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Articles 1 - 30 of 60
Full-Text Articles in Materials Chemistry
Percolation-Induced Thermo-Rheological Transitions In Biobased Graphene Nanoplatelet Nanofluids, Abiodun A. Saka, Tobechukwu K. Abor, Anthony C. Okafor, Monday U. Okoronkwo
Percolation-Induced Thermo-Rheological Transitions In Biobased Graphene Nanoplatelet Nanofluids, Abiodun A. Saka, Tobechukwu K. Abor, Anthony C. Okafor, Monday U. Okoronkwo
Mechanical and Aerospace Engineering Faculty Research & Creative Works
Biobased lubricants with thermally responsive rheology are increasingly needed for high-efficiency mechanical systems. Graphene nanoplatelet (GnP) nanofluids in vegetable oils are promising candidates, yet their percolation-driven thermo-rheological transitions remain insufficiently understood. In particular, the coupled concentration–temperature landscape controlling network-mediated flow transitions has not previously been established. Here, surfactant-free GnP nanofluids were prepared in high-oleic soybean oil (HOSO) at concentrations of 0.025–2.15% v/v (ϕ), and their rheological response was mapped between 25°C and 80 °C under steady-shear and oscillatory conditions. Below the percolation threshold (ɸ ≤ 0.1% v/v), the nanofluids exhibit near-Newtonian behavior, moderate reversible viscosity enhancement, and classical Arrhenius-type temperature …
Rheological Protocol To Assess And Optimize Latex Coagulation Dynamics For The Thin Glove Coagulant Dipping Process, Monday U. Okoronkwo, Kok Kong Ng, Wolfram Franke, Gaurav Sant
Rheological Protocol To Assess And Optimize Latex Coagulation Dynamics For The Thin Glove Coagulant Dipping Process, Monday U. Okoronkwo, Kok Kong Ng, Wolfram Franke, Gaurav Sant
Chemical and Biochemical Engineering Faculty Research & Creative Works
Many products that directly impact the quality of human life today — gloves, catheters, condoms, and baby bottle teats — are made through the latex-dipping technology. While a variety of methods have been developed – e.g., particle counting, turbidimetry, microscopy, and light scattering – which are suitable for studying the coagulation of latex at very low concentrations, much less work has focused on methods suitable for in-situ characterization of latex coagulation in concentrated solutions (e.g., as relevant to the dipping process). This paper presents a process-relevant rheological protocol for assessing and optimizing latex coagulation dynamics for the thin glove coagulant …
Investigation Of Portland Limestone Cement Blended With Biochar From Downdraft Gasification: Hydration Kinetics, Microstructure, Rheology, And Performance Mechanisms, Ugochukwu Ewuzie, Paul C. Ani, Abdulkareem O. Yusuf, Joseph D. Smith, Monday Uchenna Okoronkwo
Investigation Of Portland Limestone Cement Blended With Biochar From Downdraft Gasification: Hydration Kinetics, Microstructure, Rheology, And Performance Mechanisms, Ugochukwu Ewuzie, Paul C. Ani, Abdulkareem O. Yusuf, Joseph D. Smith, Monday Uchenna Okoronkwo
Chemical and Biochemical Engineering Faculty Research & Creative Works
The widespread adoption of Portland Limestone Cement (PLC) in U.S. concrete production has necessitated research into commercially available supplementary cementitious materials (SCMs) for formulating high-performance, low-carbon blended binders with PLC. This study investigated the influence of biochar (BC) in biochar-PLC composites (CBCs), focusing on hydration kinetics, microstructure, rheology, pore-solution chemistry, compressive strength, and the underlying mechanisms. Biochar was produced via downdraft gasification at 850 °C and incorporated into PLC at 5, 7, and 10% substitution by mass. Isothermal calorimetry and hydration data modeled using the Knudsen equation revealed that BC retarded early hydration but improved hydration degree and later-age heat …
Synthesis And Hydrothermal Evaluation Of Poly(Styrene Phosphonate) For Conformance Control In Geothermal Reservoirs, Sara Mccauley
Synthesis And Hydrothermal Evaluation Of Poly(Styrene Phosphonate) For Conformance Control In Geothermal Reservoirs, Sara Mccauley
Miners Solving for Tomorrow Research Conference
