Effects Of Rotating Magnetic Fields On Pem Fuel Cell Performance,
2018
College of Energy and Mechanical Engineering, Shanghai University of Electric Power, Shanghai, 20090
Effects Of Rotating Magnetic Fields On Pem Fuel Cell Performance, Mao-Liang Wu, En-Ze Wang, Guang-De Pan, Zhong-Jun Liu, Fei Xie
Journal of Electrochemistry
Proton Exchange Membrane (PEM) fuel cell performance may be improved by application of additional magnetic fields. In this work, one square permanent magnet, made of either 16 combination cylinder magnets with homopolarity or 16 combination cylinder magnets with heteropolarity, was exerted on the fuel cell surface to produce additional magnetic field affecting PEM fuel cell performance. The influences of magnetic field status (rotating, static and none) on polarization and power density curves measured in a PEM fuel cell were investigated. The results verified the benefit of magnetic field, proving that the magnetic field distribution could improve the fuel cell output. …
Preparation And Properties Of Manganese Oxide And Polyaniline-Carbon Composite Electrode,
2018
Key Laboratory of Photochemistry Biological Materials and Energy Story Materials, Heilongjiang Province; College of Chemistry and Chemical Engineering, Harbin Normal University, Harbin 150025, Heilongjiang, China;
Preparation And Properties Of Manganese Oxide And Polyaniline-Carbon Composite Electrode, Tian-Tian Zhou, Bing Wu, Chao Deng, Ying Gao
Journal of Electrochemistry
The polyaniline-carbon (PAnC) electrode was prepared by the polymerization of aniline monomer and activated carbon in ice water bath, and followed by chemical deposition of manganese dioxide MnO2-PAnC composite material. The specific capacitance of MnO2-PAnC reached 459 F•g-1. The cyclic voltammetric results showed a small deformation in the voltammogram curve obtained with the MnO2-PAnC electrode at high scan rate, indicating good reversibility and capacitive properties. The AC impedance results revealed that the MnO2-PAnC electrode displayed the smallest charge transfer resistance and the fastest diffusion
rate of surface ions than other …
Preparation Of Ni(Dpim)2Cl2 Complex For The Electrocatalytic Reduction Of Co2,
2018
State Key Laboratory of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China;
Preparation Of Ni(Dpim)2Cl2 Complex For The Electrocatalytic Reduction Of Co2, Li-Pu Zhang, Dong-Fang Niu, Xin-Sheng Zhang
Journal of Electrochemistry
A new Ni(dpim)2Cl2complex using 2-(diphenylphosphino)-1-methylimidazole (dpim) as ligand was prepared and served as a catalyst for the electrochemical reduction of CO2. The electrochemical redox behavior of Ni(dpim)2Cl2 in CH3CN/TPABF4 solution under nitrogen atmosphere showed the two-electron irreversible reduction at -0.7 V and one-electron quasi-reversible reduction at -1.3 V. After bubbling CO2 into the electrolyte, the reduction peak appeared at -1.3 V became irreversible and the peak current increased from 0.48 mA·cm-2 to 0.55 mA·cm-2. Moreover, the peak current at -1.3 V could further increase …
Marangoni Flows During Nonsolvent Induced Phase Separation,
2018
Brigham Young University - Provo
Marangoni Flows During Nonsolvent Induced Phase Separation, Douglas R. Tree, Tatsuhiro Iwama, Kris T. Delaney, Joshua Lee, Glenn H. Fredrickson
Faculty Publications
Motivated by the much discussed, yet unexplained, presence of macrovoids in polymer membranes, we explore the impact of Marangoni flows in the process of nonsolvent induced phase separation. Such flows have been hypothesized to be important to the formation of macrovoids, but little quantitative evidence has been produced to date. Using a recently developed multifluid phase field model, we find that roll cells indicative of a solutal Marangoni instability are manifest during solvent/nonsolvent exchange across a stable interface. However, these flows are weak and subsequently do not produce morphological features that might lead to macrovoid formation. By contrast, initial conditions …
Nanoreactors: Strategies To Encapsulate Enzyme Biocatalysts In Virus-Like Particles,
2018
Brigham Young University - Provo
Nanoreactors: Strategies To Encapsulate Enzyme Biocatalysts In Virus-Like Particles, Joshua W. Wilkerson, Seung-Ook Yang, Parker J. Funk, Steven K. Stanley, Bradley Charles Bundy
Faculty Publications
Enzyme-mediated biocatalysis is generally more selective and environmentally friendly and requires less energy than chemocatalysis. However, factors such as temperature, acidity and the presence of proteases can negate enzyme activity. Encapsulation in virus-like particles is one promising method to mitigate these difficulties. Encapsulation also can be used to create multi-reaction nanoreactors that increase process efficiency by isolating reaction intermediates. To successfully encapsulate enzymes, a variety of methods involving both non-covalent and covalent interactions have been developed. Here we review promising virus-like particle encapsulation strategies, their advantages and remaining challenges.
