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Cmk-3/Sulfur Composite (CXSY) And Room-Temperature Na/S Battery, Qing ZHAO, Yu-Xiang HU, Kai ZHANG, Li-Jiang WANG, Zhan-Liang TAO, Jun CHEN 2013 Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), College of Chemistry, Nankai University, No. 94 Weijin Road, Tianjin 300071, China;

Cmk-3/Sulfur Composite (CXSY) And Room-Temperature Na/S Battery, Qing Zhao, Yu-Xiang Hu, Kai Zhang, Li-Jiang Wang, Zhan-Liang Tao, Jun Chen

Journal of Electrochemistry

A series of ordered mesoporous carbon (CMK-3)/sulfur composite (CxSy) with different sulfur contents were synthesized via a melt-diffusion method. XRD, Raman, BET, SEM, and TEM techniques were used to characterize the structure and morphology of the as-prepared composite. The electrochemical performance of CMK-3/sulfur composite as the electrode of Na/S battery was tested at room temperature. Cyclic voltammograms show that one obvious reduction peak was located at about 1.61V, which is corresponding to the formation of Na2Sx (x=2~5), while two oxidation peaks were displayed at about 1.82V and 1.95V, which are belonging to the …


Preparation Of The Particle Size Controllable Lifepo4/C And Its Electrochemical Profile Characterization, Ming-e WANG, Jing-yuan LIU, Meng-yan HOU, Yong-yao XIA 2013 Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai 200433, China;

Preparation Of The Particle Size Controllable Lifepo4/C And Its Electrochemical Profile Characterization, Ming-E Wang, Jing-Yuan Liu, Meng-Yan Hou, Yong-Yao Xia

Journal of Electrochemistry

We adopted an effective route to prepare the particle size controllable core-shell structure carbon-coated LiFePO4 from different sized FePO4 precursors, varying from 80 nm, 200 nm and 1 μm by an in situ polymerization method integrated with a surface modification technology. The discharge capacities of the three sized LiFePO4/C are, respectively, 162 mAh·g-1, 142 mAh·g-1 and 92 mAh·g-1 at 0.1C rate. The nano-sized LiFePO4-a/C (80 nm) delivers a discharge capacity as large as 100 mAh·g-1 even at 30C, while the macroscopic LiFePO4-c/C (1 μm) exhibits a much …


Surface Composition Structure And Electrochemical Performance Of Aluminum Doped Lifepo4, Huai-fang SHANG, Wei-feng HUANG, Wang-sheng HU, Ding-guo XIA, Zi-yu WU 2013 College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100022, P. R. China;

Surface Composition Structure And Electrochemical Performance Of Aluminum Doped Lifepo4, Huai-Fang Shang, Wei-Feng Huang, Wang-Sheng Hu, Ding-Guo Xia, Zi-Yu Wu

Journal of Electrochemistry

Despite there are many successful reports about the preparation of electrode materials with surface coating for lithium ion batteries, the study in surface self-coating of cathode materials using segregation of doping elements and their electrochemical properties is still very rare. The LiFePO4 particles with rich-Al on the surface were synthesized by one step solvothermal route. TEM results demonstrated that the surface of the obtained LiFePO4 particles was well-covered by the amorphous coating. The soft X-ray absorption spectroscopy (XAS) and Auger electron spectroscopy (AES) component analyses revealed that the amorphous coating was composed of LiFe1-xAlxPO …


Preparation And Electrochemical Properties Of Amorphous Znsno3/C By Hydrothermally Carbonization Method, Guo-qing FANG, Rui-xue ZHANG, Wei-wei LIU, Bing-bo XIA, Hong-dan SUN, Hai-bo WANG, Jing-jing WU, Shinko KANEKO, De-cheng LI 2013 Key Laboratory of Lithium Battery Materials of Jiangsu Province, Institute of Chemical Power Sources, Soochow University, Suzhou, 215006, Jiangsu, China;

Preparation And Electrochemical Properties Of Amorphous Znsno3/C By Hydrothermally Carbonization Method, Guo-Qing Fang, Rui-Xue Zhang, Wei-Wei Liu, Bing-Bo Xia, Hong-Dan Sun, Hai-Bo Wang, Jing-Jing Wu, Shinko Kaneko, De-Cheng Li

