Magnetic Amphiphiles And Their Potential Applications For Low Energy Separations Processes,
2019
University of Mississippi
Magnetic Amphiphiles And Their Potential Applications For Low Energy Separations Processes, Alexander Fortenberry
Electronic Theses and Dissertations
Predicting the behavior of magnetic surfactants in magnetic fields is critical for designing magnetically driven processes such as chemical separations or the tuning of surface tensions. Our work supports the hypothesis that the ability of magnetic fields to alter the interfacial properties of magnetic surfactant solutions depends on the strength of association between the magnetic and surfactant moieties of the surfactant molecules. Our research shows that the stability of a magnetic surfactant in an aqueous environment is dependent upon the type of complex that contains the paramagnetic element and these findings provide valuable insight for the design of magnetic surfactants …
Comparative Kinetic Modeling Of Growth And Molecular Hydrogen Overproduction By Engineered Strains Of Thermotoga Maritima,
2019
University of Nebraska-Lincoln
Comparative Kinetic Modeling Of Growth And Molecular Hydrogen Overproduction By Engineered Strains Of Thermotoga Maritima, Raghuveer Singh, Rahul Tevatia, Derrick White, Yaşar Demirel, Paul H. Blum
Department of Chemical and Biomolecular Engineering: Faculty Publications
Thermotoga maritima is an anaerobic hyperthermophilic bacterium known for its high amounts of hydrogen (H2) production. In the current study, the kinetic modeling was applied on the engineered strains of T. maritima that surpassed the natural H2 production limit. The study generated a kinetic model explaining H2 overproduction and predicted a continuous fermentation system. A Leudking-Piret equation-based model predicted that H2 production by Tma200 (0.217 mol-H2 g–1-biomass) and Tma100 (0.147 mol-H2 g–1-biomass) were higher than wild type (0.096 mol-H2 g–1 -biomass) with reduced rates of maltose utilization. …
Modified Cpd Model For Coal Devolatilization At Underground Coal Thermal Treatment Conditions,
2019
University of Utah
Modified Cpd Model For Coal Devolatilization At Underground Coal Thermal Treatment Conditions, Ding Wang, Thomas H. Fletcher, Swomitra Mohanty, Hoaquan Hu, Eric G. Eddings
Faculty Publications
To study coal pyrolysis behavior at underground coal thermal treatment (UCTT) conditions, a modified CPD (M-CPD) model was developed and evaluated using two scales of experiments as well as two different coals, Utah Sufco and Illinois #6. Compared with the original CPD model, three major aspects were changed, including (1) rewriting the algorithm using MATLAB built-in functions; (2) developing a correlation method between coal elemental composition and the initial functional group population to calculate the effect of cross-linking on the lattice structure; and (3) using a two-activation energy approach for gas generation kinetics modeling. Results predicted by the M-CPD model …
Using Fluorescence Spectroscopy To Determine Concentrations Of Quantum Dot Solutions,
2019
University of Alabama in Huntsville
Using Fluorescence Spectroscopy To Determine Concentrations Of Quantum Dot Solutions, Cameron Sawyer
Summer Community of Scholars Posters (RCEU and HCR Combined Programs)
No abstract provided.
Functionalizing Mica With Silanes Using Wet Chemistry,
2019
University of Alabama in Huntsville
Functionalizing Mica With Silanes Using Wet Chemistry, John Paul Stepnowski
Summer Community of Scholars Posters (RCEU and HCR Combined Programs)
No abstract provided.
