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An Investigation Into Energy-Material Properties Interaction In Additive Manufacturing Of Polymers., Pu Han 2021 University of Louisville

An Investigation Into Energy-Material Properties Interaction In Additive Manufacturing Of Polymers., Pu Han

Electronic Theses and Dissertations

Additive manufacturing (AM), known as three-dimensional (3D) printing, is a fabrication process to build 3D objects layer by layer based on computer aided design (CAD) model or digital 3D model. Fused filament fabrication (FFF) has become a preferred method for additive manufacturing due to its cost-effectiveness and flexibility. However, the parts built using FFF process suffer from lower mechanical strength compared to that fabricated using traditional method and rough surface finish. With this motivation, this dissertation aims to develop and implement a novel in-process laser assisted technique on FFF to heal the microstructure of FFF built objects by enhancing reptation …


Tunable Compressive Mechanical Behavior Of Ice-Templated Materials, Sashanka Akurati 2021 Old Dominion University

Tunable Compressive Mechanical Behavior Of Ice-Templated Materials, Sashanka Akurati

Mechanical & Aerospace Engineering Theses & Dissertations

The inherent hierarchical microstructural organization in natural materials is responsible for their excellent mechanical properties beyond that predicted by the simple rule-of-mixtures. Further exhibit synergy between strength and toughness, otherwise mutually exclusive in brittle materials. Conventional processing methods are unable to replicate hierarchical microstructures in engineering ceramics akin to that observed in natural materials. Ice-templating has emerged as a potential technique to fabricate bioinspired hierarchical materials. This process involves simultaneous unidirectional solidification and phase segregation of aqueous suspensions. Ice-templated porous ceramic materials have received significant attention for overcoming several limitations of conventional ceramic foams currently used in numerous engineering applications. …


Super-Adsorbent Hydrogels For Removal Of Methylene Blue From Aqueous Solution: Dye Adsorption Isotherms, Kinetics, And Thermodynamic Properties, Buddhabhushan Salunkhe, Thomas P. Schuman 2021 Missouri University of Science and Technology

Super-Adsorbent Hydrogels For Removal Of Methylene Blue From Aqueous Solution: Dye Adsorption Isotherms, Kinetics, And Thermodynamic Properties, Buddhabhushan Salunkhe, Thomas P. Schuman

Chemistry Faculty Research & Creative Works

Removal of dyes through adsorption from wastewater has gained substantial interest in recent years, especially in development of hydrogel-based adsorbents, owing to their easy use and economical nature. The aim of the present study was to design a super-adsorbent hydrogel based on sodium styrene sulfonate (NaSS) monomer for removal of dyes like methylene blue (MB). NaSS displays both an aromatic ring and strongly ionic group in its monomer structure that can enhance adsorption capacity. Poly (sodium styrene sulfonate-co-dimethylacrylamide) hydrogels were prepared by solution free radical polymerization using gelatin meth acryloyl (GelMA) as crosslinker, creating a highly porous, three-dimensionally crosslinked polymer …


Bioabsorbable Metal Zinc Differentially Affects Mitochondria In Vascular Endothelial And Smooth Muscle Cells, Olivia R. M. Bagshaw, Fereshteh Moradi, Christopher S. Moffatt, Hillary A. Hettwer, Ping Liang, Jeremy Goldman, Jaroslaw Drelich, Jeffrey A. Stuart 2021 Brock University

Bioabsorbable Metal Zinc Differentially Affects Mitochondria In Vascular Endothelial And Smooth Muscle Cells, Olivia R. M. Bagshaw, Fereshteh Moradi, Christopher S. Moffatt, Hillary A. Hettwer, Ping Liang, Jeremy Goldman, Jaroslaw Drelich, Jeffrey A. Stuart

Michigan Tech Publications, Part 1

Zinc is an essential trace element having various structural, catalytic and regulatory interactions with an estimated 3000 proteins. Zinc has drawn recent attention for its use, both as pure metal and alloyed, in arterial stents due to its biodegradability, biocompatibility, and low corrosion rates. Previous studies have demonstrated that zinc metal implants prevent the development of neointimal hyperplasia, which is a common cause of restenosis following coronary intervention. This suppression appears to be smooth muscle cell-specific, as reendothelization of the neointima is not inhibited. To better understand the basis of zinc's differential effects on rat aortic smooth muscle (RASMC) versus …