As atmospheric carbon dioxide levels continue to rise, geothermal energy has emerged as a promising energy alternative to fossil fuels. A barrier to widespread implementation and energy production efficiency is macro-heterogeneity of the rock matrix. Cracks, void spaces, and flow conduits divert fluid flow away from unswept portions of the geothermal reservoir and can cause cooling of the reservoir. Flow heterogeneity has been treated in oil reservoirs by injecting hydrogel particles that travel preferentially to ultra-high permeability zones and selectively block fluid flow in these regions. We are applying polymer hydrogels that withstand hydrothermal conditions of 225 up to 275°C …
Transition Metal Chalcogenide As Multifunctional Biosenser To Detect Neurochemicals, Amitav Sen
Transition Metal Chalcogenide As Multifunctional Biosenser To Detect Neurochemicals, Amitav Sen
Miners Solving for Tomorrow Research Conference
The development of highly sensitive real-time sensing platforms for selectively detecting dopamine (DA) and norepinephrine (NE) is of significant clinical importance since these are closely associated with several neurodegenerative disorders. Herein, we report copper telluride (Cu₂Te) nanostructure as a bifunctional electrocatalyst for the simultaneous detection of dopamine and norepinephrine. Cu₂Te exhibits excellent electrocatalytic activity toward both DA and NE oxidation, as demonstrated by detailed electrochemical measurements. High sensitivities of 24 and 40 µA cm⁻² µM⁻¹ for DA and NE, respectively, were obtained with a wide linear detection range of 10–200 nM and low limit of detection (LOD), 31 nM for …
Asphalt Pavement Rejuvenation Investigated By Nuclear Magnetic Resonance Relaxometry, Catherine Skaggs
Asphalt Pavement Rejuvenation Investigated By Nuclear Magnetic Resonance Relaxometry, Catherine Skaggs
Miners Solving for Tomorrow Research Conference
Asphalt is a relatively inexpensive material commonly used for road pavements; however, asphalt ages from exposure to oxygen and UV radiation, leading to loss of elasticity, which leads to cracks and potholes. To slow or reverse asphalt aging, pavement preservation treatments are in use. It’s unclear whether these treatments truly rejuvenate the pavement structure or merely offer a short-term benefit. Nuclear Magnetic Resonance (NMR) relaxometry is an analytical technique that uses the recovery of excited nuclear magnetization as a parameter to gain insights into molecular environments. Recovery-time distributions gathered from asphalt materials show differences between regular and rejuvenated asphalt samples, …
Intramolecular Nonbonding Interactions And Geared Phenyl Twisting In Para-Disubstituted 1,4-Diphenylazines: Electron Correlation Effects On Molecular Conformations And Enantiomerization, Kaidi Yang, Harmeet Bhoday, Rainer Glaser
Intramolecular Nonbonding Interactions And Geared Phenyl Twisting In Para-Disubstituted 1,4-Diphenylazines: Electron Correlation Effects On Molecular Conformations And Enantiomerization, Kaidi Yang, Harmeet Bhoday, Rainer Glaser
Chemistry Faculty Research & Creative Works
The results are reported of potential energy surface (PES) analyses of six symmetrical azines Yp − Ph − RC=N − N=CR − Ph − Yp, namely, the benzaldehyde azines 1H, 2H, and 8H with R = H and the acetophenone azines 1M, 2M, and 8M with R = Me. The Y substituents Cl (1), Br (2), and Me (8) were studied because sets of polymorphs I (C2-symmetry, azine twist τ ≈ 135 ± 10°, disrotatory phenyl twists ϕi ≠ 0°) and II (Ci-symmetry, τ = 180°, conrotatory ϕi ≠ 0°) were crystallized for these three azines. The …
Hybrid Data-Driven Cement-Stabilized Soil Design: An Integration Of Machine Learning, Multi-Objective Optimization, And Life Cycle Assessment, Chikezie Chimere Onyekwena, Yunli Li, Ikenna J. Okeke, Ubani Obinna Uzodimma, Monday Uchenna Okoronkwo, Wenping Wu
Hybrid Data-Driven Cement-Stabilized Soil Design: An Integration Of Machine Learning, Multi-Objective Optimization, And Life Cycle Assessment, Chikezie Chimere Onyekwena, Yunli Li, Ikenna J. Okeke, Ubani Obinna Uzodimma, Monday Uchenna Okoronkwo, Wenping Wu
