Chemical Engineering Commons^™

Biofuels Production From Hydrotreating Of Vegetable Oil Using Supported Noble Metals, And Transition Metal Carbide And Nitride, Huali Wang

Wayne State University Dissertations

The focus of this research is to prepare non-sulfided hydrotreating catalysts, supported noble metal and transition metal carbide/ nitride, and evaluate their hydrocracking activities and selectivities by using soybean oil as the feedstock. For comparison study, catalytic cracking of soybean oil over a commercialized ZSM-5 was investigated. However, steady state could not be reached because significant amounts of tar and coke were generated during the reaction though a high yield (21%) of jet fuel was obtained from the process. Compared to the catalytic cracking process, less tar and coke were formed during the hydrocracking process and stable continuous flow reaction …

New Precursors And Chemistry For The Growth Of Transition Metal Films By Atomic Layer Deposition, Thomas Joseph Knisley

Wayne State University Dissertations

The advancing complexity of advanced microelectronic devices is placing rigorous demands on currently used PVD and CVD deposition techniques. The ALD deposition method is proposed to meet the film thickness and conformality constraints needed by the semiconductor industry in future manufacturing processes. Unfortunately, there is a limited number of chemical precursors available that have high thermal stability, reactivity, and vapor pressure suitable for ALD film growth to occur. These properties collectively contribute to the lack of suitable transition metal precursors available for use in ALD. In this thesis, we report the discovery of a series of novel transition metal diazadienate …

Investigation Of Wellbore Stability In A North Sea Field Development, Steven Austin Hilgedick

Doctoral Dissertations

"Planning drilling operations is key to the development of oil and natural gas fields. As part of well design, wellbore stability and pore pressure analysis are main factors in determining the safe operating window for selecting mud density. The motivation for this research was to conduct wellbore stability based on exploration wells as basis for planning new offshore field developments with deviated and horizontal wells. A second objective was to investigate the use of a probabilistic approach to wellbore stability, and compare it to the conventional deterministic methods, in order to evaluate the value of including a probabilistic approach to …

Modeling Carbon Sequestration In Transition Zone To Optimize Storage Potential, Fang Yang

Doctoral Dissertations

"Shallow aquifers are potential candidates for carbon sequestration because of their wide distribution and low injection cost. Injected CO₂ in a shallow region segregates into two zones according to CO₂ phases within the initial reservoir pressure and the maximum bottom hole pressure: gas zone and transition zone. Transition zone is a better option because of favorable CO₂ properties. This work investigated the CO₂ storage potential in transition zone using the compositional simulator CMG-GEM and a design of experiment software iSIGHT. First, it addressed the basic characteristics of CO₂ sequestration in transition zone, and then modeled CO₂ injection with simultaneous water …

Global Homotopy Continuation And Stability Analysis: Optimal Application To Chemical Engineering Design, David Anthony Harney

Doctoral Dissertations

"The design of chemical engineering process equipment routinely necessitates the solution of large systems of non-linear equations. The processing speed of standard desktop computers have allowed for equation-oriented process simulators to become commercially viable. For a fully equation-oriented simulator to be competitive with standard iterative solvers, a robust and reliable non-linear equation solver is required and standard Newton methods fail to provide the necessary reliability.

Homotopy continuation methods have been proposed as a way to greatly expand the domain of convergence of the process simulator's equation solving algorithm. This research expands upon existing homotopy continuation algorithms, investigates bounding algorithms, corrector …

Development Of Eco-Friendly Flame Retardant Fabric Using Phosphorus Based Intumescence Chemistry, Vikas P. Joshi

Master's Theses and Doctoral Dissertations

The research aims at developing Eco-friendly flame retardant textile fabric using phosphorous based intumescence chemistry. Phosphorous in the structure of Spirocyclic pentaerythriol diphosphoryl chloride (SPDPC) acts as the main group to impart flame retardancy. Intermediate compounds were synthesized in the laboratory and finally converted into sol. The silane sol was applied to the textile material using pad-dry-cure method. The intermediate compounds and the coated material were tested using Fourier transform infrared spectroscopy (FTIR), Differential scanning calorimeter (DSC), and Thermogravemetric analysis (TGA) testing instruments. Vertical flammability testing was performed as per ASTM D-6413 standards to test the fabric for its flame …

Polymeric Nanocarriers For The Regional And Systemic Delivery Of Therapeutics To And Through The Lungs, Balaji Bharatwaj

