Ceramic Materials Commons^™

Improvement Of Lithium-Metal Electrode All-Solid-State Batteries Performance By Shot Peening And Magnetron Sputtering, Atsuro Okumura, Manabu Kodama

15th International Conference on Shot Peening

To enable fast charging in lithium-metal anode all-solid-state batteries, suppressing lithium dendrite formation at the solid electrolyte (SE) interface is critical. Increasing fracture toughness via shot peening (SP) and improving interfacial contact with Au sputtering can inhibit dendrite growth. However, conventional sputtering may reduce toughness due to localized thermal damage. This study investigated magnetron sputtering as a low-damage, plasma-based Au deposition method. SEs with and without SP were fabricated and coated via normal and magnetron sputtering. Critical current density (CCD) and fracture toughness were evaluated. Without SP, CCD improvement was limited regardless of sputtering method due to poor bonding. With …

Antibacterial Activity Of Zno/Geopolymer Composite Granules And Their Potential Application In Water Treatment, Ziyan Tirta Maulitia, Putri Nur Angelina, Pipit Erlita Sari, Sri Sugiarti, Irma Isnafia Arief, Zaenal Abidin

Makara Journal of Science

Water pollution has become a major global concern owing to its complexity and widespread impact. Staphylococcus aureus (S. aureus) and Escherichia coli (E. coli) are the most common bacterial contaminants in water sources, which pose significant threats to public health. To mitigate water contamination by these pathogenic microorganisms, developing and implementing effective water treatment technologies are essential. A promising approach involves using antibacterial water filtration systems. Herein, zinc oxide (ZnO) nanoparticles were synthesized via hydrothermal and precipitation methods as antibacterial agents for water treatment. These preparation methods required considerably low synthesis time. A capping agent was …

Enabling Carbon Dioxide Mineralization And Active Set Control In Portlandite-Based Cementitious Suspensions, Xiaodi Dai, Sharu Bhagavathi Kandy, Rui Xiao, Manas Sarkar, Shubham Wani, Thiyagarajan Ranganathan, Narayanan Neithalath, Aditya Kumar, Mathieu Bauchy, Edward Garboczi, Torben Gädt, Samanvaya Srivastava, Gaurav Sant

Materials Science and Engineering Faculty Research & Creative Works

The real-time control of concrete's stiffening allows users to better control pumping and extrusion during 3D-printing processes. Here, a portlandite-based cementitious formulation (i.e., slurry or suspension) that features the potential for rapid CO₂ uptake is adapted for 3D-printing applications. In particular, we showcase a portlandite-fly ash binder system combined with a thermo responsive polymer, wherein precise control via thermal activation allows set control and rapid solidification. Through the thermally induced polymerization of polyacrylamide, the hybrid binder system rapidly undergoes stiffening at trigger onset temperatures ranging from 60 °C to 80 °C, exhibiting average stiffening rates of up to 2600 …

In Situ High-Temperature Raman Spectroscopy For Online Eaf Slag Analysis, Bohong Zhang, Hanok Tekle, Ronald J. O'Malley, Jeffrey D. Smith, Farhan Mumtaz, Jie Huang

Electrical and Computer Engineering Faculty Research & Creative Works

Real-time monitoring of slag chemistry is critical for optimizing Electric Arc Furnace (EAF) steelmaking operations, where dynamic variations in slag composition directly influence slag foaming, refractory degradation, and thermal efficiency. Conventional techniques such as X-ray fluorescence (XRF), Fourier-transform infrared (FTIR), and scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy (SEM-EDS) are commonly used to analyze slag composition, but their offline nature and equipment constraints limit their applicability for online monitoring in harsh industrial environments. To address this challenge, we present an in situ, high-temperature analytical approach that integrates Raman spectroscopy with a custom-designed fiber-optic probe for real-time slag characterization at …

Tensile Creep Of A Hybrid Polymer-Matrix/Ceramic-Matrix Composite At Elevated Temperature, Waleed S. Alshehri

