Chemical Engineering Commons^™

Graphene Based Barrier Membrane For Gas Separation Processes, Cheng Peng

Dissertations

Novel graphene oxide (GO) flake-based composite lamellar membrane structure is being developed as a potential component of a garment for protection against chemical warfare agents (CWAs) represented here by simulants, dimethyl methyl phosphonate (DMMP) (a sarin-simulant) and 2-chloroethyl ethyl sulfide (2-CEES) (a simulant for sulfur mustard), yet allowing a high moisture transmission rate. GO flakes of dimensions 300-800 nm, 0.7-1.2 nm thickness and dispersed in an aqueous suspension are formed into a membrane by vacuum filtration on a porous polyethersulfone (PES) or poly (ether-ether-ketone) (PEEK) support membrane for noncovalent π-π interactions with GO flakes. After physical compression of such a …

Moisture Permeable Barrier Membranes For Toxic Gases And Vapors, Yufeng Song

Dissertations

Defense against small molecule toxic gases is an important aspect of protection against chemical and biological threat as well as chemical releases from industrial accidents. Current protective respirators/garments cannot effectively block small molecule toxic gases and vapors and retain moisture transmission capability without a heavy burden.

Metal organic frameworks (MOFs) have been used as highly effective adsorbents and catalysts to remove ammonia, cyanogen chloride, and sulfur dioxide from air. A nanopacked bed of nanoparticles of MOF by synthesizing them in the pores of microporous membranes is developed in the study. The submicron scale size of membrane pores ensures a large …

Numerical Study Of Paraffin Wax Melting In A Cavity With A Gradient Of Hot Wall Inclination, Agus Dwi Korawan

Makara Journal of Technology

The melting of a phase change material (PCM) in a cavity with a gradient of hot wall inclination was simulated numerically using five models, namely, Model-A, Model-B, Model-C, Model-D, and Model-E with gradients of −2, −4, ∞, 4, and 2, respectively. The PCM was paraffin wax, which was melted using an enthalpy porosity technique with a pressure-based method. Model-A was found to be the best model. For the completion of the melting process, the models were assigned with the liquid fraction of 1. Model-A required the shortest time, followed by Model-B, Model-C, Model-E, and Model-D, respectively. Compared with Model-C, Model-A …

Influence Of Epoxidized Cardanol Functionality And Reactivity On Network Formation And Properties., Emre Kinaci, Erde Can, John J La Scala, Giuseppe R Palmese

Henry M. Rowan College of Engineering Departmental Research

Cardanol is a renewable resource based on cashew nut shell liquid (CNSL), which consists of a phenol ring with a C15 long aliphatic side chain in the meta position with varying degrees of unsaturation. Cardanol glycidyl ether was chemically modified to form side-chain epoxidized cardanol glycidyl ether (SCECGE) with an average epoxy functionality of 2.45 per molecule and was cured with petroleum-based epoxy hardeners, 4-4'-methylenebis(cyclohexanamine) and diethylenetriamine, and a cardanol-based amine hardener. For comparison, cardanol-based diphenol diepoxy resin, NC514 (Cardolite), and a petroleum-based epoxy resin, diglycidyl ether of bisphenol-A (DGEBA) were also evaluated. Chemical and thermomechanical analyses showed that for …

Ecg Processing And Analysis Technique Based On Neural Network Learning Vector Quantization, Talat Madievich Magrupov, Sherzod Kalandarovich Nеmatov, Yokubjon Talatovich Talatov

Chemical Technology, Control and Management

The main parameters of the electrocardiogram (ECG) were processed on the basis of the neural network apparatus. A decision support algorithm for ECG analysis using a neural network for learning vector quantization is proposed. For the study was chosen such features as the duration of QRS complex, RR interval, amplitude of R-wave and the change in the slope of ST segment and heart rate, which are five inputs to the neural network learning vector quantization. Methods of pre-processing and analysis of extraction of ECG functions based on the ECG database of a medical institution in Matlab are presented. The generalized …

Static Characteristics Of Thermal Humidity Converters Of Liquid Materials In Continuous Flow, N.I. Avezova, P.R. Ismatullaev, Paraxat Matyakubova

Chemical Technology, Control and Management

Thermal systems with distributed heat sources based on a pipeline segment with radial holes are proposed for the development of designs of thermal humidity converters for liquid materials. Across the liquid flow there are tubular arguments with cylindrical heat-sensitive elements, on the surface of which the heating element winding was wound, which significantly increased their sensitivity, speed, reliability and allowed the use of standard semiconductor heat-sensitive elements.

