Chemical Engineering Commons^™

Alos/Palsar Image Processing Using Dinsar And Log Ratio For Flood Early Detection In Jakarta Based On Land Subsidences, Dodi Sudiana, Mia Rizkinia

Makara Journal of Technology

Flood that occurred in Jakarta is not only influenced by rainfall, urban planning system and drainage alone, but also may be involved land subsidence (LS). LS is possible in because Jakarta stands on top of layers of sediments and the presence of ground water consumption in very large quantities. In this research, the Advanced Land Observing Satellite (ALOS)/Phased Array type L-band Synthetic Aperture Radar (PALSAR) data was processed to determine the level of LS in Jakarta area and its relation to flood potential area. Differential interferometry method (DInSAR) was performed on two PALSAR data with different acquisition years, i.e. 2007 …

Analytical And Computational Simulation Approaches To Design Low Energy Glass Block, Floriberta Binarti, Agustinus Djoko Istiadji, Prasasto Satwiko, Priyo Tri Iswanto

Makara Journal of Technology

Analytical and Computational Simulation Approaches to Design Low Energy Glass Block. An environmentally friendly process was developed to produce a low embodied energy glass block from waste glasses. The energy efficiency of the glass block is represented by its thermal conductance (U)

Improvement Of High Temperature Oxidation Of Low Carbon Steel Exposed To Ethanol Combustion Product At 700 °C By Hot-Dip Aluminizing Coating, Mohammad Badaruddin

Makara Journal of Technology

Low carbon steel (AISI 1005) was coated by hot-dipping into a molten Al-10% Si bath at 700 °C for 18s. After hotdipping treatment, the coating layers consisted of Al, Si, FeAl3, τ5-Fe2Al8Si, and Fe2Al5. The bare steel and the aluminized steel were isothermally oxidized at 700 °C in ethanol combustion product at atmospheric pressure for 49 h. The aluminized steel shows good performance in high temperature oxidation because the formation of Al2O3 layer on the coating surface. The growth of iron oxide nodules on the surface coating was accelerated by rapid outward diffusion of Fe-ions due to the presence of …

Establishment Code Hand Palm (Palm Code) 2d Gabor-Based Method, I Ketut Gede Darma Putra, Wira Bhuana, Erdiawan Erdiawan

Makara Journal of Technology

Establishment Code Hand Palm (Palm Code) 2D Gabor-Based Method. Palmprint is relatively new in physiological biometrics. Palmprint ROI segmentation and feature extraction are two important issues in palm print recognition. This paper introduces two steps in the center of mass moment method for ROI segmentation that will be applied in the Gabor 2D filter to obtain palm code as palmprint feature vector. Normalized Hamming distance was used to measure the similarity degrees of two feature vectors of palmprint. The system was tested using database 1000 palmprint images generated from 5 samples from each of the 200 persons randomly selected with …

Flutter Analysis Of Rx-420 Balistic Rocket Fin Involving Rigid Body Modes Of Rocket Structures, Novi Andria

Makara Journal of Technology

Flutter Analysis of RX-420 Balistic Rocket Fin Involving Rigid Body Modes of Rocket Structures. Flutter is a phenomenon that has brought a catastrophic failure to the flight vehicle structure. In this experiment, flutter was analyzed for its symmetric and antisymmetric configuration to understand the effect of rocket rigid modes to the fin flutter characteristic. This research was also expected to find out the safety level of RX-420 structure design. The analysis was performed using half rocket model. Fin structure used in this research was a fin which has semispan 600 mm, thickness 12 mm, chord root 700 mm, chord tip …

Flexible Connection Elastomeric Rubber As A Pounding Resisting Element Between Two Adjacent Buildings, Yuskar Lase, James Jatmiko Oetomo

Makara Journal of Technology

Flexible Connection Elastomeric Rubber as a Pounding Resisting Element between Two Adjacent Buildings To solve pounding problem of two adjacent buildings, structural designer usually employs a dilatation between the structures or make the two structures as a monolith structure. Other alternative is by using an elastomeric rubber as a pounding resisting element between the two structures. Effectiveness in applying elastomeric rubber component as flexible connection of two adjacent structures is the main focus of this paper. Various simulations such as structure models, earthquake excitations and openings in gap element are studied. Observation of maximum structural responses will be performed for …

Optimation Of Nitrogen And Phosphorus In Azolla Growth As Biofertilizer, Hany Handajani

Makara Journal of Technology

Nitrogen is one of the most important minerals for living organisms. Azolla is known as a small water fern which can fix nitrogen through the symbiotic association with the blue green algae Anabaena. Experimental studies were carried out in the glass house, investigating the growth of Azolla using different levels of nitrogen and phosphorus in the media. The experiment used 12 treatments with 3 levels of nitrogen (0, 5, and 10 mg atom/L) and 4 levels of phosphorus (0, 10, 20, and 30 mg atom/l) in a factorial design with 3 replicates. The results show that the highest biomass for …

