Chemical Engineering Commons^™

An Integrated Approach For Phytate Degradation And Recovery Of Myo-Inositol And Phosphate As Valued-Added Products From The By-Products Of Corn Ethanol Industry, Jun Dang

Department of Chemical and Biomolecular Engineering: Dissertations, Theses, and Student Research

An integrated process was developed to hydrolyze the phytates in light steep water (LSW) and to simultaneously isolate inorganic phosphate (Pi) and myo-inositol products. The proposed integrated process is helpful in resolving the environmental and nutritional concerns in the use of corn gluten feed (CGF) in the animal diets. This process comprised of partial and total hydrolysis of LSW and intermediate anion exchange separation technique. The phytates in LSW were initially degraded to negatively charged myo-inositol phosphates (InsP₂ - InsP₅). The optimized experimental parameters for the partial hydrolysis of LSW were determined to be 2 h hydrolysis …

Purification Of Synthetic Oligomers, Shiyue Fang

Michigan Tech Patents

This invention provides a novel method for purifying synthetic oligomers comprising capping, polymerizing and separating any failure sequences produced during oligomer synthesis. Either the failure sequence or the full-length oligomer may be polymerized. Optionally, small molecule impurities may also be incorporated into the polymerized material. The invention provides novel capping agents having a polymerizable functional group. The invention also provides kits comprising at least one composition of the present invention.

The Effects Of Electricity Pring On Phev Competitiveness, Shisheng Huang, Bri-Mathias S. Hodge, Farzad Taheripour, Joseph F. Pekny, Gintaras V. Reklaitis, Wallace E. Tyner

PPRI Digital Library

Plug-in Hybrid Electric Vehicles (PHEVs) will soon start to be introduced into the transportation sector, thereby raising a host of issues related to their use, adoption and effects on the electricity sector. Their introduction has the potential to significantly reduce carbon emissions from the transportation sector, which has led to government policies aimed at easing their introduction. If their wide-spread adoption is set as a target it is imperative to consider the effects of existing policies that may increase or decrease their adoption rate. In this study, we present a micro level electricity demand model that can gauge the effects …

Process To Produce High Surface Area Nanoparticle Vanadium Phosphorus Oxide Catalyst And Product Derives Thereof, Yun Hin Taufiq-Yap, Ali A. Rownaghi

Chemical and Biochemical Engineering Faculty Research & Creative Works

An improved process to produce high surface area nanoparticle vanadium phosphorus oxide catalysts comprises the steps of reducing vanadium-containing compounds in an alcohol solution selected from the group consisting of isobutanol and benzyl alcohol and any combination derives thereof under reflux for 4 to 6 hours to form a suspended mixture; reacting dopants and phosphorus-containing compounds to the suspended mixture under reflux for 30 minutes to 3 hours to form precursors of the vanadium phosphorus oxide catalysts; drying the formed precursors; and calcining the dried precursors in a flow of gaseous n-butane/air mixture at 400 to 460° C. to form …

“Hydraulic Fracturing Efficiency In The Olmos Sand Formation”, Lauren N. Fogarty

Honors Capstones

No abstract provided.

Doug Ruthven And Jorg Karger: Their Individual And Collective Contributions To The Field Of Zeolite Science And Engineering, Dhananjai B. Shah

Chemical & Biomedical Engineering Faculty Publications

Prof. Doug Ruthven and Prof. Jörg Kärger are two giants in the field of zeolite science and engineering. Over their academic careers encompassing almost forty years each, they have contributed significantly to the advancement of fundamental understanding of adsorption and diffusion in zeolites as well as their industrial applications. The author, in the beginning of his academic career, had an opportunity to spend two years as a post-doctoral fellow in Prof. Ruthven’s laboratory at the University of New Brunswick (1975–1977). This experience actually motivated me to spend my academic career in working in the field of zeolite adsorption and …

Petroleum Industry Linkages And Nigeria's Economic Development, Chinyere U. Nwolisa, Chinyelu N. Ugoji

Bullion

Nigeria, Africa's most populous country and potentially its largest economy, has witnessed decades of dictatorship and misrule. Accompanying this misrule are severe economic problems of an unprecedented magnitude. This paper intends to add further clues to the solution for this national developmental puzzle. The remaining part of the paper is arranged thus: Part 2 presents an overview of the Nigerian Petroleum industry while the part 3 looks at the literature of economic development the country appears to be executing. Parl4 discusses the various linkages the Petroleum industry offers visa-vis Nigeria's exploration of their potentials. The penultimate part will offer some …

Polymer (Su-8) Optofluidic Device With Embedded Hydrogel Oxygen Sensing Elements, Zhan Gao, David B. Henthorn, Chang-Soo Kim

Chemical and Biochemical Engineering Faculty Research & Creative Works

The SU-8 photopolymer is an excellent alternative for traditional materials used in fluidic devices such as glass- or silicon-Based inorganic materials. We describe a new chemically anchored, lithographically patterned hydrogel sensing element embedded in a completed SU-8 fluidic channel structure after the channel bonding process. Polyethylene glycol (PEG) hydrogel films incorporating oxygen-responsive ruthenium-complex fluorophores are grafted and patterned by photopolymerization of solution-phase precursors on the modified SU-8 channel surface. the optofluidic sensing platform with this embedded sensing elements exhibited excellent performance in measuring dissolved oxygen content. a unique advantage of this method is the selective growth of various functional films …

