Materials Chemistry Commons^™

Various Ways Of Preventing The Formation Of Scale In Sea Water Evaporators, James M. Stanek

Bachelors’ Theses

Previous work carried out at Marquette University has proved that the formation of scale in sea water evaporators can be prevented if such things as dehydrated alfalfa foliage or dehydrated corn, oats, peas, and grass foliage are added to the feed sea water. It has also been proved that the maturity of the plant from which the corn foliage has been stripped varies the scale preventing ability of the foliage, and that the storing of the corn foliage increases its scale preventing ability. The object of this work is to determine what effect the combination of various types of stainless …

The Analysis Of Brass And Bronze For Aluminum, Gordon Kenneth Gregory

Bachelors’ Theses

The problem of the analysis of brass and bronze for aluminum is one that has received the attention of analytical chemists for decades. The problem was originally proposed to me by Mr. H.E. Gregory of the American Brass Company. Since there appears to be no direct way of determining aluminum in brass and bronze, this thesis will concern itself with a comparison of four methods of determination with emphasis on their relative advantages and disadvantages. The gathering and arranging of the steps in the methods were done by the author, although the steps themselves have been described in chemical literature.

A Study Of The Equilibrium Distribution Of A Solute Between Two Immiscible Solvents, Francis A. Smith

Bachelors’ Theses

Because of the wide application of Distribution Law, for it should hold for the distribution of a dissolved substance between any two phases, for instance, liquid-liquid, gas-liquid, liquid-solid, and so forth, this subject was choosen for further investigation. The tendency for a solute to distribute itself between two immiscible solvents, so that the concentration ratio is a constant, is a direct consequence of the thermodynamic requirements for equilibrium. The reactions of various organic and inorganic acids distributed between water and several organic solvents will be studied.

Determination Of Saponification Rate By Change In Hydrogen Ion Concentration Measured With Quinhydrone And Glass Electrodes, Richard Porter

Bachelors’ Theses

The measurement or hydrogen ion concentration is becoming more important in all the fields of chemistry since the states or many chemical systems can to some extent be defined by their hydrogen ion concentration. If the hydrogen ion concentration or a particular solution can be measured accurately, in many cases other important relations and quantities may be determined. Methods or measurement are therefore important instruments or investigation.

When an ester is saponified by an alkali, the hydrogen ion concentration increases as the reaction proceeds. Thus, it the hydrogen ion concentration can be calculated at different intervals of time, some knowledge …

Preparation And Properties Of Diethylene Glycol Fumarate Resin, Marian Sargent

Bachelors’ Theses

Fumaric acid, an unsaturated acid , condensed with diethylene glycol forms diethylene glycol fumarate, a resinous product of high molecular weight. This reaction is typical of condensation reactions. Since this is only the first step in making suitable finished products, the author wished to make a study of the preparation and properties of this condensation product and determine which of the known polymerizing agents were best suited for practical use.

Concrete And Cement Surface Coatings, Gabriel J. Popovich

Bachelors’ Theses

It has been with difficulty that precise information of any kind regarding the surface coating of concrete and cement finishes had been found. In fact, there was limited information to be found after 1930. Having but a short time to conduct any research, it was impossible to delve too deeply into this branch of the thesis. It is sincerely hoped that in the very near future a more thorough, extensive and comprehensive study can be made on this subject. The purpose of this thesis is to determine the best composition of concrete and the best surface coating for it and …

An Experimental Study Of The Destruction Distillation Of Corn Cobs, Wendall Lee Perry

Bachelors’ Theses

The utilization of waste products is daily becoming more and more important. It has always been a big problem of industry to utilize its waste material; and as a result, limitless effort has been spent in the attempt to stress utility and economy in all forms of production. Under ordinary circumstances, the utilization of many waste products has been disregarded because of the large expense involved; but in critical times such as the present, expense becomes a secondary issue, and the actual production of necessary material becomes foremost. It is true that the waste connected with large industries is very …

