Ceramic Materials Commons^™

Studying The Effects Of Various Process Parameters On Early Age Hydration Of Single- And Multi-Phase Cementitious Systems, Rachel Cook

Doctoral Dissertations

”The hydration of multi-phase ordinary Portland cement (OPC) and its pure phase derivatives, such as tricalcium silicate (C₃S) and belite (ß-C₂S), are studied in the context varying process parameters -- for instance, variable water content, water activity, superplasticizer structure and dose, and mineral additive type and particle size. These parameters are studied by means of physical experiments and numerical/computational techniques, such as: thermodynamic estimations; numerical kinetic-based modelling; and artificial intelligence techniques like machine learning (ML) models. In the past decade, numerical kinetic modeling has greatly improved in terms of fitting experimental, isothermal calorimetry to kinetic-based modelling …

Oxygen Transport Kinetics Of Surface Modified Mixed Conductor (La0.60sr0.40)0.95co0.20fe0.80o3-X As Solid Oxide Fuel Cell Cathode, Manuel Serrano Laguna

Graduate Theses, Dissertations, and Problem Reports

The oxygen transport kinetics of the electrodes of Solid Oxide Fuel Cells (SOFC) are critical properties to achieve higher efficiencies in the cell. (La0.60Sr0.40)0.95Co0.20Fe0.80O3-x (LSCF) is a mixed ion-electron conductor material that is expected to be optimized and utilized as the cathode of the SOFC’s. The reason for LSCF to be considered as the next cathode material for SOFC is due to its high ionic and electronic conductivities, and high oxygen transport kinetics. Additionally, to the excellent properties that this material offers, it has been seen that the kinetic properties of the material can be further optimized by adding a …

Intrinsic Mechanical Properties Of Zirconium Carbide Ceramics, Nicole Mary Korklan

Masters Theses

“This research focuses on the processing and mechanical properties of zirconium carbide ceramics (ZrC_x). The first goal of this project was to densify near stoichiometric (i.e., x as close to 1 as possible) and nominally phase pure ZrC_x. The maximum stoichiometry achieved for the ZrC_x (C/Zr ratio of 0.92) was measured using gas fusion analysis. Hot pressing was used to obtain dense ZrC_x. Archimedes was used to determine the relative density of hot pressed ZrC_x at > 95%. Scanning electron microscopy (SEM) was used to determine the overall microstructure of the hot pressed …

Characterization And Computational Modelling For The Garnet Oxide Solid State Electrolyte Ta-Llzo, Colin A. Versnick

Electronic Thesis and Dissertation Repository

The all-solid-state-battery (ASSB) serves as a promising candidate for next generation lithium ion batteries for significant improvements in battery safety, capacity, and longevity. Of the material candidates researched to replace the conventionally used liquid electrolyte, the garnet oxide Ta-LLZO (Li_6.4La₃Zr_1.4Ta_0.6O₁₂) has received much attention thanks to its high chemical and electrochemical stability, and ionic conductivity which rivals that of liquid electrolytes. While much investigation has taken place regarding the electrochemical performance of Ta-LLZO, much less is known about the micromechanics, including microstructural characterization, stress and strain development, and material failure …

Effect Of Incorporating Pottery And Bottom Ash As Partial Replacement Of Cement, Bassam A. Tayeh, Doha M. Alsaffar, Lawend K. Askar, Asmahan Issa Jubeh

Karbala International Journal of Modern Science

This study addressed the environmental constraints in cement produc­tion. Ordinary Portland cement (OPC) was replaced with pottery powder (PP, produced by grinding locally available pottery) and bottom ash (BA) at 10%, 20% and 30% of cement mass. Moreover, 4% calcium chloride solution (CaCl₂.2H₂O) was used as mixing water. Material properties, such as standard consistency, setting time and compressive strength, were measured with different percentages of OPC replacement with PP and BA. Results indicated that the replacement with PP and BA increased the water demand to achieve the standard consistency. These results revealed that the strength evolution …

Study Of Amorphous Boron Carbide And Hydrogenated Boron Carbide Materials Using Molecular Dynamics And Hybrid Reverse Monte Carlo, Rajan Khadka

MSU Graduate Theses

We present a computational study of amorphous boron carbide (a-B_xC) models using Molecular Dynamics (MD) studied with Stillinger-Weber (SW) and ReaxFF potential. The atomic structure factor (S(Q)), radial distribution function (RDF) and bond lengths comparison with other experimental and ab initio models shows that a random arrangement of icosahedra (B₁₂, B₁₁C) interconnected by chains (CCC, CBC) are present in a-B_xC. Afterward, Hybrid Reverse Monte Carlo (HRMC) technique is used to recreate a-B_xC structures. The existing SW potential parameters of Boron are optimized for the α-rhombohedral (Icosahedral B_{12 …}

Development Of Novel Solid-State Electrolytes For Sodium Ion Batteries, Fei Sun

Electronic Thesis and Dissertation Repository

Sodium ion battery is considered as a potential candidate to replace lithium ion battery. To eliminate the need for containment of the liquid electrolyte, the solid-state electrolytes attract more attention. However, solid state electrolytes are still restricted to be applied for commercialization because of the inherent low ionic conductivity and the poor mechanical properties. Therefore, my Ph.D. research is focused on developing advanced solid-state electrolytes by improving ionic conductivity and disclosing mechanisms of the electrolytes.

