Electrocatalytic Activity Of Palladium Nanocatalysts Supported On Carbon Nanoparticles In Formic Acid Oxidation,
2012
Department of Chemistry and Biochemistry, University of California, Santa Cruz, California 95064, United States;State Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi’an 710072, China;
Electrocatalytic Activity Of Palladium Nanocatalysts Supported On Carbon Nanoparticles In Formic Acid Oxidation, Jie Huang, Zhiyou Zhou, Yang Song, Xiongwu Kang, Ke Liu, Wancheng Zhou, Shaowei Chen
Journal of Electrochemistry
Palladium nanostructures were deposited onto carbon nanoparticle surface by a chemical reduction method. Transmission electron microscopic studies showed that whereas the resulting metal-carbon (Pd-CNP) nanocomposites exhibited a diameter of 20 to 30 nm, the metal components actually showed a cauliflower-like surface morphology that consisted of numerous smaller Pd nanoparticles (3 to 8 nm). Electrochemical studies showed that the effective surface area of the Pd-CNP nanoparticles was about 40% less than that of Pd black, possibly because the Pd nanoparticles were coated with a layer of carbon nanoparticles; yet, the Pd-CNP nanocomposites exhibited marked enhancement of the electrocatalytic activity in formic …
Adsorption And Electrooxidation Of Carbon Monoxide On Platinum Surfaces Modified With Sulfur,
2012
Department of Chemistry & Biochemistry, Miami University, Oxford, OH 45056, USA;
Adsorption And Electrooxidation Of Carbon Monoxide On Platinum Surfaces Modified With Sulfur, A. Mattox Mathew, W. Henney Matthew, Johnson Adam, Zou Shouzhong
Journal of Electrochemistry
Adsorbed sulfur is commonly considered as a reaction poison. However, small amounts of sulfur on platinum significantly increase the surface reactivity toward carbon monoxide (CO) electrooxidation. For the solution CO oxidation, the onset potential was shifted up to over 300 mV negative to that on S-free surface, and the extent of the negative potential shift increases with the sulfur coverage (Xs) up to about 0.6. The enhanced CO oxidation also depends on the solution pH. For the adsorbed CO, at low sulfur coverages (Xs < 0.3), the oxidation peak potential is about 40 mV negative to that of the corresponding clean Pt. However, at higher coverages, the peak potential is about 30 mV more positive. Surface-enhanced Raman spectra show that the adsorption of sulfur significantly redshifts the Pt-CO stretching frequency. These observations are explained by the weakening of the Pt-CO bond and the hindrance of CO diffusion by Sads.
Kinetic Study Of Photoelectrochemical Oxidation Of Lignin Model Compounds On Tio2 Nanotubes,
2012
Department of Chemistry, Lakehead University, 955 Oliver Road, Thunder Bay, Ontario P7B 5E1, Canada;
Kinetic Study Of Photoelectrochemical Oxidation Of Lignin Model Compounds On Tio2 Nanotubes, Min Tian, Daniel Liba, Aicheng Chen
Journal of Electrochemistry
In this study, TiO2 nanotubes were prepared via the electrochemical oxidation of titanium substrates in a non-aqueous electrolyte and their morphology and microstructures were examined by scanning electron microscopy (SEM) and X-ray diffraction (XRD). The photoelectrochemical oxidation of two lignin model compounds, 1-(3,4-dimethoxyphenoxy)-2-(2-methoxyphenoxy)-1,3-propanediol (DMP) and 3-hydroxy-1-(3,4-dimethoxyphenoxy)-2-(2-methoxyphenoxy)-1,3-propanone (HDM), was investigated. A new band appeared at ~304 nm during the photoelectrochemical oxidation of DMP. The rate of DMP intermediate formation was amplified with the increase of initial concentrations, while it was diminished with increased temperature. Despite the similarity in structure between HDM and DMP, there are only small increases in absorbance …
Condition-Dependent Risk Assessment Of Large-Scale Grid-Tied Photovoltaic Power Systems,
2012
University of Connecticut - Storrs
Condition-Dependent Risk Assessment Of Large-Scale Grid-Tied Photovoltaic Power Systems, Sherwin Li
Master's Theses
This thesis reviews the methods for evaluating the reliability of large PV systems and techniques for quantifying the impacts of PV interconnection on distribution system reliability. In addition, a comparative study is performed to evaluate the seasonal condition-dependent risk performance of central-inverter and string-inverter grid-tied PV power systems. Major contributions include: 1) risk analysis of seasonal impacts for string and centralized PV systems. Seasonal sensitivities of PV system risks to system structures, temperature variation, solar insolation, and capacitor equivalent series resistance are analyzed; and 2) the incorporation of the effect of operational conditions and the aging failure model into the …
