol/L H2SO4 solution and examined by means of EDS, SEM and XRD. The electrocatalytic activity and the electrochemical stability of the prepared electrode were found to be superior.

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Direct Electrochemical Reaction Of Cytochrome C At The Poly (Ethylene Oxide) Film Modified Gold Electrodes, Xiao-Gang Qu, Gong-Quan Sun, Hui Yang, Tian-Hong Lu Aug 1998

Direct Electrochemical Reaction Of Cytochrome C At The Poly (Ethylene Oxide) Film Modified Gold Electrodes, Xiao-Gang Qu, Gong-Quan Sun, Hui Yang, Tian-Hong Lu

Journal of Electrochemistry

In this paper, the direct electrochemical reaction of cytochrome c was sudied at the poly (ethylene oxide) film modified gold electrodes. It was found the PEO is a good promoter for the electrochemical reaction of cytochrome c, and the reversibility of reaction of cytochrome c was found to depend on the molecular weight of PEO and the morphology of the PEO films.

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Ac Impedance Study Of The La0.8Sr0.2Mno3/Ysz Electrode, Shi-Zhong Wang, Yi Jiang, Ya-Hong Zhang, Jing-Wang Yan, Wen-Zhao Li Aug 1998

Ac Impedance Study Of The La0.8Sr0.2Mno3/Ysz Electrode, Shi-Zhong Wang, Yi Jiang, Ya-Hong Zhang, Jing-Wang Yan, Wen-Zhao Li

Journal of Electrochemistry

Electrochemical reaction of oxygen on the La0.8Sr0.2MnO3/YSZ electrode has been investigated in detail with AC impedance. The results demonstrated that the rate determining step(rds) of the reaction varies with the temperature, oxygen partial pressure and overpotential applied. At open circuit potential, the rds is the dissociative adsorption of oxygen on the LSM surface. A large number of electron holes are generated at high anodic overpotentials, while oxygen vacancies are formed at high cathodic overpotentials. The formation of the electron holes results in the electronic conduction of the YSZ electrolyte and the extension of the …

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The Hydrogen Evolution Reaction On The Hydrogen Storage Alloy Electrode, Shi-Gang Lu, Qun Li, Qing-Guo Liu, Chun Lu, Bing Dang, Han-Xi Yang Aug 1998

The Hydrogen Evolution Reaction On The Hydrogen Storage Alloy Electrode, Shi-Gang Lu, Qun Li, Qing-Guo Liu, Chun Lu, Bing Dang, Han-Xi Yang

Journal of Electrochemistry

The hydrogen evolution reaction was studied in 1 mol/L KOH solution on the hydrogen storage alloy Mm(NiCoMnAl)5 electrode using open circuit potential decay and ac impedance technique. The reaction was found to proceed by the Volmer(discharge)-Tafel(recombination)mechanism. The measured overpotential η can be subdivided into two components η 1 and η 2 corresponding to the elementary Volmer and Tafel reaction. The Faradaic impedance was analyzed and characterized by the Volmer reaction. Then the exchange current density was evaluated . It was founded that the activity of hydrogen storage alloy electrode for the hydrogen evolution reaction was similar to that of …

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Modification Of Carbon Anode Materials Of Lithium-Ion Secondary Battery, Yuping Wu, Chun-Rong Wan, Chang-Yin Jiang, Jiang-Iun Li Aug 1998

Modification Of Carbon Anode Materials Of Lithium-Ion Secondary Battery, Yuping Wu, Chun-Rong Wan, Chang-Yin Jiang, Jiang-Iun Li

Journal of Electrochemistry

In this paper, the latest research work on modification of carbon anode materials of lithium ion secondary battery is reviewed. Modification methods include: incorporation of nonmetal elements such as boron, silicon, nitrogen, phosphorus and sulfur, metal elements such as potassium, aluminum, gallium and transitional metal elements such as vanadium, nickel, cobalt, copper and iron and surface treatment such as oxidation and formation of surface layer. Since these methods can affect the carbon materials' electronics state, crystal structure and surface structure, the electrochemical properties of the carbon materials could probably be improved. Besides, mechanisms for lithium storage in carbonaceous materials are …

