Novel Modified Polyethersulfone High Temperature And Low Humidity Fuel Cell Membrane: Experimental And Simulation Study, Mohammed K. Al Mesfer, Muthanna H. Al-Dahhan, Mohd Danish, Mumtaj Shah

Chemical and Biochemical Engineering Faculty Research & Creative Works

The Present Study Focuses on Synthesizing a High-Temperature Stable Membrane Working under Low Relative Humidity (RH) by Aminating the Traditional Polyethersulfone Polymer with Aniline for Fuel Cell Applications. a Condensed-Phase Optimized Molecular Potentials for Atomistic Simulation Studies Force Field-Based Molecular Dynamics Simulation Was Used to Explore the Microscopic Properties and Transport of Water and Hydronium (H3O+) Ions Across the Electrolyte at Varied Temperatures and RHs. COMSOL Calculates Oxygen and Hydrogen Concentrations after Examining the Polymer–ion Interaction with the Radial Distribution Function (RDF). the High H3O+ Diffusion Coefficient of the Aniline-Treated Membrane Shows the Benefit of the Modification. the RDF Confirmed …

Robust Triso-Fueled Pebble Identification By Digit Recognition, Roshan Kenia, Jihane Mendil, Ahmed Jasim, Muthanna Al-Dahhan, Zhaozheng Yin

Chemical and Biochemical Engineering Faculty Research & Creative Works

Nuclear Power Plays a Vital Role in Providing Reliable and Clean Energy to Fulfill Increasing Demands in Electricity Worldwide. It Continues to Be an Essential Source of National Power Supply as Growing Concerns About Fossil Fuel Depletion, Global Warming, and Emissions Require Utilizing Sustainable Energy Sources. One Area Contributing to the Growth of Nuclear Power is the Development of Reactors that Have Enhanced Protection and Security, Thermal Efficiency, and Design. Reactor Efficiency Can Be Studied by the Burnup that Occurs When a TRISO-Fueled Pebble is Inserted into the Nuclear Core and Subsequently Removed. the Levels of Burnup Are Measured based …

Molecular Imaging Nanoprobes And Their Applications In Atherosclerosis Diagnosis, Huari Kou, Hu Yang

Chemical and Biochemical Engineering Faculty Research & Creative Works

Molecular imaging has undergone significant development in recent years for its excellent ability to image and quantify biologic processes at cellular and molecular levels. Its application is of significance in cardiovascular diseases, particularly in diagnosing them at early stages. Atherosclerosis is a complex, chronic, and progressive disease that can lead to serious consequences such as heart strokes or infarctions. Attempts have been made to detect atherosclerosis with molecular imaging modalities. Not only do imaging modalities develop rapidly, but research of relevant nanomaterials as imaging probes has also been increasingly studied in recent years. This review focuses on the latest developments …

Injectable Dendrimer Hydrogel Delivers Melphalan In Both Conjugated And Free Forms For Retinoblastoma, Remy C. Cooper, Juan Wang, Hu Yang

Chemical and Biochemical Engineering Faculty Research & Creative Works

We report the successful synthesis of an injectable dendrimer hydrogel (DH) carrying melphalan, a clinical drug for retinoblastoma treatment, in both conjugated and free forms. Polyamidoamine (PAMAM) dendrimer generation 5 (G5) is surface-modified with an acid-sensitive acetal-dibenzocyclooctyne linker and then undergoes azide-alkyne cycloaddition with melphalan-PEG-N3 conjugate to form G5-acetal-melphalan. During the DH gelation between G5-acetal-melphalan and PEG-diacrylate, free melphalan is added, resulting in a hydrogel (G5-acetal-melphalan-DH/melphalan) that carries the drug in both conjugated and free forms. Melphalan is slowly released from G5-acetal-melphalan-DH/melphalan, with the conjugated melphalan released more quickly at pH 5.3 due to acid-triggered acetal bond cleavage. The formulation's …

Magnetic Separation Of Lunar Regolith Simulants With Applications To In Situ Resource Utilization On The Moon, Peter Bachle, Jeffrey Smith, Fateme Rezaei, David Bayless, William Schonberg, Daoru Han