The Architecture Selection, Design, And Discharge Modeling Of A Passive Compensation, Iron-Core, Two-Phase, Permanent Magnet Compulsator To Power A Small Railgun Platform,
2012
California Polytechnic State University, San Luis Obispo
The Architecture Selection, Design, And Discharge Modeling Of A Passive Compensation, Iron-Core, Two-Phase, Permanent Magnet Compulsator To Power A Small Railgun Platform, Collin Macgregor
Aerospace Engineering
The goal of this project was to design and build a compensated pulsed alternator, or compulsator, to power the Cal Poly Electromagnetic Railgun Mark 1.1. This project examines the feasibility of implementing mechanical pulsed power supplies for repeatable use with a railgun load for orbital debris hypervelocity testing. The final system architecture chosen was a passively compensated, iron-core, 2-phase, permanent magnet compulsator. The Cal Poly Compulsator will be capable of storing 45 kJ of mechanical energy with a peak operating speed of 5,000 rpm at 190 V. Theoretical calculations resulted in the following predicted electrical performance values: a peak output …
Performance And Cost Analysis Of A Structured Concrete Thermocline Thermal Energy Storage System,
2012
University of Arkansas, Fayetteville
Performance And Cost Analysis Of A Structured Concrete Thermocline Thermal Energy Storage System, Matt Nicholas Strasser
Graduate Theses and Dissertations
Increasing global energy demands and diminishing fossil fuel resources have raised increased interest in harvesting renewable energy resources. Solar energy is a promising candidate, as sufficient irradiance is incident to the Earth to supply the energy demands of all of its inhabitants. At the utility scale, concentrating solar power (CSP) plants provide the most cost-efficient method of harnessing solar energy for conversion to electrical energy. A major roadblock to the large-scale implementation of CSP plants is the lack of thermal energy storage (TES) that would allow the continued production of electricity during the absence of constant irradiance. Sensible heat TES …
Conductive Concrete For Electromagnetic Shielding – Methods For Development And Evaluation,
2012
University of Nebraska-Lincoln
Conductive Concrete For Electromagnetic Shielding – Methods For Development And Evaluation, Aaron P. Krause
Department of Computer Electronics and Engineering: Dissertations, Theses, and Student Research
This research investigates the development and evaluation innovative methods for the use of conductive concrete as an electromagnetic shield. New testing methods are developed to determine the best conductive components to use in the design of a concrete mixture for shielding that shows the best promise. The conductive concrete mixture has the potential to provide electromagnetic shielding that is cost-effective in terms of construction, operation, and maintenance compared to conventional approaches. Two testing methods, Small Sample Testing and Large Slab Testing, are developed based on standardized testing methods that have been modified for the testing of conductive concrete mixtures. As …
Smart Wall Plug Design For The Dc House Project,
2012
California Polytechnic State University, San Luis Obispo
Smart Wall Plug Design For The Dc House Project, Edward Constant Sibal
Master's Theses
The DC House project at Cal Poly State University faces a challenge of supplying DC voltage to household appliances. Each appliance in the DC House constitutes a DC load that has a unique voltage and power rating, hence the need to develop a smart DC wall plug that will automatically adjust to the operating voltage required by any DC load. This thesis entails a proof of concept design of the smart DC wall plug which can automatically detect an appliance’s voltage rating. The design employs a dc-dc converter in conjunction with a microcontroller to sense load current to properly adjust …
Energy Harvesting Of Human Kinetic Movement,
2012
California Polytechnic State University - San Luis Obispo
Energy Harvesting Of Human Kinetic Movement, David Marusiak, Julia Carrillo
Electrical Engineering
Development of kinetic energy scavenging applications from the human body necessitates additional research to assist in designating a mounting position for a potential device. A data acquisition system adequately provides a parametric average power comparison among four locations on the body (waist, upper arm, hand, and calf) for both a male and female subject. Experimentally, the hand-held device provided the highest average power. Thus, subsequent investigation at set speeds provides further analysis of the output’s characteristically linear behavior. The physical energy-harvesting device features a plastic tube casing wrapped with the stationary coiled wire through which a neodymium magnet oscillates. While …
