Chemical Engineering Commons^™

Multiphase Flow Modeling For Design And Optimization Of A Novel Down-Flow Bubble Column, Mutharasu Lalitha Chockalingam

LSU Doctoral Dissertations

The application of the Euler-Euler framework based Computational Fluid Dynamics (CFD) models for simulating the two-phase gas-liquid bubbly flow in down-flow bubble columns is discussed in detail. Emphasis is given towards the modelling and design optimization of a novel down-flow bubble column. The design features of this novel down-flow bubble column and its advantages over a conventional Plunging Jet down-flow bubble column are discussed briefly. Then, some of the present challenges in simulating a conventional Plunging Jet down-flow bubble column in the Euler-Euler framework is highlighted, and a sigmoid function based drag modification function is implemented to overcome those challenges. …

Layer-By-Layer Assembled Membranes With Immobilized Porins, Sebastián Hernández, Cassandra Porter, Xinyi Zhang, Yinan Wei, Dibakar Bhattacharyya

Chemical and Materials Engineering Faculty Publications

New and advanced opportunities are arising for the synthesis and functionalization of membranes with selective separation, reactivity, and stimuli-responsive behavior. One such advancement is the integration of bio-based channels in membrane technologies. By a layer-by-layer (LbL) assembly of polyelectrolytes, outer membrane protein F trimers (OmpF) or “porins” from Escherichia coli with central pores ∼2 nm in diameter at their opening and ∼0.7 × 1.1 nm at their constricted region are immobilized within the pores of poly(vinylidene fluoride) microfiltration membranes, in contrast to traditional ruptured lipid bilayer or vesicle processes. These OmpF-membranes demonstrate selective rejection of non-charged organics over ionic solutes, …

Sexual Recombination And Increased Mutation Rate Expedite Evolution Of Escherichia Coli In Varied Fitness Landscapes, George Peabody, Hao Li, Katy Kao

Faculty Publications

Sexual recombination and mutation rate are theorized to play different roles in adaptive evolution depending on the fitness landscape; however, direct experimental support is limited. Here we examine how these factors affect the rate of adaptation utilizing a “genderless” strain of Escherichia coli capable of continuous in situ sexual recombination. The results show that the populations with increased mutation rate, and capable of sexual recombination, outperform all the other populations. We further characterize two sexual and two asexual populations with increased mutation rate and observe maintenance of beneficial mutations in the sexual populations through mutational sweeps. Furthermore, we experimentally identify …

Combined Noncyclic Scheduling And Advanced Control For Continuous Chemical Processes, Damon Petersen, Logan D. R. Beal, Derek Prestwich, Sean Warnick, John Hedengren

Faculty Publications

A novel formulation for combined scheduling and control of multi-product, continuous chemical processes is introduced in which nonlinear model predictive control (NMPC) and noncyclic continuous-time scheduling are efficiently combined. A decomposition into nonlinear programming (NLP) dynamic optimization problems and mixed-integer linear programming (MILP) problems, without iterative alternation, allows for computationally light solution. An iterative method is introduced to determine the number of production slots for a noncyclic schedule during a prediction horizon. A filter method is introduced to reduce the number of MILP problems required. The formulation’s closed-loop performance with both process disturbances and updated market conditions is demonstrated through …

Synergistic Interactions Of H2 And N2 With Molten Gallium In The Presence Of Plasma, Maria L. Carreon, Daniel F. Jaramillo-Cabanzo, Indira Chaudhuri, Madhu Menon, Mahendra K. Sunkara

Physics and Astronomy Faculty Publications

The present study examines the interaction of hydrogen and nitrogen plasmas with gallium in an effort to gain insights into the mechanisms behind the synergetic effect of plasma and a catalytic metal. Absorption/desorption experiments were performed, accompanied by theoretical-computational calculations. Experiments were carried out in a plasma-enhanced, Ga-packed, batch reactor and entailed monitoring the change in pressure at different temperatures. The results indicated a rapid adsorption/dissolution of the gas into the molten metal when gallium was exposed to plasma, even at a low temperature of 100 °C. The experimental observations, when hydrogen was used, indicate that gallium acts as a …