Journal of Electrochemistry

The amorphous ZnSnO3@C composite was synthesized via a simple glucose hydrothermal and subsequent carbonization approach. The structure, morphology and electrochemical property of the composite were characterized by XRD, TEM and electrochemical measurements. Compared to bare ZnSnO3, the ZnSnO3/C composite exhibited markedly enhanced lithium storage property and cycle performance, delivering a reversible capacity of 659 mAh·g-1 after 100 cycles at a current density of 100 mA·g-1.


Synthesis And Electrochemical Property Of Li2Fesio4/C Cathode Material By Solid State Method, Jiao-li SUN, Zhi-jiao CHEN, Yi-xiao LI, Hu CHENG 2013 School of Chemistry and Material Science, Guizhou Normal University, Guiyang 550001, Guizhou, China;

Synthesis And Electrochemical Property Of Li2Fesio4/C Cathode Material By Solid State Method, Jiao-Li Sun, Zhi-Jiao Chen, Yi-Xiao Li, Hu Cheng

Journal of Electrochemistry

Li2FeSiO4/C cathode material was synthesized using Li2SiO3 and FeC2O4 as raw materials by solid state method. The structure and morphology of the material were characterized by XRD and SEM. The electrochemical properties of the material were studied by constant-current cyclic testing. The results show that Li2FeSiO4/C has a good electrochemical performance. The first discharge capacity of Li2FeSiO4/C cathode material at 30oC reached 167 mAh∙g-1 when cycled at 10 mA∙g-1 between 1.5 and 4.8 V.


Electrochemical Na-Storage Materials And Their Applications For Na-Ion Batteries, Jiang-feng QIAN, Xue-ping GAO, Han-xi YANG 2013 1. Department of Chemistry, Wuhan University, Wuhan, 430072, Hubei, China

Electrochemical Na-Storage Materials And Their Applications For Na-Ion Batteries, Jiang-Feng Qian, Xue-Ping Gao, Han-Xi Yang

Journal of Electrochemistry

Oncoming large scale electric energy storage (EES) requires battery systems not only to have sufficient storage capacity but also to be cost-effective and environmentally friendly. Li-ion batteries for widespread EES applications may be limited due to the constraint of global lithium resource. From the considerations of available resources and environmental impact, Na-ion batteries have potential advantages as next generation secondary batteries and an alternative to Li-ion batteries. However, in the present state of the art, the Na-storage cathodes reported so far are still deficient both in energy density and power capability, while the carbon and alloy anodes for Na-ion batteries …


Predicting Voltage Abnormality Using Power System Dynamics, Nagendrakumar Beeravolu 2013 LSU New Orleans

Predicting Voltage Abnormality Using Power System Dynamics, Nagendrakumar Beeravolu

LSU New Orleans Theses and Dissertations

The purpose of this dissertation is to analyze dynamic behavior of a stressed power system and to correlate the dynamic responses to a near future system voltage abnormality. It is postulated that the dynamic response of a stressed power system in a short period of time-in seconds-contains sufficient information that will allow prediction of voltage abnormality in future time-in minutes. The PSSE dynamics simulator is used to study the dynamics of the IEEE 39 Bus equivalent test system. To correlate dynamic behavior to system voltage abnormality, this research utilizes two different pattern recognition methods one being algorithmic method known as …


Battery Energy Storage Systems To Mitigate The Variability Of Photovoltaic Power Generation, Heath Alan Gurganus 2013 Portland State University

Battery Energy Storage Systems To Mitigate The Variability Of Photovoltaic Power Generation, Heath Alan Gurganus

Dissertations and Theses

Methods of generating renewable energy such as through solar photovoltaic (PV) cells and wind turbines offer great promise in terms of a reduced carbon footprint and overall impact on the environment. However, these methods also share the attribute of being highly stochastic, meaning they are variable in such a way that is difficult to forecast with sufficient accuracy. While solar power currently constitutes a small amount of generating potential in most regions, the cost of photovoltaics continues to decline and a trend has emerged to build larger PV plants than was once feasible. This has brought the matter of increased …