Firstly, a series of La substituted NASICON electrolytes are prepared to achieve high ionic conductivity of mS/cm, and the effects of La substitution concentration are …

Vanadium-Based Nanomaterials For Improved Zn Ion Storage, Jianwei Lai

LSU Master's Theses

Rechargeable aqueous zinc-ion batteries (ZIBs) have been intensively studied as novel promising large-scale energy storage systems recently, owing to their advantages of high abundance, cost effectiveness, and high safety. However, the development of suitable cathode materials with superior performance are severely hampered by the sluggish kinetics of Zn²⁺ with divalent charge in the host structure.

Our Work demonstrates boosting the electrochemical performances of nanostructured cathode materials for aqueous ZIBs. The first project is focused on the interlayer-expanded V₆O₁₃∙nH₂O nanosheets as promising cathodes. Benefiting from the synthetic merits of its favorable architecture and expanded …

Synthesis Of Amorphous Hydrogenated Boron Carbide From Orthocarborane Using Argon Bombardment: A Reaxff Molecular Dynamics Study, Nirmal Baishnab

MSU Graduate Theses

In this study, the synthesis process of a-B­_xC:H_y using argon bombardment from the orthocarborane precursor was modeled by using reactive molecular dynamics (MD). Utilizing the MD simulations, the formation of free radicals as a result of ion bombardment was identified and quantified. Then, the densification process that is aided by the mixture of free radicals and orthocarborane was analyzed. The densification process by creating the initial structure composed of free radicals and orthocarborane with active sites created by partially removing some of the hydrogen atoms from the icosahedral cage was also modelled. Overall, a better understanding of …

Braze For Ceramic And Ceramic Matrix Composite Components, Sean E. Landwehr, Scott Nelson, Jeremy Lee Watts, Greg Hilmas, William Fahrenholtz, Derek Scott King

Materials Science and Engineering Faculty Research & Creative Works

In some examples, a technique may include positioning a first part comprising a ceramic or ceramic matrix composite and a second part comprising a ceramic or a CMC adjacent to each other to define a joint region at the interface of the first part and the second part. In some examples, the joint region may be heated using at least one of a laser or a plasma arc source to heat the joint region to an elevated temperature. The first and second parts may be pressed together and cooled to join the first and second parts at the joint region. …

Methods Of Use And Manufacture Of Silver-Doped, Nano-Porous Hydroxyapatite, Cheol-Woon Kim, Richard K. Brow

Nuclear Engineering and Radiation Science Faculty Research & Creative Works

A silver-doped, nano-porous hydroxyapatite material is provided that can be utilized to capture radioactive iodine, ¹²⁹I. Methods of using the silver-doped, nano-porous hydroxyapatite material to remove radioactive iodine, and methods of manufacturing the material are also provided.

Bioprinting With Human Stem Cell-Laden Alginate-Gelatin Bioink And Bioactive Glass For Tissue Engineering, Krishna C. R. Kolan, Julie A. Semon, Bradley Bromet, D. E. Day, Ming-Chuan Leu

Biological Sciences Faculty Research & Creative Works

Three-dimensional (3D) bioprinting technologies have shown great potential in the fabrication of 3D models for different human tissues. Stem cells are an attractive cell source in tissue engineering as they can be directed by material and environmental cues to differentiate into multiple cell types for tissue repair and regeneration. In this study, we investigate the viability of human adipose-derived mesenchymal stem cells (ASCs) in alginate-gelatin (Alg-Gel) hydrogel bioprinted with or without bioactive glass. Highly angiogenic borate bioactive glass (13-93B3) in 50 wt% is added to polycaprolactone (PCL) to fabricate scaffolds using a solvent-based extrusion 3D bioprinting technique. The fabricated scaffolds …

Spark Plasma Sintering Of 2d Nitride And Carbide Based Ceramics, Archana Loganathan

FIU Electronic Theses and Dissertations

Two-dimensional (2D) nanomaterials have stimulated significant interest among materials community due to a wide variety of application ranging from functional to structural properties. Boron nitride nanosheets (BNNS), boron-carbon-nitride (BCN), and MXene (M_n+1X_n, transition metal carbides, nitrides or carbonitrides) belongs to 2D materials family with van der Waals bonding between the layers. The research on synthesis and properties of BNNS, BCN and MXene have been predominantly explored for single- or multi-layered 2D nanosheets. In this study, the focus is to synthesize bulk layered BNNS and BCN using single or multilayered 2D nanomaterials by spark plasma sintering (SPS). …

