Chemical Engineering Commons^™

Metabolic Comparison Of Wild-Type And Transgenic Synechocystis Pcc 6803 Cyanobacteria, Ian A. Mcluckey, John A. Morgan, Joel Yu King Hing

The Summer Undergraduate Research Fellowship (SURF) Symposium

The Calvin-Benson (CBB) cycle is an essential part of nature. This phenomenon allows carbon molecules in carbon dioxide from the atmosphere to be converted into useful energy in the form of sugars. Cyanobacteria are single-celled organisms capable of utilizing energy from sunlight to drive this cycle and are also readily engineered. In hopes of improving this cycle, we compared a wild-type version of the Synechocystis PCC6803 cyanobacteria to an engineered version overexpressing the enzyme FBA (fructose-biphosphate aldolase), called 70 glpX, to deduce how the overexpressing strain is able to be more photosynthetically efficient. To do this, comparative metabolomics were done …

Modal Phonon Transport Across Interfaces By Non-Equilibrium Molecular Dynamics Simulation, Yang Zhong, Tianli Feng, Xiulin Ruan

The Summer Undergraduate Research Fellowship (SURF) Symposium

Phonons represent the quantization of lattice vibration, responsible for heat transfer in semiconductors and dielectrics. Phonon heat conduction across interfaces is crucially important for the thermal management of real-life devices such as smartphones, electric vehicles, and satellites. Although recent studies have broadly investigated spectral phonon contribution to lattice thermal conductivity, the mechanism of phonon modal transport across interfaces is still not well-understood. Previous models, including the acoustic mismatch model (AMM) and diffuse mismatch model (DMM), only consider elastic process while neglecting inelastic phonon contributions. Herein, we employ spectral Non-Equilibrium Molecular Dynamics Simulation (NEMD) to probe the temperature and heat flux …

Spectroscopic Contrast Of Diarylethene Molecules On Octanethiol Monolayer, Arramel Arramel, Tibor Kudernac, Nathalie Katsonis, Bernard Lucas Feringa, Bart Jan Van Wees

Makara Journal of Technology

We present a systematic scanning tunneling microscopy (STM) study of bias-dependent imaging of disulfur diarylethene (2S-DE) molecules on octanethiol (C8) monolayer at room temperature. In a rigid confinement of the C8 matrix, we did not observe any significant variation in the appearance of the 2S-DE. On the contrary, a reversal in the apparent height of the 2S-DE was present when the molecule was situated on a gold vacancy island. We attributed this finding to the presence of a new electronic state that became accessible for a tunneling event. In addition, the C8 surface structure underwent a reversible phase transformation from …

Residual Stress Measurements On The Tig Weld Joint Of 57fe15cr25ni Austenitic Steel For Structural Material Applications By Means X-Ray Diffraction Techniques, Parikin Parikin, Agus Hadi Ismoyo, Riza Iskandar, Arbi Dimyati

Makara Journal of Technology

Measurements of residual stress on the 57Fe25Cr15Ni steel plate with no-filler TIG-welding process were carried out. This work was conducted to determine the nature of weld ability in synthesized steel. The bulks were formed in a dimension of 30x20x7 mm3 to ease data retrieval. Results show that the largest residual stress occurred in the weld metal area, amounting to 82.40 MPa with lattice stretching of 0.18%. Conversely, the values decreased to 65.92 MPa and a stretch of 0.14% in the HAZ area. This residual stress is a tensile stress that can reduce the mechanical strength of the material since it …

An Efficient Palladium-Thiourea Catalysed Heck Cross-Coupling Reaction For Molecular Electronic Interest, Wan M. Khairul, Mohd Shahrul Shahmi Md Shariff, Rafizah Rahamathullah, Adibah Izzati Daud, Mustaffa Shamsuddin, Siti Kamilah Che Soh

