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- Oxygen evolution reaction (5)
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Articles 1 - 22 of 22
Full-Text Articles in Materials Chemistry
Intramolecular Nonbonding Interactions And Geared Phenyl Twisting In Para-Disubstituted 1,4-Diphenylazines: Electron Correlation Effects On Molecular Conformations And Enantiomerization, Kaidi Yang, Harmeet Bhoday, Rainer Glaser
Intramolecular Nonbonding Interactions And Geared Phenyl Twisting In Para-Disubstituted 1,4-Diphenylazines: Electron Correlation Effects On Molecular Conformations And Enantiomerization, Kaidi Yang, Harmeet Bhoday, Rainer Glaser
Chemistry Faculty Research & Creative Works
The results are reported of potential energy surface (PES) analyses of six symmetrical azines Yp − Ph − RC=N − N=CR − Ph − Yp, namely, the benzaldehyde azines 1H, 2H, and 8H with R = H and the acetophenone azines 1M, 2M, and 8M with R = Me. The Y substituents Cl (1), Br (2), and Me (8) were studied because sets of polymorphs I (C2-symmetry, azine twist τ ≈ 135 ± 10°, disrotatory phenyl twists ϕi ≠ 0°) and II (Ci-symmetry, τ = 180°, conrotatory ϕi ≠ 0°) were crystallized for these three azines. The …
Synergistic V2ctₓ Mxene–Pani Hybrid With Expanded Interlayers For Ultrastable And High-Rate Pseudocapacitive Energy Storage, Amideddin Nouralishahi, Maryam Sharifi Paroushi, Mansour Razavi, Amarachi Clare Nnachor, Harish Singh, Manashi Nath
Synergistic V2ctₓ Mxene–Pani Hybrid With Expanded Interlayers For Ultrastable And High-Rate Pseudocapacitive Energy Storage, Amideddin Nouralishahi, Maryam Sharifi Paroushi, Mansour Razavi, Amarachi Clare Nnachor, Harish Singh, Manashi Nath
Chemistry Faculty Research & Creative Works
Recently, MXene-conducting polymer hybrids have emerged as promising electrode materials for sustainable energy storage applications, owing to their impressive electrochemical properties. Herein, we report the synthesis of vanadium carbide MXene nanoparticles (V2CTx-MXene) using innovative Spark Plasma Sintering (SPS) technology followed by exfoliation steps. The V2CTx nanoparticles were incorporated with PANI (MXene-PANI) by electrochemical polymerization of aniline monomers in the presence of V2CTx nanolayers, to be used as a highly efficient material for charge storage application. PANI nanofibers form a conductive and porous architecture, which intercalates the V2CTx nanoflakes. The resulting structure increases the interlayer spacing …
Evaluation Of A Novel Re-Crosslinkable Preformed Particle Gel For Conformance Control In Ultra-High Temperature Reservoirs, Yanbo Liu, Tao Song, Caleb Kwasi Darko, Thomas P. Schuman, Mingzhen Wei, Baojun Bai
Evaluation Of A Novel Re-Crosslinkable Preformed Particle Gel For Conformance Control In Ultra-High Temperature Reservoirs, Yanbo Liu, Tao Song, Caleb Kwasi Darko, Thomas P. Schuman, Mingzhen Wei, Baojun Bai
Chemistry Faculty Research & Creative Works
Preferential fluid flow remains a major challenge in subsurface energy production and gas storage operations, resulting in excessive water production in mature oil fields, reduced heat extraction in geothermal reservoirs, and low sweep and storage efficiency in CO2-EOR projects. Polymer gels are widely used to mitigate high-permeability channels; however, conventional systems exhibit limited plugging efficiency and short lifetimes in ultra-high-temperature reservoirs due to poor thermal stability. This study presents a novel ultra-high-temperature-resistant preformed particle gel (UHT-PPG) developed for conformance control in reservoirs with temperatures of 150–275 °C and severe super-K or channeling problems. The material was evaluated in …
Synergistic Doping And Coating Strategy For Boosting Na0.7mno2 Cathode Performance In Sodium-Ion Batteries, Ahmad Helaley, Han Yu, Manashi Nath, Xinhua Liang
Synergistic Doping And Coating Strategy For Boosting Na0.7mno2 Cathode Performance In Sodium-Ion Batteries, Ahmad Helaley, Han Yu, Manashi Nath, Xinhua Liang
Chemistry Faculty Research & Creative Works