Theses and Dissertations

Advanced aerospace systems require structural materials that can perform reliably in high-temperature environments for long durations. The performance of standard polymer matrix composites (PMCs) in these conditions is often limited by their susceptibility to time-dependent deformation, such as creep. The objective of this research is to characterize the high-temperature creep behavior of a novel unitized material system comprising a polymer matrix composite (PMC) and a ceramic matrix composite (CMC) co-cured together. The PMC part consists of the polyimide matrix reinforced with laminated carbon fibers woven in an eight harness satin weave (8HSW). The CMC part consists of a zirconia-based ceramic …

Discovery Of High-Performance Cathode Materials For Protonic Ceramic Fuel Cells, Liang Han

All Dissertations

Environmental pollution and rapid energy consumption have become common problems in global development and will continue to grow with the world population. PCFCs use proton-conducting ceramics as electrolytes, with low activation energy and high ionic conductivity at intermediate temperatures, enabling them to operate at intermediate-temperature conditions, which can effectively solve the problems of poor stability and high cost of exotic materials of traditional solid oxide fuel cells. However, as the operating temperature decreases, the electrocatalytic activity of the cathode decreases significantly, seriously affecting PCFC’s performance. Therefore, developing high-performance cathode material suitable for working under intermediate-temperature conditions has become the key …

Investigation Of Solid-State Reactive Sintering And Rapid Laser Reactive Sintering For Al-Doped Li7la3zr2o12 Solid-State Electrolyte, Aaron Santomauro

All Dissertations

As a society, we’ve exhausted an extreme amount of fossil fuels and put an overwhelming strain on Earth’s natural resources. From this, it is critical to think about the successful future of our planet and ourselves by developing energy devices such as all-solid-state lithium-ion batteries (ASSLIBs). These devices offer a greener and more efficient alternative to power our daily lives, such as electric vehicles (EVs), portable electronics, medical devices, grid-scale energy storage, and aerospace/aviation. ASSLIBs are an excellent alternative to liquid-state batteries, which pose dangerous safety concerns (e.g., flammability, electrolyte leakage, etc.). These ASSLIBs are known to have generally high …

Ultra-Low Dosages Of Novel Graphene Types Enhance The Rheological Properties And Buildability Of 3d Printed Binders, Sahil Surehali, Akshay Venkatachalam, Ranjith Divigalpitiya, Aditya Kumar, Narayanan Neithalath

Materials Science and Engineering Faculty Research & Creative Works

The use of graphene as a high-performance concrete additive is attractive; but, its cost and concerns about production scalability and dispersion efficiency in concrete are impediments to widespread use. This study explores the impact of ultra-low dosages (≤0.02 % by mass of binder) of two novel graphene types—fractal graphene (FG) and reactive graphene (RG)—produced through a cost-effective, environmentally friendly, and scalable process, on the rheological properties of 3D-printable concrete. Both FG and RG significantly enhance the dynamic and static yield stresses and viscoelastic properties of the binder, with RG-modified mixtures exhibiting slightly more pronounced enhancements due to the presence of …

Mno2 Nanoscale Interface Modification, Alexander C. Skoppe

Doctoral Dissertations and Master's Theses

Interface modification of carbon fibers has been shown to improve the mechanical performance of composites. In addition, interface modification of carbon fiber composites can impart multifunctionality into the resulting composite. This work will explore ZnO and MnO2 as interface modifications for use on carbon fibers. When exposed to high temperatures, carbon fibers undergo fiber degradation, leading to the need for low-temperature hydrothermal processes. This work will develop and characterize a nanoscale ZnO and MnO2 interface modification for use on carbon fibers. These nanomodifications will be developed with low-temperature processes, minimizing the fiber degradation that the fibers undergo. Fourier transform infrared …

Thermomechanical And Thermal Characterization Of Pressureless Sintered Tib2, Simone Taraborelli, Simone Failla, Diletta Sciti, Steven M. Smith, Jeremy Watts, William G. Fahrenholtz, Greg E. Hilmas