Chemical and Biochemical Engineering Faculty Research & Creative Works

The development of in situ resource utilization (ISRU) for metal extraction is imperative as a steppingstone for habitation construction in lunar and non-terrestrial environments. Separation of minerals by chemical composition is important to optimize metal and oxygen liberation from lunar ore. To this effect, devices capable of separating aluminum bearing minerals from iron-bearing minerals from the lunar regolith simulants have been developed. Twenty-eight different simulants have been used in this study. A dual-belt separator was designed to reduce middling. Para-magnetic minerals were reliably separated using a neodymium N52-magnet-separator system. Effective separation of aluminum-bearing minerals from iron-bearing minerals was greater than …

Thermal Management Of Adsorption-Based Biogas Upgrading Systems Via Incorporation Of Phase-Change Materials, Kyle Newport, Khaled Baamran, Ali A. Rownaghi, Fateme Rezaei

Chemical and Biochemical Engineering Faculty Research & Creative Works

Thermal management of adsorption columns is necessary to maintain their effectiveness while reducing the energy requirements of the overall separation process. In this work, we aimed at investigating the suitability of blending adsorbents with phase-change materials (PCMs) to adjust the thermal profile of a biogas upgrading column. A commercially available PCM (Nextek 28D) in quantities of 10, 20, and 30 wt. % was blended with zeolite 13X in two configurations, namely, traditional pellets and 3D-printed monoliths. The use of different structures allows for better analysis of thermal profiles and assessment of the effectiveness of the PCM in a packed bed …

Transitioning To A Lower Global Warming Refrigerant, A Performance Study Of R-513a And Hfc-134a In Commercial Chillers, Hossein Abedsoltan, Mark B. Shiflett

Chemical and Biochemical Engineering Faculty Research & Creative Works

The performance of R-513A and HFC-134a refrigerants is compared in two identical chillers operating at the University of Kansas. R-513A is a more environmentally friendly refrigerant due to its lower global warming potential that can be used as a retrofit replacement for HFC-134a in chillers. This study investigates the performance comparison of transitioning from HFC-134a to R-513A. The chillers have been in operation for two years, and cooling capacity, coefficient of performance, and other operating parameters are compared under similar cooling conditions. Cooling capacities ranged from 100 to 500 kW for both chillers. Overall, the energy consumption and coefficient of …

Fit-For-Purpose Heavy-Duty Fishing Equipment Designed To Safely Retrieve A Damaged Wireline Cable From An Active, Sour Gas Well Located Offshore, M. N. Amri, R. Macaulay, S. Aboelnaga, A. Abouganem, M. Al Dahhan

Chemical and Biochemical Engineering Faculty Research & Creative Works

Wireline operations play a crucial role in the oil and gas industry, facilitating essential tasks like well maintenance, data collection, and intervention. These operations involve deploying substantial downhole tools and large cables into the wellbore, but this endeavor is not without its challenges. Particularly, when a wireline cable breaks downhole, it poses significant risks. Unplanned wireline breakages result in demanding heavy-duty fishing operations when they occur in challenging offshore environments and unfavorable downhole conditions. in this work, strategic planning and execution were applied in a complex e-line cable recovery in a live, sour gas well without the need for well …

Integrated Downhole-Measurement-Enabled Coiled Tubing And Mechanical Wireline Recovery Of E-Line Cable In A Live, Sour Gas Well, C. Villagrana, A. Abouganem, A. M. Afsal, M. Al-Dahhan, J. Delaune, W. R. Tapia, M. Amri

Chemical and Biochemical Engineering Faculty Research & Creative Works

This study details a complex wire recovery operation in a live well that involved transitioning from coiled tubing (CT) to mechanical wireline (MWL), in both slickline [MA1] or braided line, to retrieve the wire in good condition and later hand it over to an electrical wireline (e-line) unit to spool it onto a drum. the operation was carried out on a live, sour gas well, demanding a unique setup and emphasizing safety. Two successful recovery operations removed a significant amount of e-line left in the well plus the upper section of the e-line bottomhole assembly (BHA) while safely pushing the …