Synthesis Of Polyethylene Glycol-Based Hydrogels And Silver/Gold Nanostructures For Biomedical Applications, Isabelle Ishimwe Niyonshuti 2021 University of Arkansas, Fayetteville

Synthesis Of Polyethylene Glycol-Based Hydrogels And Silver/Gold Nanostructures For Biomedical Applications, Isabelle Ishimwe Niyonshuti

Graduate Theses and Dissertations

This work focuses on the synthesis of biocompatible polyethylene glycol (PEG)-based hydrogels, silver nanoparticles (AgNPs), and silver-gold nanocages (Ag-AuNCs) for biomedical applications. The dissertation includes two parts with Part I on the work of PEG-based hydrogel for wound healing applications and Part II on the work of Ag/Au nanostructures for antimicrobial applications. Part I studies PEG-based hydrogel for the delivery of fibroblast growth factors (FGFs) for wound healing applications, aiming to overcome the challenge of designing hydrogels capable of the sustained release of bioactive FGFs. This research develops new biocompatible anionic injectable hydrogel formulations based on Poly (Oligo Ethylene Glycol …


Hybrid Two Dimensional Quantum Devices, Joshua Patrick Thompson 2021 University of Arkansas, Fayetteville

Hybrid Two Dimensional Quantum Devices, Joshua Patrick Thompson

Graduate Theses and Dissertations

This thesis describes measurements on hybrid material systems involving two dimensional (2D) materials and phenomena along with the development of a small, hermetically sealed cell. The hermetic cell is designed to assist with analyzing sensitive 2D materials outside of an inert environment. When working with van der Waals materials that are especially sensitive to oxygen or water, it can be difficult to identify usable thin flakes without exposing them to air. To help preserve materials for analysis in air, a capsule was designed that isolates the material in an inert environment. Although the capsule is hermetically sealed, the encapsulated material …


Incorporation Of Zinc In Pre-Alloyed Cuin[Zn]S2/Zns Quantum Dots, Jean Carlos Morales Orocu 2021 University of Arkansas, Fayetteville

Incorporation Of Zinc In Pre-Alloyed Cuin[Zn]S2/Zns Quantum Dots, Jean Carlos Morales Orocu

Graduate Theses and Dissertations

Since the early 2000s heavy-metal-free quantum dots (QDs) such as CuInS2/ZnS have attempted to replace CdSe, their heavy-metal-containing counterparts. CuInS2/ZnS is synthesized in a two-step process that involves the fabrication of CuInS2 (CIS) nanocrystals (NCs) followed by the addition of zinc precursors. Instead of the usual core/shell architecture often exhibited by binary QDs, coating CIS QDs results in alloyed and/or partially alloyed cation-exchange (CATEX) QDs. The effect that zinc has on the properties of CIS NCs was studied by incorporating zinc during the first step of the synthesis. Different In:Cu:Zn ratios were employed in this study, maintaining a constant 4:1 …


Two-Dimensional Black Phosphorus For Terahertz Emission And Near-Field Radiative Heat Transfer, Mahmudul Hasan Doha 2021 University of Arkansas, Fayetteville

Two-Dimensional Black Phosphorus For Terahertz Emission And Near-Field Radiative Heat Transfer, Mahmudul Hasan Doha

Graduate Theses and Dissertations

The main focus of this work is to investigate two potential optical and optoelectronic applications of black phosphorus (BP): the near-field radiative heat transfer in plasmonic heterostructures with graphene and terahertz emission from multi-layer BP photoconductive antennas. When the separation distance between graphene-black phosphorene is much smaller than or comparable to the thermal wavelength at different temperatures, a near-field radiation heat transfer breaks the Planck blackbody limit. The magnitude of the near-field radiation enhancement acutely depends on the gate voltage, doping, and vacuum gap of the graphene and BP pair. The strong near-field radiation heat transfer enhancement of the specific …