Materials Science and Engineering Faculty Research & Creative Works

The impact of high-energy milling using WC[sbnd]Co media on the pressureless sintering and properties of TiB₂ was studied. After 30 mins of milling, samples sintered at 2200 °C achieved a high relative density (>98 %) and a fine mean grain size (<2 >µm). In the microstructure WxBy phases, often containing Co, were observed at triple points, due to contamination from the milling media. Moreover, core-rim structures with multiple rims were detected: the cores consisted of pure TiB₂ grains, the rims were (TixWy)B2 solid solutions. The core-rim formation was significantly more pronounced compared to a reference sample of …

Fire Fossils: Biomineral Infrastructures In Untangling Climates, Tanmayee More

Masters Theses

Diatoms drift, sediments sink, wildfires generate their own weather. Lightning strikes can blast sand into glass, and microscopic organisms do the same in the cold recesses of the ocean. What alchemies and metabolisms catalyze space, time, and energy? What are the thermodynamics of infrastructure in Climate Change?

Places, materials, and beings are afterimages. Through alchemical experiments, and multi-scalar imaging, I develop simulations of wildfires, and their profound, reverberating effects. In this thesis, a glass-meets-landscape experimental process enters these obscured conditions and renders new material relations for the built environment.

Reliability Of Cazro3 And Mgo Capacitors At High Temperatures, Alan Devoe, Hung Trinh, Fatih Dogan

Materials Science and Engineering Faculty Research & Creative Works

Calcium zirconate and magnesium oxide have both been found to have useful dielectric properties at high temperatures. Multilayer ceramic capacitors (MLCCs) were made with these dielectrics and platinum electrodes. The relationship between the lifespan (mean-time to failure) and applied voltage was determined using Weibull statistics. CaZrO₃ capacitors were tested between 550◦C and600◦C while MgO capacitors were tested between 600◦C and 650◦C. The temperature coefficient Ea and the voltage coefficient n of the Prokopowicz Vaskas equation were determined under various test conditions. Activation energiesforcalciumzirconateandmagnesiumoxidewere3.25eVand3.48eV, respectively. Resistance degradation of CaZrO₃ and MgO capacitors, tested at 600◦Cand250V, were compared.

Interfacial Defect Properties Of High-Entropy Carbides: Stacking Faults, Shockley Partial Dislocations, And A New Evans-Polanyi-Semenov Relation, Samuel E. Daigle, Stefano Curtarolo, William G. Fahrenholtz, Jon Paul Maria, Douglas E. Wolfe, Eva Zurek, Donald W. Brenner

Materials Science and Engineering Faculty Research & Creative Works

Using first principles calculations, {111} intrinsic stacking fault (ISF) energies in groups IVB, VB, and VIB high-entropy transition metal carbides (HETMCs) are shown to be predictable from an optimized rule of mixtures based on the atomic arrangement near the stacking fault. A composition-independent linear relationship is demonstrated between the ISF energies and the unstable stacking fault (USF) energies along the (112¯){111} γsurface slip path. This relationship represents a new application of the Evans-Polanyi-Semenov principle by treating the ISF and USF energies as analogous to the heat of reaction and transition state barrier in chemical reactions. Further, a full defect energy …

Intermediate Stage Densification Kinetics Of High-Entropy Ceramics During Spark Plasma Sintering, Steven M. Smith, William G. Fahrenholtz, Greg E. Hilmas, Stefano Curtarolo

Materials Science and Engineering Faculty Research & Creative Works

The intermediate stage densification kinetics of (Hf, Nb, Ta, Ti, Zr) B2 and (Hf, Nb, Ta, Ti, Zr) C were studied using a Coble creep rate model. (Hf, Nb, Ta, Ti, Zr) B2 was synthesized by boro/carbothermal reduction and (Hf, Nb, Ta, Ti, Zr) C was synthesized by carbothermal reduction. Both ceramics were densified by spark plasma sintering at 1700–1850°C. The activation energies for densification were 575 ± 53 kJ/mol for the high-entropy boride and 646 ± 4 kJ/mol for the high-entropy carbide. The densification mechanisms were grain boundary diffusion for the high-entropy boride and lattice diffusion for the high-entropy …

Effects Of Processing And Microstructure On The Oxidation Of Zrb2-Sic In Co2, Marharyta Lakusta, Jeremy L. Watts, William G. Fahrenholtz, David W. Lipke