Gan Hemt And Air Core Magnetics Based Power Converters Evaluations At Cryogenic Temperature, Yuqi Wei, Md Maksudul Hossain, H. Alan Mantooth

Electrical Engineering Faculty Publications and Presentations

Cryogenic power electronics is both advantageous and indispensable in many applications, like deep space probe, military electric vehicle, magnetic resonance imaging etc. Among different semiconductors, the gallium nitride (GaN) high electron mobility transistor (HEMT) is the most promising candidate for cryogenic applications with significant conduction loss and switching loss reductions. Moreover, there is no carrier freeze out effect for the GaN HEMTs, which is applicable in extreme low temperature operating conditions. In this work, the efficiency of GaN HEMTs based power converters with different power levels (from several Watts to several kiloWatts) are evaluated at cryogenic temperature. Three different commercial …

The Impact Of Modern Buildings On Traditional Urban Environments And Urban Identity, Ann S. Ibrahim

Al-Esraa University College Journal for Engineering Sciences

Contemporary cities face significant challenges in integrating modern buildings into traditional urban environments while preserving urban identity. This study focuses on the relationship between modern architecture and urban heritage. The research problem revolves around how modern buildings affect urban identity in traditional areas, and whether they can interact positively with the urban context without distorting its traditional character.

The study aims to analyze this impact by examining a range of global examples using architectural indicators such as visual integration, spatial integration, material harmony, urban scale, accessibility, and environmental impact. A three-point scale (weak, partial, excellent) was applied to assess each …

Modeling, Control, And Fault Detection Of Energy Systems Under Limited High-Confidence Data Scenarios, Selorme K. Agbleze

Graduate Theses, Dissertations, and Problem Reports (ETD)

Abstract

Modeling, Control, and Fault Detection of Energy Systems under Limited High-Confidence Data Scenarios

Selorme K. Agbleze

Utilizing process measurements for fault detection is an established approach for processes with adequate datasets. For systems with limited high-confidence data representing fault cases and some amount of low-confidence data, few quantitative hybrid techniques exist for performing fault detection. In real systems, it is time-consuming, expensive, and sometimes not productive to generate enough high-confidence data with fault characteristics of a specific process. The problem of limited high-confidence data scenarios may also arise due to process novelty, the need for new operating conditions, or …

Development Of Probabilistic Dynamic Model Building And Bayesian Machine Learning Approaches, Samuel Oladayo Adeyemo

Graduate Theses, Dissertations, and Problem Reports (ETD)

Abstract

Development of Probabilistic Dynamic Model Building and Bayesian Machine Learning Approaches

Samuel Adeyemo

The recent years have seen a tremendous increase in the use of artificial intelligence (AI) and machine learning (ML) for the development of data-driven mathematical models needed for performing real-time optimization, model-based control, performance optimization, dynamic data reconciliation, and process performance monitoring. However, the development of data-driven models is faced with some challenges including lack of model interpretability, sensitivity of algorithm to noise in training data, limited extrapolation capabilities and violation of conservation laws. Drawing motivation from these existing gaps, this work aims to develop robust …

Development Of Dynamic Mass-Energy-Thermodynamics Constrained Hybrid Neural Network Models For Process Systems Applications, Angan Mukherjee

Graduate Theses, Dissertations, and Problem Reports (ETD)

First-principles models can provide very good predictions even for cases when there are no data at all, or data are limited in certain range of operating conditions, or for cases where data collection is infeasible. However, the development of accurate first-principles models for complex nonlinear dynamic systems can be time consuming, computationally expensive, and may be infeasible for certain systems due to lack of sufficient knowledge (information). It is also challenging to adapt first-principles models for time-varying systems. Furthermore, it can be difficult, if not impossible, to develop accurate models for some complex phenomena that are poorly understood. On the …

Investigation Of Synergistic Effect Between Polystyrene And Polyethylene Under Conventional Thermal Heating And Microwave Heating, Thang Luong

Graduate Theses, Dissertations, and Problem Reports (ETD)