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Formation And Effect Of Tribo Cell For Fe Cr Alloy, Dong-Bai Sun, Tao Li, Hong-Ying Yu, De-Ji Yang Aug 1998

Formation And Effect Of Tribo Cell For Fe Cr Alloy, Dong-Bai Sun, Tao Li, Hong-Ying Yu, De-Ji Yang

Journal of Electrochemistry

The micro galvanic corrosion of 1Cr18 alloy and its effects on the triboelectrochemical behavior were investigated and analyzed in this article. It is shown that the micro galvanic corroson is due to the electrochemical inhomogenity on the surface of the alloy during the friction process. Like galvanic corrosion,the micro galvanic corrosion behaviors are greatly affected by the area ratio of unrubbed to rubbed surface.The load effects on electrochemical behavior of 1Cr18 alloy are also attributed to existence of electrochemical inhomogenity on the surface of materal.

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Lithiun Insertion In Carbon Nanotubes, Guo-Tao Wu, Chun-Sheng Wang, Zhong-Fu Qi, Wenz-Hu Li Aug 1998

Lithiun Insertion In Carbon Nanotubes, Guo-Tao Wu, Chun-Sheng Wang, Zhong-Fu Qi, Wenz-Hu Li

Journal of Electrochemistry

Carbon nanotubes were produced by chemical vapour deposition(CVD) of acetylene under hydrogen gas.The reversible specific capacity of carbon nanotubes is up to 700 mAh/g, much higher than the theoretical specific capacity of graphite(372 mAh/g).After twenty charge/discharge cycles,the discharge capacity of carbon nanotube anode still maintains 65.3% of its original discharge capacity . Besides, the charge/discharge efficiency of carbon nanotube in the first charge/discharge cycle was found to improve from 42.6% up to 55.9% by coating carbon nanotubes with copper.

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External Transducing Measurement Of The Internal Pressure In Sealed Battery By Resistance Strain Gauge, Han-Xi Yang, Rong-Hui Hu, Xin-Ping Ai, Cong-Zhi Yang, Sheng-Xian Li Aug 1998

External Transducing Measurement Of The Internal Pressure In Sealed Battery By Resistance Strain Gauge, Han-Xi Yang, Rong-Hui Hu, Xin-Ping Ai, Cong-Zhi Yang, Sheng-Xian Li

Journal of Electrochemistry

A novel method to monitor dynamically the internal pressure of sealed battery with no damage of the battery by using of resistance strain measurement technique is presented. This technique employs the resistence strain gauges in touch of the battery case and to detect the minimal change in the battery deformation due to the increasing internal pressure, electrode expantion or intrenal temperature rise. Application of the technique for the study of the effects of the battery processing factors on the battery performance is described taking Ni MH battery as example.

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Photoelectrochemical Studies On Nanoporous Tio2/Pan Film Electrode, Min-Sheng Liu, Yan-Zhong Hao, Xue-Bin Qiao, Mai-Zhi Yang, Sheng-Min Cai Aug 1998

Photoelectrochemical Studies On Nanoporous Tio2/Pan Film Electrode, Min-Sheng Liu, Yan-Zhong Hao, Xue-Bin Qiao, Mai-Zhi Yang, Sheng-Min Cai

Journal of Electrochemistry

The photon to electricity conversion process of nanoporous TiO2/PAn film electrode was studied in electrolytes with and without redox couple by using the photocurrent action spectra and potential dependence of photocurrent. It is concluded that the nanoporous TiO2/PAn film electrode has a structure of duplex n type semiconductor layers. The band gap of PAn film is 2.88eV.The TiO2 nanoporous film electrode modified by PAn can extend the range of optical absorption into visible and infrared region and effectively increase the photocurrent in the visible and infrared region. The photocurrent threshold shifts to>600nm and conversion …