Wayne State University Dissertations

The lungs are considered as one of the fastest portals of entry to the bloodstream and oral inhalation (OI) has long been accepted as the preferred mode of administration of therapeutics to the respiratory tract. However, despite its advantages, the lungs have been largely underutilized to target ailments not only of systemic relevance but also several other grave conditions including lung cancer and tuberculosis. Polymeric nanocarriers (PNCs) have several advantages over other drug delivery vehicles including sustained release of moieties, ease of cellular internalization and improved targeting, and hence hold the promise to greatly augment the potential of OI therapies. …

Catalytic Effects Of Period Iv Transition Metal In The Oxidation Of Biodiesel, Bradley Clark

Wayne State University Theses

CATALYTIC EFFECTS OF PERIOD IV TRANSITION METALS IN THE OXIDATION OF BIODIESEL

BRADLEY R CLARK

December 2011

Advisors: Dr. Steve Salley, Dr. Simon Ng, Dr. Naiem Henien

Major: Alternative Energy Technology

Degree: Masters of Science

Transition metals have the ability to catalyze free radical autoxidation of unsaturated fatty acid methyl esters (i.e., biodiesel). The catalytic effects of the eight period IV transition metals: V, Cr, Mn, Fe, Co Ni, Cu and Zn in soybean oil and cottonseed oil-based biodiesel are investigated. All metals produced a reduction of the induction period of biodiesel, although there are considerable differences in their catalytic …

Room Temperature Ionic Liquid (Rtil) Membranes For Bio-Methane Dehumidification, Ryan Amos

Electronic Theses and Dissertations

Renewable fuels are heavily researched due to the increasing price of and resulting pollution from fossil fuels. The production of useable energy from waste—animal, sewage, discarded food, landfill matter would be a valuable renewable fuel production method. Biogas is a renewable fuel that is produced by anaerobic digestion, composed mainly of methane, carbon dioxide and small percentages of hydrogen sulfide and water vapor. Before this biogas—predominately bio-methane—can be converted to fuel, it must be dehumidified to become useable. Typically membrane-based gas dehumidification uses hydrophilic polymer membrane materials, such as polydimethylsiloxane (PDMS) and cellulose acetate (CA). The main problems with polymer …

A Fractal Analysis Of The Detection Of Glucose Molecules On Biosensor Surfaces, Lokesh Taneja

Electronic Theses and Dissertations

A fractal analysis for the binding and dissociation of glucose molecules to different biosensor surfaces is presented. The sensors contain immobilized glucose oxidase enzymes that have an affinity for the glucose molecules in solution. Data for different modified biosensors is modeled and analyzed, and a single, dual or triple-fractal analysis is applied where adequate. The binding and dissociation kinetics coefficient where applicable are calculated for each of models along with the fractal dimensions. When both binding and dissociation phases are present, the affinity, K of the receptor to the glucose molecule is calculated and its variation with the fractal dimension …

Thermal And Photochemical Interaction Of Co2 With Biochar, Eneruvie Uyoyou Okinedo

Electronic Theses and Dissertations

With interest in the changes that may occur to the carbonaceous portion of biochar obtain through the pyrolysis of biomass, the simple interaction between CO2 and biochar with water or a mixture of water and ethanol as hydrogen donor resulted in three significant observations. These reactions were carried out thermally at 333K and photochemically by simulating energy from the with a xenon lamp. The photochemical reaction involving biochar, CO2 with water or a mixture of water and ethanol as hydrogen donor led to a decrease in oxygen content of the parent biochar material, as observed by an increase in the …

Computational Analysis Of Conjugate Heat Transfer And Particulate Deposition On A High Pressure Turbine Vane, Weiguo Ai, Thomas H. Fletcher

Faculty Publications

Numerical computations were conducted to simulate flash deposition experiments on gas turbine disk samples with internal impingement and film cooling using a computational fluid dynamics (CFD) code (FLUENT). The standard k-epsilon turbulence model and Reynoldsaveraged Navier–Stokes were employed to compute the flow field and heat transfer. The boundary conditions were specified to be in agreement with the conditions measured in experiments performed in the BYU turbine accelerated deposition facility (TADF). A Lagrangian particle method was utilized to predict the ash particulate deposition. Userdefined subroutines were linked with FLUENT to build the deposition model. The model includes particle sticking/rebounding and particle …

Design Mixers To Minimize Effects Of Erosion And Corrosion Erosion, Julian B. Fasano, Eric E. Janz, Kevin J. Myers

Chemical and Materials Engineering Faculty Publications

A thorough review of the major parameters that affect solid-liquid slurry wear on impellers and techniques for minimizing wear is presented. These major parameters include (i) chemical environment, (ii) hardness of solids, (iii) density of solids, (iv) percent solids, (v) shape of solids, (vi) fluid regime (turbulent, transitional, or laminar), (vii) hardness of the mixer's wetted parts, (viii) hydraulic efficiency of the impeller (kinetic energy dissipation rates near the impeller blades), (ix) impact velocity, and (x) impact frequency. Techniques for minimizing the wear on impellers cover the choice of impeller, size and speed of the impeller, alloy selection, and surface …