Single-Walled Carbon Nanotubes Inhibit Trpc4-Mediated Muscarinic Cation Current In Mouse Ileal Myocytes, Lina T. Al Kury, Dimitrios Papandreou, Vasyl V. Hurmach, Dariia O. Dryn, Mariia I. Melnyk, Maxim O. Platonov, Yuriy I. Prylutskyy, Uwe Ritter, Peter Scharff, Alexander V. Zholos 2021 Zayed University

Single-Walled Carbon Nanotubes Inhibit Trpc4-Mediated Muscarinic Cation Current In Mouse Ileal Myocytes, Lina T. Al Kury, Dimitrios Papandreou, Vasyl V. Hurmach, Dariia O. Dryn, Mariia I. Melnyk, Maxim O. Platonov, Yuriy I. Prylutskyy, Uwe Ritter, Peter Scharff, Alexander V. Zholos

All Works

Single-walled carbon nanotubes (SWCNTs) are characterized by a combination of rather unique physical and chemical properties, which makes them interesting biocompatible nanostruc-tured materials for various applications, including in the biomedical field. SWCNTs are not inert carriers of drug molecules, as they may interact with various biological macromolecules, including ion channels. To investigate the mechanisms of the inhibitory effects of SWCNTs on the muscarinic receptor cation current (mICAT), induced by intracellular GTPγs (200 µM), in isolated mouse ileal myocytes, we have used the patch-clamp method in the whole-cell configuration. Here, we use molecular docking/molecular dynamics simulations and direct patch-clamp recordings of …


Pulsed Laser Annealing On The Optoelectronic Properties Of Zno Thin Films, Md Abu Zobair 2021 Missouri State University

Pulsed Laser Annealing On The Optoelectronic Properties Of Zno Thin Films, Md Abu Zobair

Graduate Theses/Dissertations

ZnO thin films have attracted great attention recently due to their unique electronic and optical properties. However, for proper implementation of ZnO in electronic devices it is necessary to understand the role of native point defects present inside the material as these wide bandgap semiconductors are inherently n-type due to oxygen vacancies. The objective is to control the electronic and optical properties of ZnO thin films through pulsed laser annealing (PLA). Thin films of ZnO have been grown on different substrates using pulsed laser deposition. Then PLA of the films are done by changing laser parameters (energy, frequency, pulse width, …


Polyvinyl Chloride Gels: Theoretical Modeling Of Their Actuation Mechanism And Characterization Of Their Properties, Zachary Frank 2021 University of Nevada, Las Vegas

Polyvinyl Chloride Gels: Theoretical Modeling Of Their Actuation Mechanism And Characterization Of Their Properties, Zachary Frank

UNLV Theses, Dissertations, Professional Papers, and Capstones

Polyvinyl chloride (PVC) gels are an electroactive polymer smart material which has been considered in a variety of actuator applications. Their large deformation, fast response rates, optical transparency, and soft nature has made them a key area of interest in fields ranging from soft robotics to optics. PVC gels are made from PVC mixed with large quantities of plasticizer, such as dibutyl adipate (DBA). When a voltage is applied, the gel experiences an “anodophilic” deformation (in which it moves preferentially towards the anode). This unique characteristic is the result of a charge buildup near the anode surface, which creates electromechanical …


Energy Efficient Configuration Or Perforated Solar Screens For Residential Desert Buildings, Rasha Arafa 2021 The American University in Cairo AUC

Energy Efficient Configuration Or Perforated Solar Screens For Residential Desert Buildings, Rasha Arafa

Archived Theses and Dissertations

In hot arid desert environments, the solar radiation passing through windows increases the cooling loads and energy consumption of buildings. Shading of windows can reduce these loads. External perforated wooden solar screens were traditionally used for windowsâ shading. However, there is a lack in understanding their performance in a quantitative manner and unavailability of scientific means that could be used for developing new efficient designs that suit the harsh desert conditions. This thesis investigates the impact of changing screen configurations such as perforation percentage, depth, perforation openings aspect ratio and reflectivity on the energy loads, hence defining the most efficient …


Design Of Shielded Metal Arc Welding Parameters For Optimum Tensile Strength Using Taguchi Method, Moh. Dedy Setiawan, Yanuar Rohmat A. P. Pradana, Suprayitno Suprayitno 2021 Mechanical Engineering Department, Universitas Negeri Malang, Indonesia