Single-use plastics (Low Density Polyethylene, LDPE; Polystyrene, PS; Polypropylene, PP) are increasingly used in the modern world, with their usage growing every year. An effective method to manage the resulting waste is urgently needed, as landfilling and incineration have proven harmful to the environment in the long term. Mechanical recycling may not maintain the desirable characteristics of the single-use plastics through several cycles. Pyrolysis emerges as a promising approach to address plastic waste. Given that single-use plastic waste often comes in a mixture, combining plastic in the feedstock is a viable solution to effectively convert these polymers altogether to gain …

Application Of Predictive Control Strategies For Water-Gas Shift Membrane Reactors Using Data-Driven Models, Bernardo De Oliveira Vecchio

Graduate Theses, Dissertations, and Problem Reports (ETD)

As demand for more efficient processes keeps rising and more restrictive environmental legislation requires higher levels of both yield and purity, the process industry has now, more than ever, been looking for new ways to achieve these goals. One approach has been the implementation of Process Intensification (PI). PI aims to combine multiple unit operations into a single one, promoting efficiency gains on multiple levels. This combination, however, leads to complex process dynamics, and controlling such processes, particularly when setup as multi-input-multi-output (MIMO) systems, presents a great challenge due to highly interactive complex process dynamics and the imposition of many …

Cellular Level Changes Induced In Cancer Cells Due To Microgravity, Sai Deepika Reddy Yaram

Graduate Theses, Dissertations, and Problem Reports (ETD)

The increase in human activity in space has revealed several kinds of physiological challenges brought on by the absence of Earth's gravitational pull. NASA observed that during spaceflight, astronauts experience a 1-1.5% monthly loss in the mineral density of weight-bearing bones, with rehabilitation efforts on Earth often proving ineffective. This issue extends to muscles, the neuro vestibular system, the cardiovascular system, and vision. Cancer has emerged as a significant cause of mortality among astronauts, with studies up to 2017 showing that 41.3% of natural cause deaths among U.S. astronauts were due to cancer, primarily due to space radiation exposure. Cancer …

Triggered Online System Re-Identification Applied To Model Predictive Control Using Gaussian Processes, Daniel Augusto Kestering

Graduate Theses, Dissertations, and Problem Reports (ETD)

Safety, product quality, enhanced performance, and increased profit all depend on the control of chemical and energy processes. However, operational issues can lead to control challenges, especially when processes are subject to disturbances during their operation. Process control methods work best when processes operate close to their designed operat- ing conditions, but lack of performance or other issues may occur when the process is far from such conditions. To overcome these challenges, in this dissertation, online model re- identification is proposed for Model Predictive Control (MPC). This involves reassessing the predictive model of an advanced controller, namely MPC, when re-identification …

Dough Rheology And Its Influence On Sheeting Behavior, Najat Albarakati

Graduate Theses, Dissertations, and Problem Reports (ETD)

Dough is the starting material for a large number of baked products, including cookies, crackers and bread. In commercial food processing operations, it is desired to obtain the same product and with the same dimensions in a reproducible manner in order to minimize waste. In the case of dough, the flour used, and the nature and amount of ingredients employed depend on the specific product and the market served. This research was aimed at relating cracker dough rheology to sheeting behavior between two counter-rotating rollers. The sheet that is formed is used to punch out the crackers that are then …

Novel Membrane Materials For Nutrient Recovery From Nutrient-Rich Resources, Km Prottoy Shariar Piash

Graduate Theses, Dissertations, and Problem Reports (ETD)

Global demand for fertilizer production is expanding substantially to meet the food demand of an increasing world population. Anaerobic digestate (AD) of various centralized wastewater facilities contains substantial amounts of ammonium (NH₄⁺) (300-800 mg/L), potassium (K⁺) (13-120 mg/L), and phosphorus (P) (30-100 mg/L)- based nutrients. In addition to reducing energy costs and CO₂ emissions compared to conventional fertilizing raw material manufacturing, recovering nutrients from these waste streams could help mitigate problems such as eutrophication, which otherwise incurs billions of dollars losses to US economy annually. Apart from nutrients, wastewater streams also contain organic pollutants …