A Review Of The Benefits And Applications Of The Thorium Fuel Cycle, Vincent Hall

Chemical Engineering Undergraduate Honors Theses

This paper aims to inform the reader of the benefits that can be achieved by using thorium as a fuel for nuclear power. Stages of the thorium cycle are directly compared against the current uranium based nuclear fuel cycle. These include mining, milling, fuel fabrication, use of various reactor designs, reprocessing, and disposal. Thorium power promises several key advantages over traditional nuclear power methods, namely a dramatic decrease in long lived radioactive waste, increased fuel efficiency, greater chemical stability during disposal, and higher adaptability for differing reactor designs across a wider range of the thermal neutron spectrum. Obstacles that face …

Fibronectin For Use In Hemostats And Wound Stabilization In Trauma, Mohammed Halhouli

Department of Chemical and Biomolecular Engineering: Dissertations, Theses, and Student Research

Exploring the phase during wound healing when fibrinogen (FBG) and fibronectin (FN) interact forming a small thin layer for cells to migrate and proliferate at the injury site is necessary for the primary building blocks and initial stages of skin recovery. The aim of this thesis is to illustrate that administrating a reasonable amount of (FN) and FBG, in a semi-organizational technique, to the wound site will encourage cell population and ECM formation, as well as, improve the wound healing process. WE hypothesized that FBG and FN interactions will configure the construction of dermal cells and their final fate to …

Hydrothermal Reduction Synthesis Of Lifepo4 And Its Electrochemical Performance, Hong-Li Zou, Guang-Hui Zhang, Pei-Kang Shen

Journal of Electrochemistry

The cathode materials of LiFePO₄ were prepared via a hydrothermal reduction method using FeCl₃ as Fe source and iron as a reducing agent.The results showed that ferric salt could be reduced to ferrous salt completely under the hydrothermal condition and pure-phase LiFePO₄ was obtained based on the test results of XRD and FTIR.Carbon-coated LiFePO₄ was synthesized by pyrolysisng glucose at high temperature.The morphologies of pure LiFePO₄ displayed cluster-like while the LiFePO₄/C displayed sphere-like particles.The electrochemical test showed that the LiFePO₄/C had good rate performance,while LiFePO₄ delivered much lower discharge capacity.

Electrodeposition Of Lead Dioxide From Dluoroborate Solutions, Chun-Mei Kong, Yong-Ming Tang, Wen-Zhong Yang, Xiao-Yuan Yang

Journal of Electrochemistry

The PbO₂ anodes were prepared on platinum from fluoroborate media and its doped solutions by electrodeposition technique.Elecchemical and pysicochemical properties of these PbO₂ films were studied by cyclic voltammetry methods,XRD and SEM.The results showed that the presence of BF₄-increased PbO₂ electrodeposition rate;the prepared lead dioxide consisted of β-PbO₂;the preferential orientation of crystals and surface morphology were affected a lot by doping F-and Fe³⁺.The FB/F-Fe-PbO₂ electrode exhibited regular-shaped layers with compact morphology.Furthermore,increasing current density also change the preferential orientation of PbO₂ crystals.

The Sol-Gel Synthesis And Electrochemical Performance Of Li3V2(Po4)3/C Cathode Material For Lithium Ion Battery, Li-Ying Liu, Lian Chen, Hai-Yan Zhang, Yu-Chun Zhai

Journal of Electrochemistry

Li₃V₂(PO₄)₃/C was synthesized by sol-gel method with citric acid as chelate and C sources. Physical and electrochemical performances of as-prepared materials were characterized through XRD, SEM and galvanostatic charge-discharge tests,etc. The results showed that products produced by calcining at 800 ℃ for 12 h had a single phase crystal structure and relatively small particle sizes with uniform distribution. At 0.1 C, 0.5 C and 1 C, the initial specific discharge capacities were 153.0, 143.1 and 130.6 mAh·g^-1, respectively, and capacity efficiencies were 93.1%, 85.4% and 77.3% after 50 cycles, respectively. …

Effects Of Solvents And Electrolyte Salts On The Electrochemical Reduction Of Oxygen In Non-Aqueous Electrolytes, Yan-Yan Tian, Wei Wu, Jun Gao, Yong Yang

Journal of Electrochemistry

The electrochemical reduction processes of oxygen in different non-aqueous solvents such as acetonitrile(MeCN),propylene carbonate(PC) and their mixtures were investigated by cyclic voltammetry method.The results indicated a one electron reduction of oxygen to O^2-occured in these systems as a first step reduction,no matter whether in tetrabutylammonium hexafluorophosphate(TBAPF₆)/MeCN or TBAPF₆/PC electrolyte.However,the CV curves in 0.1 mol·L^-1 TBAPF₆/MeCN showed a couple of reversible redox peaks,indicating that the reduction process of oxygen was irreversible in the 0.1 mol·L^-1 TBAPF₆/PC electrolyte.In the PC-based electrolyte,the reduction current peak reduced largely and the oxidation peak …

The Conversion Of Low-Grade Heat Into Power Using Supercritical Rankine Cycles, Huijuan Chen

USF Tampa Graduate Theses and Dissertations

Low-grade heat sources, here defined as below 300 ºC, are abundantly available as industrial waste heat, solar thermal, and geothermal, to name a few. However, they are under-exploited for conversion to power because of the low efficiency of conversion. The utilization of low-grade heat is advantageous for many reasons. Technologies that allow the efficient conversion of low-grade heat into mechanical or electrical power are very important to develop.