Advancing sodium-ion battery (SIB) technology requires novel approaches to optimize cathode materials for improved electrochemical performance. In this study, we employ atomic layer deposition (ALD) to precisely modify the surface of P2-type Na0.7MnO2 cathodes with different coating materials including ZnO, NiO, and Al2O3, followed by post-annealing at 750°C for 10 hours. The strategic combination of ALD and thermal treatment can achieve thin film coating on particle surface and promote element doping into the near-surface lattice, as confirmed by electron energy loss spectroscopy (EELS) analysis. The incorporation of Zn, Al, and Ni results in …
Revisiting The Spin–Lattice Relaxation Of Homonuclear In-Phase And Antiphase Nmr Magnetization, Lauren M. Kehoe, Zachary G. Mayes, Kelsey E. Brakensiek, Emma L. Ellis, Adam J. Alderfer, Lingyu Chi, Klaus Woelk
Revisiting The Spin–Lattice Relaxation Of Homonuclear In-Phase And Antiphase Nmr Magnetization, Lauren M. Kehoe, Zachary G. Mayes, Kelsey E. Brakensiek, Emma L. Ellis, Adam J. Alderfer, Lingyu Chi, Klaus Woelk
Chemistry Faculty Research & Creative Works
Hyperpolarization techniques such as dynamic nuclear polarization (DNP), chemically induced dynamic nuclear polarization (CIDNP), and parahydrogen-induced polarization (PHIP) enhance the sensitivity of NMR spectroscopy and MRI, but the associated antiphase magnetization patterns often relax faster than those of conventional in-phase signals. This study analyzes the spin–lattice relaxation matrix for single-quantum transitions in an isolated, weakly coupled two-spin AX system to identify eigenvectors and eigenvalues that govern the time evolution of in-phase and antiphase longitudinal magnetization. The analysis predicts that AX antiphase magnetization, such as that generated by PHIP hydrogenations in high magnetic field, can relax up to twice as fast …
Laboratory Investigation Of High-Temperature Preformed Particle Gels For Fluid Control In Granite Cores For Geothermal Applications, K. Caleb Darko, Yanbo Liu, Thomas P. Schuman, Mingzhen Wei, Baojun Bai
Laboratory Investigation Of High-Temperature Preformed Particle Gels For Fluid Control In Granite Cores For Geothermal Applications, K. Caleb Darko, Yanbo Liu, Thomas P. Schuman, Mingzhen Wei, Baojun Bai
Chemistry Faculty Research & Creative Works
To understand the applicability of high-temperature preformed particle gel (HT-PPG) for control of short-circuiting in enhanced geothermal systems (EGSs), core flooding experiments were conducted on fractured granite cores under varying fracture widths, gel particle sizes and swelling ratios. Key parameters such as injection pressure, water breakthrough pressure, and residual resistance factor were measured to evaluate HT-PPG performance. The gel exhibited strong injectability, entering granite fractures at pressure gradients as low as 0.656 MPa/m; HT-PPG yields a superior sealing performance by significantly reducing the permeability; and dehydration occurs during HT-PPG propagation, with a dehydration ratio ranging from 4.71% to 11.36%. This …
Mechanical And Thermal Characterization Of Additively Manufactured Carbon/Nylon 12 And Carbon/Peek Composites, Matik Heskin, Bradley Deuser, Thomas P. Schuman, K. Chandrashekhara, John Bayldon, Jeff Degrange, Steven Patterson, Neiko Levenhagen
Mechanical And Thermal Characterization Of Additively Manufactured Carbon/Nylon 12 And Carbon/Peek Composites, Matik Heskin, Bradley Deuser, Thomas P. Schuman, K. Chandrashekhara, John Bayldon, Jeff Degrange, Steven Patterson, Neiko Levenhagen
Chemistry Faculty Research & Creative Works
This study explores additive manufacturing of carbon fiber-reinforced thermoplastic composites using the Composite-Based Additive Manufacturing (CBAM) process. Carbon/Nylon 12 and Carbon/PEEK composites were fabricated and evaluated through mechanical (compression, tensile, flexural, and impact) and thermal (DSC and TGA) tests. Carbon/PEEK exhibited superior mechanical performance, with 97.5% higher tensile strength, 79.8% higher elastic modulus, and 59.6% higher flexural strength compared to Carbon/Nylon 12. Thermal testing showed that Carbon/PEEK had higher thermal stability, beginning degradation at 350 °C versus 298 °C for Carbon/Nylon. These results indicate that CBAM-fabricated Carbon/PEEK composites are suitable for applications requiring high strength and temperature resistance.
