Materials Science and Engineering Commons^™

Method Of Making Temperature-Immune Self-Referencing Fabry–Pérot Cavity Sensors, Hengky Chandrahalim, Jonathan W. Smith

AFIT Patents

A method of making passive microscopic Fabry-Pérot Interferometer (FPI) sensor includes forming a three-dimensional microscopic optical structure on a cleaved tip of an optical fiber that reflects a light signal back through the optical fiber. The reflected light is altered by refractive index changes in the three-dimensional structure that is subject to at least one of: (i) thermal radiation; and (ii) volatile organic compounds.

Research And Applications Of Artificial Neural Network In Pavement Engineering: A State-Of-The-Art Review, Xu Yang, Jinchao Guan, Ling Ding, Zhanping You, Vincent C.S. Lee, Mohd Rosli Mohd Hasan, Xiaoyun Cheng

Michigan Tech Publications, Part 1

Given the great advancements in soft computing and data science, artificial neural network (ANN) has been explored and applied to handle complicated problems in the field of pavement engineering. This study conducted a state-of-the-art review for surveying the recent progress of ANN application at different stages of pavement engineering, including pavement design, construction, inspection and monitoring, and maintenance. This study focused on the papers published over the last three decades, especially the studies conducted since 2013. Through literature retrieval, a total of 683 papers in this field were identified, among which 143 papers were selected for an in-depth review. The …

Synergistic Anticancer Response Of Curcumin And Piperine Loaded Lignin-G-P (Nipam-Co-Dmaema) Gold Nanogels Against Glioblastoma Multiforme, Xinyi Zhao, Bilal Javad, Daxing Cui, James Curtin, Furong Tian

Articles

Glioblastoma multiforme (GBM) is the most aggressive and commonly diag- 11 nosed brain cancer and presents a strong resistance to routine chemotherapeutic drugs. 12 The present study involves the synthesis of Lignin-g- p (NIPAM-co-DMAEMA) gold 13 nanogel, loaded with curcumin and piperine to treat GBM. The application has three 14 functions: (1) overcome the limitations of biodistribution, (2) enhance the toxicity of an- 15 ticancer drugs against GBM, (3) identify the uptake pathway. Atom transfer radical 16 polymerization was used to synthesize the Lignin-g-PNIPAM network, crosslinked with 17 the gold nanoparticles (GNPs) to self-assemble into nanogels. The size distribution and …

Customizable Aptamer Transducer Network Designed For Feed-Forward Coupling, Tim Hachigian, Drew Lysne, Elton Graugnard, Jeunghoon Lee

Materials Science and Engineering Faculty Publications and Presentations

Solution-based biosensors that utilize aptamers have been engineered in a variety of formats to detect a range of analytes for both medical and environmental applications. However, since aptamers have fixed base sequences, incorporation of aptamers into DNA strand displacement networks for feed-forward signal amplification and processing requires significant redesign of downstream DNA reaction networks. We designed a novel aptamer transduction network that releases customizable output domains, which can then be used to initiate downstream strand displacement reaction networks without any sequence redesign of the downstream reaction networks. In our aptamer transducer (AT), aptamer input domains are independent of output domains …

Chitosan Graphene Composite Fabrication And Characterization For Treatment Of Harmful Algal Blooms And Toxins, Sarah Zetterholm

Master's Theses

Chitosan graphene composites were fabricated and characterized as a management strategy for harmful algal blooms (HABs) caused by various species of cyanobacteria. These chitosan graphene materials were compared to previously studied chitosan graphene-oxide composites in both material properties and HAB treatment. In previous studies, adsorption of the cyanobacteria onto the surface of the composite materials has been observed. Investigations of the pure materials for these composites are also included in this study to determine whether removal is a result of charge interactions with the composite, or as an inherent property of the graphene or graphene oxide. Initial results suggest that …

Development Of The Composition Of A Composite Material Based On Thermoreactive Binder Ed-20, Umida Ziyamukhamedova, Gavhar Miradullayeva, Erkin Rakhmatov, Jasur Nafasov, Mavtuna Inogamova