Single-Phase High Efficiency Motor Testing,
2012
California Polytechnic State University - San Luis Obispo
Single-Phase High Efficiency Motor Testing, Marc Henry Perez
Electrical Engineering
A three-phase induction motor has higher efficiency than the single-phase motor counterpart. It is possible to run a three-phase motor with a single-phase source to develop a single-phase high efficiency system. The single-phase high efficiency motor, or SHE-motor, uses capacitor banks to operate at a balanced three phase induction motor using a single phase source. Unfortunately, this design has been limited, as it can only be balanced for one load configuration at a time. This provides the system to have maximum system performance. Due to this limitation in operations, it has proven to be non-ideal in commercial applications. It is …
Residential Grid-Tied With Battery Backup Photovoltaic System,
2012
California Polytechnic State University - San Luis Obispo
Residential Grid-Tied With Battery Backup Photovoltaic System, Thomas Stobuagh
Electrical Engineering
When power outages occur, many homes are left without power for some time as they are dependent on the power grid. This project aims to design a residential grid tied battery backup photovoltaic system that will provide up to 7.2kW in an area that gets 5.36-5.49 kWh/m2/day [1] to support a home with an average daily usage of 28.4 kWh/day. To effectively use this system the house remains connected to the electric utility at all times, so any power needed above what the solar system can produce is simply drawn from the utility. It includes battery backup or uninterruptible power …
Thermal And Electrical Parasitic Modeling For Multi-Chip Power Module Layout Synthesis,
2012
University of Arkansas, Fayetteville
Thermal And Electrical Parasitic Modeling For Multi-Chip Power Module Layout Synthesis, Zihao Gong
Graduate Theses and Dissertations
This thesis presents thermal and electrical parasitic modeling approaches for layout synthesis of Multi-Chip Power Modules (MCPMs). MCPMs integrate power semiconductor devices and drive electronics into a single package. As the switching frequency of power devices increases, the size of the passive components are greatly reduced leading to gains in efficiency and cost reduction. In order to increase switching frequency, electrical parasitics in MCPMs need to be reduced through tighter electronic integrations and smaller packages. As package size is decreased, temperature increases due to less heat dissipation capability. Thus, it is crucial to consider both thermal and electrical parasitics in …
Optimization Of Nonlinear Switch Cells For Switching Converters,
2012
University of Arkansas, Fayetteville
Optimization Of Nonlinear Switch Cells For Switching Converters, Bradley Alan Reese
Graduate Theses and Dissertations
Switch cells consist of an array of power switches and passive components which can replace the main switches alone in many power topologies, allowing reduced switching loss without altering the power topology directly. This thesis discusses the development of a switch cell topology that utilizes a saturable resonant inductor to reduce the size and power loss of the cell. Additionally, the cell transfers energy stored in the inductor into a capacitor for efficient energy storage during the cell's conduction region. This energy is then transferred back to the system when the cell turns off, thus reducing the total switching energy.
Electrochemical Synthesis Of Silver-Tetracyanoquinodimethane Nanorods At Agar Supported Water/1,2-Dichloroethane Interface,
2012
Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian, China;State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University, Xiamen 361005, Fujian, China;
Electrochemical Synthesis Of Silver-Tetracyanoquinodimethane Nanorods At Agar Supported Water/1,2-Dichloroethane Interface, Li Huang, Yixian Wang, Michael V. Mirkin, Bin Ren, Dongping Zhan
Journal of Electrochemistry
Silver-tetracyanoquinodimethane (AgTCNQ) is an important charge transfer salt due to its high conductivity and other electronic properties. In this communication, we report the synthesis of AgTCNQ at the liquid/liquid interface. Agar was used as a gelling agent to support water/1,2-dichloroethane (DCE) interface. Silver ions were transferred from the hydrogel into DCE phase, where they combined with TCNQ- to form AgTCNQ nanorods. The developed method can provide a new route for synthesis of functional materials based on the electrochemistry at the liquid/liquid interface.