Makara Journal of Technology

The synthesis and utilization of C-C bonds formation are concerned about the key steps for the building of several conducting molecular electronics involving many asymmetric catalysts approached, which is an essential task that most researchers would ignore in preparing these materials to enhance the production yield of cross-coupling materials. Despite the enormous progress, there still remains a great demand for economic and practicable cross-coupling processes involving ultra-low catalyst loadings with high turnover numbers due to the employment of conventional metal catalyst. Thus, there has been an excessive interest to cultivate non-phosphine palladium catalysts for excellent achievement of activity, stability, and …

A Study On Dielectric Properties Of The Cellulose Derivative-Nh4br-Glycerol- Based The Solid Polymer Electrolyte System, Nur Muhitul Jalilah Rasali, Saifful Kamaluddin Muzakir, Ahmad Salihin Samsudin

Makara Journal of Technology

The characterization of biopolymer-based solid polymer electrolytes (SPEs) has been carried out in this present work. Cellulose derivative was chosen due to its superior physical attributes. In this work, NH4Br-doped glycerol plasticized carboxyl methylcellulose-based SPEs were successfully prepared via the solution casting method. The conductivity and dielectric properties of the prepared films were investigated using the impedance analysis which presented ~1.91×10-3 Scm-1 (with addition of 6 wt% of glycerol). In addition, the studied SPE system shows a non-Debye behaviour without a single relaxation time. The findings of the research indicate that the complexes of NH4Br and glycerol in the cellulose …

Urban Drainage Management And Flood Control Improvement Using The Duflow Case Study: Aur Sub Catchment, Palembang, South Sumatra, Indonesia, Charlotte De Fraiture, Robiyanto Hendro Susanto, F.X. Suryadi, Harrini Mutiara Hapsari Wahyu

Makara Journal of Technology

Urban flooding often times staggers the livelihood in an urban area, which most likely happens in the lowland urban area. Therefore, the existing urban drainage system should be improved in order to tackle the upcoming urban flooding events, which are more than likely to be more devastating than those in the previous years. The research location is in Palembang, Sumatra, Indonesia, where 30% of its urban part is a lowland area. The selected Aur Sub Catchment is located in Silaberanti. The main objective of this research is to improve the current drainage system in order to achieve the optimal design …

Ethanol Purification Using Activated Natural Zeolite, Chandra Wahyu Purnomo, Nelliza Putri, Indra Perdana, Hirofumi Hinode

Makara Journal of Technology

Bio ethanol is one of the potential fuels in the future. However, ethanol in water mixture has an azeotropic concentration of 95.6 wt. %, which makes it difficult to purify further. The common method of purification is by using an azeotropic distillation column, which requires an intensive energy and an addition of specific solvent. In this study, ethanol purification is done using an adsorption column packed with zeolite Raschig rings. The natural zeolite ring was modified beforehand using the NaOH solution to enhance the material’s water adsorption performance. The ethanol purity can reach more than 99% with the modified zeolite …

Physical And Mechanical Properties Of Palm Kernel Oil-Based Polyester Polyurethane/Multi-Walled Carbon Nanotube Composites, Khairul Anuar Mat Amin, Muhammad Alif Zailani, Nurul Nabilah Zulkifli, Khairiah Haji Badri

Makara Journal of Technology

In this study, polyurethane (PU) films from palm kernel oil-based polyester (PKO-p) incorporated multi-walled carbon nanotubes (MWNTs) are prepared via a evaporative casting method. Nanoparticle fluid dispersions containing 0.02%, 0.03%, and 0.05% wt. of MWNTs are added into PKO-p based resin and mixed by digital probe sonicator for 30 min followed by mixing with isocyanate to produce PU-MWNTs composite films. The mechanical properties, swelling, water vapour transmission rate (WVTR) and conductivity of the PU-MWNTs composite films are examined. Results show that the toughness (T) or flexibility, the tensile strength (TS), and Young’s modulus (YM) values of PU-MWNTs composite films increase …

Personality Trait Based Intervention For Workplace Accident Prevention, Yassierli Yassierli, Nurhayati Nurhayati, Marisa Anatasia, Shamsul Bahri