A Review Of Some Subtleties Of Practical Relevance, Keqin Gu

SIUE Faculty Research, Scholarship, and Creative Activity

This paper reviews some subtleties in time-delay systems of neutral type that are believed to be of particular relevance in practice. Both traditional formulation and the coupled differential-difference equation formulation are used. The discontinuity of the spectrum as a function of delays is discussed. Conditions to guarantee stability under small parameter variations are given. A number of subjects that have been discussed in the literature, often using different methods, are reviewed to illustrate some fundamental concepts. These include systems with small delays, the sensitivity of Smith predictor to small delay mismatch, and the discrete implementation of distributed-delay feedback control. The …

Formation Of Amyloid Fibrils By Diblock Peptides, Kunal Mukesh Naik

Masters Theses

"The objective of this study was to identify and then synthesize a series of peptides which were able to form fibrils rich in ß-sheet structure and to study the effect of the presence of surfaces on their formation. We decided to focus our experimental work on a family of peptides containing one "beta-sheet forming amino acid" and one 'alpha-helix forming amino acid'. This selection covers a wide range of hydrophillicites and charges and, by avoiding highly hydrophobic amino acids we can assure that the diblock peptides are soluble in a wide range of concentrations and solvent conditions. Three different diblocks …

Investigation Of Drillstring Vibration Reduction Tools, Mohammed Fayez Al Dushaishi

Masters Theses

"Drilling related problems such as drillstring vibration is an important cause of premature failure of drillstring components and drilling inefficiency. The vibration of drillstring interferes with measurement collected while drilling. In severe cases, drillstring vibration will lead to wellbore instability that will result in an increase in the operation cost. In the late 1980's, a lot of studies and techniques were developed to mitigate drillstring vibration and downhole vibration measurements were introduced to the industry in two forms; real time measurements and memory devices measurements

A study of drillstring vibration of three different wells located in the Norwegian North Sea …

Hydraulic Fracturing Experiments To Investigate Circulation Losses, Maximiliano Liberman

Masters Theses

"In recent years the oil and gas industry has been drilling more challenging wells due to long deviated wells, drilling through already depleted reservoirs, sub salt wells and increasing water depth. A major challenge these wells create is to prevent fluid loss into the formation and wellbore breakouts by having accurately determined the mud weight operational window. In addition to accurately determine the fracture gradient, additives in the drilling fluid have been used to enhance the fracture gradient in an industry process named wellbore strengthening. In order to study the phenomenon of fracture gradient alteration, a hydraulic fracturing apparatus was …

Investigation Of Geosteering In Non-Trivial Geological Settings, Anuroop Pandey

Masters Theses

"The well placement technology has advanced to a stage where we can explore small tolerance targets such as thin reservoirs. Well placement with geosteering, which is the real time adjustment of the well path based on the geological responses to place and maintain the well within the best part of the reservoir, is the technology that has made this progress possible. Geosteering however can get very complex with the increasing heterogeneities of the formations and there is no fixed methodology to devise a steering strategy in such complex geological settings. To accommodate this challenge, we investigated three methods to verify …

Surfactant Enhanced Oil Recovery By Wettability Alteration In Sandstone Reservoirs, Omar Elmofty

Masters Theses

"Recovering more oil from existing oil reservoirs using enhanced oil recovery methods holds the key for meeting future energy demands. Even though wettability is a cornerstone in oil recovery, few studies have focused on increasing oil recovery in sandstone reservoirs through wettability alteration. The objective of this thesis is to prove that altering the wettability of a sandstone rock to preferentially water-wet condition will reduce the remaining oil saturation and thus increase the percentage of recovered oil.

Two commercial surfactants were selected after studying both the phase behavior and the interfacial properties of 30 surfactants with oil and 1.00% sodium …

Geomechanical Characterization Of Reservoir & Cap Rocks For Co₂ Sequestration, Sudarshan Govindarajan

Masters Theses

"Geological sequestration of CO₂ has been identified as one method to reduce global emissions of CO₂ and achieve lower levels of CO₂ concentrations in the atmosphere. Geological formations have to be assessed in terms of their capacity, sealing capabilities and economic feasibility before CO₂ sequestration can commence. Potential leakage of injected CO₂ from the reservoir formation could occur due to natural or injection induced faults or fractures in the reservoir or sealing formations. As part of a potential leakage investigation a geomechanical characterization which refers to the assessment of the in-situ stress conditions, rock strength and stiffness properties of the …