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Studies On The Electrode Kinetics Of Electrooxidation Of Mn2+, Wan-Li Hu, Tong Su, Wei Guo, Ding Zhou Aug 1998

Studies On The Electrode Kinetics Of Electrooxidation Of Mn2+, Wan-Li Hu, Tong Su, Wei Guo, Ding Zhou

Journal of Electrochemistry

The mechanism of electrooxidation of MnSO4 on Pb Sb As alloy anode was investigated by using rotating disc electrode technique. The results shown that the conditional standard potential of Mn(Ⅲ)/Mn(Ⅱ)in 40% H2SO4 is 0.886 4 V.The rate controlling step of electrode process is mixed controlled by charge transfer and diffusion.

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Electrochemical Behavior Of Chemically Prepared Ring-Substituted Polyanilines, Li-Zong Dai, Hui-Huang Wu Aug 1998

Electrochemical Behavior Of Chemically Prepared Ring-Substituted Polyanilines, Li-Zong Dai, Hui-Huang Wu

Journal of Electrochemistry

Polyaniline (PAn) has been known as a promising conducting polymer for technological applications. In research work elecrochemically synthesized PAn has been frequently used since electropolymerization is convenient to prepare the polymer film with controllable thickness or dopingon electrodes. However , the processibility of elecrosynthesized PAn is too poor to produce largearea devices because of its insolubility and infusibility. Recently, therefore, chemical polymerization has attracted a considerable attentionfl-3],  especially suitably derivatized ring substituted (e.g. alkyl or alkoxy) polyanilines have been synthesized, and their appreciable solubility in commonorganic solvents enable the preparation of film on industrial scale by casting. Moreover, emulsionpolymerization reduces …

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Study Of Proton Exchange Membrane Fuel Cells(Pemfc), Shan-Hai Ge, Bao-Lian Yi, Hong-Fen Xu, Ming Han, Zhi-Gang Shao Aug 1998

Study Of Proton Exchange Membrane Fuel Cells(Pemfc), Shan-Hai Ge, Bao-Lian Yi, Hong-Fen Xu, Ming Han, Zhi-Gang Shao

Journal of Electrochemistry

The electrode kinetic parameters for proton exchange membrane fuel cells(PEMFC) were investigated by measuring the relations of cell potential and current density. An experimental stack of PEMFC which can be operated at E cell =0.7V, I =0.55A/cm2 steadily is presented, and the effects of electrode structure and operation conditions such as temperature, pressure, humidification, flow rate on the performance of PEMFC are discussed.

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Studies On The Preparation Of Nanophase Electrode Materials And Its Electrochemical Properties(Ⅲ)—Performance Of Nm-Γ-Mno2 Obtained By Microemulsion Method, Ling Liu, Xi Xia Aug 1998

Studies On The Preparation Of Nanophase Electrode Materials And Its Electrochemical Properties(Ⅲ)—Performance Of Nm-Γ-Mno2 Obtained By Microemulsion Method, Ling Liu, Xi Xia

Journal of Electrochemistry

A nanophase MnO2 was synthesized using w/o microemulsion as reation media, The most favorable experiment conditions for the preparation of nm MnO2 were researched. XRD,TEM,AC impedance, cyclic voltammetry etc. examinations were used to characterize the sample comparison with the classical MnO2 (I.C.No.1EMD,electrolytic manganese dioxide). Sample shows that the crystal styucture of the synthesized samples are mainly γ-MnO2, with average particle size in the nanometer as shown by TEM. It was found that the discharge capacity of nm MnO2 obtained is significantly higher than that of the I.C.No.1 EMD.