Adjust Decision-Making Targets Based On Psychological Thresholds, Jian Liu, Shun Xiang Wu, Si Feng Liu, Qiao Wang 2013 Missouri University of Science and Technology

Adjust Decision-Making Targets Based On Psychological Thresholds, Jian Liu, Shun Xiang Wu, Si Feng Liu, Qiao Wang

Electrical and Computer Engineering Faculty Research & Creative Works

This paper study the impact of psychological thresholds (PTs) on the decision maker's (DM's) decision target when making decision. A new approach of decision making is proposed in this paper. First, we construct criterion expected functions according to three different types of criteria: profit type, cost-type and intermediate-type, respectively. Then, we calculate the local degree of satisfaction (LDS) of each object when PTs exists, in order to adjust the initial decision target to make up new decision table. Later, by weighting the criteria reaching the DM's degree of satisfaction (DS) along with information aggregation algorithm, we obtain the overall satisfaction …


Fea Estimation And Experimental Validation Of Solid Rotor And Magnet Eddy Current Loss In Single-Sided Axial Flux Permanent Magnet Machines, Xu Yang 2013 University of Nebraska-Lincoln

Fea Estimation And Experimental Validation Of Solid Rotor And Magnet Eddy Current Loss In Single-Sided Axial Flux Permanent Magnet Machines, Xu Yang

Department of Electrical and Computer Engineering: Dissertations, Theses, and Student Research

The rotor and magnet loss in single-sided axial ux permanent magnet (AFPM) machines with non-overlapped windings is studied in this dissertation. Finite element analysis (FEA) estimations of the loss are carried out using both 2D and 3D modeling. The rotor and magnet losses are determined separately for stator slot passing and MMF space harmonics from currents in the stator. The segregation of loss between the solid rotor plate and the magnet is addressed. The eddy current loss reduction by magnet segmentation is discussed as well. Two prototype 24 slot/22 pole single-sided AFPMs, fabricated with both single layer (SL) and double …


Portable Nano-Hydro Power Generator For The Dc House Project, Andrew Aw, James Biggs 2013 California Polytechnic State University - San Luis Obispo

Portable Nano-Hydro Power Generator For The Dc House Project, Andrew Aw, James Biggs

Electrical Engineering

This senior project report explains the construction and design of a small, portable water generator that converts kinetic energy flowing in small creeks to electrical energy as a renewable source of energy for the DC House. The DC House, in short, is a project to build a self-sustainable house for Third World countries that utilizes only DC electricity. The system consists of two converters and a charge controller for a 12V lead-acid battery. The first converter converts the hydro generator voltage output to 15 Volts for safe and proper charging of the lead-acid battery by the charge controller. The second …


Motor Protection Lab Experiment Using Sel-710, Ozro Corulli 2013 California Polytechnic State University - San Luis Obispo

Motor Protection Lab Experiment Using Sel-710, Ozro Corulli

Electrical Engineering

Advancements in microprocessor based relay technology for power protection applications provide quicker response times and new methods of mitigation. This project develops a lab experiment for Cal Poly class EE444 - Power Systems Laboratory based on the Schweitzer SEL-710 motor protection relay. Learning objectives for this lab include relay setup, programming, and protection schemes for the following conditions: undervoltage, loss of phase, fault, locked rotor, and thermal overload. Today, utility companies across the globe use SEL relays for primary system protection, putting engineers familiar with their operation in high demand.