The Oxidation Of Hydrogen Peroxide On Nanostructured Rhodium Microelectrodes,
2012
Chemistry, University of Southampton, Southampton, SO17 1BJ, UK;
The Oxidation Of Hydrogen Peroxide On Nanostructured Rhodium Microelectrodes, N. Bartlett Philip, F. Esterle Thomas
Journal of Electrochemistry
Mesoporous Rh films were deposited onto platinum microelectrodes from the H1 lyotropic liquid crystalline phase of C12EO8 (octaethyleneglycol monododecyl ether). The electrodes show well defined voltammetry for the oxidation and the reduction of hydrogen peroxide at low concentrations (<10 mmol•L-1) with excellent stability for operation at neutral pH. Based on the hysteresis in the current and the potential dependence the oxidation of hydrogen peroxide occurs through a CEE mechanism involving Rh(OH)3 on the mesoporous Rh electrode surface. At higher hydrogen peroxide concentrations the current reaches a plateau that is due to either saturation of the binding sites for hydrogen peroxide or limitation of the reaction due to acidification of the solution within the pores. For the thin films (below 200 nm) the hydrogen peroxide calibration curves we …
Voltage Flicker Evaluation For Wave Energy Converters – Assessment Guidelines,
2012
Technological University Dublin
Voltage Flicker Evaluation For Wave Energy Converters – Assessment Guidelines, Fergus Sharkey, Elva Bannon, Joe Macenri, Kevin Gaughan, Michael Conlon
Conference papers
Voltage flicker is a power quality problem caused by regularly oscillating active and reactive power either from a load or generator. The regular power oscillations induce a voltage change at the grid connection which is proportional to the amplitude of the power oscillation and at the same frequency. The impedance of the grid (grid strength) at the point of connection is a factor in the amplitude of the voltage oscillation. The frequency band of interest for flicker evaluation is from 0.01-20Hz, and is most severe at 8.8Hz. The frequency of the primary resource for wave energy converters lies within this …
Practical Analysis Of Key Electrical Interfaces For Wave Energy Converter Arrays,
2012
Technological University Dublin
Practical Analysis Of Key Electrical Interfaces For Wave Energy Converter Arrays, Fergus Sharkey, Michael Conlon, Kevin Gaughan
Conference papers
The authors have previously outlined a proposed path for the development of electrical networks for deepwater wave farms. This path broadly followed that of offshore wind farms as the least cost solution. The main differences between wind farm and wave farm electrical networks were identified as the method of installation and maintenance and the components at the WEC interface with the electrical network. Components such as dynamic cables, submarine connectors, submarine switchgear all form part of these interfaces. This paper examines the key electrical interfaces for WEC arrays such as the dynamic cable to WEC interface, dynamic cable to static …
Advancing The Beamed Energy Ablation Driven Propulsion Engine Concept,
2012
University of Alabama in Huntsville
Advancing The Beamed Energy Ablation Driven Propulsion Engine Concept, Grant Bergstue
Von Braun Symposium Student Posters
No abstract provided.
Development And Implementation Of A Calibration Procedure For Complex Impedance Spectrum Measurements With Applications To Embedded Battery Health Monitoring And Management Systems,
2012
University of Connecticut - Storrs
Development And Implementation Of A Calibration Procedure For Complex Impedance Spectrum Measurements With Applications To Embedded Battery Health Monitoring And Management Systems, William H. Morrison
Master's Theses
Energy storage devices such as rechargeable Lithium ion batteries are assuming an increasingly prominent role in society, covering applications from electric / hybrid electric vehicles to personal portable electronics. In response to this increasing demand, technologies that monitor battery health and remaining useful life have developed. One such system is the Smart Battery Status Monitor (SBSM), developed by the Idaho National Laboratory, Montana Tech and Qualtech Systems, Inc. The SBSM utilizes impedance spectrum measurements using a subsystem called the Impedance Measurement Box (IMB). The impedance measurements are complex quantities (having both a resistive and a reactive component) and are made …
Design And Test Of A Linear Switched Reluctance Generator For Use In Wave-Energy Applications,
2012
Technological University Dublin
Design And Test Of A Linear Switched Reluctance Generator For Use In Wave-Energy Applications, Garret Brady, Cathal O'Loughlin, John Massey, David Griffiths, Carlos Villegas
Conference Papers
This paper describes the design of a double-sided linear switched reluctance generator for use in wave energy applications, and the build and test of a working bench-scale prototype. Beginning with a standard shape, the development of the design, from concept to detail, is presented. Numerical simulation results – magnetic, mechanical and electrical – inform the detailed design. Construction of the generator and test rig is described. Experimental results give good agreement with simulation predictions.