Chemical and Biochemical Engineering Faculty Research & Creative Works
Soil stabilization is crucial in geotechnical engineering, yet conventional methods are often time-consuming, resource-intensive, and environmentally unsustainable. Despite growing interest in Machine Learning (ML) and optimization tools for mix design, few studies integrate these methods with decision-making techniques and environmental assessment to support practical implementation. This study proposes a hybrid data-driven framework for predicting strength, optimizing mix compositions, and evaluating environmental impacts via life cycle assessment of cement-stabilized soft soils. Six ML models were evaluated, and the top-performing eXtreme Gradient Boosting (XGB) model was further improved using the Grey Wolf Optimizer (GWO). The optimized XGB-GWO model, integrated with a polynomial …
Performance And Mechanistic Insights Into Cement Systems Modified With Wastewater-Recovered Struvite, Ugochukwu Ewuzie, Rupack R. Halder, Abdulkareem O. Yusuf, Abiodun A. Saka, Godwin I. Ogbuehi, Titus C. Egbosiuba, Damilola A. Daramola, Monday Uchenna Okoronkwo
Performance And Mechanistic Insights Into Cement Systems Modified With Wastewater-Recovered Struvite, Ugochukwu Ewuzie, Rupack R. Halder, Abdulkareem O. Yusuf, Abiodun A. Saka, Godwin I. Ogbuehi, Titus C. Egbosiuba, Damilola A. Daramola, Monday Uchenna Okoronkwo
Chemical and Biochemical Engineering Faculty Research & Creative Works
Struvite, the stable hydration product and primary strength phase in magnesium ammonium phosphate cement (MAPC), derived from wastewater treatment, has recently been utilized as a sustainable additive to Portland cement (PC). However, its impacts on cement hydration kinetics, pore refinement, rheology, and the mechanisms underlying these processes have not been comprehensively studied. This study developed Portland cement-struvite (PCS) systems by replacing PC with 3–20 % struvite (ST wt.%: PCS3–PCS20) and evaluated these processes using isothermal calorimetry, 3D micro-computed tomography (μXCT), time-dependent rheometry, X-ray diffraction (XRD), and Fourier-transform infrared spectroscopy (FTIR), and the Krstulović-Dabić (K-D) model. The FTIR/XRD confirmed the coexistence …
Synergistic V2ctₓ Mxene–Pani Hybrid With Expanded Interlayers For Ultrastable And High-Rate Pseudocapacitive Energy Storage, Amideddin Nouralishahi, Maryam Sharifi Paroushi, Mansour Razavi, Amarachi Clare Nnachor, Harish Singh, Manashi Nath
Synergistic V2ctₓ Mxene–Pani Hybrid With Expanded Interlayers For Ultrastable And High-Rate Pseudocapacitive Energy Storage, Amideddin Nouralishahi, Maryam Sharifi Paroushi, Mansour Razavi, Amarachi Clare Nnachor, Harish Singh, Manashi Nath
Chemistry Faculty Research & Creative Works
Recently, MXene-conducting polymer hybrids have emerged as promising electrode materials for sustainable energy storage applications, owing to their impressive electrochemical properties. Herein, we report the synthesis of vanadium carbide MXene nanoparticles (V2CTx-MXene) using innovative Spark Plasma Sintering (SPS) technology followed by exfoliation steps. The V2CTx nanoparticles were incorporated with PANI (MXene-PANI) by electrochemical polymerization of aniline monomers in the presence of V2CTx nanolayers, to be used as a highly efficient material for charge storage application. PANI nanofibers form a conductive and porous architecture, which intercalates the V2CTx nanoflakes. The resulting structure increases the interlayer spacing …
Effect Of Ionic Strength On Gelation Time And Strength Of Amps-Based Polymer Gels, Maryam Sharifi Paroushi, Xuyang Tian, Baojun Bai, Thomas P. Schuman, Yin Zhang, Mingzhen Wei
Effect Of Ionic Strength On Gelation Time And Strength Of Amps-Based Polymer Gels, Maryam Sharifi Paroushi, Xuyang Tian, Baojun Bai, Thomas P. Schuman, Yin Zhang, Mingzhen Wei
Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works