Design, Fabrication And Characterization Of Plasmonic Fishnet Structures For The Enhancement Of Absorption In Thin Film Solar Cells, Sayan Seal 2013 University of Arkansas, Fayetteville

Design, Fabrication And Characterization Of Plasmonic Fishnet Structures For The Enhancement Of Absorption In Thin Film Solar Cells, Sayan Seal

Graduate Theses and Dissertations

Incorporating plasmonic structures into the back spacer layer of thin film solar cells (TFSCs) is an efficient way to improve their performance. The fishnet structure; which is a tunable, plasmonic light scatterer is used to enhance light absorption. Unlike other plasmonic particles that have been previously suggested, the fishnet is an electrically connected wire mesh and does not result in electric field localization, hence it results in greater absorption in the intrinsic Si layer. Unlike other designs, the fishnet structure is placed in the back spacer layer of the TFSC, so it does not block any incident light. There is …


Synthesis Of Pani/Nihcf Nanocomposite Particles And Eqcm Measurement Of Ion Exchange Properties In Solutions Containing Cd2+, yu-jiao Yang, Xiao-gang Hao, Xu-li MA, Zhong-de WANG, Zhong-lin ZHANG, Nian-chen HAN 2013 Department of Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, China;

Synthesis Of Pani/Nihcf Nanocomposite Particles And Eqcm Measurement Of Ion Exchange Properties In Solutions Containing Cd2+, Yu-Jiao Yang, Xiao-Gang Hao, Xu-Li Ma, Zhong-De Wang, Zhong-Lin Zhang, Nian-Chen Han

Journal of Electrochemistry

The PANI/NiHCF nanocomposite particles were synthesized on the CNTs-modified Pt substrate by one-step co-polymerization using cyclic voltammetry. Electrochemical quartz crystal microbalance (EQCM) technique was adopted to investigate the polymerization process of the nanocomposite particles and the mechanism of ion exchange in aqueous solution containing Cd2+. The morphology and structure of the as-prepared composite particles were characterized by scanning electron microscope (SEM), transmission electron microscope (TEM), and Fourier transform infrared spectroscopy (FT-IR). Combined with cyclic voltammetry (CV) and energy dispersive spectroscopy (EDS), the electrochemical behavior and the mechanism of ion exchange were also investigated in electrolytes of Cd2+ …


A Comparative Study In Pretreatments Of Acid Chemical Wastewater By Electrochemical Oxidation And Ozonation, Han-shui LIU, su YU, Shao-ping TONG, Chun-an MA 2013 College of Chemical Engineering and Materials Science, State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, Zhejiang University of Technology, Hangzhou 310032,China;

A Comparative Study In Pretreatments Of Acid Chemical Wastewater By Electrochemical Oxidation And Ozonation, Han-Shui Liu, Su Yu, Shao-Ping Tong, Chun-An Ma

Journal of Electrochemistry

Under the condition of keeping certain acidity, the pretreatment efficiency of an acid chemical wastewater (pH 0.85) by electrochemical oxidation was compared with that by ozonation. The results showed that the electrochemical oxidation pretreatment could obtain a better result than the ozonation at pH 0.85. After the addition of 2 g·L-1 NaCl and with the electrochemical oxidation pretreatment at 30 mA·cm-2, the removal rate of chemical oxygen demand (CODCr) reached 43.4%, and the value of biochemical oxygen demand/chemical oxygen demand (BOD5/CODCr) also increased from 0.034 to 0.14 in 20 minutes, indicating significantly improvement …


Preparation Of Benzoquinone From Phenol By Electrooxidation, Dong-fang NIU, Cheng-kai YU, Xin-sheng ZHANG 2013 State Key Laboratory of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China;

Preparation Of Benzoquinone From Phenol By Electrooxidation, Dong-Fang Niu, Cheng-Kai Yu, Xin-Sheng Zhang

Journal of Electrochemistry

The benzoquinone was prepared from phenol by electrooxidation in an H-type cell with cation exchange membrane, in which lead plates were used both as an anode and a cathode, while H2SO4 was used as a supporting electrolyte. The effects of current density, concentration of sulphuric acid, concentrations of benzoquinone in electrolyte and extractant on the yields and efficiencies of electrolysis were investigated. Under the optimized conditions of current density being 4 A·dm-2, concentration of sulphuric acid 1 mol·L-1, passed charge 3.2 A·h, the yield and current efficiency of benzoquinone could reach 68% and …