Waste Vegetable Oil Properties With Usage And Its Impact On Artisan Soap Making,
2018
Brigham Young University
Waste Vegetable Oil Properties With Usage And Its Impact On Artisan Soap Making, Jenalyn Thorpe
Undergraduate Honors Theses
This thesis examines the impact of vegetable oil usage in industrial and home settings on the properties of the vegetable oil and how its usage in soap affects the final product. Waste vegetable oil (WVO) is often used to make soap as a way to be more environmentally-friendly and create soap at a low cost in developing countries. Two settings are examined: home usage (i.e. short-term, small-scale usage) and industrial (i.e. long-term, almost continuous usage). This thesis found that lightly used oil (household use) had little to no impact on the quality of the oil, except for its scent. This …
Multienzyme Immobilized Polymeric Membrane Reactor For The Transformation Of A Lignin Model Compound,
2018
University of Kentucky
Multienzyme Immobilized Polymeric Membrane Reactor For The Transformation Of A Lignin Model Compound, Rupam Sarma, Md. Saiful Islam, Mark P. Running, Dibakar Bhattacharyya
Chemical and Materials Engineering Faculty Publications
We have developed an integrated, multienzyme functionalized membrane reactor for bioconversion of a lignin model compound involving enzymatic catalysis. The membrane bioreactors were fabricated through the layer-by-layer assembly approach to immobilize three different enzymes (glucose oxidase, peroxidase and laccase) into pH-responsive membranes. This novel membrane reactor couples the in situ generation of hydrogen peroxide (by glucose oxidase) to oxidative conversion of a lignin model compound, guaiacylglycerol-β-guaiacyl ether (GGE). Preliminary investigation of the efficacy of these functional membranes towards GGE degradation is demonstrated under convective flow mode. Over 90% of the initial feed could be degraded with the multienzyme immobilized membranes …
Distillation Optimization In The Pharmaceutical Industry,
2018
Western Michigan University
Distillation Optimization In The Pharmaceutical Industry, Daniel Vanzweden
Honors Theses
Distillations are commonly used throughout industry to perform separations by phase change, producing a liquid phase and vapor distillate. However, the process of distilling can be slow and energy intensive, providing a limitation in the production process. Possible improvements to current distillation systems were considered on the basis of thermal efficiency, material throughput (cycle time), and material tolerance. Consideration was given to ensure maintenance is straightforward and relatively quick, as fouling, contamination and tank utilization were concerns. Economic viability of the improvements was completed to determine the project benefit. The optimized design offers increased efficiency for production lines.
Distillation Optimization In The Pharmaceutical Industry,
2018
Western Michigan University
Distillation Optimization In The Pharmaceutical Industry, Clayton Carter
Honors Theses
Distillations are commonly used throughout industry to perform separations by phase change. producing a liquid phase and vapor distillate. However. the process of distilling can be slow and energy intensive, providing a limitation in the production process. Possible improvements to current distillation systems were considered on the basis of thermal efficiency, material throughput (cycle time), and material tolerance. Consideration was given to ensure maintenance is straightforward and relatively quick, as fouling, contamination and tank utilization were concerns. Economic viability of the improvements was completed to determine the project benefit. The optimized design offers increased efficiency for production lines.
Natural Polymer Barrier Coatings For Oil And Grease Resistance,
2018
Western Michigan University
Natural Polymer Barrier Coatings For Oil And Grease Resistance, Andrew Kathan
Honors Theses
Many barrier coating formulations currently used for oil and grease resistance development in the paper industry have issues with sustainability, biodegradation, or have health concerns associated with them. This thesis tests two starches as barrier coatings to develop oil and grease resistance for food grade packaging sheets. Starch is compatible with almost all papermaking chemicals, is biodegradable, and is easily treated in wastewater systems making it a great candidate to create a more sustainable barrier coating. Cooked hydrophobic starch esters have a unique shear-thinning rheology that allow for high solid starch coatings to be applied with a reduced risk of …
Optimizing Frosted Mini-Wheats' Finished Food Cooling Process,
2018
Western Michigan University
Optimizing Frosted Mini-Wheats' Finished Food Cooling Process, Jessica Graves
Honors Theses
Analyzing energy intensive processes in industry is crucial for improving sustainability, lowering costs, and increasing profit margins on products. Material and energy balances were performed to identify process losses in the cooling of Frosted Mini-Wheats. Existing cooling technology was compared to alternate technology available on the market, and a cost analysis was performed to compare all options explored. Recommendations were made to the system to potentially reduce the line's energy usage and downtime, with the objective of creating a more sustainable and efficient process.