Erosion Resistance Of Tungsten-Carbide Coatings For Steel Pipes In Fluid Catalytic Cracking Units, Davis Vannasing, Jennifer Hulfachor

Materials Engineering

In petroleum processing, the flow of catalyst readily leads to erosion of piping in a fluid catalytic cracking unit. Advances in coating materials and processes necessitate a re-evaluation of current protection methods. Commercially available tungsten-carbide (WC) claddings and nanostructured WC-W CVD coatings were investigated as potential alternative erosion-resistant coatings. Erosion tests by solid particle impingement were conducted on 2 variations of claddings and 1 variation of WC-W coatings following ASTM standard G76. A36 steel coupons were used as reference samples. For statistical validation, 2-3 replications of the tests were performed for the claddings and WC-W coating. Testing was conducted using …

Fracture Toughness Improvement Of ����� Ceramics By Grain Size Control And Ductile Phase Reinforcement, Kesong Wang

McKelvey School of Engineering Theses & Dissertations

This study used grain size control and ductile phase reinforcement to improve fracture toughness of ����� ceramics. Alpha alumina particles of 100 nm, 0.5-1 micrometers, and 10 micrometers were coated with 1-5 nm nickel by electroless nickel plating (ENP). The coated powders were consolidated at 1200℃-1500℃ by spark plasma sintering (SPS). The sintered samples were annealed at 1100 oC for 1.5 hours and 10 hours to determine the effect of post sintering annealing on hardness and fracture toughness. Density of the samples were measured by the standard Archimedes method using a 5 mL pycnometer. Hardness values were determined by Vickers …

Synthesis And Characterization Of Dielectric And Multiferroic Nanocrystalline Transition Metal Oxide Materials And Nanocomposites, Frederick A. Pearsall

Dissertations, Theses, and Capstone Projects

Nanocrystalline transition metal oxides with unique chemical, physical, magnetic and dielectric properties have very broad applications, ranging from photocatalysis, capacitor energy storage and 4-state memory. Frequency stable, high permittivity nanocomposite capacitors produced under mild processing conditions offer an attractive replacement to MLCCs derived from conventional ceramic firing. In one project reported herein, 0-3 nanocomposites were prepared using BaTiO₃ (barium titanate, BTO) nanocrystals, suspended in a poly(furfuryl alcohol) matrix, resulting in a stable, high effective permittivity, low and stable loss dielectric. Effective medium approximations were used to compare this with similar nanocomposite systems. The use of synthesized BTO nanocrystal photocatalysts …

Tixzr(1-X)N Thin Films For Advanced Plasmonic Materials, Susan R. Schickling, Codi Ferree, Amy Godfrey, Andre Hillsman, Hannah Robinson

Chancellor’s Honors Program Projects

No abstract provided.

Plasma Oxidation Of Liquid Precursors For Complex Metal Oxides., Babajide Patrick Ajayi

Electronic Theses and Dissertations

Clean energy production and storage are two of the most significant challenges in the 21^st century currently limited by the discovery and development of new and advanced materials. Complex oxides and alloys made using earth-abundant elements will play a crucial role in technology development moving forward, however, current preparation techniques are limited by their inability to produce complex oxides and alloys with precise composition control at fast timescales. A concept was proposed to produce mixed metal oxides with composition control through the oxidation of liquid precursors via plasma oxidation. It was hypothesized that the oxidation process can be completed …

Synthesis And Characterization Of A-Site And B-Site Disordered High-Entropy Perovskites, Quinton Wright

EURēCA: Exhibition of Undergraduate Research and Creative Achievement

Entropy-stabilized oxides are a new class of ceramic material inspired by high-entropy alloys. In entropy-stabilized oxides, many metallic elements in approximately equal amounts occupy one lattice site. The large number of atom types present in the crystal results in a high degree of disorder in the material. The purpose of this study was to determine if a single-phase samples of two entropy-stabilized oxides could be successfully created through solid-state synthesis. The first of these materials - (Gd0.2La0.2Nd0.2Sm0.2Y0.2)MnO3 - has has 5 A-site elements creating a high degree of disorder. The second of these materials - La(Co0.2Cr0.2Fe0.2Mn0.2Ni0.2)O3 - has 5 B-site …

Method And Apparatus For Fabricating Ceramic And Metal Components Via Additive Manufacturing With Uniform Layered Radiation Drying, Ming-Chuan Leu, Amir Ghazanfari, Wenbin Li, Greg Hilmas, Robert G. Landers

Mechanical and Aerospace Engineering Faculty Research & Creative Works

A freeform extrusion fabrication process for producing three - dimensional ceramic, metal and functionally gradient composite objects, including the steps of filling a plurality of paste sources with a respective plurality of aqueous paste compositions, operationally connecting respective syringes containing respective aqueous paste compositions to a mix ing chamber, moving a first aqueous paste composition from a first respective paste source into the mixing chamber, moving a second aqueous paste composition from a second respective paste source into the mixing chamber, mixing the first and second aqueous paste compositions to define a first admixture having a first admixture composition, extruding …