Materials Science and Engineering Faculty Research & Creative Works

Oxidation kinetics and oxide scale microstructures were compared for ZrB2-30 vol% SiC composites fabricated by hot press sintering of powders and by pressure less sintering of additively manufactured billets. Oxidation in CO₂ was conducted at temperatures up to 1400 °C with durations up to 900 h. All specimens exhibited parabolic oxidation kinetics. Materials with similar composition but different processing histories exhibited differences in oxidation behavior that become evident at extended durations (200–900 h) and higher temperatures (1200–1400 °C). Oxidation rates generally increased with grain size, e.g., at 1000 °C for 200 h, oxide scale thickness increased from 36 to …

The Evolution Of Nanoparticles In Nanoparticle Doped Optical Fibers, Mary Cahoon

All Dissertations

Optical fiber and fiber laser technologies based on silica glass are critical to many technologies today. One method to improve the optical performance of laser fibers is engineer the local environment around the active elements in the glass. To that end, this Dissertation focused on the fabrication and characterization of fibers made with nanoparticles incorporated into the glass to control the local composition. First, the nanoparticle composition and structure was analyzed as it evolved from from the initially-synthesized form to incorporation into the dense aluminum-silicate glass. The aluminum oxide in the glass was found to be important not only to …

Advanced Manufacturing Of Multifunctional Shape Memory Polymer Composites And Self-Healing Systems, John B. Konlan

LSU Doctoral Dissertations

The need for multifunctional light weight structures for engineering applications is on the rise. Multifunctional composites are desired because of their ability to combine multiple functionalities into one structure. The advantages of a high strength-to-weight ratio of multifunctional composites make them desirable and suitable for use in energy-efficient applications. Shape-memory polymers (SMPs) have attracted interest over the past several decades because of their multifunctional nature. They have found use in many applications such as aerospace, satellites, automobiles, textiles, and biomedical devices, where lightweight and multifunctionality are key. The self-healing nature of most SMPs makes them suitable for use in lightweight …

Compositionally Complex Diborides: Competing Solubility During Sintering And Properties, Laura Silvestroni, Carlo Baldisserri, Jacopo Matteo Tabaglio, Nicola Gilli, Jeremy Watts, Steven M.I. Smith, Gregory E. Hilmas, William G. Fahrenholtz

Materials Science and Engineering Faculty Research & Creative Works

An ultra-high temperature ceramic based on ZrB2, TiB2, and SiC was hot pressed to full density at 1850 °C. Addition of 5 vol% of different metal-compounds, in the form of HfC, VC, NbC or CrB2, increased the densification temperature to 1910 °C. The resulting compositionally complex ceramics had homogeneous microstructures with boride grains exhibiting core-shell features. The shell was a solid solution containing variable amounts of the three metals. Notably, TiB2 remained as a discrete phase in the reference material and in the presence of the V- and Cr- based additions, whilst it dissolved into the main ZrB2-based grains for …

Numerical Simulation Of Heat Transfer In Self-Propagating High-Temperature Synthesis (Shs)-Based Calcination Of Limestone, Sayee Srikarah Volaity, Shubham Agrawal, Srinivas Kilambi, Patrick Phelan, Aditya Kumar, Narayanan Neithalath

Materials Science and Engineering Faculty Research & Creative Works

Calcination of limestone, a high temperature (∼900 °C) process that emits 44 % of the mass of limestone as CO₂, is a critical process in the production of many industrially important materials. To soften the CO₂-related impacts of traditional calcination, and to enable ultrafast synthesis of lime, a novel approach based on self-propagating high-temperature synthesis (SHS) has been put forward. SHS uses exothermic heat released by the combustion of fuel intermixed with the reactants to advance the reaction, and hence requires the provision of lower external temperatures. This study introduces a microstructure-guided modeling approach to understand …

Fabrication Of Ultra High-Temperature Compact Heat Exchanger By Extrusion-Based Ceramic Additive Manufacturing, Abid Hasan Rafi, David W. Lipke, Jeremy Lee Watts, Greg Hilmas, Ming-Chuan Leu

Miners Solving for Tomorrow Research Conference

No abstract provided.