CHEMISTRY AND CHEMICAL ENGINEERING

The aim of the study is to determine the effect of the type of structural modifier and filler on the structure formation and technological properties of potting composite polymeric materials (HCPM) and protective coatings for sheet and complex-configuration technological equipment, taking into account their rheological properties. Compositions of composite polymer materials based on a thermosetting binder of epoxy-diane resin ED-20 filled with a mineral filler - kaolin modified with gassipol resin (GS) - were developed using Newton's interpolation formula and the Lagrange method. The optimal amount of gossypol resin determined in the composition of the composite – in the amount …

Effect Of Talc On The Properties Of A Compound Based On Ethylene-Propylene Copolymer, Ikromjon Usmanov, Farrukh Kurbanbekov, Bobir Aykhodjaev, Ravshan Adilov

CHEMISTRY AND CHEMICAL ENGINEERING

The aim of the research is to study the possibility of replacing Korean-made talc with inexpensive talc from an Afghan deposit, processed in Uzbekistan and used for the production of polypropylene compounds. In the future, these compounds are used for the manufacture of plastic car parts. A block copolymer produced by Uz Kor Gaz Chemical was chosen as a binder. For this, the influence of the content and type of talc on the properties of a compound based on an ethylene-propylene copolymer was studied.

The properties of the obtained compounds checked using ISO standards. The fractional composition of the studied …

Physical And Chemical Studies Of Overroof Rocks Of Clay Shales Of The Dzherdanak Deposit, Mastura Aripova, Ivan Levitskiy, Khabiba Khamidova, Odelbek Ammanov

CHEMISTRY AND CHEMICAL ENGINEERING

The purpose of this study is study of the physical and chemical properties of the overburden of the Dzherdanak deposit. The chemical and mineralogical composition of the overburden of the Djerdanak deposit has been studied by the methods of X-ray and thermography, electron microscopy and infrared spectroscopy. The main phases are quartz, kaolinite and muscovite. The study of the fine structure of the rock under an electron microscope showed the homogeneity of the rock with pronounced uniform inclusions, which is preserved even after firing. Changes in the rock after firing at 1050 °C have been determined. The formation of mullite …

On The Possibility Of Obtaining Effective Phosphoric Fertilizers As A Result Of Interaction Of Phosphorite-Containing Waste With Activated Glauconite Sands, Nargisa Takhirova, Fazlidin Khudoyberdiev, Shahlo Daminova

CHEMISTRY AND CHEMICAL ENGINEERING

These studies are devoted to the study of the chemical properties obtained as a result of chemical activation of glauconite and further neutralization of activated glauconite by waste products of phosphorite concentrates. Based on the results of X-ray structural studies of the obtained products, it is possible to obtain granular complex fertilizers after adding phosphorites to the system. Activation with mineral acids (nitric or sulfuric) should be carried out to accelerate the transformation of minerals from glauconite sands into an easily digestible form. Since the obtained compounds form an acidic environment, it is necessary to neutralize them. The neutralization process …

Study Of Sorption Of Rhenium Ions On Solid Extragents, Otabek Pardaev, Dildora Ilkhomjonkizi Khakimboeva, Shahlo Daminova, Ulugbek Sharafutdinov, Sharipov Khasan Turabovich

CHEMISTRY AND CHEMICAL ENGINEERING

In this work, the aim is to study the possibility of extracting rhenium from sulfuric acid solutions by sorption of impregnated sorbents based on polystyrene-divinylbenzene (MN202) and an organic reagent MAB (2-amino-1-methylbenzimidazole).New sorbent based on MN202 (Purolite) impregnated with organic reagents have been obtained and investigated. The sorbent characteristics determined using SEM, XRD and FTIR methods. The optimal conditions for the sorption of rhenium (VII) ions for the "element-sorbent" systems have been established. Under static conditions, the sorption of rhenium on impregnated sorbents in a sulfuric acid solution was studied in the periodic system with respect to the contact time, …

Fabrication And Characterization Of Manganese Oxide Surfaces From Polymer-Based Fiber Precursors, Molly C. Brockway