Optimal Ratio Of Primary And Secondary Clarifier Characteristics In Wastewater Treatment Plants, Makhsud Idrisovich Makhmudov, Zafarbek Esanovich Kuziev, Siroj Sobirovich Nurov, Sanjar Siroj Ugli Sidikov

Chemical Technology, Control and Management

The issues of optimization of aerobic biological wastewater treatment processes are considered. Optimal ratios of characteristics and sizes of primary and secondary sedimentation tanks, as well as their relationship with the concentration of activated sludge by volume, are revealed. Graphical representations of the dependence of the volumes of primary, secondary and total volumes of structures on the concentration of activated sludge in cleaning processes with low and high loads are obtained. Experimental studies have shown that the concentration of activated sludge in the aeration tank and the silt index directly affect the deposition characteristics of activated sludge, in particular the …

Conceptual Basis For Modeling Multi-Cordinate Mechatronic Robot Modules, Yusupbekov Azizbek Nodirbekovich, Nazarov Khayriddin Nuritdinovich, Matyokubov Nurbek Rustamovich, Temurbek Omonboyevich Rakhimov

Chemical Technology, Control and Management

The conceptual foundations of modeling multi-coordinate mechatronic modules of robots are considered. The use of a multi-coordinate mechatronic movement module in robots made it possible to obtain at the output of one module several linear and angular coordinates, which reduces the weight and dimensions of the robot and thereby improves its dynamic characteristics. The proposed original concept of the mathematical description of a multi-coordinate mechatronic module, which is focused on displaying their structural and operating features. A structural diagram of a developed industrial robot operating in a Cartesian coordinate system and built on the basis of a multi-coordinate mechatronic module …

Capacity Transformer Of Coaxial And Cylindrical Form Of Humidity Meter, Erkin Uljaev, Utkirjon Murodillaevich Ubaydullaev, Shohrux Nurali O'G'Li Narzullaev

Chemical Technology, Control and Management

The question of development and calculation of construction of a coaxial and cylindrical form of the capacity transformer of a humidity meter is considered. As basic data, the sizes and the materials ditches allowing to measure the humidity of different volumes of bulks from 5 to 50 gr are selected. As materials of a ditch, plastic are selected, and as tanks, the magnetizing materials are selected. It is briefly cited the advantages and disadvantages of ways to measure humidity and the basic dielectric characteristics of capacitive converters. The electrical replacement scheme of the proposed capacitive converter was provided and the …

Identification Of Transition Matrix Of Controlled Objects Under Parametric Uncertainty Condition, Uktam Farkhodovich Mamirov

Chemical Technology, Control and Management

The questions of formation and construction of algorithms for identification of elements of the transition matrix of controlled objects in conditions of parametric uncertainty are considered. To identify elements of the transition matrix, we suggest using a custom model based on the type of Kalman filtration equations. Algorithms for stable calculation of a pseudo-inverse matrix using matrix decomposition are analyzed. Regular algorithms for solving argumentative problems of minimization of the identification quality criterion are given. These algorithms allow us to regularize the problem of adaptive identification of the transition matrix of an object based on regular methods for minimizing functionals …

Reliable Risk Assessment Method For Effective Organization Of Information Security At Enterprise, Fayzullajon Bakhtiyorovich Botirov

Chemical Technology, Control and Management

The problems of the new industry 4.0 automation paradigm are considered and the latest technologies in the field of information and communication technologies that stimulate it are analyzed, including cyber-physical systems, cloud computing, the Internet of things and big data. Some methods of multidimensional, multi-faceted industrial representation and analysis of big data are proposed. The basics of big data processing using granular computing methods have been developed. Marked the emergence of the problem of creation of special cognitive tool for constructing artificial agents, understanding integrated intelligence enterprises. In the process of information protection at the enterprise, it is proposed to …

Detection Method For “Denial Of Service” Attacks On Web Applications, Azizbek Ravshonbek Ugli Ibrohimov

Chemical Technology, Control and Management

A method for detecting denial-of-service attacks on web applications based on the use of a multi-layer perceptron is considered. The main issues related to the use of the neural network are described: the process of collecting and preparing statistical data, the features of forming indicators that characterize the state of the web application, as well as the issues of training and evaluating the quality of the neural network.

A Study Of Security Problems In Big Data And Their Solutions, Nozima Akhmedova

Chemical Technology, Control and Management

Statistical data on information security that concerns Big Data and is the most important for enterprises are provided. Based on this data, we studied problems such as the lack of big data practices and protection, the lack of techniques for protecting big data, the lack of standards for protecting big data, the lack of regulation of big data and ecosystems, security problems in Big Data, and proposed several proposals to improve the security of systems that use this technology.