Design Of Shielded Metal Arc Welding Parameters For Optimum Tensile Strength Using Taguchi Method, Moh. Dedy Setiawan, Yanuar Rohmat A. P. Pradana, Suprayitno Suprayitno

Journal of Mechanical Engineering Science and Technology (JMEST)

Shielded Metal Arc Welding (SMAW), an arc welding process, is widely used in applications. In practice, SMAW is widely applied to the welding process on hollow square pipe. Performance expected from this welding is the tensile strength of weld joint. The tensile strength is influenced by parameters process which have possibility for an optimization process to become ‘robust’. Robust is a design which less sensitive to the effect of uncertain quantities or noise factors. Taguchi method is the most efficient optimization method which accommodates the noise factors effect and requires less experiment. This study is focusing on optimizing the welding …


Effect Of Variations In Pyrolysis Reactor With Glass Wool Equipped And Without Glass Wool On The Weight Of The Oil Produced, I Gusti Ngurah Nitya Santhiarsa 2021 Department of Mechanical Engineering, University of Udayana, Jimbaran, Bali, Indonesia

Effect Of Variations In Pyrolysis Reactor With Glass Wool Equipped And Without Glass Wool On The Weight Of The Oil Produced, I Gusti Ngurah Nitya Santhiarsa

Journal of Mechanical Engineering Science and Technology (JMEST)

Currently, plastic waste is a very serious threat because plastic waste pollution can harm all living things around and also harm the environment. The increasing volume of plastic waste is due to the lack of processing technology, so that the volume of plastic waste is increasing day by day. Plastic is a material that is difficult to decompose because it is non-biodegradable. One application of plastic waste processing technology offered in this study is to use the pyrolysis principle. Pyrolysis is a method of converting plastic into fuel oil through a thermal decomposition process without the use of oxygen. The …


Spray Characteristics At Preheating Temperatur Of Diesel-Biodiesel-Gasoline Fuel Blend, Moch. Miftahul Arifin, Nasrul Ilminnafik, Agus Triono 2021 Postgraduate Program, Mechanical Engineering Department, University of Jember, Jember, 68121, Indonesia

Spray Characteristics At Preheating Temperatur Of Diesel-Biodiesel-Gasoline Fuel Blend, Moch. Miftahul Arifin, Nasrul Ilminnafik, Agus Triono

Journal of Mechanical Engineering Science and Technology (JMEST)

Technological developments in diesel engines require improvements to the fuel injection system to meet the criteria for economical, high-power and efficient combustion and meet environmental regulatory standards. One method that has a lot of interest is changing the characteristics of the fuel, with the aim of producing optimal combustion. Spray characteristics have a big role in determining the quality of combustion in diesel engines. A good spray can improve the quality of fuel atomization and the homogeneity of the air-fuel mixture in the combustion chamber so that it can produce good engine performance and low emissions. This study aims to …


Characterization Of Bacterial Nanocellulose - Graphite Nanoplatelets Composite Films, Bili Darnanto Susilo, Heru Suryanto, Aminnudin Aminnudin 2021 Master Program of Mechanical Engineering, Universitas Negeri Malang, Indonesia

Characterization Of Bacterial Nanocellulose - Graphite Nanoplatelets Composite Films, Bili Darnanto Susilo, Heru Suryanto, Aminnudin Aminnudin

Journal of Mechanical Engineering Science and Technology (JMEST)

Bacterial cellulose (BC) was synthesized from pineapple peel extract media with addition of fermentation agent bacteria Acetobacter xylinum. BC was disintegrated from the pellicle into bacterial nanocellulose (BNC) by using a high-pressure homogenizer (hph) machine, which has a three-dimensional woven nanofibrous network. The synthesis of composite films started when BNC, graphite nanoplatelets, and cetyltrimethylammonium bromide (CTAB) were homogenized using an ultrasonic homogenizer then baked on a glass mold at a temperature of 80 degrees Celcius for 14h. A scanning electron microscope (SEM) was used to analyze its morphology. X-Ray diffraction spectra were used to analyze the composite films structure. The …


Implementation Of Internet Of Things (Iot) In A Plastic Blow Moulding Machine And Its Performance Measurement, Muhammad F. Faqih, Mahros Darsin, Aris Z. Muttaqin, Danang Yudistiro 2021 Department of Mechanical Engineering, Jember University, Indonesia