Synthesis And Characterization Of Thermoresponsive Hydrogels Based On N-Isopropylacrylamide Crosslinked With 4,4′-Dihydroxybiphenyl Diacrylate, Shuo Tang, Martha Floy, Rohit Bhandari, Manjula Sunkara, Andrew J. Morris, Thomas D. Dziubla, J. Zach Hilt

Chemical and Materials Engineering Faculty Publications

A novel crosslinker [4,4′-dihydroxybiphenyl diacrylate (44BDA)] was developed, and a series of temperature-responsive hydrogels were synthesized through free radical polymerization of N-isopropylacrylamide (NIPAAm) with 44BDA. The temperature-responsive behavior of the resulting gels was characterized by swelling studies, and the lower critical solution temperature (LCST) of the hydrogels was characterized through differential scanning calorimetry. Increased content of 44BDA led to a decreased swelling ratio and shifted the LCST to lower temperatures. These novel hydrogels also displayed resiliency through multiple swelling–deswelling cycles, and their temperature responsiveness was reversible. The successful synthesis of NIPAAm-based hydrogels crosslinked with 44BDA has led to a …

Reducing Biomass Recalcitrance By Heterologous Expression Of A Bacterial Peroxidase In Tobacco (Nicotiana Benthamiana), Ayalew Ligaba-Osena, Bertrand Hankoua, Kay Dimarco, Robert Pace, Mark Crocker, Jesse Mcatee, Nivedita Nagachar, Ming Tien, Tom L. Richard

Center for Applied Energy Research Faculty and Staff Publications

Commercial scale production of biofuels from lignocellulosic feed stocks has been hampered by the resistance of plant cell walls to enzymatic conversion, primarily owing to lignin. This study investigated whether DypB, the lignin-degrading peroxidase from Rodococcus jostii, depolymerizes lignin and reduces recalcitrance in transgenic tobacco (Nicotiana benthamiana). The protein was targeted to the cytosol or the ER using ER-targeting and retention signal peptides. For each construct, five independent transgenic lines were characterized phenotypically and genotypically. Our findings reveal that expression of DypB in the cytosol and ER does not affect plant development. ER-targeting increased protein accumulation, and …

Energy Potentials Of Briquette Produced From Tannery Solid Waste, Olatunde Ajani Oyelaran, Faralu Muhammed Sani, Olawale Monsur Sanusi, Olusegun Balogun, Adeyinka Okeowo Fagbemigun

Makara Journal of Technology

The vast quantity of waste generated from industries is one of the serious outcomes of unplanned development, resulting into quantum of hazardous organic and inorganic waste generating daily. Proper waste management is a challenging issue that must be addressed adequately. This is, therefore, carried out with a view of assessing the energy and combustion quality of tannery solid waste with a view of converting them into briquettes for cooking, heating and small home industries and reducing the menace caused by tannery waste disposal. The results of the experiments showed that the combustion rate ranged between 0.171 and 0.217 g/min, the …

Adsorption Of Cu(Ii) Ions In Aqueous Solution Onto Limonia Acidissima Shellbased Activated Carbon: Kinetic And Isotherm Studies, Abrar Muslim, Syahiddin Dahlan Said, Gita Suci Hariati, Siti Fajar Karina, Fauzi Muhammad Djuned, Rizka Mulyawan

Makara Journal of Technology

Adsorption of Cu(II) ions from aqueous solution using activated carbon prepared from Limonia acidissima fruit shell (LAFS-AC) was conducted in batch mode experiments at pH 5 (±0.15), 100 rpm and 1 atm. The effects of contact time, initial Cu(II) ions concentration, KOH concentration, and adsorption temperature on Cu(II) ions adsorption capacity were investigated. Fourier Transform Infrared Spectroscopy and Scanning Electron Microscopy analyses were performed to investigate the active site and surface morphology of the LAFS-AC, respectively. The Cu(II) ions adsorption was fitted very well (R2 = 0.94 on average) to the pseudo second-order adsorption kinetic with the adsorption capacity and …