A Study Of Resins From Carbohydrates, Edward F. Sullivan

Bachelors’ Theses

The availability of large amounts of carbohydrates, and the need in the past years of larger markets for the available supplies of sugar have lead a number of sugar companies to investigate the possibilities of synthetic resins from carbohydrates. Although in the last ten or twelve years, a number of steps have been taken in the investigation of sugar resins, the information available has been restricted to a few patents. Consequently, information on the chemistry of the problem has been neglected. Thus, this work, for the most part, covers partially the possibilities of producing alkyd resins from saccharides, as well …

A Comparison Between Saponification And Iodine Values And Melting Point Curves For Mixtures Of Various Natural Waxes And Halowax 1012, William Kenneth Watts

Bachelors’ Theses

This thesis 1s concerned with the nature of the action of the lowering of the melting point of the various natural waxes by the addition of Halowax. The problem was suggested by the work of Louis Kroening in his thesis, "The Effect of Halowax 1012, 1013, and 1014 on the Melting Points of the Various Waxes", and also by that of Joseph M. Sevenich in his thesis, "An Investigation of Halowaxes in Trinary Wax Mixtures". The former showed conclusively that the presence of Halowax in a wax mixture invariably lowered the melting point of the natural wax. The latter showed …

A Study Of The Proteolytic Activity Of The Enzyme Papain On Various Brands Of Gelatine, Mary Christella Zeszuto

Bachelors’ Theses

The measurement of the ·viscosity of liquids by means of capillary tubes has been carried on for more than a hundred years. It was not, however, until 1846 that the results of Poiseuille's research were given to the public. For the comprehensive study he made of the problem, the concept of the laws controlling viscometry flow is attributed to him. The study of the same problem. was continued by many others in subsequent years. Their results, in general, verify the principles given by Poiseuille, but corrections attributed to conditions other than viscous flow have been suggested. These involve drainage, liquid …

A Method For Comparing And Measuring The Drying Time Of Glues, William C. Strutz

Bachelors’ Theses

The measurements or quality in glue testing are arbitrary and are of value only when compared to a standard glue or when comparing one glue to another. Glues have been used for hundreds of years, but it has been only in the last forty or fifty years that any scientific investigations of any consequence have been made. Prior to this time glues were made by rule of thumb by practical men who learned the art of glue making from other practical men in the business and by contact with the industry. "When the United States entered the Great War and …

A Study Of The Gelation Of Several Paraffins In Various Solutions, Joseph John Wocasek

Bachelors’ Theses

In the selection of various waxes for commercial use, it has long been the custom to depend solely upon melting-point for property determination. Thus, for example, all paraffin waxes which had a melting range between 50 and 65 degrees centigrade, were thought to have much the same properties and that any or the commercial paraffins of this range would therefore impart the same characteristics to the product in which they were to be used. But with increased use, these waxes have come under more careful observation and experimentation. Very little data has as yet been released for publication but already …

The Effect Of Ultra-Violet Light On Ethyl Acetate, Homer W. Wiesner

Bachelors’ Theses

The present work, is a study of the effect of ultraviolet light on pure organic compounds. In particular, it is a qualitative and quantitative study of_ the decomposition products of ethyl acetate as effected by ultraviolet radiations, together with the development of experimental apparatus. In as much as the work required special apparatus, much of the time was spent in the development and construction of such apparatus.