Makara Journal of Technology

Previous research has suggested that some traits may be useful as the predictors of risk behaviours behaviors. Therefore, personality traits seem to play a role in accident involvement. The purpose of this study is was to explore the relationship between the personality traits based on the Big Five Inventory (BFI) and worker accident experiences in order to elaborate personality traits based intervention for workplace accident prevention. A cross cross-sectional study was conducted among 173 workers in a cement company using a set of questionnaires consisting of respondents’ characteristics, BFI, and self-reported accident experience. The correlations were computed using Goodman Kruskal’s …

Current State Of The Assets In The Chemical Engineering Laboratory At Rose-Hulman Institute Of Technology And Their Use In The Undergraduate Laboratory Course Sequence, Matthew Adams

Graduate Theses - Chemical Engineering

The Chemical Engineering Laboratory, also referred to as the Unit Operations (UO) Laboratory, is integral to any undergraduate Chemical Engineering curriculum as it provides students with the opportunity to gain practical and hands-on experience with processes that are commonplace throughout industry. The Chemical Engineering Department at Rose-Hulman Institute of Technology prides itself in providing its students with a practical education that will allow for an easy transition into industry as well as continued success throughout the students’ careers; as such, the assets in the Chemical Engineering Laboratory space and their use are paramount to this objective. The Chemical Engineering Department …

Forces And Disease: Electrostatic Force Differences Caused By Mutations In Kinesin Motor Domains Can Distinguish Between Disease-Causing And Non-Disease-Causing Mutations, Lin Li, Yunhui Peng, Subash Godar, Ivan Getov, Shaolei Teng, Joshua Alper, Emil Alexov

Publications

The ability to predict if a given mutation is disease-causing or not has enormous potential to impact human health. Typically, these predictions are made by assessing the effects of mutation on macromolecular stability and amino acid conservation. Here we report a novel feature: the electrostatic component of the force acting between a kinesin motor domain and tubulin. We demonstrate that changes in the electrostatic component of the binding force are able to discriminate between disease-causing and non-disease-causing mutations found in human kinesin motor domains using the receiver operating characteristic (ROC). Because diseases may originate from multiple effects not related to …

Enhancements In Mass Transfer For Carbon Capture Solvents Part I: Homogeneous Catalyst, Leland R. Widger, Moushumi Sarma, Jonathan J. Bryant, David S. Mannel, Jesse G. Thompson, Cameron A. Lippert, Kunlei Liu

Center for Applied Energy Research Faculty and Staff Publications

The novel small molecule carbonic anhydrase (CA) mimic [Co^III(Salphen-COO⁻)Cl]HNEt₃ (1), was synthesized as an additive for increasing CO₂ absorption rates in amine-based post-combustion carbon capture processes (CCS), and its efficacy was verified. 1 was designed for use in a kinetically slow but thermally stable blended solvent, containing the primary amines 1-amino-2-propanol (A2P) and 2-amino-2-methyl-1-propanol (AMP). Together, the A2P/AMP solvent and 1 reduce the overall energy penalty associated with CO₂ capture from coal-derived flue gas, relative to the baseline solvent MEA. 1 is also effective at increasing absorption kinetics of kinetically fast solvents, such …

Membranes For Food And Bioproduct Processing, Alexandru Marius Avram

Graduate Theses and Dissertations

Modified membranes for process intensification in biomass hydrolysis

Production of biofuels and chemicals from lignocellulosic biomass is one of the leading candidates for replacement of petroleum based fuels and chemicals. However, conversion of lignocellulosic biomass into fuels and chemicals is not cost effective compared to the production of fuels and chemicals from crude oil reserves. Some novel and economically feasible approaches involve the use of ionic liquids as solvents or co-solvents, since these show improved solvation capability of cellulose over simple aqueous systems. Membranes offer unique opportunities for process intensification which involves fractionation of the resulting biomass hydrolysate leading to …

Evaluating One-Step Catalytic Free Method Including Hydrolysis, Esterification, Transesterification, And Degradation Reactions To Produce Biodiesel From Soybean Oil, Mahmood Gheni Jebur