Optimization Of Toaster Pastry Icing Preparation And Application,
2018
Western Michigan University
Optimization Of Toaster Pastry Icing Preparation And Application, Rebecca Martus
Honors Theses
The Kellogg Company is interested in optimizing the way the icing for a baked good is prepared and applied during production. The current method has not been significantly changed since the item was first introduced over 50 years ago. A new process was developed to make a more efficient preparation and application of the icing operation. New equipment was identified based on established methods in the food industry. The new equipment and process was verified after the mass and energy balances were calculated. A capital and operating cost analysis was performed to determine if the introduction of the new process …
Spectro-Electrochemical Platforms For Dynamic Analyses Of Catalytic Cascade Systems,
2018
University of New Mexico - Main Campus
Spectro-Electrochemical Platforms For Dynamic Analyses Of Catalytic Cascade Systems, Nalin I. Andersen
Nanoscience and Microsystems ETDs
The development of spectro-electrochemical platforms that facilitate the dynamic analyses of complex catalytic cascade systems was explored in this research. These systems facilitated multiple modalities of catalysts and were used as platforms for monitoring catalytic transformations quasi-in situ. The analytical platforms allowed for the characterization of intermediates and products using surface-enhanced Raman spectroscopy (SERS). The design and fabrication of these devices proved to be reproducible, made of materials that can be manipulated for multiple applications, and incorporate fluid mechanics, electrochemistry, and multimodal catalysis. Microfluidic technology offers capabilities for understanding catalytic cascade systems by providing precise dynamic control of …
An Investigation Of The Effects Of The Second Pyrolysis On The Chemistry, Morphology, And Performance Of Iron-Nicarbazin Catalysts,
2018
University of New Mexico
An Investigation Of The Effects Of The Second Pyrolysis On The Chemistry, Morphology, And Performance Of Iron-Nicarbazin Catalysts, Elizabeth B. Weiler
Chemical and Biological Engineering ETDs
Proton exchange membrane fuel cells offer a cost-effective, environmentally friendly, and sustainable alternative to petroleum-based power sources to the transportation sector. However, slow electrochemical reactions at the cathode of these fuel cell prevent the technology from being competitive. Iron-nitrogen-carbon based catalysts have emerged as a viable answer to this problem, yet further progress is needed to improve their performance beyond that of current state-of-the-art platinum-based catalysts, which are economically and geopolitically impractical to be a final solution. Currently, a two-step high temperature pyrolysis method has proven a promising way to synthesize iron-nitrogen-carbon catalysts for optimized performance, but there is a …
The Catalytic Activity Of Copper Oxide Nanoparticles Towards Carbon Monoxide Oxidation Catalysis: Microwave – Assisted Synthesis Approach,
2018
The British University in Egypt
The Catalytic Activity Of Copper Oxide Nanoparticles Towards Carbon Monoxide Oxidation Catalysis: Microwave – Assisted Synthesis Approach, Hany A. Elazab Dr
Chemical Engineering
In this research, we report a simple, versatile, and reproducible method for the synthesis of copper oxide nanoparticles via microwave assisted synthesis approach. The important advantage of this catalyst is due to its important role not only in the low temperature oxidation of CO but also in potential applications in pharmaceutical and fine chemical synthesis. The results reveal that the copper oxide catalyst has particularly a remarkable high activity for CO oxidation catalysis as it was found that copper oxide (CuO) catalyst has 100% conversion of carbon monoxide into carbon dioxide at 175 oC. This also could be attributed to …
Review Of Challenges And Advances In Modification Of Food Package Headspace Gases,
2018
University of Florida
Review Of Challenges And Advances In Modification Of Food Package Headspace Gases, Ziynet Boz, Bruce A. Welt, Jeffrey K. Brecht, William Pelletier, Eric Mclamore, Gregory A. Kiker, Jason E. Butler
Journal of Applied Packaging Research