Polymer gel treatment has been widely applied for improving sweep efficiency and controlling excessive water and gas production. Their performance depends on gelation time and final gel strength. In most studies, brine salinity is used to describe the effect of formation water on gel behavior. However, changing salinity also changes ionic strength and ion composition at the same time. Because of this coupling, it is difficult to identify the mechanisms controlling gelation, which has led to inconsistent trends in the literature. Increasing salinity has been reported to either slow or accelerate gelation and to weaken or strengthen gels depending on …
Evaluation Of Chromium-Crosslinked Amps-Hpam Copolymer Gels: Effects Of Key Parameters On Gelation Time And Strength, Maryam Sharifi Paroushi, Baojun Bai, Thomas P. Schuman, Yin Zhang, Mingzhen Wei
Evaluation Of Chromium-Crosslinked Amps-Hpam Copolymer Gels: Effects Of Key Parameters On Gelation Time And Strength, Maryam Sharifi Paroushi, Baojun Bai, Thomas P. Schuman, Yin Zhang, Mingzhen Wei
Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works
Controlling CO2 channeling in heterogeneous reservoirs remains a major challenge for both enhanced oil recovery (EOR) and secure geological storage. AMPS-HPAM copolymers exhibit high-temperature resistance and brine tolerance compared with conventional HPAM gels, making them well suited for the harsh environments associated with CO2 injection. Chromium-based crosslinkers (CrAc and CrCl3) were investigated because sulfonic acid groups in AMPS can coordinate with trivalent chromium ions, enabling dual ionic crosslinking and the formation of a robust gel network. While organic crosslinked AMPS-HPAM gels have been widely studied, the behavior of chromium-crosslinked AMPS-containing systems, particularly their gelation kinetics under …
Evaluation Of A Novel Re-Crosslinkable Preformed Particle Gel For Conformance Control In Ultra-High Temperature Reservoirs, Yanbo Liu, Tao Song, Caleb Kwasi Darko, Thomas P. Schuman, Mingzhen Wei, Baojun Bai
Evaluation Of A Novel Re-Crosslinkable Preformed Particle Gel For Conformance Control In Ultra-High Temperature Reservoirs, Yanbo Liu, Tao Song, Caleb Kwasi Darko, Thomas P. Schuman, Mingzhen Wei, Baojun Bai
Chemistry Faculty Research & Creative Works
Preferential fluid flow remains a major challenge in subsurface energy production and gas storage operations, resulting in excessive water production in mature oil fields, reduced heat extraction in geothermal reservoirs, and low sweep and storage efficiency in CO2-EOR projects. Polymer gels are widely used to mitigate high-permeability channels; however, conventional systems exhibit limited plugging efficiency and short lifetimes in ultra-high-temperature reservoirs due to poor thermal stability. This study presents a novel ultra-high-temperature-resistant preformed particle gel (UHT-PPG) developed for conformance control in reservoirs with temperatures of 150–275 °C and severe super-K or channeling problems. The material was evaluated in …
Synergistic Doping And Coating Strategy For Boosting Na0.7mno2 Cathode Performance In Sodium-Ion Batteries, Ahmad Helaley, Han Yu, Manashi Nath, Xinhua Liang
Synergistic Doping And Coating Strategy For Boosting Na0.7mno2 Cathode Performance In Sodium-Ion Batteries, Ahmad Helaley, Han Yu, Manashi Nath, Xinhua Liang
Chemistry Faculty Research & Creative Works
Advancing sodium-ion battery (SIB) technology requires novel approaches to optimize cathode materials for improved electrochemical performance. In this study, we employ atomic layer deposition (ALD) to precisely modify the surface of P2-type Na0.7MnO2 cathodes with different coating materials including ZnO, NiO, and Al2O3, followed by post-annealing at 750°C for 10 hours. The strategic combination of ALD and thermal treatment can achieve thin film coating on particle surface and promote element doping into the near-surface lattice, as confirmed by electron energy loss spectroscopy (EELS) analysis. The incorporation of Zn, Al, and Ni results in …
Elucidating The Effects Of Water Activity On The Hydration Kinetics And Thermodynamics Of Ye’Elimite–Calcium Sulfate Hydrate Systems, Godwin I. Ogbuehi, Rupack R. Halder, Aditya Kumar, Gaurav Sant, Monday U. Okoronkwo
Elucidating The Effects Of Water Activity On The Hydration Kinetics And Thermodynamics Of Ye’Elimite–Calcium Sulfate Hydrate Systems, Godwin I. Ogbuehi, Rupack R. Halder, Aditya Kumar, Gaurav Sant, Monday U. Okoronkwo