Application Of Principal Component Proximity Transform And Geostatistics Methods For Volume Shale Distribution As Reservoir Characreristic Imaging In Seismic 3d, Nur Islami

Makara Journal of Technology

Application of Principal Component Proximity Transform and Geostatistics Methods for Volume Shale Distribution as Reservoir Characreristic Imaging in Seismic 3D. Principal component proximity transform (PCPT) technique was used to predict the content of volume shale into seismic data in reservoir modeling framework. The goal in this research is to get the volume shale imaging in three dimensions and allow for reservoir modelling. The reservoir modelling requires an integrated quantitative and qualitative data sources collected separately, such as well and seismic data. Integrating PCPT and Geostatistic methods can generate the detail information for characterization of reservoir’s properties. Finally, it shows that …

Antibacterial Activity Of Papaya Leaf Extracts Against Pathogenic Bacteria, Elisa Friska Romasi, Jessica Karina, Adolf Jan Nexson Parhusip

Makara Journal of Technology

It was reported that the extracts of papaya leaves could inhibit the growth of Rhizopus stolonifer. Antibacterial activity of Carica papaya leaf extracts on pathogenic bacteria was observed in this study. Papaya leaves were extracted by using maceration method and three kinds of solvents: ethanol, ethyl acetate, and hexane. Papaya leaf extracts were tested against Bacillus stearothermophilus, Listeria monocytogenes, Pseudomonas sp., and Escherichia coli by agar diffusion method. The objectives of this study were to determine extract ability against pathogenic bacteria, to observe the influence of pH, NaCl, and heat on extracts ability, and to observe extract ability against B. …

Giant Magnetostriction In Annealed Co1-XFeX Thin-Films, Dwight Hunter, Will Osborn, Ke Wang, Nataliya Kazantseva, Jason R. Hattrick-Simpers, Richard Suchoski, Ryota Takahashi, Marcus L. Young, Apurva Mehta, Leonid A. Bendersky, Same E. Lofland, Manfred Wuttig, Ichiro Takeuchi

Faculty Publications

Chemical and structural heterogeneity and the resulting interaction of coexisting phases can lead to extraordinary behaviours in oxides, as observed in piezoelectric materials at morphotropic phase boundaries and relaxor ferroelectrics. However, such phenomena are rare in metallic alloys. Here we show that, by tuning the presence of structural heterogeneity in textured Co_1−xFe_x thin films, effective magnetostriction λeff as large as 260 p.p.m. can be achieved at low-saturation field of ~10 mT. Assuming λ100 is the dominant component, this number translates to an upper limit of magnetostriction ofλ100≈5λeff >1,000 p.p.m. Microstructural analyses …

Comparison Of Microwave And Conventionally Sintered Yttria-Doped Zirconia Ceramics, Colin J. Reidy, Thomas J. Fleming, Stuart Hampshire, Mark R. Towler

Chemical and Biochemical Engineering Faculty Research & Creative Works

This paper reports on improvement of the physical and mechanical properties of Y₂O₃-ZrO₂ ceramics through compositional optimization, the use of nanograined powders and utilization of microwave sintering. ZrO₂ with 2-5 mol% Y₂O₃, prepared from nanopowders, was sintered in both conventional and microwave furnaces under exactly the same heating schedule. It was found that microwave sintering improves physical and mechanical properties of Y₂O₃-ZrO₂ ceramics compared with conventional sintering. Compositions containing 2 mol% Y₂O₃ exhibit the greatest improvement due to retention of tetragonal ZrO …

Supported Monoethanolamine For Co2 Separation, Morris D. Argyle, Zhuoyan Sun, Maohong Fan

Faculty Publications

An alternative method for using monoethanolamine (MEA) in CO2 separation is developed from the viewpoints of the MEA-CO2 reaction environment and the process of spent sorbent regeneration. The method could be used to considerably reduce energy consumption compared to conventional aqueous MEA processes. MEA-TiO2 (MT) CO2 sorbent is synthesized using pure MEA and a support material, TiO2. The performance of the MT sorbent on CO2 separation was investigated in tubular reactors under various experimental conditions. The effects of several major factors on CO2 sorption by the MT sorbent were investigated. The sorption capacity of the MT sorbent increased with MEA …

Computational Studies Of Ion Transport In Polymer Electrolytes, Hui Wu

Doctoral Dissertations

Improving ionic conductivity and lithium mobility in polymer electrolytes is important for their practical use for battery electrolytes. In this study, a combination of molecular dynamics and Monte Carlo simulations was used to bring insight into lithium ion transport in poly(ethylene oxide) (PEO) with plasticizers and also next to alumina solid surface doped with lithium salt. The simulations were performed using a moderately high molecular weight polymer (Mn = 10,000 g/mol) at an EO:Li ratio of 15. For the plasticized system, the PEO with LiN(CF3SO 2)2 (LiTFSI) was mixed with 10 wt% plasticizers that included either cyclic ethylene carbonate …

Role Of Ammonia In The Activiation Of Methanol Dehydrogenase/Cytochrome C(L) Enzyme, Ancy Kunjumon

Doctoral Dissertations

Recent advancement in enzyme catalysis has opened ways to design efficient biocatalysts, bio-sensors and bio-fuel cells. An in-depth knowledge about the mechanism of the reaction taking place within the enzymes is of great importance to achieve these goals. In this dissertation, various computation methods are applied to investigate the mechanism behind enzyme catalysis in the presence of compounds called activators.