A Study Of The Cooling Curve Of Several Waxes And Various Binary Mixtures Of These Waxes, Casimir A. Smyk

Bachelors’ Theses

A cooling curve may be defined as a graphic representation of the relationship which exists in the elapse of time and temperature of a substance surrounded by a medium of a temperature lower than itself. There is no heat added to the substance and the only heat taken away from the substance is by means of the surrounding medium. It is time plotted against temperature. Time on the x-axis and temperature on the y-axis. Many methods have been mentioned for the determination of purity and identification of a wax. But the methods are not standardized because of the length and …

Wax Analysis With Special Reference To Montan, Spermaceti, And Chinese Insect Wax, Margaret M. Plonsker, Margaret E. Seippel

Bachelors’ Theses

The presentation of this thesis under joint authorship finds its justification in the fact that much of the experimental work, though performed individually, is of such a nature as to warrant a unified description. In this way the reader is afforded a better representation and clearer conception of the problem, and a substantial guide for further investigation. Though much work has been done in the field of wax analysis, little is known of the higher fatty acids and alcohols of many of the waxes. Their isolation has been infrequent, and few if any of their derivatives have been formed. It …

The Electrodeposition Of Chromium And Iron Alloy, Duane J. Windau

Bachelors’ Theses

The plating of stainless steel, or more correctly, the plating of iron chromium alloys is among the recent projects undertaken by the steel industry to improve its products. Publications on this industrial endeavor are few, although undoubtedly there is considerable work going on. The reason for the sudden interest in stainless steel may be traced to the interesting and valuable properties of chromium steels and especially the stainless steels. However, articles made entirely of stainless steel are expensive and therefore cheaper substitutes have been considered, names the plating of a base metal with chrom-iron alloys. This project will be of …

Substitution Of Hydrofluoric Acid For Sulphuric Acid In Chromium Plating, Leonard Schulze

Bachelors’ Theses

Chromium plating or the electrodeposition of chromium from chromic acid baths has been an accomplished fact for almost a century. However, it has not been until the last few years that considerable attributive information has been published to make the mechanism of the process sufficiently understood to permit its commercial operation.¹ Most of the scientific information published on chromium plating thus far is general there being very little specific information revealed as yet. Material, as shall be referred to occasionally, may be read about its early successful applications stressing the unusual properties, advantages, interests, and activities but very little …

A Study Of The Plating Prohibitive Properties Of Various Separators, Bruno J. Pozorski

Bachelors’ Theses

The problem of this thesis is to study the plating prohibitive properties of the various materials commonly used in the manufacturing of separators, and to indicate which material would be most serviceable and feasible in a separator. At one time positives and negatives were kept not more than 0.25 inches apart, with the idea of reducing the intervening layers of electrolyte, and, therefore, the internal resistance of the cell, as much as possible. It was, however, found that the output could actually be increased by putting the plates at greater distances, the fact being that the larger bulk of solution …

Hardness And Porosity In Chromium Plating, Waldemar Wick

Bachelors’ Theses

In recent years chromium plating has been subjected to much research due to its ever-increasing demand. The results of these investigations have demonstrated the valuable properties of this plate. Of its many advantageous properties, hardness is one of the outstanding ones, but its application in industry is as yet not fully realized. This being due to the fact that it is difficult to produce a plate that is uniform and does not chip. Many chemists have investigated the porosity of the chromium plate in order to produce a coating that could be used for protective purposes, but there seems to …

A Study Of Gel Formation In Kerosene In Contact With Sodium, Jerome M. Weller

Bachelors’ Theses

The origin of the problem to be considered in this paper is traced to the observations of John R. Koob, Ph.D., Head of the Chemistry Department of Marquette University. It was his experience to note that the kerosene, in a bottle, containing cut sodium for the organic laboratory, had solidified to a gel, resembling Vaseline in appearance.

The Study Of The Effects Of Different Metallic Soaps On The Water Content Of Water-In-Gasoline Emulsions, Lynn D. Wilson

Bachelors’ Theses

The study of emulsions and emulsification is of very great theoretical and practical interest. From the standpoint of pure science it throws much light on the problems of surface tension, surface concentration, absorption, surface films, electrical double layers. Brownian movement, and the general theory of disperse systems and colloids. It is also of importance in biological science, e.g., the adsorption of fats and the permeability of membranes. When industrial and applied science are considered, it is remarkable how many subjects of interest and importance are dependent on a knowledge of the formation, behavior, and stability of emulsions. In this connection, …