Materials Science and Engineering Faculty Research & Creative Works
Relative humidity and water activity (aH) reductions have been known to suppress the hydration of anhydrous cement clinker phases. However, the relationship between ye'elimite (C4A3$) hydration kinetics and water activity remain unclear. This study employs experimental and thermodynamic modeling approaches to investigate the influence of water activity on ye'elimite hydration in the "C4A3$ + water", and "C4A3$ + gypsum + water" systems. Experimental findings indicate that as water activity decreases, C4A3$ hydration diminishes until the reaction is brought to a halt at a threshold aH. The critical aHand corresponding solubility constant of C4A3$ (KC4A3S¯) estimated from thermodynamic analysis are 0.46 …
Revisiting The Spin–Lattice Relaxation Of Homonuclear In-Phase And Antiphase Nmr Magnetization, Lauren M. Kehoe, Zachary G. Mayes, Kelsey E. Brakensiek, Emma L. Ellis, Adam J. Alderfer, Lingyu Chi, Klaus Woelk
Revisiting The Spin–Lattice Relaxation Of Homonuclear In-Phase And Antiphase Nmr Magnetization, Lauren M. Kehoe, Zachary G. Mayes, Kelsey E. Brakensiek, Emma L. Ellis, Adam J. Alderfer, Lingyu Chi, Klaus Woelk
Chemistry Faculty Research & Creative Works
Hyperpolarization techniques such as dynamic nuclear polarization (DNP), chemically induced dynamic nuclear polarization (CIDNP), and parahydrogen-induced polarization (PHIP) enhance the sensitivity of NMR spectroscopy and MRI, but the associated antiphase magnetization patterns often relax faster than those of conventional in-phase signals. This study analyzes the spin–lattice relaxation matrix for single-quantum transitions in an isolated, weakly coupled two-spin AX system to identify eigenvectors and eigenvalues that govern the time evolution of in-phase and antiphase longitudinal magnetization. The analysis predicts that AX antiphase magnetization, such as that generated by PHIP hydrogenations in high magnetic field, can relax up to twice as fast …
Laboratory Investigation Of High-Temperature Preformed Particle Gels For Fluid Control In Granite Cores For Geothermal Applications, K. Caleb Darko, Yanbo Liu, Thomas P. Schuman, Mingzhen Wei, Baojun Bai
Laboratory Investigation Of High-Temperature Preformed Particle Gels For Fluid Control In Granite Cores For Geothermal Applications, K. Caleb Darko, Yanbo Liu, Thomas P. Schuman, Mingzhen Wei, Baojun Bai
Chemistry Faculty Research & Creative Works
To understand the applicability of high-temperature preformed particle gel (HT-PPG) for control of short-circuiting in enhanced geothermal systems (EGSs), core flooding experiments were conducted on fractured granite cores under varying fracture widths, gel particle sizes and swelling ratios. Key parameters such as injection pressure, water breakthrough pressure, and residual resistance factor were measured to evaluate HT-PPG performance. The gel exhibited strong injectability, entering granite fractures at pressure gradients as low as 0.656 MPa/m; HT-PPG yields a superior sealing performance by significantly reducing the permeability; and dehydration occurs during HT-PPG propagation, with a dehydration ratio ranging from 4.71% to 11.36%. This …
Synergetic Adsorptive Mechanisms, Reusability And Cost Evaluations Of Green Fabricated Hybrid Barium Cobalt Nanocomposites For Methylene Blue And Lead Removal From Wastewater, Titus Chinedu Egbosiuba, Chibuike Christogonus Njoku, Ijeoma Jacinta Ani, Godwin Ifeanyi Ogbuehi, Abdulkareem Omeiza Yusuf, Abiodun Azeez Saka, Ugochukwu Ewuzie, Ebuka Emmanuel Ezennajiego, Blessing Onyinye Okafor, Walter Chibuike Anene, Cecilia Chika Unegbu, Florence Acha, Monday Uchenna Okoronkwo
Synergetic Adsorptive Mechanisms, Reusability And Cost Evaluations Of Green Fabricated Hybrid Barium Cobalt Nanocomposites For Methylene Blue And Lead Removal From Wastewater, Titus Chinedu Egbosiuba, Chibuike Christogonus Njoku, Ijeoma Jacinta Ani, Godwin Ifeanyi Ogbuehi, Abdulkareem Omeiza Yusuf, Abiodun Azeez Saka, Ugochukwu Ewuzie, Ebuka Emmanuel Ezennajiego, Blessing Onyinye Okafor, Walter Chibuike Anene, Cecilia Chika Unegbu, Florence Acha, Monday Uchenna Okoronkwo