Methanol dehydrogenase (MDH) is a well-known bio-catalyst that can oxidize excess of methanol from the environment to formaldehyde. The enzyme works well within the bacterial environment, but under in vitro, it loses activity. Ammonia is used as an activator …

Polymorphic Structures Of Alzheimer's Beta-Amyloid Globulomers, Jie Zheng

Chemical, Biomolecular, and Corrosion Engineering Faculty Research

Misfolding and self-assembly of Amyloid-β (Aβ) peptides into amyloid fibrils is pathologically linked to the development of Alzheimer's disease. Polymorphic Aβ structures derived from monomers to intermediate oligomers, protofilaments, and mature fibrils have been often observed in solution. Some aggregates are on-pathway species to amyloid fibrils, while the others are off-pathway species that do not evolve into amyloid fibrils. Both on-pathway and off-pathway species could be biologically relevant species. But, the lack of atomic-level structural information for these Aβ species leads to the difficulty in the understanding of their biological roles in amyloid toxicity and amyloid formation.

Evaluation Of Dye And Pigment Based Ink Jet Ink Sets, Veronika Chovancova

The Hilltop Review

The development of high performance inkjet printers and inks is advancing rapidly. Manufacturers seem to introduce their new technology inks to the market on an almost daily basis. Chemists in ink laboratories are still fighting with the issue of combining a wide gamut of dye-based inks with the lightfast and weather resistance qualities of pigment-based inks into new-age ink formulations.

Three different inkjet printers and inks were investigated in this work: the Epson Stylus® Pro 5000, using a dye-based ink set, the Epson Stylus® Pro 5500, employing Archival ink technology, and the Epson Stylus® Photo 2200, with 7-color UltraChrome™ inks. …

Effects Of Pressure On The Properties Of Coal Char Under Gasification Conditions At High Initial Heating Rates, Randy C. Shurtz

Theses and Dissertations

The effects of elevated pressure and high heating rates on coal pyrolysis and gasification were investigated. A high-pressure flat-flame burner (HPFFB) was designed and built to conduct these studies. The HPFFB was designed to provide an environment with laminar, dispersed entrained flow, with particle heating rates of ~10^5 K/s, pressures of up to 15 atm, and gas temperatures of up to 2000 K. Residence times were varied from 30 to 700 ms in this study. Pyrolysis experiments were conducted at particle heating rates of ~10^5 K/s and maximum gas temperatures of ~1700 K at pressures of 1 to 15 atm. …

The Study Of Ink Pigment Dispersion Parameters, Lokendra Pal, Paul D. Fleming Iii

The Hilltop Review

The purpose of this study was to investigate the influence of rotation speed and milling time on the pigment dispersion quality. The information can be used to obtain a standard laboratory condition at which a wide range of pigments may be dispersed to formulate water-based rotogravure inks. The influence of pigment concentration and shear forces on the pigment dispersion were also studied.

The procedure consisted of dispersing the pigment using a laboratory Dispermat® SL bead mill at various milling times with two different rotation speeds and measuring the particle size and particle size distribution of the milled samples. The pigment …

Phospholipid Transport In Silicon Hydrogel Contact Lenses, Yibei Zhao

Theses and Dissertations

Dry eye syndrome has been associated with the lack of phospholipids in the tear film, leading to disruption of the tear film and subsequent irritation. Characterization of the transport and release of phospholipids from a silicone hydrogel contact lens is required to assess the possible use of these lenses for phospholipid delivery to increase patient comfort. This thesis examines the use of silicone hydrogel contact lenses as phospholipid delivery devices. Contact lenses of silicone hydrogel composition were loaded with varying amounts of radiolabeled 1,2-dimyristoyl-sn-glycero-3-phosphocholine (DMPC) from a solution of n-propanol. These lenses were eluted at 35°C into artificial …

A Modified Surface On Titanium Deposited By A Blasting Process, Caroline O' Sullivan, Peter O'Hare, Greg Byrne, Liam O'Neill, Katie B. Ryan, Abina M. Crean

Publications

Abstract

: Hydroxyapatite (HA) coating of hard tissue implants is widely employed for its biocompatible and osteoconductive properties as well as its improved mechanical properties. Plasma technology is the principal deposition process for coating HA on bioactive metals for this application. However, thermal decomposition of HA can occur during the plasma deposition process, resulting in coating variability in terms of purity, uniformity and crystallinity, which can lead to implant failure caused by aseptic loosening. In this study, CoBlast™, a novel blasting process has been used to successfully modify a titanium (V) substrate with a HA treatment using a dopant/abrasive regime. …