Cobalt Molybdenum Telluride As An Efficient Trifunctional Electrocatalyst For Seawater Splitting, Rajarshi Kar, Amideddin Nouralishahi, Harish Singh, Manashi Nath
Cobalt Molybdenum Telluride As An Efficient Trifunctional Electrocatalyst For Seawater Splitting, Rajarshi Kar, Amideddin Nouralishahi, Harish Singh, Manashi Nath
Chemistry Faculty Research & Creative Works
A mixed-metal ternary chalcogenide, cobalt molybdenum telluride (CMT), has been identified as an efficient tri-functional electrocatalyst for seawater splitting, leading to enhanced oxygen evolution reaction (OER), hydrogen evolution reaction (HER), and oxygen reduction reaction (ORR). The CMT was synthesized by a single step hydrothermal technique. Detailed electrochemical studies of the CMT-modified electrodes showed that CMT has a promising performance for OER in the simulated seawater solutions, exhibiting a small overpotential of 385 mV at 20 mA cm−2, and superior catalyst durability for prolonged period of continuous oxygen evolution. Interestingly, while gas chromatography analysis confirmed the evolution of oxygen …
Excellent Bifunctional Oxygen Evolution And Reduction Electrocatalysts (5a1/5)Co2o4 And Their Tunability, Xin Wang, Harish Singh, Manashi Nath, Kurt Lagemann, Katharine Page
Excellent Bifunctional Oxygen Evolution And Reduction Electrocatalysts (5a1/5)Co2o4 And Their Tunability, Xin Wang, Harish Singh, Manashi Nath, Kurt Lagemann, Katharine Page
Chemistry Faculty Research & Creative Works
Hastening the Progress of Rechargeable Metal-Air Batteries and Hydrogen Fuel Cells Necessitates the Advancement of Economically Feasible, Earth-Abundant, Inexpensive, and Efficient Electrocatalysts Facilitating Both the Oxygen Evolution Reaction (OER) and Oxygen Reduction Reaction (ORR). Herein, a Recently Reported Family of Nano (5A1/5) Co2O4 (A = Combinations of Transition Metals, Mg, Mn, Fe, Ni, Cu, and Zn) Compositionally Complex Oxides (CCOs) [Wang Et Al., Chemistry of Materials, 2023, 35 (17), 7283-7291.] Are Studied as Bifunctional OER and ORR Electrocatalysts. among the Different Low-Temperature Soft-Templating Samples, Those Subjected to 600 °C Post annealing Heat Treatment Exhibit Superior Performance in Alkaline Media. One …
Mesoporous Re0.5ce0.5o2-X Fluorite Electrocatalysts For The Oxygen Evolution Reaction, Sreya Paladugu, Ibrahim Munkaila Abdullahi, Harish Singh, Sam Spinuzzi, Manashi Nath, Katharine Page
Mesoporous Re0.5ce0.5o2-X Fluorite Electrocatalysts For The Oxygen Evolution Reaction, Sreya Paladugu, Ibrahim Munkaila Abdullahi, Harish Singh, Sam Spinuzzi, Manashi Nath, Katharine Page
Chemistry Faculty Research & Creative Works
Developing highly active and stable electrocatalysts for the oxygen evolution reaction (OER) is key to improving the efficiency and practical application of various sustainable energy technologies including water electrolysis, CO2 reduction, and metal air batteries. Here, we use evaporation-induced self-assembly (EISA) to synthesize highly porous fluorite nanocatalysts with a high surface area. In this study, we demonstrate that a 50% rare-earth cation substitution for Ce in the CeO2 fluorite lattice improves the OER activity and stability by introducing oxygen vacancies into the host lattice, which results in a decrease in the adsorption energy of the OH* intermediate in …
Quaternary Rare-Earth Oxyselenides Re4ga2se7o2 (Re = Pr, Nd) With Trigonal Bipyramidal Gase5 Units: Evaluation Of Optical, Thermoelectric, And Electrocatalytic Properties, Vidyanshu Mishra, Ibrahim Munkaila Abdullahi, Dundappa Mumbaraddi, Mohammed Jomaa, Louis Guérin, Manashi Nath, Arthur Mar
Quaternary Rare-Earth Oxyselenides Re4ga2se7o2 (Re = Pr, Nd) With Trigonal Bipyramidal Gase5 Units: Evaluation Of Optical, Thermoelectric, And Electrocatalytic Properties, Vidyanshu Mishra, Ibrahim Munkaila Abdullahi, Dundappa Mumbaraddi, Mohammed Jomaa, Louis Guérin, Manashi Nath, Arthur Mar
Chemistry Faculty Research & Creative Works