Chemical and Biochemical Engineering Faculty Research & Creative Works
Barium nanoparticles (BaNPs), cobalt nanoparticles (CoNPs), and hybrid barium-cobalt nanocomposites (BaCoNCs) were synthesized using an eco-friendly green technique with Anacardium occidentale leaf extract for sequestration of methylene blue (MB) dye and lead (Pb (II)) ions from industrial wastewater. The nanoparticles and nanocomposites were characterized using Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), high-resolution scanning electron microscopy (HRSEM), and Brunauer-Emmett-Teller (BET) analysis to assess their functional groups, crystalline structure, morphology, and surface properties, confirming successful synthesis. Batch adsorption studies showed that optimal pollutant removal occurred at pH values of 8 for MB and 5 for Pb(II), with a contact time …
Investigating The Thixotropy Of Fresh Struvite Cement-Based Composite: Insights On Mechanisms Of The Pastes’ Thixotropic Behavior, Ugochukwu Ewuzie, Abdulkareem O. Yusuf, Damilola Daramola, Monday Uchenna Okoronkwo
Investigating The Thixotropy Of Fresh Struvite Cement-Based Composite: Insights On Mechanisms Of The Pastes’ Thixotropic Behavior, Ugochukwu Ewuzie, Abdulkareem O. Yusuf, Damilola Daramola, Monday Uchenna Okoronkwo
Chemical and Biochemical Engineering Faculty Research & Creative Works
Struvite (ST) recovered during wastewater treatment has been sparsely applied in cement-based composites. This study systematically evaluated the thixotropic behavior of cement-struvite (CST) pastes, a mix of 5–20 % ST by mass of cement, and proposed the interaction mechanisms leading to the pastes' thixotropy. The hysteresis loop area was used to establish the pastes' thixotropy and investigate its relationship with increased ST content, temperature, and yield stress. In the thixotropic behavior model used, the equilibrium shear stress was employed to examine the CST pastes' irreversible change; the characteristic time of deflocculation was used to study the flocs destruction process; and …
Performance Evaluation Of Aminated Multi-Walled Carbon Nanotubes Incorporated With Green Synthesized Iron Nanoparticles For Toxic Dyes Sequestration From Textile Wastewater, Titus Chinedu Egbosiuba, Cynthia Chukwuemeka, Jonah Chukwudi Umeuzuegbu, Nwanneka Chibuzo Mmonwuba, Ugochukwu Ewuzie, Monday Uchenna Okoronkwo, Valentine Chikaodili Anadebe, Saheed Mustapha, Ambali Saka Abdulkareem, Jimoh Oladejo Tijani, Ashish Patel, Virendra Kumar Yadav
Performance Evaluation Of Aminated Multi-Walled Carbon Nanotubes Incorporated With Green Synthesized Iron Nanoparticles For Toxic Dyes Sequestration From Textile Wastewater, Titus Chinedu Egbosiuba, Cynthia Chukwuemeka, Jonah Chukwudi Umeuzuegbu, Nwanneka Chibuzo Mmonwuba, Ugochukwu Ewuzie, Monday Uchenna Okoronkwo, Valentine Chikaodili Anadebe, Saheed Mustapha, Ambali Saka Abdulkareem, Jimoh Oladejo Tijani, Ashish Patel, Virendra Kumar Yadav
Chemical and Biochemical Engineering Faculty Research & Creative Works
This study evaluates the performance of aminated multi-walled carbon nanotubes (AM-MWCNTs) integrated with zerovalent iron nanoparticles (ZVI) synthesized using cashew leaf (Anacardium occidentale) extract (AM-MWCNTs@ZVI) for the removal of Congo Red (CR) and Methylene Blue (MB) dyes from textile industrial wastewater. The nanocomposite was characterized using FTIR, XRD, BET, HRSEM, and HRTEM analyses, confirming its functional groups, crystalline structure, and enhanced surface area of 1050.4 m2/g. The ecological risk degree of the textile pollutants was assessed to determine the percentage concentrations of crystal violet, Congo red, methyl orange, methylene blue and rhodamine B. Batch adsorption experiments identified optimal …
Transition Metal Nanocomposites: Nonenzymatic Biosensor For Neurochemical Detection, Amitav Sen, Ace Cannon, Manashi Nath
Transition Metal Nanocomposites: Nonenzymatic Biosensor For Neurochemical Detection, Amitav Sen, Ace Cannon, Manashi Nath
Miners Solving for Tomorrow Research Conference
No abstract provided.