Graduate Theses & Non-Theses

Supercapacitors are an energy storage technologycombining properties of both capacitors and batteries to deliver high power and energydensities. Supercapacitors store charge through electrostatic and faradaic interactions between the electrode and ionic electrolyte. By improving the physical structure of electrodes, the interfacial area where energy storage occurs can be increased and electrochemical performance improved. New, fibrous, manganese oxide web-based structures tested for use as a supercapacitor electrode were fabricated by electrospinning and direct calcinationof metal salt-containing polymer fibers, and the effects of fabrication parameters on electrochemical performance were investigated. Data show that high polymer concentrations and low oxide precursor concentrations during …

Stiffness Degradation In Fatigue Life Of Composites Using Dielectric State Variables, Muthu Ram Prabhu Elenchezhian, Partha Pratim Das, Minhazur Rahman, Vamsee Vadlamudi, Rassel Raihan, Kenneth Reifsnider

Institute of Predictive Performance Methodologies (IPPM-UTARI)-Archive

Composite materials are widely used in aerospace and automotive structures for decades and over the years the community has gained a better understanding of the damage and failure modes of composites under fatigue. In this article, a dielectric characterization methodology for in-situ monitoring of composites under fatigue environments is proposed. A novel method of measuring the dielectric state variables in Broadband Dielectric Spectroscopy (BbDS) using Extremely Conductive Silver Epoxy Adhesive (ECSEA) paste is presented. These dielectric state variables serve to identify the precursor of the beginning of the end of life of the composite material under fatigue loading. The reliability …

Perovskite Film Formation For Solar Cell Absorbers: Effects Of Substrate Modification, Mirra M. Rasmussen, Kyle M. Crowley, Ina T. Martin

Student Scholarship

As perovskite solar cell efficiencies have risen rapidly, practical constraints have made durability a critical concern. Whereas much attention has been paid to the development of the perovskite absorber layer, the charge transport layers can also be engineered to better the performance and stability of the device. This work uses the molecular modifier bromopropyltrimethoxysilane (BPTMS) to alter the interface between indium tin oxide (ITO, a common thin film solar cell transparent electrode) and methylammonium lead iodide (MAPbI3, a common perovskite absorber) to improve the morphology and stability of the perovskite absorber film. The substrate, molecular modifier, and perovskite film were …

Machine Learning For High-Fidelity Prediction Of Cement Hydration Kinetics In Blended Systems, Rachel Cook, Taihao Han, Alaina Childers, Cambria Ryckman, Kamal Khayat, Hongyan Ma, Jie Huang, Aditya Kumar

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

The production of ordinary Portland cement (OPC), the most broadly utilized man-made material, has been scrutinized due to its contributions to global anthropogenic CO₂ emissions. Thus -- to mitigate CO₂ emissions -- mineral additives have been promulgated as partial replacements for OPC. However, additives -- depending on their physiochemical characteristics -- can exert varying effects on OPC's hydration kinetics. Therefore -- in regards to more complex systems -- it is infeasible for semi-empirical kinetic models to reveal the underlying nonlinear composition-property (i.e., reactivity) relationships. In the past decade or so, machine learning (ML) has arisen as a promising, …

Poly(2-Hydroxyethyl Methacrylate) Hydrogels For Contact Lens Applications–A Review, Kushendarsyah Saptaji, Nurlaely Rohmatul Iza, Sinta Widianingrum, Vania Katherine Mulia, Iwan Setiawan

Makara Journal of Science

The emerging technology in biomedical engineering requires biocompatible materials, which are also referred to as biomaterials. For a material to be considered biocompatible, it should not interact with human tissues in a harmful way, and vice versa. Various properties of biocompatible materials, such as mechanical and optical properties, have to be considered for different biomedical applications. One of the most popular applications of biomaterials is for contact lenses. Hydrogels, specifically poly(2-hydroxyethyl methacrylate) (PHEMA) hydrogels, are among the most popular ones in ophthalmologic applications, especially in soft contact lenses. This paper reviews the use of PHEMA hydrogels as one of the …

Development Of Carbon And Silicon Carbide Based Microelectrode Implantable Neural Interfaces, Chenyin Feng