Phase-pure samples and single crystals of the rare-earth oxyselenides RE4Ga2Se7O2 (RE = Pr, Nd) were prepared by reactions at 950 °C. They adopt a new structure type (orthorhombic, space group Pnma, a = 11.721(2)-11.683(2) Å, b = 3.9882(7)-3.9667(7) Å, c = 29.644(5)-29.581(5) Å, Z = 4) consisting of RESe6 trigonal prisms, GaSe4 tetrahedra, and GaSe5 trigonal bipyramids linked to form corrugated layers between which strips of edge-sharing RE4O tetrahedra are inserted. The bonding character is mostly ionic within RE-O and RE-Se blocks but mostly covalent with Ga-Se blocks, …
Tailored (La0.2pr0.2nd0.2tb0.2dy0.2)2ce2o7 As A Highly Active And Stable Nanocatalyst For The Oxygen Evolution Reaction, Sreya Paladugu, Ibrahim Munkaila Abdullahi, Palani Raja Jothi, Bo Jiang, Manashi Nath, Katharine Page
Tailored (La0.2pr0.2nd0.2tb0.2dy0.2)2ce2o7 As A Highly Active And Stable Nanocatalyst For The Oxygen Evolution Reaction, Sreya Paladugu, Ibrahim Munkaila Abdullahi, Palani Raja Jothi, Bo Jiang, Manashi Nath, Katharine Page
Chemistry Faculty Research & Creative Works
Designing highly active and robust catalysts for the oxygen evolution reaction is key to improving the overall efficiency of the water splitting reaction. It has been previously demonstrated that evaporation induced self-assembly (EISA) can be used to synthesize highly porous and high surface area cerate-based fluorite nano catalysts, and that substitution of Ce with 50% rare earth (RE) cations significantly improves electrocatalyst activity. Herein, the defect structure of the best performing nano catalyst in the series are further explored, Nd2Ce2O7, with a combination of neutron diffraction and neutron pair distribution function analysis. It is …
Solar Enhanced Oxygen Evolution Reaction With Transition Metal Telluride, Harish Singh, Taishi Higuchi-Roos, Fabrice Roncoroni, David Prendergast, Manashi Nath
Solar Enhanced Oxygen Evolution Reaction With Transition Metal Telluride, Harish Singh, Taishi Higuchi-Roos, Fabrice Roncoroni, David Prendergast, Manashi Nath
Chemistry Faculty Research & Creative Works
The Photo-Enhanced Electrocatalytic Method of Oxygen Evolution Reaction (OER) Shows Promise for Enhancing the Effectiveness of Clear Energy Generation through Water Splitting by using Renewable and Sustainable Source of Energy. However, Despite Benefits of Photo electrocatalytic (PEC) Water Splitting, its Uses Are Constrained by its Low Efficiency as a Result of Charge Carrier Recombination, a Large overpotential, and Sluggish Reaction Kinetics. Here, We Illustrate that Nickel Telluride (NiTe) Synthesized by Hydrothermal Methods Can Function as an Extremely Effective Photo-Coupled Electrochemical Oxygen Evolution Reaction (POER) Catalyst. in This Study, NiTe Was Synthesized by Hydrothermal Method at 145°C within Just an Hour …
Modulation Of Electrocatalytic Activity By Tuning Anion Electronegativity: Case Study With Copper Chalcogenides, Harish Singh, David Prendergast, Manashi Nath
Modulation Of Electrocatalytic Activity By Tuning Anion Electronegativity: Case Study With Copper Chalcogenides, Harish Singh, David Prendergast, Manashi Nath
Chemistry Faculty Research & Creative Works
Anion-tuning in metallic chalcogenides has been shown to have a significant impact on their electrocatalytic ability for overall water splitting. In this article, copper-based chalcogenides (Cu2 X, X= O, S, Se, and Te) have been systematically studied to examine the effect of decreasing anion electronegativity and increasing covalency on the electrocatalytic performance. Among the copper chalcogenides, Cu2Te has the highest oxygen evolution reaction (OER) activity and can sustain high current density of 10 and 50 mA cm−2 for 12 h. The difference in intrinsic catalytic activity of these chalcogenide surfaces have been also probed through density functional theory calculations, which …
Molecular Cluster Complex Of High-Valence Chromium Selenide Carbonyl As Effective Electrocatalyst For Water Oxidation, Ibrahim Munkaila Abdullahi, Manashi Nath
Molecular Cluster Complex Of High-Valence Chromium Selenide Carbonyl As Effective Electrocatalyst For Water Oxidation, Ibrahim Munkaila Abdullahi, Manashi Nath