Additive Manufacturing Of Thermoplastic Composites, Matik Heskin, K. Chandrashekhara, Richard Billo, Ming-Chuan Leu, Thomas P. Schuman
Additive Manufacturing Of Thermoplastic Composites, Matik Heskin, K. Chandrashekhara, Richard Billo, Ming-Chuan Leu, Thomas P. Schuman
Miners Solving for Tomorrow Research Conference
No abstract provided.
Polymerization Methods For Vinyl Phosphonate Monomers: Challenges And Perspectives, Sara Mccauley
Polymerization Methods For Vinyl Phosphonate Monomers: Challenges And Perspectives, Sara Mccauley
Miners Solving for Tomorrow Research Conference
No abstract provided.
An Open-Framework Iron-Selenite As Cathode For Li- Ion Batteries, Sutapa Bhattacharya, Aleksandr V. Chernatynskiy, Amitava Choudhury
An Open-Framework Iron-Selenite As Cathode For Li- Ion Batteries, Sutapa Bhattacharya, Aleksandr V. Chernatynskiy, Amitava Choudhury
Miners Solving for Tomorrow Research Conference
No abstract provided.
Preliminary Assessment Of Non-Volatile Particulate Matter And Gaseous Emissions From A Premixed Pre-Vaporized Combustor Designed For Civil Supersonic Transport, Ugochukwu Ewuzie, Godwin Ifeanyi Ogbuehi, Steven Achterberg, Monday Uchenna Okoronkwo, Philip D. Whitefield
Preliminary Assessment Of Non-Volatile Particulate Matter And Gaseous Emissions From A Premixed Pre-Vaporized Combustor Designed For Civil Supersonic Transport, Ugochukwu Ewuzie, Godwin Ifeanyi Ogbuehi, Steven Achterberg, Monday Uchenna Okoronkwo, Philip D. Whitefield
Miners Solving for Tomorrow Research Conference
No abstract provided.
Mechanical And Thermal Characterization Of Additively Manufactured Carbon/Nylon 12 And Carbon/Peek Composites, Matik Heskin, Bradley Deuser, Thomas P. Schuman, K. Chandrashekhara, John Bayldon, Jeff Degrange, Steven Patterson, Neiko Levenhagen
Mechanical And Thermal Characterization Of Additively Manufactured Carbon/Nylon 12 And Carbon/Peek Composites, Matik Heskin, Bradley Deuser, Thomas P. Schuman, K. Chandrashekhara, John Bayldon, Jeff Degrange, Steven Patterson, Neiko Levenhagen
Chemistry Faculty Research & Creative Works
This study explores additive manufacturing of carbon fiber-reinforced thermoplastic composites using the Composite-Based Additive Manufacturing (CBAM) process. Carbon/Nylon 12 and Carbon/PEEK composites were fabricated and evaluated through mechanical (compression, tensile, flexural, and impact) and thermal (DSC and TGA) tests. Carbon/PEEK exhibited superior mechanical performance, with 97.5% higher tensile strength, 79.8% higher elastic modulus, and 59.6% higher flexural strength compared to Carbon/Nylon 12. Thermal testing showed that Carbon/PEEK had higher thermal stability, beginning degradation at 350 °C versus 298 °C for Carbon/Nylon. These results indicate that CBAM-fabricated Carbon/PEEK composites are suitable for applications requiring high strength and temperature resistance.