Implementation Of Internet Of Things (Iot) In A Plastic Blow Moulding Machine And Its Performance Measurement, Muhammad F. Faqih, Mahros Darsin, Aris Z. Muttaqin, Danang Yudistiro

Journal of Mechanical Engineering Science and Technology (JMEST)

Efficiency and effectiveness are indispensable things in the production process. Accurate use of existing resources and the shorter cycle time of production are of particular concern to optimize the production process. This research aims to implement automation to a conventional blow molding. An advanced attempt was carried out to use the Internet of Things (IoT) to increase its efficiency while maintaining the quality of the products. The use of the nodeMCU microcontroller and the blynk application allows the operator to operate the machine without having to come into or having direct contact with the machine. The performance of automation and …


Dechlorination Apparatus For Treating Chloride Salt Wastes: System Evaluation And Scale-Up, Brian J. Riley, Saehwa Chong, Charmayne E. Lonergan 2021 Missouri University of Science and Technology

Dechlorination Apparatus For Treating Chloride Salt Wastes: System Evaluation And Scale-Up, Brian J. Riley, Saehwa Chong, Charmayne E. Lonergan

Materials Science and Engineering Faculty Research & Creative Works

This paper describes an apparatus used to remove chlorine from chloride salt-based nuclear wastes from electrochemical reprocessing and/or chloride-based molten salt reactors (MSRs) through dechlorination by reacting the salts with ammonium dihydrogen phosphate (NH4H2PO4 or ADP) at temperatures up to 600 °C to produce NH4Cl as a byproduct. The benefits of removing the Cl from these salts include 37Cl recovery from Cl-based MSR salts, formation of UCl3 from the NH4Cl, as well as removal of Cl from the salts and conversion of the salt cations to oxides to allow …


Comparative Studies On Combustion Characteristics Of Blended Crude Jatropha Oil With Magnetic Liquid Catalyst And Dex Under Normal Gravity Condition, Hendry Y. Nanlohy 2021 Department of Mechanical Engineering, Jayapura University of Science and Technology, Indonesia

Comparative Studies On Combustion Characteristics Of Blended Crude Jatropha Oil With Magnetic Liquid Catalyst And Dex Under Normal Gravity Condition, Hendry Y. Nanlohy

Journal of Mechanical Engineering Science and Technology (JMEST)

A comparative study on the combustion characteristics of a single droplet fueled by DEX, crude jatropha oil (CJO), and a mixture of CJO with a magnetic liquid catalyst of rhodium trisulfate has been carried out under normal gravity conditions. The high viscosity of crude jatropha oil makes it difficult to burn under normal conditions (room temperature and atmospheric pressure), therefore the addition of a magnetic liquid catalyst rhodium trisulfate is needed to improve the properties of crude jatropha oil. As a catalyst, rhodium trisulfate has the potential to improve combustion performance while improving the physical properties of crude jatropha oil …


Wear Property Of Machined Ultra High Molecular Weight Polyethylene (Uhmwpe) Acetabular Liner Product With Cnc Milling, W D. Lestari, A T. Danaryanto, A Nugroho, R Ismail, J Jamari, A P. Bayuseno 2021 Department of Mechanical Engineering, Faculty of Engineering, University of Pembangunan Nasional “Veteran” Jawa Timur, Indonesia

Wear Property Of Machined Ultra High Molecular Weight Polyethylene (Uhmwpe) Acetabular Liner Product With Cnc Milling, W D. Lestari, A T. Danaryanto, A Nugroho, R Ismail, J Jamari, A P. Bayuseno

Journal of Mechanical Engineering Science and Technology (JMEST)

UHMWPE has been used as a cushion in artificial hip joint for the last decades. The reliability of the components of a hip joint implant can be achieved by understanding their wear behavior. This study observed the tribological performance of the UHMWPE acetabular liner manufactured with a CNC milling machine on the femoral head made of SS 316L. Materials commonly used for tribo pairs in hip joint replacement. The wear tests were performed on a hip joint simulator in dry condition. The wear test is carried out by applying a constant load of 800N. Before and after the wear test, …


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