Cataloging The Degree Of Sensitization Via Electrochemical Reactivation For Studying The Corrosion Behavior Of Inconel 718, Austenitic, And Duplex Stainless Steels,
2019
The University of Akron
Cataloging The Degree Of Sensitization Via Electrochemical Reactivation For Studying The Corrosion Behavior Of Inconel 718, Austenitic, And Duplex Stainless Steels, Bradley Lynes
Williams Honors College, Honors Research Projects
Corrosion resistant materials can be expensive, but usually reduce the life cycle cost of metallic assets. However, negligent sensitization of these materials can lead to aggressive, intergranular corrosion. Using the methodology of the double loop electrochemical potentiokinetic reactivation (DL-EPR), this project investigates different steel reinforced bars and Inconel to determine the degree of sensitization after a heat treatment of 900°C for 2 hours. The purpose of this research is to validate and determine the appropriate test parameters for performing further DL-EPR test in the future. Additionally, the kinetics observed for each sample during the DL-EPR test will be analyzed and …
Developing A Portable Prototype To Utilize An Electrospun Colorimetric Sensor For The Detection Of Trihalomethanes In Water,
2019
The University of Akron
Developing A Portable Prototype To Utilize An Electrospun Colorimetric Sensor For The Detection Of Trihalomethanes In Water, Amanda Svensson
Williams Honors College, Honors Research Projects
Trihalomethane (THM) detection in water is important due to the potential health effects caused by their presence, including increased cancer risk. A cheap, quick, and portable method of identifying THM concentration at the Environmental Protection Agency limit of 80 parts per billion (ppb) will improve detection and water treatment. Electrospinning was used to make nanofiber membranes using a 2.6 wt% polypropylene solution. These membranes were utilized in the Fujiwara reaction, which creates a color change in the presence of THMs, to detect the THM bromoform in water. The color intensity of the reaction was quantified for 250 and 80 ppb …
Effects Of Hofmeister Ions On Transition Temperature Of Two Thermo-Responsive Polymers,
2019
The University of Akron
Effects Of Hofmeister Ions On Transition Temperature Of Two Thermo-Responsive Polymers, Joshua Moser
Williams Honors College, Honors Research Projects
It was hypothesized that through the use of Hofmeister Ions, the lower critical solution temperature (LCST) of poly(vinyl methyl ether) (PVME) and poly(ethylene glycol)- poly(N-isopropylacrylamide) (PEG-b-pNIPAAm) block-copolymer could be controlled. Through literature searches and small lab experiments, our team found that there may be a connection between Hofmeister effects and phase transition of a thermo-responsive polymer. To try and prove this, the lab team decided to take four cations (Mg2+,Na+, Cs+, K+) in solution with the thermo-responsive polymers and compared their LCST to solutions of the thermo-responsive polymer in de-ionized …
Requalification Of Coated Fabrics Using Chemlok 2332 In Place Of Chemlok 233,
2019
The University of Akron
Requalification Of Coated Fabrics Using Chemlok 2332 In Place Of Chemlok 233, Daniel Madler
Williams Honors College, Honors Research Projects
Rubber coated fabrics are an essential component in the deicing systems of the aerospace industry. Adhesives cements are applied to a fabric prior to being pressed into a rubber compound that will adhere to the fabric. The resulting fabric maintains the strength of the fabric with the added benefits of elasticity and compatibility from the rubber compound. UTC Aerospace Systems relies on these coated fabrics to create safe deicers for the aerospace industry. Chemlok 233, a now obsolete primer cement, was used extensively in the coated fabrics used by UTC. Materials testing and performance evaluation allowed for a replacement cement, …
Compression Set Improvement Of Thermoplastic Vulcanizates For High Temperature Tubing,
2019
The University of Akron
Compression Set Improvement Of Thermoplastic Vulcanizates For High Temperature Tubing, Mitchell Valaitis
Williams Honors College, Honors Research Projects
It was hypothesized that increasing the curative level of the fluorocarbon rubber (FKM) used in manufacturing of thermoplastic vulcanizate (TPV) materials would decrease the compression set values of the TPV enough for it to be suitable as a flexible, lightweight alternative to high operating temperature thermoset rubber tubing currently being used for power steering hose. First, promising TPV formulations were identified by varying the polyamide (PA) and FKM used in a Brabender mixer. Four different types of polyamide and four different types of FKM were investigated, with two of the FKM types and one polyamide type identified as being promising. …
Form Stable Phase-Change Materials,
2019
University of Akron
Form Stable Phase-Change Materials, Russell Dent, Marjan Kashfipour, Nitin Mehra, Jiahua Zhu