Thermo-Rheological And Tribological Properties Of Low- And High-Oleic Vegetable Oils As Sustainable Bio-Based Lubricants, Abiodun Saka, Tobechukwu K. Abor, Anthony C. Okafor, Monday U. Okoronkwo
Thermo-Rheological And Tribological Properties Of Low- And High-Oleic Vegetable Oils As Sustainable Bio-Based Lubricants, Abiodun Saka, Tobechukwu K. Abor, Anthony C. Okafor, Monday U. Okoronkwo
Mechanical and Aerospace Engineering Faculty Research & Creative Works
Vegetable oil-based lubricants have attracted increased research attention in recent decades as sustainable alternatives to conventional petroleum-based lubricants in metal machining. However, more studies are required to fully elucidate the thermo-rheological and tribological properties. This study presents an investigation of the thermo-rheological and tribological properties of different vegetable oils, including low- and high-oleic soybean oil, high-oleic sunflower, safflower, and canola oils. The lubricity, and evolution of viscosity and thermodynamic properties as a function of temperature were investigated to obtain important parameters including the viscosity index, flow behavior index, flow activation energy, specific heat capacity, thermal conductivity, coefficient of friction, contact …
Thermal Conductivity Characterization Of High Oleic Vegetable Oils Based Hybrid Nanofluids Formulated Using Gnp, Tio2, Mos2, Al2o3 Nanoparticles For Mql Machining, Anthony Chukwujekwu Okafor, Tobechukwu Kingsley Abor, Saidanvar Esanjonovich Valiev, Ignatius Echezona Ekengwu, Abiodun Saka, Monday Uchenna Okoronkwo
Thermal Conductivity Characterization Of High Oleic Vegetable Oils Based Hybrid Nanofluids Formulated Using Gnp, Tio2, Mos2, Al2o3 Nanoparticles For Mql Machining, Anthony Chukwujekwu Okafor, Tobechukwu Kingsley Abor, Saidanvar Esanjonovich Valiev, Ignatius Echezona Ekengwu, Abiodun Saka, Monday Uchenna Okoronkwo
Chemical and Biochemical Engineering Faculty Research & Creative Works
This paper presents the results of thermal conductivity characterization of six high oleic soybean oil (HOSO) and four high oleic canola oil (HOCO)-Based hybrid nanofluids formulated with four types of nanoparticles (Graphene nanoplatelet (xGnP), TiO2, MoS2, and Al2O3) at nanoparticles wt.% concentration from 1 % to 7 % in 1 % increment using the two-step method for use in MQL machining of difficult-to-cut metals. Thermal conductivity of the formulated hybrid nanofluids were measured using Thermtest Transient Hot Wire Liquid Thermal Conductivity Meter at temperatures from 25 °C to 75 °C in increment …
Fitting Quality Of Nmr Relaxation Data To Differentiate Asphalt Binders, Rebecca M. Herndon, Kevin Lai, Magdy Abdelrahman, Klaus Woelk
Fitting Quality Of Nmr Relaxation Data To Differentiate Asphalt Binders, Rebecca M. Herndon, Kevin Lai, Magdy Abdelrahman, Klaus Woelk
Civil, Architectural and Environmental Engineering Faculty Research & Creative Works
Asphalt binder performance grades (PGs) are important metrics in designing pavements for effective transportation infrastructure. the PG system relies on the binder's stiffness and is determined through energy- and time-intensive physical testing. Physical properties, like stiffness, can also be determined by spin–lattice NMR relaxometry, a non-destructive chemical method. NMR relaxometry can quantify the molecular mobility of materials by determining relaxation times from exponential decays of excited nuclear magnetization. While relaxation times have been used to determine physical properties of materials, a quantitative relation to the PG grades of asphalt binder is yet to be established. in this study, T1 NMR …
Thermal Conductivity Characterization Of High Oleic Vegetable Oils Based Hybrid Nanofluids Formulated Using Gnp, Tio2, Mos2, Al2o3 Nanoparticles For Mql Machining, Anthony Chukwujekwu Okafor, Tobechukwu Kingsley Abor, Saidanvar Esanjonovich Valiev, Ignatius Echezona Ekengwu, Abiodun Saka, Monday Uchenna Okoronkwo
Thermal Conductivity Characterization Of High Oleic Vegetable Oils Based Hybrid Nanofluids Formulated Using Gnp, Tio2, Mos2, Al2o3 Nanoparticles For Mql Machining, Anthony Chukwujekwu Okafor, Tobechukwu Kingsley Abor, Saidanvar Esanjonovich Valiev, Ignatius Echezona Ekengwu, Abiodun Saka, Monday Uchenna Okoronkwo
Mechanical and Aerospace Engineering Faculty Research & Creative Works
This paper presents the results of thermal conductivity characterization of six high oleic soybean oil (HOSO) and four high oleic canola oil (HOCO)-based hybrid nanofluids formulated with four types of nanoparticles (Graphene nanoplatelet (xGnP), TiO2, MoS2, and Al2O3) at nanoparticles wt.% concentration from 1 % to 7 % in 1 % increment using the two-step method for use in MQL machining of difficult-to-cut metals. Thermal conductivity of the formulated hybrid nanofluids were measured using Thermtest Transient Hot Wire Liquid Thermal Conductivity Meter at temperatures from 25 °C to 75 °C in increment of 10 °C. Obtained results showed that thermal …