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Electrooxidation Of Benzene To Benzoquinone In A Packed Bed Reactor, Xin-Sheng Zhang, Ping Ding, Ying-Chun Dai, Wei-Kang Yuan Aug 1998

Electrooxidation Of Benzene To Benzoquinone In A Packed Bed Reactor, Xin-Sheng Zhang, Ping Ding, Ying-Chun Dai, Wei-Kang Yuan

Journal of Electrochemistry

A packed electrode reactor was used to oxidize to benzoquinone. Anode bed of the reactor has a size of 10～30 mm×450 mm×50 mm(thickness×length×width),and was packed porous lead alloy. A dispersion of benzene in 1 mol/L aqueous sulfuric acid was passed through the reactor. Current efficiency for benzoquinone generation is 62.9% at optimal operating condition: velocity of electrolyte flow, 0.19 ms -1 ;current, 10 A; thickness of anode bed, 10 mm, and percentage of benzene, 24%.

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Electrochemical Preparation Of Rare Earth Functional Materials And Application Of Rare Earth To Electrochemistry, Qi-Qin Yang, Tong-Xiang Ye May 1998

Electrochemical Preparation Of Rare Earth Functional Materials And Application Of Rare Earth To Electrochemistry, Qi-Qin Yang, Tong-Xiang Ye

Journal of Electrochemistry

The new progress and related mechanism of the electrochemical preparation of rare earth materials (magnets, magnetooptic materials, battery materials, luminescent devices, semiconductors, superconductors) and the application of rare earth to the electrochemical areas (e.g. electroplating, corrosion, electrosynthses) have introduced.

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In-Situ Raman Spectroscopic Study Of The Oxidation And Reduction Of Ag Electrode In Na2So4, Yan-Xia Chen, Kai-Qi Huang, Zhong-Qun Tian May 1998

In-Situ Raman Spectroscopic Study Of The Oxidation And Reduction Of Ag Electrode In Na2So4, Yan-Xia Chen, Kai-Qi Huang, Zhong-Qun Tian

Journal of Electrochemistry

In-situ Raman spectroscopy combined with cyclic voltammogram measurements was used to investigate formation of oxygen species at Ag electrode surfaces during the oxidation and reduction process in 0.1 mol/L Na2SO4 solution. The time dependent Raman spectra show that at potentials positive of 0.2 V, adsorption of oxygen atom occurs, while at the potentials positive of 0.4 V, some oxygen atoms migrate into subsurface of the Ag electrode and the other form strongly bound oxygen on the surface through chemical bond. At the same potentials, part of the silver atoms are oxidized and form Ag2SO4 …

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Study Of Charged Property On The Interface Of Porous Membrane Of Anodized Aluminum, Ya-Fei Kuang, Ling Wang, Fei Hu May 1998

Study Of Charged Property On The Interface Of Porous Membrane Of Anodized Aluminum, Ya-Fei Kuang, Ling Wang, Fei Hu

Journal of Electrochemistry

Using electrodialytic method, the relation between the pH value of tested solution and the ζ potential of porous anodized aluminum membrane, which was separated by reverse electrolysis from aluminum substrate, has been investigated. The following results can be obtained in 1.0×10-2 mol/L KCl solution: The pHIEP (isoelectric potential) of the porous membrane is equal to 9.20. In the range of 2.00

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An Investigation On Galvanic Corrosion Behavior Of Co-Cr-Mo Alloy And Ti-6al-4v Alloy, Zhi-Jun Bai, Yin-Shun Wu, Tian-Cheng Zhang May 1998

An Investigation On Galvanic Corrosion Behavior Of Co-Cr-Mo Alloy And Ti-6al-4v Alloy, Zhi-Jun Bai, Yin-Shun Wu, Tian-Cheng Zhang