Graduate Theses and Dissertations

Due to the environmental and economic impacts of diesel fuel based on petroleum, several studies have been done to find an alternative source of energy. Biodiesel is considered one of these alternative sources. It is a renewable source of energy produced from vegetable oils and animal fats. There are two main reaction routes used to produce biodiesel (fatty acid methyl esters). Transesterification reaction is the first route used to convert triglycerides to fatty acid methyl esters (FAMEs), while hydrolysis followed by esterification reactions are the second route employed to convert triglycerides to free fatty acids (FFA) and then further converted …

Removal Of Endocrine Disrupting Compounds Using Membrane Bioreactor, Mohanad Ali Abdulsahib Kamaz

Graduate Theses and Dissertations

The presence of endocrine disrupting compounds (EDCs) and pharmaceutically active compounds (PhAC) such as pesticides, personal care products, antibiotics and pharmaceutical compounds, in sewage, industrial, and domestic waters has extensively become the major concern for health and environmental organizations. These compounds have the ability to interact with mammalian endocrine system and disrupting their functions. The traditional activated sludge processes are designed to degrade solids, organic carbon and nitrogen loading. Although several treatment steps in a wastewater treatment plant can contribute to partial removal of EDCs, effective removal has been a challenge due to their resistant chemical and biological degradation and …

Peptide-Directed Nanoparticle Synthesis With A Denovo Pd-Binding Sequence Fused To A Reporter Protein, Rita Eloisa Tejada Vaprio

Graduate Theses and Dissertations

There is a need for low-cost nanoparticle materials in the context of new technologies for catalyst development. The purpose of this work was to recombinantly produce a 45- amino acid long metal binding peptide that is useful for nanoparticle synthesis. Using splicing by overlap extension PCR, a synthetic gene containing the fusion of the metal binding peptide with Green Fluorescent Protein (GFPUV) was constructed. The metal binding peptide, fused to reporter protein GFPUV, was expressed using high cell density fermentation. Palladium nanoparticles of an average diameter of 1.18 0.45 nm were synthesized by using the crude cell extract containing the …

Peptoid-Based Microsphere Coatings For Use As Tunable Biocompatible Interfaces, German Raul Perez Bakovic

Graduate Theses and Dissertations

The pursuit of sensitive, non-invasive, and cost efficient diagnostic tools for early stage disease detection have led to the development of sophisticated biosensor technologies for proteomic studies. As these markers increase in complexity, the role of support substrates grows increasingly important. Limitations in existing support substrates include the potential for increased sensitivity, binding specificity, and bio-stability. Ideal support substrates need to provide biocompatible and bioresistant surfaces, that offer high surface areas for binding, and enables the incorporation of diverse chemistries. The use of peptoids as the basis for the deposition of uniform microsphere coatings offers a mean to the attainment …

Membrane Surface Engineering For Biochemical Applications, Anh T. Vu

Graduate Theses and Dissertations

Synthetic membranes have been frequently used for many fields, such as, the food and beverage, biopharmaceutical, and biofuel industries. In the beer industry, microfiltration frequently suffers from fouling due to the interaction between different species. It is shown that polyphenols can form cross-links with protein molecules, forming insoluble aggregates. However, by adding an optimal amount of polysaccharides these aggregates can be disrupted thus reducing fouling by the aggregates. Confocal laser scanning microscopy (CLSM) is a powerful technique to locate the foulants inside the wet membrane in order to understand more about the behavior of fouling in microfiltration.

Membrane surface modification …

Novel Processing Approaches For Thin Film Solar And Related Technologies., Brandon Lavery

Electronic Theses and Dissertations

A growing population along with developing nations are increasing the demand for energy. The International Energy Agency forecasts a global electricity demand increase of 70 percent by 2040. This is an increase from nearly 18 TW to over 30 TW. The sun can be a great clean source of achieving this energy demand. Despite the large solar industry development, the market is still growing as solar energy only accounted for 0.87% of the global energy production in 2013. The opportunity exists to manufacture more affordable solar energy that can penetrate more of the global energy market. In this dissertation, a …