Experimental Study On Automatic Control For Collision Avoidance Of Ships, Daeng Paroka, Muhammad Fahmi Kamil, Andi Haris Muhammad

Makara Journal of Technology

Automatic control system is widely applied to control the ship direction or heading angle in accordance with the decided trajectory. Several methods for improving performance of control system have been developed such as Proportional-Integral-Derivative (PID) control and fuzzy logic based control. Within the last decade, application of automatic control system is not only for ship navigation but also for avoiding collision risk of ships in seaways. This paper discusses the application of automatic control system for avoiding ship collision by free running experiment. Fuzzy logic based control was developed using Mamdani Centroid method to estimate the necessary rudder angle in …

Indonesia’S Municipal Solid Waste 3r And Waste To Energy Programs, Farizal Farizal, Radityo Aji, Amar Rachman, Nasruddin Nasruddin, Teuku Meurah Indra Mahlia

Makara Journal of Technology

Like most cities in the world, population in Indonesia continues to grow every year. Problems that can arise from this are the increasing amount of municipal solid waste (MSW) production and the growing demand for electricity. To deal with the problems, Indonesian government runs 3R (Reduce, Reuse and Recycle) and WTE (Waste to Energy) Programs simultaneously. 3R program aims to reduce the number of waste, while WTE program aims to generate electricity as an alternative energy source. This study aims to find out the optimal proportion of MSW treated through the 3R and WTE programs. For the purpose, a goal …

Study On Semiconductor Properties Of Acetylide-Thiourea Fabricated Onto Interdigitated Electrodes (Ides) Platform Towards Application In Gas Sensing Technology, Adibah Izzati Daud, Wan M. Khairul, M. I. N. Isa, Khairul Anuar Abdul Wahid

Makara Journal of Technology

In the past few decades, the unique properties of acetylide and thiourea moieties individually have attracted great attention from researchers in various fields to be developed in numerous applications in advanced materials technology, especially as an active layer in gas sensing devices. The molecular systems of acetylide and thiourea provide a wide range of electronic properties as they possess rigid π-systems in their designated structures. In this study, a derivative of acetylide-thiourea featuring N-(4[4-aminophenyl] ethynyl benzonitrile)-N’-(4-ethyl benzoyl) thiourea (TCN) has been synthesised with the general formula of ArC(O)NHC(S)NHC≡C)Ar adopted the system of D-π-A for the significant development of conductive materials. …

Experimental Study Of The Chimney Height Variation Against Double Pots Biomass Stove Performance, Faisal Faisal, Adi Setiawan, Wusnah Wusnah, Khairil Khairil, Luthfi Luthfi, Mona Fajriana

Makara Journal of Technology

This research aims to get optimal chimneys height of double pots biomass stove. Optimal chimneys height needs to provide best performance of the stove. Experimental study was done by varied the chimney heights. Water boiling test as the standard method was used to obtained stove performance for each chimney height variation. The results showed that best performance stove was the one with 1.65 cm chimney height, with thermal efficiency at 37.66%.

Assessment On Heck-Immine Derivatives As Organic Semiconductor Materials, Rafizah Rahamathullah, Lim Keemi, Wan M. Khairul

Makara Journal of Technology

This paper reports the synthetic, characterization and theoretical evaluation of new class of hybrid Heck-immine system involving mixed moieties of vinylene (C=C) and azomethines (CH=N) which has been successfully integrated into an addition of organic semiconducting materials. The assessment of 4-[(hexyloxyphenyl)methylene]amino)-4’-chloro-stilbene (HEXCS) based on Donor (D)-π-Acceptor (A) was evaluated as active semiconductor material candidates via several spectroscopic and analytical techniques. In turn, the investigation of its potential as dopant system in conductive film was successfully deposited on indium tin oxide (ITO) coated substrate via spin coating method. The relationship between electronic and optical properties, chemical modelling at molecular interactions and …

Innovation Of Hydrocarbon Investigation Using Audio-Magnetotelluric In Cepu Field, Indonesia, Iqbal Fauzi Aditama, Widodo Widodo