Williams Honors College, Honors Research Projects
This work investigates the use of two different polyols, xylitol (Xyl) and erythritol (Ery), in conjunction with boron nitride (BN) aerogels, for the purpose of creating thermally conductive composites. While the BN filler in Xyl composites achieved a high anisotropic thermal conductivity of up to 4.53 W/m-K at 18.2 weight percent filler loading, they do not exhibit good phase-change material qualities due to a low solidification enthalpy even at low cooling rates. Alternatively, the BN-Ery composites have shown promising results with a solidification enthalpy of 225.14 J/g and a melting enthalpy of 385.84 J/g at a heat rate of 5 …
Multidimensional Mass Spectrometry Of Chemonic™ Ccg-6 Nonionic Surfactant With Separation By Polarity And Shape,
2019
The University of Akron
Multidimensional Mass Spectrometry Of Chemonic™ Ccg-6 Nonionic Surfactant With Separation By Polarity And Shape, Charles Johnson
Williams Honors College, Honors Research Projects
Chemonic™ CCG-6 surfactant is a water-soluble poly(ethylene glycol) (PEG) conjugated alkyl glyceride emollient. This surfactant exists as a complex mixture of a glycerol cores conjugated with poly(ethylene glycol) branches (PEGylation) that were partially esterified with caprylic (C8) and capric (C10) acids. These may be esterified on one, two, or all three arms of the glyceride. The architecture of the structures in this mixture was studied using multidimensional mass spectrometry (MS). Mass spectrometry was interfaced with ultra-performance liquid chromatography (UPLC) and ion mobility (IM) separation. The mixture was separated by reversed-phase LC, oligomers of the star-branched polymer were separated according to …
Prevention Of Harmful Algal Blooms By The Mitigation Of Phosphorus Nutrient Loading Via Filtration By Steel Wool And Activated Carbon,
2019
The University of Akron
Prevention Of Harmful Algal Blooms By The Mitigation Of Phosphorus Nutrient Loading Via Filtration By Steel Wool And Activated Carbon, Ronald Simpson, Sara Kidd, Samantha Zidd
Williams Honors College, Honors Research Projects
Harmful Algal Blooms (HABs) are a devastating ecological and economic consequence of the abundance of nutrient-rich agricultural runoff entering aquatic ecosystems (Baker et al. 2014). Bio-available phosphorus from synthetic fertilizers is one of the major nutrients contributing to this global issue. Previous studies indicated that dissolved phosphorus can be removed from an aqueous environment when passed through a composite mixture of granular steel wool particles and activated carbon (Erickson, Gulliver, and Weiss, 2007). In this project, we conducted experiments using higher quality concentration measurements to determine what grades of steel wool (SW-0000, SW-000, SW-00) and types of activated carbon (granulated …
Towards Sustainable Production Of Chemicals And Fuels From The Fast Pyrolysis Of Waste Polyolefin Plastics,
2019
Michigan Technological University
Towards Sustainable Production Of Chemicals And Fuels From The Fast Pyrolysis Of Waste Polyolefin Plastics, Ulises Gracida Alvarez
Dissertations, Master's Theses and Master's Reports
The increasing amount of plastic waste (PW) generation has become an important concern due to the leveled-off recycling rates. Therefore, governmental agencies around the world, including state governments in the United States, have proposed initiatives to minimize the amount of PW that is landfilled and encourage recycling or energy recovery. Circular economy is a strategy that attempts on reusing PW to produce new polymers while avoiding its disposal and the use of virgin material. Chemical recycling raises an interesting technology prospect due to the potential reduction of pollutant emissions and the establishment of a circular economy through the production of …
Extraction Of Astaxanthin From Engineered Camelina Sativa Seed Using Ethanol-Modified Supercritical Carbon Dioxide,
2019
University of Nebraska - Lincoln
Extraction Of Astaxanthin From Engineered Camelina Sativa Seed Using Ethanol-Modified Supercritical Carbon Dioxide, Liyang Xie, Edgar B. Cahoon, Yue Zhang, Ozan Ciftci
Department of Food Science and Technology: Faculty Publications
Natural astaxanthin, a high-value carotenoid that is currently extracted mainly from marine organisms, was extracted from engineered camelina seed using ethanol-modified supercritical carbon dioxide (SC-CO2) for the first time, and compared with hexane and accelerated solvent extraction using hexane and ethanol. Response surface methodology (RSM) based on central composite rotatable design was employed to investigate the effect of pressure (30–45 MPa), temperature (40–60 °C), and ethanol concentration (10–35%, w/w). RSM-optimized conditions (41.6 MPa, 36.6 °C and 42.0% ethanol concentration) predicted the astaxanthin concentration as 437 μg/g oil, whereas the actual concentration was 421 ± 14 μg/g oil. Astaxanthin …