This work investigates the potential of supercritical Rankine cycles in the conversion of low-grade heat into power. The performance of supercritical Rankine cycles is studied using ChemCAD linked with customized excel macros …

Enhancing Oxygen Reduction Reaction Activity Via Pd-Au Alloy Sublayer Mediation Of Pt Monolayer Electrocatalysts, Yangchuan Xing, Yun Cai, Miomir B. Vukmirovic, Wei Ping Zhou, Hiroko Karan, Jia X. Wang, Radoslav R. Adzic

Chemical and Biochemical Engineering Faculty Research & Creative Works

New Pt monolayer electrocatalysts were prepared using galvanic displacement of a copper monolayer deposited at underpotentials on a Pd core. by performing underpotential deposition twice, two monolayers were deposited, forming a core-shell structure with double shells. the double shells consist of an outermost shell of Pt monolayer and a sublayer shell of Pd-Au alloy. It was found that by adjusting the compositions of the alloy sublayer, it is possible to mediate the oxygen reduction reaction (ORR) activity of the Pt catalysts. an alloy with 10% (atomic) Au was found to be the most active among the catalysts tested. Furthermore, the …

Simulation On The Use Of Losat Data For Rice Field Mapping, Bambang H. Trisasongko, Dyah R. Panuju, Boedi Tjahjono, Baba Barus, Hari Wijayanto, Mahmud A. Raimadoya, Irzaman Irzaman

Makara Journal of Technology

Simulation on the Use of LOSAT Data for Rice Field Mapping. Since the launch of LAPAN-TUBSAT satellite in 2007, Indonesia has been developing mission on earth observation missions for various applications. The next generation mission, called LAPAN-ORARI Satellite (LOSAT), is currently under development and expected to be launched in 2011. In order to facilitate the applications, a thorough assessment of the sensor should be made. This paper presents an examination of simulated LOSAT data for rice monitoring and mapping purposes coupled with QUEST statistical tree. We found that three-band simulated LOSAT data were suitable for the task with reasonably high …

An Empirical Model For Build-Up Of Sodium And Calcium Ions In Small Scale Reverse Osmosis, Subriyer Nasir

Makara Journal of Technology

A simple models for predicting build-up of solute on membrane surface were formulated in this paper. The experiments were conducted with secondary effluent, groundwater and simulated feed water in small-scale of RO with capacity of 2000 L/d. Feed water used in the experiments contained varying concentrations of sodium, calcium, combined sodium and calcium. In order to study the effect of sodium and calcium ions on membrane performance, experiments with ground water and secondary effluent wastewater were also performed. Build-up of salts on the membrane surface was calculated by measuring concentrations of sodium and calcium ions in feed water permeate and …

The Effect Of Enzymatic Hydrolysis On The Properties Of Protein Hydrolysate From Paddy Mushroom, Niken Widya Palupi, Wiwik Siti Windrati, Tamtarini Tamtarini

Makara Journal of Technology

Protein hydrolysate was prepared from Paddy (Volvariella volvaceae) mushroom. Hydrolysis uses commercially protease available Protamex ™ with enzyme concentration of 0.1% (w/w). Hydrolysis was performed at three different temperatures (room temperature, 40 °C, and 50 °C) with different incubation periods (60, 90, and 120 minutes). Enzyme inactivation was done in 90 °C for 3 minutes. Yield and degree of hydrolysis ranged from 94.76% to 99.55% and 19.06% to 24.59%. Protein solubility was about 89–11,8%. The longer time of hydrolysis, the darker the color of protein hydrolysate. Protein hydrolysate which has hydrolysis at 50 °C for 120 minutes has the highest …

Effect Of Diafiltration On Preparation Of Fermented Mung Beans Concentrate As Probiotic Savory Flavor Through Ultrafiltration Membrane, Aspiyanto Aspiyanto, Agustine Susilowati

Makara Journal of Technology

Diafiltration by means of the ultrafiltration system of probiotic fermented Mung beans (Phaseolus radiatus L.) concentrate has been performed to reduce or eliminate salts and smaller impurities than the nominal cut-off of the membrane of 20,000 nominal weight cut-off (NWCO). These processes have been conducted as an attempt in order to get a probiotic product with organoleptic acceptability, composition, and the optimal total lactic acid bacteria (LAB) counts because the presence of salts will affect on the viability of LAB and the cell lysis of LAB and limit its utility in food products. Concentrate of probiotic mung beans was prepared …