Chemistry Faculty Research & Creative Works
Developing Simple, Affordable, and Environmentally Friendly Water Oxidation Electrocatalysts with High Intrinsic Activity and Low overpotential Continues to Be an Area of Intense Research. in This Article, a Trichromium Diselenide Carbonyl Cluster Complex (Et4N)2[Se2Cr3(CO)10], with a Unique Bonding Structure Comprising Bridging Se Groups, Has Been Identified as a Promising Electrocatalyst for Oxygen Evolution Reaction (OER). This Carbonyl Cluster Exhibits a Promising overpotential of 310 MV and a Low Tafel Slope of 82.0 MV Dec−1 at 10 MAcm−2, with Superior Durability in an Alkaline Medium, for a Prolonged …
Nanostructured Ternary Nickel-Based Mixed Anionic (Telluro)-Selenide As A Superior Catalyst For Oxygen Evolution Reaction, Ibrahim Munkaila Abdullahi, Siby Thomas, Alessio Gagliardi, Mohsen Asle Zaeem, Manashi Nath
Nanostructured Ternary Nickel-Based Mixed Anionic (Telluro)-Selenide As A Superior Catalyst For Oxygen Evolution Reaction, Ibrahim Munkaila Abdullahi, Siby Thomas, Alessio Gagliardi, Mohsen Asle Zaeem, Manashi Nath
Chemistry Faculty Research & Creative Works
Developing Protocols for Designing High-Efficiency, Durable, Cost-Effective Electrocatalysts for Oxygen Evolution Reaction (OER) Necessitates Deeper Understanding of Structure–property Correlation as a Function of Composition. Herein, It Has Been Demonstrated that Incorporating Tellurium into Binary Nickel Chalcogenide (NiSe) and Creating a Mixed Anionic Phase Perturbs its Electronic Structure and Significantly Enhances the OER Activity. a Series of Nanostructured Nickel Chalcogenides Comprising a Layer-By-Layer Morphology Along with Mixed Anionic Ternary Phase Are Grown in Situ on Nickel Foam with Varying Morphological Textures using Simple Hydrothermal Synthesis Route. Comprehensive X-Ray Diffraction, X-Ray Photoelectron Spectroscopy, and in Situ Raman Spectroscopy Analysis Confirms the Formation …
Perfect Polar Alignment Of Parallel Beloamphiphile Monolayers: Synthesis, Characterization, And Crystal Architectures Of Unsymmetrical Phenoxy-Substituted Acetophenone Azines, Harmeet Bhoday, Michael Lewis, Steven P. Kelley, Rainer Glaser
Perfect Polar Alignment Of Parallel Beloamphiphile Monolayers: Synthesis, Characterization, And Crystal Architectures Of Unsymmetrical Phenoxy-Substituted Acetophenone Azines, Harmeet Bhoday, Michael Lewis, Steven P. Kelley, Rainer Glaser
Chemistry Faculty Research & Creative Works
It remains a great challenge to achieve polar order in organic molecular crystals because anti-parallel alignment of side-by-side molecules is intrinsically preferred. We have addressed this problem with a rational design that focuses on the polar stacking of parallel beloamphiphile monolayers (PBAMs) with strong lateral quadrupole-quadrupole attractions. We employ arene-arene interactions as lateral synthons. The first successes were achieved with unsymmetrical donor (X), acceptor (Y) substituted acetophenone azines which form polar PBAMs with double T-contacts between the azines. Near-perfect alignment was achieved with the methoxy series of (MeO, Y)-azines with Y=Cl, Br, I. Here, we report on the synthesis, the …
Super-Adsorbent Hydrogels For Removal Of Methylene Blue From Aqueous Solution: Dye Adsorption Isotherms, Kinetics, And Thermodynamic Properties, Buddhabhushan Salunkhe, Thomas P. Schuman
Super-Adsorbent Hydrogels For Removal Of Methylene Blue From Aqueous Solution: Dye Adsorption Isotherms, Kinetics, And Thermodynamic Properties, Buddhabhushan Salunkhe, Thomas P. Schuman
Chemistry Faculty Research & Creative Works
Removal of dyes through adsorption from wastewater has gained substantial interest in recent years, especially in development of hydrogel-based adsorbents, owing to their easy use and economical nature. The aim of the present study was to design a super-adsorbent hydrogel based on sodium styrene sulfonate (NaSS) monomer for removal of dyes like methylene blue (MB). NaSS displays both an aromatic ring and strongly ionic group in its monomer structure that can enhance adsorption capacity. Poly (sodium styrene sulfonate-co-dimethylacrylamide) hydrogels were prepared by solution free radical polymerization using gelatin meth acryloyl (GelMA) as crosslinker, creating a highly porous, three-dimensionally crosslinked polymer …