Experimental Design Methodology Applied To The Oxidation Of Quinolines In Aqueous Medium By Electro-Fenton Process, Souhaila TRABELSI SOUISSI, Nihal OTURAN, Nizar BELLAKHAL, Mehmet A. OTURAN 2013 Université Paris-Est, Laboratoire Géomatériaux et Environnement (LGE), UPEMLV, 77454 Marne-la-Vallée, France;Laboratoire de Chimie Analytique et Electrochimie, Département de Chimie, Faculté des Sciences de Tunis, Campus Universitaire 2092, El Manar Tunis, Tunisia;

Experimental Design Methodology Applied To The Oxidation Of Quinolines In Aqueous Medium By Electro-Fenton Process, Souhaila Trabelsi Souissi, Nihal Oturan, Nizar Bellakhal, Mehmet A. Oturan

Journal of Electrochemistry

The degradation behavior of 8-hydroxyquinoleine sulfate (8-HQS), a model molecule of quinolines, was studied in an aqueous medium by electro-Fenton process using a carbon felt cathode and a platinum anode. The great oxidation ability of this process is due to a large production of hydroxyl radical (OH) by electrochemically induced Fenton’s reagent (H2O2, Fe2+). Hydroxyl radicals are very powerful oxidizing agents which react on organics up to complete mineralization. A factorial experimental design was used for determining the operating parameters on the degradation of 8-HQS in an aqueous medium. The results showed that the …


Synthesizing Bismuth Telluride Nanowires In A Large Scale And Investigating The Energy Filtering Effect By Blending Bismuth Telluride Nanowires And Silver Nanoparticle In Thermoelectrics, Henka Darsono, Haiyu Fang, Yue Wu 2013 Purdue University

Synthesizing Bismuth Telluride Nanowires In A Large Scale And Investigating The Energy Filtering Effect By Blending Bismuth Telluride Nanowires And Silver Nanoparticle In Thermoelectrics, Henka Darsono, Haiyu Fang, Yue Wu

The Summer Undergraduate Research Fellowship (SURF) Symposium

More than 50% of the energy sources becomes “waste” energy generally dissipated to the atmosphere in the form of heat. Thermoelectric effect is a conversion of temperature difference to electric voltage and can be used to convert the wasted heat to useful work. Nanomaterials have great potentials in the field of thermoelectric effect since they have properties that can allow higher efficiency in converting this wasted heat to electricity as compared to bulk materials. The purpose of this project is to develop a method to synthesize bismuth telluride (Bi2Te3) nanowires on a large scale and incorporate …


Stanford Stratified Structure Solver (S4) Simulation Tool, Chang Liu, Xufeng Wang, Peter Bermel 2013 Purdue University

Stanford Stratified Structure Solver (S4) Simulation Tool, Chang Liu, Xufeng Wang, Peter Bermel

The Summer Undergraduate Research Fellowship (SURF) Symposium

The Stanford Stratified Structure Solver (S4) developed in 2012 allows for fast, accurate prediction of optical propagation through complex 3D structures. However, there have been two key challenges preventing wider use to date: the use of a specialized control language, and the difficulty of incorporating realistic materials parameters. In this project, both concerns have been addressed. We have constructed a graphical user interface as an alternative, using the open-source Rappture platform on nanoHUB. This has been combined with a comprehensive materials database known as PhotonicsDB, which incorporates materials optical data drawn from carefully vetted sources. An Octave script file was …


Thread Based Battery For Low Power E-Textile Applications, Pranav Laxmanan, Girish Chitnis, Rahim Rahimi, Babak Ziaie 2013 Purdue University

Thread Based Battery For Low Power E-Textile Applications, Pranav Laxmanan, Girish Chitnis, Rahim Rahimi, Babak Ziaie

The Summer Undergraduate Research Fellowship (SURF) Symposium

Textile electronic systems, or e-textiles, are on the rise but their utility is limited by its power demand. Potential applications include point-of-care diagnostic systems that would enable medical monitoring at the site of care. A small, inexpensive, and easy to use battery would enhance the capabilities of e-textile. Here we propose a thread based battery that attempts to satisfy these requirements. The thread based battery uses chemistry similar to an alkaline battery. The fabrication process involves patterning of current collector (silver epoxy or carbon ink) followed by zinc electroplating and manganese dioxide deposition. Thread present in between these two electrodes …


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