Journal of Electrochemistry

The combination of Co-Cr-Mo alloy and Ti-6Al-4V alloy is widely used as total hip prostheses. The objective of this work is to quantify the possibility of the acceleration of corrosion due to the galvanic effect. Electrochemical tests based on mixed potential and protection potential theories were used to study the galvanic corrosion behavior of coupling these alloys. The results indicated that the galvanic potential between two alloys always was in the passive potential zone of the isolated alloy respectively, and that the galvanic current of the couple is same as the corrosion current of isolated alloy under passive state. The …

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Investigation Of Pb/Pb2+ And Polypyrrole Electrodes By Use Of Ac Electrochemical-Thermal Method, Ji-Hua Zhuang, Jie Zhang, Liang-Jun Dong, Hong Xie, Zhi-Yu Jiang May 1998

Investigation Of Pb/Pb2+ And Polypyrrole Electrodes By Use Of Ac Electrochemical-Thermal Method, Ji-Hua Zhuang, Jie Zhang, Liang-Jun Dong, Hong Xie, Zhi-Yu Jiang

Journal of Electrochemistry

The values of entropy change for Br-/Br2 and Pb/Pb2+ electrode reactions were measured by use of the ac electrochemical-thermal method. The influence of alkaline pretreatment on the electrochemical behavior for a polypyrrole electrode was also investigated by this method. It was found that after alkaline pretreatment the eletrochemical activity of polypyrrole electrode was decreased obviously, but it kept partly electrochemical-thermal characteristic as same as that before pretreatment.

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Studies On Impedance Of Acid-Copper Electroplating System, Wen Deng, Zhao Liu, Xiang-Min Lin, He-Tong Guo May 1998

Studies On Impedance Of Acid-Copper Electroplating System, Wen Deng, Zhao Liu, Xiang-Min Lin, He-Tong Guo

Journal of Electrochemistry

The impedance characteristics of elementary solution (0.3 mol/L CuSO4+1.94 mol/L H2SO4) and that with the addition of 60 mg/L Cl-, 300 mg/L OP-21, 30 mg/L PEG, 10 mg/L 2thiazolinyldithiopropane sulfate (self-synthesized additive) are investigated and interpreted in terms of equivalent circuit. The results indicated: (1) Cl- ion can increase cathodic polarization. (2) A twostep reaction mechanism corresponds to Cu2+ reduction, that is: Cu2+→Cu+, Cu+→Cu(adsorption)→Cu(lattice), Cu2+ react in different forms of complex ion in sulfuric acidcupric sulfate solution with or without Cl- ion. …

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Application Of Electrochemical Process To Recycling Waste Water From Flotation Of Phosphate Ores, Shi-Xin Yu, Wen Sun May 1998

Application Of Electrochemical Process To Recycling Waste Water From Flotation Of Phosphate Ores, Shi-Xin Yu, Wen Sun

Journal of Electrochemistry

The waste water from flotation of phosphate ores can be used to recycling by electrochemical process. The suitable factors of electrochemical process is made by measuring ζ potential and transmittance of the waste water in modified way.

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Studies Of Surface Alloy As High Efficient Electrocatalyst For Glyoxylic Acid Synthesis, Sheng-Pei Chen, Sheng-Qing Xia, Shi-Gang Sun May 1998

Studies Of Surface Alloy As High Efficient Electrocatalyst For Glyoxylic Acid Synthesis, Sheng-Pei Chen, Sheng-Qing Xia, Shi-Gang Sun

Journal of Electrochemistry

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Influences Of Ptfe On Electrochemical Properties Of Foam-Type Ni(Oh)2 Electrodes, Zhen Zhou, Jie Yan, Xian-You Wang, Jin Lin, Hua-Tang Yuan, De-Ying Song, Yun-Shi Zhang May 1998

Influences Of Ptfe On Electrochemical Properties Of Foam-Type Ni(Oh)2 Electrodes, Zhen Zhou, Jie Yan, Xian-You Wang, Jin Lin, Hua-Tang Yuan, De-Ying Song, Yun-Shi Zhang

Journal of Electrochemistry

Research work was performed for the influences of PTFE on the electrochemical properties of foam-type Ni(OH)2 electrodes by constant current discharge. CV and EIS method. Experimental results exhibit that the existence of PTFE would decrease the reversibility of electrode reaction and increase the reaction resistance of the electrode; thus lower the discharge potential and capacity, so PTFE should be added as little as possible during the preparation of paste-type electrodes.