Nanostructured Copper Selenide As An Ultrasensitive And Selective Non-Enzymatic Glucose Sensor, Siddesh Umapathi, Harish Singh, Jahangir Masud, Manashi Nath
Nanostructured Copper Selenide As An Ultrasensitive And Selective Non-Enzymatic Glucose Sensor, Siddesh Umapathi, Harish Singh, Jahangir Masud, Manashi Nath
Chemistry Faculty Research & Creative Works
CuSe nanostructures exhibit high-efficiency for glucose detection with high sensitivity (19.419 mA mM-1 cm-2) and selectivity at a low applied potential of +0.15 V vs. Ag|AgCl, a low detection limit of 0.196 μM and a linear range of glucose detection from 100 nm. to 40 μM. This journal is
Feni2se4–Reduced Graphene Oxide Nanocomposite: Enhancing Bifunctional Electrocatalytic Activity For Oxygen Evolution And Reduction Through Synergistic Effects, Siddesh Umapathi, Jahangir Masud, Abdurazag T. Swesi, Manashi Nath
Feni2se4–Reduced Graphene Oxide Nanocomposite: Enhancing Bifunctional Electrocatalytic Activity For Oxygen Evolution And Reduction Through Synergistic Effects, Siddesh Umapathi, Jahangir Masud, Abdurazag T. Swesi, Manashi Nath
Chemistry Faculty Research & Creative Works
Water splitting reaction using earth-abundant and environmentally benign catalysts is critical for renewable energy generation and storage. Herein a hybrid composite, FeNi2Se4 nanoparticles supported on nitrogen doped reduced graphene oxide (FeNi2Se4–NrGO) is reported as an efficient and dependable bifunctional electrocatalyst for oxygen evolution and oxygen reduction reactions (OER and ORR, respectively) under alkaline conditions. While FeNi2Se4 nanoparticles themselves show good catalytic activity for water oxidation, the constructed hybrid nanocomposite with NrGO as the supporting matrix show enhanced catalytic activity with a small overpotential of 170 mV @ 10 mA cm …
Co7se8 Nanostructures As Catalysts For Oxygen Reduction Reaction With High Methanol Tolerance, Jahangir Masud, Manashi Nath
Co7se8 Nanostructures As Catalysts For Oxygen Reduction Reaction With High Methanol Tolerance, Jahangir Masud, Manashi Nath
Chemistry Faculty Research & Creative Works
Co7Se8 nanostructures electrodeposited on glassy carbon (GC) electrodes show high efficiency for oxygen reduction reaction (ORR) with high methanol tolerance as compared to Pt electrocatalysts. In the presence of methanol, the onset potential for the ORR at Pt/GC is shifted from 0.931 V (vs reversible hydrogen electrode (RHE)) to 0.801 V (vs RHE), whereas it remains the same (0.811 V vs RHE) at Co7Se8/GC in the presence and absence of methanol in 0.5 M H2SO4 solution. The Co7Se8/GC electrodes also showed high cyclability in the presence …
Manufacturing Of Transparent Composites Using Vacuum Infusion Process, V. G.K. Menta, R. R. Vuppalapati, K. Chandrashekhara, Thomas P. Schuman
Manufacturing Of Transparent Composites Using Vacuum Infusion Process, V. G.K. Menta, R. R. Vuppalapati, K. Chandrashekhara, Thomas P. Schuman
Chemistry Faculty Research & Creative Works
A novel optically transparent glass fiber reinforced polymer matrix composite has been developed by infusing a clear epoxy resin system of matching refractive index into a conventional E-glass fabric preform. Transparent composites are manufactured using a low cost, environmentally friendly vacuum infusion process. Physical and mechanical tests have been conducted. Transparent composites manufactured using the modified vacuum infusion process had a fiber volume fraction of 40%. Tensile strength and tensile modulus of these composites were 374.9 MPa and 31.74 GPa respectively. The results indicate that the transparent composites possess good physical and mechanical properties. These transparent composites form a good …