USF Tampa Graduate Theses and Dissertations

The use of neural modulation techniques to treat nervous system disorders, as well as neural recording to study brain function, continues to be of intense interest around the world. Due to the need to treat diseases such as Parkinson’s, dementia, depression and return normal function to patients suffering from nervous system damage and trauma, neural implants continue to be developed globally. One of these devices, the microelectrode implantable neural interface (mINI), has been rapidly developed, thanks to advanced semiconductor fabrication processes. However, the long-term reliability of present-day devices has still to be demonstrated and is delaying the application of this …

Improved Predictive Modeling Techniques For Non-Linear Solder Material Behavior, Arman Millian Ahari

Dissertations and Theses

Accurate prediction of fatigue life of solder joints in electronic packaging applications becomes of critical importance as semiconductor device technology and manufacturing constraints grow in complexity. To gain visibility on IC device performance and reliability, thermo-mechanical simulation is performed based on a unified, viscoplastic material model, which is dependent on nine parameters.

In this study, an improved method of Anand parameter extraction, which involves curve-fitting non-linear experimental stress data, is proposed to improve the accuracy of numerical predictions for solder reliability. Theoretical equations for uni-axial stress-strain response and creep response are derived, then details on their relevance to experimental and …

Biodegradable Nanocomposite Multifunctional Packaging Film For Fruits, Kalpani Y. Perera, Shubham Sharma, Dileswar Pradhan, Amit Jaiswal, Swarna Jaiswal

Articles

Biopolymers have been used in food packaging in recent years due to high pollution rates and decreased biodegradation of synthetic polymers. Chitosan (CH) and Sodium alginate (SA) are both biodegradable biopolymers with excellent film forming capability. TiO2 nanoparticles have high mechanical strength, degradation ability and antimicrobial properties, which are beneficial in food packaging. The aim of the current work is to develop the biodegradable multifunctional nanocomposite film for fruit (i.e., Pear) packaging applications. Bionanocomposite film was prepared by solvent casting method using CH-SA and various concentrations of TiO2. The multifunctional properties such as UV barrier, thermal, water retention, mechanical, chemical, …

Fabrication And Comparative Study Of Horizontal And Vertical Electrospun Protein-Polysaccharide Nanofiber Biomaterials, Ashley Rivera-Galleti

Theses and Dissertations

The use of biocompatible and biodegradable composite materials for biomedical applications has attracted the attention of many researchers in the past few years. In this study, we fabricated nanofibers of silk fibroin and cellulose and its derivatives to amalgamate their unique properties into a single material. The production of these nanofibers via electrospinning is of particular interest, and whereas several studies have been done on normal nanofibers, the formation of branched nanofibers is an exciting area not currently explored. Blend solutions are formed by dissolving silk and cellulose/cellulose acetate in formic acid separately and mixing to achieve the desired ratios. …

Mechanical Properties And Characterization Of Epoxy Composites Containing Highly Entangled As-Received And Acid Treated Carbon Nanotubes, Aaron Krieg, Julia A. King, Gregory M. Odegard, Timothy Leftwich, Leif K. Odegard, Paul D. Fraley, Ibrahim Miskioglu, Claire Jolowsky, Matthew Lundblad, Jin Gyu Park, Richard Liang

Michigan Tech Publications, Part 1

Huntsman–Merrimack MIRALON® carbon nanotubes (CNTs) are a novel, highly entan-gled, commercially available, and scalable format of nanotubes. As-received and acid-treated CNTs were added to aerospace grade epoxy (CYCOM® 977-3), and the composites were characterized. The epoxy resin is expected to infiltrate the network of the CNTs and could improve mechanical properties. Epoxy composites were tested for flexural and viscoelastic properties and the as-re-ceived and acid treated CNTs were characterized using Field-Emission Scanning and Transmission Electron Microscopy, X-Ray Photoelectron Spectroscopy, and Thermogravimetric Analysis. Composites containing 0.4 wt% as-received CNTs showed an increase in flexural strength, from 136.9 MPa for neat epoxy …