Structural – Parametric Analysis And Synthesis Of Glass Furnace Condition Observer, Utkir Uktam O‘G‘Li Kholmanov

Chemical Technology, Control and Management

A modified Kalman filter of the glass cooking process is synthesized, taking into account perturbations in the form of a sequence of colored noises. The possibility of expanding this filter by noise filters to improve functioning in the presence of low-frequency disturbances is studied and a corresponding estimation scheme with additional noise filters is proposed. The results of the simulation allow us to assume that low-frequency disturbances in the glass furnace act at the input and affect the state of the control object.

Analysis Of Information Security System Standards And Key Aspects Of Security Control, Abduhalil Abdujalilovich Ganiyev

Chemical Technology, Control and Management

The standards of the information security management system (IMS) are considered and the main aspects of information security management are studied, in particular the international standard ISO/IEC 27001, the Process approach to the management of IS, the stages of development of the information security management system. The measures taken for the organization of information security management systems are defined. Organizational measures include the implementation of information security management systems in the organization.

A Study Of Static And Dynamic Characteristics Of Multifunctional Signal Converters, Akmal Abdumalikov

Chemical Technology, Control and Management

The issues of continuity, accuracy, speed and reliability of signal conversion, which are the main problems of quality control and management of production processes, remain relevant. Research shows that in practice there are different signal variables, the study of which is highly formalized in a number of modeling tasks and basic classification studies, in particular transients in converters, its sources and elements requires a unified mathematical approach, that is, visual, highly formalized modeling and research based on it. The paper presents a graph model of multifunctional signal converters that provide microprocessor and electronic devices with signals in the form of …

Recent Progress In Bifunctional Catalysts For Zinc-Air Batteries, Neng-Neng Xu, Jin-Li Qiao

Journal of Electrochemistry

Zinc-air battery has attracted great attention from researchers due to its high energy density and power density, which is expected to be widely used in energy conversion and storage. Air electrode as the core area of oxygen catalytic reaction is the focus of the entire zinc-air battery research. Recently, many research achievements have been made in non-noble metal bifunctional catalysts/electrodes with high activity, low cost and abundant species. In this review, we mainly focus on the reaction mechanism and the recent progress in non-noble metal oxide catalyst, carbon-based catalyst, and carbon-based transition metal compound composite and self-supporting electrode. In addition, …

Research Progress Of Metal-Nitrogen-Carbon Catalysts Toward Oxygen Reduction Reaction Inm Changchun Institute Of Applied Chemistry, Ming-Jun Xu, Jie Liu, Jun-Jie Ge, Chang-Peng Liu, Wei Xing

Journal of Electrochemistry

The development of highly active and stable catalysts toward oxygen reduction reaction (ORR) has been facing severe challenges. In recent years, pyrolytic M-N-C catalysts and metal-organic framework derived materials made the performance of non-noble metal catalysts greatly improved, however, the molecular and atomic level understanding in the reaction active sites and the mechanism are still lacking. Here, we summarize the recent research progress made in the Changchun Institute of Applied Chemistry. We present a microporous metal-organic-framework confined strategy toward the preferable formation of ORR catalysts. Firstly, we studied the active site and proposed a new active site structure for the …

Electrochemical Carbon Dioxide Reduction In Flow Cells, Jia Fan, Na Han, Yan-Guang Li

Journal of Electrochemistry

Electrochemical carbon dioxide reduction (CO₂RR) is an appealing approach to convert atmospheric CO₂ to value-added fuels and industrial chemicals, and may play an important role during the transition to a carbon-neutral economy. In order to make this technology commercially viable, it is essential to pursue CO₂RR in flow reactors instead of conventional H-type reactors, and to combine electrocatalyst development with system engineering. In this review, we overview the cell configurations and performance advantages of the two types of flow reactors, analyze their shortcomings, and discuss the effects of their different components including gas diffusion electrode …

Electrolyte Tailoring For Electrocatalytic Reduction Of Stable Molecules, Jin-Han Li, Fang-Yi Cheng

Journal of Electrochemistry

Reduction of stable molecules such as CO₂ and N₂ is important process in electrochemical energy conversion and storage technologies for electrofuels production. However, for the inert nature of CO₂/N₂ molecule and competitive proton reduction in conventional aqueous electrolytes, selective electrochemical carbon/nitrogen fixation suffers from high overpotential, low reaction rate and low selectivity. While addressing these issues has witnessed substantial advances in electrocatalysts, much less attention has been placed on the electrolytes, which play an important role in regulating the local environment and thus the performance of catalysts under operating conditions. Rational design of electrolytes has …