Makara Journal of Technology

An audio-magnetotelluric (AMT) survey has been performed at Cepu oil field located in Indonesia. The objective of this research is to detect resistivity structures of this important hydrocarbon rock. This research can be classified as an innovation in application of the AMT method for hydrocarbon exploration. The lack of seismic resolution has been provided by the AMT method, especially in the location of sub-basalt and sub-salt plays. In additional, the cost of AMT survey is quite low compared to seismic. The forward modelling is included in this research to understand the measurement data response from a mathematical model. In the …

Sustainable Clean Coal Technology With Power And Methanol Production, Xiaomeng Wang

Department of Chemical and Biomolecular Engineering: Dissertations, Theses, and Student Research

The coal-based chemical process is still indispensable in modern society due to the worldwide vast reserves and popular price of coal. Power generation and chemical production from coal still play an important role in the global chemical industrial market. Electricity generation and chemical production from coal is still the trend as long as the coal is plentiful and inexpensive. Modern chemical industry aims at sustainability and hence the development of clean coal technologies is critical.

Coal-based methanol economy, as an attractive liquid transportation fuel as well as an essential intermediate chemical feedstock, can fill a possible gap between declining fossil …

Anodic Catalysts For Anion Exchange Membrane Fuel Cells, Aaron Joseph Roy

Chemical and Biological Engineering ETDs

With a limited availability of energy resources from petroleum and other fossil fuels, as well as growing concerns relating to the environmental implications of fossil fuel emissions, non-carbon fuels which can be utilized in proton and anion exchange membrane fuel cells (PEMFC’s/AEMFC’s), such as hydrogen and hydrazine hydrate (HH), are becoming more attractive as alternative fuels. Historically, platinum and platinum group metal catalysts (PGM) have been used as cathode and anode catalyst materials for both PEMFC’s and AEMFC’s. Although these catalysts are the highest performing catalysts available for the conversion of hydrogen energy in fuel cells, the limited availability and …

Green Chemistry Oxidative Modification Of Peptoids Utilizing Bleach And Tempo, Jesse Leland Roberts

Graduate Theses and Dissertations

Biotherapeutic drugs, derived from biological molecules such as proteins and DNA, are becoming an integral and exceptionally critical aspect of modern medicine. Compared to common pharmaceutical drugs, biotherapeutics are much larger in size and have greater target specificity, allowing them to treat many chronic diseases ranging from cancer to rheumatoid arthritis. The major issue with protein based therapeutics is that they readily undergo proteolysis, or enzymatic degradation, when administered through subcutaneous injections. Traditionally, biotherapeutic modification procedures have centered on the use of PEG derivatives. This process, called PEGylation, is unfavorable due to the increases in molecular weights of the proteins …

Artificial Olfactory System For Multi-Component Analysis Of Gas Mixtures., Alexander Aleksandrovich Larin

Electronic Theses and Dissertations

Gas analysis is an important part of our world and gas sensing technology is becoming more essential for various aspects of our life. A novel approach for gas mixture analysis by using portable gas chromatography in combination with an array of highly integrated and selective metal oxide (MOX) sensors has been studied. We developed a system with small size (7 x 13 x 16 inches), low power consumption (~10 W) and absence of special carrier gases designed for portable field analysis (assuming apriori calibration). Low ppb and even sub-ppb level of detection for some VOCs was achieved during the analysis …

Self-Generated Absorption Filter Based Optical Densitometry Calculations For Expanded Gamut And Spot Color Printing On Paperboard For Packaging Applications And Proposed Oba Index, Awadhoot Vijaykant Shendye

Dissertations

In the printing industry, process color printing is a very common way of reproduction of color photographic images. As continuous tone reproduction is not possible, images are converted to halftone format. Process control of a halftone image quality is carried out by measuring optical density of solid patches. ISO 5 defines measurement of optical density, formula, filters and requirements. As per ISO document optical density can be calculated only for the 4 colors cyan, magenta, yellow and black, known as process colors. To enhance quality of color reproduction of images, the number of reproducible colors are increased by gamut expansion. …