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Study Of The Mechanisms Of The Electrochemical Reactions Of The Soluble Polyimides, Ying Zhu, Wei Xing, Hui Zhao, Gui-Zheng Shi, Yue-Sheng Li, Meng-Xian Ding, Hui Yang, Tian-Hong Lu May 1998

Study Of The Mechanisms Of The Electrochemical Reactions Of The Soluble Polyimides, Ying Zhu, Wei Xing, Hui Zhao, Gui-Zheng Shi, Yue-Sheng Li, Meng-Xian Ding, Hui Yang, Tian-Hong Lu

Journal of Electrochemistry

For the first time, the electrochemical behaviors of the three soluble polyimides were studied in the organic and aqueous solutions. It was found that the electrochemical behaviors of PI in the organic solutions are significantly different from that in the aqueous solution. Using the IR spectroscopy and semi-empirical molecular orbital calculation and combining the results of the electrochemical measurements, the mechanisms of the electrochemical reactions of polyimides were demonstrated.

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A Novel Pt(Ir) Plated Stainless Steel Electrode, Jing-Ying Shi, Xiu-Feng Xiao, Ze-Shan Zhu, Xi Zheng, Yan-Zhen Chen, Wen-Yun Hu May 1998

A Novel Pt(Ir) Plated Stainless Steel Electrode, Jing-Ying Shi, Xiu-Feng Xiao, Ze-Shan Zhu, Xi Zheng, Yan-Zhen Chen, Wen-Yun Hu

Journal of Electrochemistry

A novel Pt(Ir) plated stainless steel electrode have been developed, to be applied underpotential deposition and anchor effect. The electrode is provided with the excellent electrochemical characteristic, lt is possible to use the matter as micro-sensor.

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Studies On The Transport Properties Of Zn2+ In The Zn/V2O5 Secondary Battery With Aqueous Medium, Jia-Hong Zhou, Kuan-Hong Xue, Gu-Ping Pan May 1998

Studies On The Transport Properties Of Zn2+ In The Zn/V2O5 Secondary Battery With Aqueous Medium, Jia-Hong Zhou, Kuan-Hong Xue, Gu-Ping Pan

Journal of Electrochemistry

The transport properties and the reaction mechanism of Zn2+ in the cathode material of Zn/V2O5 secondary battery with aqueous medium were studied by use of intermittent titration experiments and X-Ray diffraction analysis. The relations of some kinetic parameters to the discharge depth were discussed. The results of the experiments show that the cathodic discharge reaction is an intercalation process.

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Electrode Process Of Lithium Ions On Aluminum Electrode In Molten Licl-Kcl, Shu-Zhen Duan, Cong-Sheng Guan, Qing-Rong Shi, Xin-Dong Wang May 1998

Electrode Process Of Lithium Ions On Aluminum Electrode In Molten Licl-Kcl, Shu-Zhen Duan, Cong-Sheng Guan, Qing-Rong Shi, Xin-Dong Wang

Journal of Electrochemistry

The Deposition mechanism of Lithium on aluminium electrode was studied by using linear sweep voltammetry and potential step method. The formation of α-solid solution was controlled by the diffusion of lithium within the aluminium substance. The formation of β-LiAl alloy was limited by the rate of forming the alloy at the legining, and by diffiusion of lithium through the β- LiAl alloy layer was limited by the rate of forming the alloy at the begining, and by the diffusion of lithium through the β-LiAl alloy later. Neucleation polarization for the formation of β-LiAl alloy was observed. This polarization is an …

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