Modified Atmosphere Packaging (MAP) has been widely used as an effective way to preserve foods. Fresh produce, meat and meat products, seafood, and dairy products can benefit from modified gaseous atmospheres, which are usually achieved by reducing oxygen and increasing carbon dioxide concentrations, within limits, defined by product tolerances. MAP of fresh produce is particularly challenging because products are living and respiring. Respiration rates depend on several factors including temperature, oxygen, and carbon dioxide concentrations. Balancing package permeation with respiration is challenging, often due to limited selection of practical packaging materials. Failing to remain within tolerance limits of products leads …
Waste Management By Waste: Removal Of Acid Dyes From Wastewaters Of Textile Coloration Using Fish Scales,
2018
Louisiana State University and Agricultural and Mechanical College
Waste Management By Waste: Removal Of Acid Dyes From Wastewaters Of Textile Coloration Using Fish Scales, S M Fijul Kabir
LSU Master's Theses
Removal of hazardous acid dyes by economical process using low-cost bio-sorbents from wool industry wastewaters is of a pressing need, since it causes skin and respiratory diseases and disrupts other environmental components. Fish scales (FS), a by-product of fish industry, a type of solid waste, are usually discarded carelessly resulting in pungent odor and environmental burden. In this research, the FS of black drum (Pogonias cromis) were used for the removal of acid dyes (acid red 1 (AR1), acid blue 45 (AB45) and acid yellow 127 (AY126)) from wool industry wastewaters by absorption process with a view to …
Lyophilized Escherichia Coli-Based Cell-Free Systems For Robust, High-Density, Long-Term Storage,
2018
Brigham Young University - Provo
Lyophilized Escherichia Coli-Based Cell-Free Systems For Robust, High-Density, Long-Term Storage, Mark Thomas Smith, Scott D. Berkheimer, Christopher J. Werner, Bradley Charles Bundy
Faculty Publications
Cell-free protein synthesis (CFPS) is a versatile tool for rapid recombinant protein production and engineering. One drawback of cell-free technology is the necessity to store the major components—cell extracts and energy systems—below freezing in bulky aqueous solutions. Here we describe simple methods for lyophilizing extracts and preparing powdered energy systems for CFPS. These techniques allow for high-density storage of cell-free systems that are more robust against temperature and bacterial degradation. Our methods have the potential to decrease storage expenses, allow for longer shelf-life of cell extracts at room temperature, and enable durable portable protein production technologies.
Streamlined Extract Preparation For Escherichia Coli-Based Cell-Free Protein Synthesis By Sonication Or Bead Vortex Mixing,
2018
Brigham Young University - Provo
Streamlined Extract Preparation For Escherichia Coli-Based Cell-Free Protein Synthesis By Sonication Or Bead Vortex Mixing, Prashanta Shrestha, Troy Michael Holland, Bradley Charles Bundy
Faculty Publications
Escherichia coli-based cell extract is a vital component of inexpensive and high-yielding cell-free protein synthesis reactions. However, effective preparation of E. coli cell extract is limited to high-pressure (French press-style or impinge-style) or bead mill homogenizers, which all require a significant capital investment. Here we report the viability of E. coli cell extract prepared using equipment that is both common to biotechnology laboratories and able to process small volume samples. Specifically, we assessed the low-capital-cost lysis techniques of: (i) sonication, (ii) bead vortex mixing, (iii) freeze-thaw cycling, and (iv) lysozyme …
Mobility Of Nano-Particles In Rock Based Micro-Models,
2018
Louisiana State University and Agricultural and Mechanical College
Mobility Of Nano-Particles In Rock Based Micro-Models, Jagannath Upadhyay
LSU Doctoral Dissertations
A confocal micro-particle image velocimetry (C-μPIV) technique along with associated post-processing algorithms is detailed for obtaining three dimensional distributions of nano-particle velocity and concentrations at select locations of the 2.5D (pseudo 3D) Poly(methyl methacrylate) (PMMA) and ceramic micro-model. The designed and fabricated 2.5D micro-model incorporates microchannel networks with 3D wall structures with one at observation wall which resembles fourteen morphological and flow parameters to those of fully 3D actual reservoir rock (Boise Sandstone) at resolutions of 5 and 10 μm in depth and 5 and 25 μm on plane. In addition, an in-situ, non-destructive method for measuring the geometry of …