Approximate Analytical Solution For Mathematical Models Of Thermal Ignition And Non-Isothermal Catalytic Zero Order Reaction In A Spherical Geometry,
2019
The British University in Egypt
Approximate Analytical Solution For Mathematical Models Of Thermal Ignition And Non-Isothermal Catalytic Zero Order Reaction In A Spherical Geometry, Moustafa A. Soliman
Chemical Engineering
In this paper an approximate analytical solution for the Frank-Kamenetskii equation modeling thermal ignition without the depletion of the combustibles in a spherical annulus and non-isothermal zero order reaction in spherical catalyst particle is presented. The approximate solution is compared with the numerical solution and is in good agreement with the numerical solution. The approximate solution obtained is valid for all values of the distance parameter. Multiple solutions occur for some range of Frank-Kamenetskii parameter (λ). The multiplicity is infinite for the case of a solid sphere and λ=2.Interesting relation is obtained for λ at the turning points. For the …
Process Synthesis And Design Of Integrated Biorefinery In Pulp And Paper Industry,
2019
Faculty of Engineering
Process Synthesis And Design Of Integrated Biorefinery In Pulp And Paper Industry, Ghochapon Mongkhonsiri
Chulalongkorn University Theses and Dissertations (Chula ETD)
Integration of biorefinery into pulp and paper industry has been considered as sustainable development for pulp and paper industry and lignocellulosic biorefinery. High value-added biochemical, biofuel and bioenergy productions could be implemented into existing pulp mills by material and utility integration. A systematic methodology employing a superstructure-based process synthesis, process design and innovation is an effective approach to explore potential pathways for both economic and environmental sustainability with support from computer-aided tools. A superstructure of the multi-product biorefinery process network with the pulp and paper industry is developed and optimized with the objective to maximize profit. The synthesis results project …
Techno-Economic Feasibility Analysis Of Hydrogen Recovery In Bio-Hydrogenated Diesel From Palm Oil For Methanol Synthesis Via Aspen Plus,
2019
Faculty of Engineering
Techno-Economic Feasibility Analysis Of Hydrogen Recovery In Bio-Hydrogenated Diesel From Palm Oil For Methanol Synthesis Via Aspen Plus, Nitipat Phichitsurathaworn
Chulalongkorn University Theses and Dissertations (Chula ETD)
A bio-hydrogenated diesel (BHD) or green diesel can be produced from refined palm oil obtained from palm oil refinery. A simulation model of BHD production process from palm oil is developed by Aspen Plus. The conventional process which is the heterogeneous catalytic hydro-deoxygenation reaction of triglycerides required high H2/oil volumetric ratio. To reduce high hydrogen loss in gaseous by-product, the design of hydrogen gas recovery process of the BHD process by coupling with methanol synthesis is proposed. The two processes (i.e., conventional BHD process and BHD process coupled with methanol synthesis) are compared in terms of hydrogen recovery and economic …
Pre-Feasibility Study Of Improving Quality Of Low-Grade Fluorite. A Case Study At Phanomthuan Deposit, Kanchanaburi, Thailand,
2019
Faculty of Engineering
Pre-Feasibility Study Of Improving Quality Of Low-Grade Fluorite. A Case Study At Phanomthuan Deposit, Kanchanaburi, Thailand, Keosaychai Souvannavong
Chulalongkorn University Theses and Dissertations (Chula ETD)
In this study was presented the pre-feasibility study of improving quality of low-grade fluorite from Phanomthuan deposit, Kanchanaburi province, Thailand. The purpose of this study aims to explore the optimal condition in order to remove the impurities which contained high SiO2, CaCO3 and other minerals, also evaluate the project in term of economic. Therefore, the improvement quality of fluorite by using froth flotation techniques was reach the ceramic grade. The raw material characterization contains CaF2 = 29.4 Wt.%, SiO2 = 43.9 Wt.% and CaCO3 = 6.9 Wt.%. After flotation process the optimal condition result which contains CaF2 = 96.46 Wt.%, …
The Study Of Sulfur Compounds For Oils Fingerprinting Application,
2019
The Petroleum and Petrochemical College
The Study Of Sulfur Compounds For Oils Fingerprinting Application, Titiparn Prasantongkolmol
Chulalongkorn University Theses and Dissertations (Chula ETD)
Oil spills are one of the serious problems to marine and coastal environment worldwide. Besides the known incidents, a number of oil spills are unknown, which may come from both accident and unauthorized drainage. Moreover, the spills cause tarball to arise on the beach and the origin of tarballs are still subtle. Thus, the development of oil fingerprinting is important in order to identify the origin of oil spills and tarballs. Generally, the current standard technique is using GCxGC-TOFMS to analyze the biomarker compounds in oil such as hopane groups. However, this technique is expensive and requires long time for …
