Analysis Of Errors Of The Ultrasonic Level And Increasing The Accuracy Of Measuring The Level Of Liquid Materials In Non-Stationary Media,
2021
Tashkent State Technical University, Address: 2 Universitetskaya st., 100095, Tashkent city, Republic of Uzbekistan E-mail: [email protected], Phone: +998-97-781-09-60.
Analysis Of Errors Of The Ultrasonic Level And Increasing The Accuracy Of Measuring The Level Of Liquid Materials In Non-Stationary Media, Azamat Alijonovich Yusupov
Chemical Technology, Control and Management
This article is devoted to the analysis of the total error of an ultrasonic level meter designed to measure the level of liquid materials in order to improve the accuracy of the measuring system in tanks. The components of the total error of the process of measuring transformation of the liquid level are determined and the analysis of the main characteristics is carried out, to reduce the random error of the measurement system, the task of ensuring the accuracy of measurement and control of the level using an ultrasonic level gauge is presented, by averaging the measurement results when calculating …
Formalization Of The Procedure For Choosing The Optimality Criterion And Formulation The Problem Of Ammonium Nitrate Production Control,
2021
Full member (academician) of the academy of sciences of the Republic of Uzbekistan, doctor of technical sciences, professor of the department “Information Processing Systems and Control” at Tashkent state technical university named after Islam Karimov, Address: 2 Universitetskaya st., 100095, Tashkent city, Republic of Uzbekistan, E-mail: [email protected];
Formalization Of The Procedure For Choosing The Optimality Criterion And Formulation The Problem Of Ammonium Nitrate Production Control, Husan Zakirovich Igamberdiev, Uktam Farkhodovich Mamirov
Chemical Technology, Control and Management
The article discusses the questions of formalization of the procedure for choosing an optimality criterion and setting the problem of controlling the production of ammonium nitrate. The analysis of the technical and economic features of the considered production is carried out. As a criterion for the efficient operation of ammonium nitrate production, such a technological indicator as specific technological costs for the main stages, determined by the interval of quasi-stationarity of the object, is used, i.e. the time of its stable work. To solve the control problem, it is proposed to use the decomposition of the control problem into a …
Dft Study Of NiM@Pt1AuN-M-1 (N=19, 38, 55, 79; M = 1, 6, 13, 19) Core-Shell Orr Catalyst,
2021
1. State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, Liaoning, China;
Dft Study Of NiM@Pt1AuN-M-1 (N=19, 38, 55, 79; M = 1, 6, 13, 19) Core-Shell Orr Catalyst, Wen-Jie Li, Dong-Xu Tian, Hong Du, Xi-Qiang Yan
Journal of Electrochemistry
The slow kinetics of oxygen reduction reaction (ORR) limits the performance of low temperature fuel cells. Thus, it needs to design effective catalysts with low cost. Core-shell clusters (CSNCs) show promising activity because of their size-dependent geometric and electronic effects. The ORR activity trend of Nim@Pt1Aun-m-1(n = 19, 38, 55, 79; m = 1, 6, 13, 19) was studied using the GGA-PBE-PAW methods. The adsorption configurations of *O, *OH and *OOH were optimized and the reaction free energies of four proton electron (H+ + e-) transfer steps …
One-Pot Synthesis Of Fe2O3@Fe-N-C Oxygen Reduction Electrocatalyst And Its Performance For Zinc-Air Battery,
2021
College of Energy, Xiamen University, Xiamen 361005, Fujian, China;
One-Pot Synthesis Of Fe2O3@Fe-N-C Oxygen Reduction Electrocatalyst And Its Performance For Zinc-Air Battery, Hua Lin, Yi-Jin Wu, Jun-Tao Li, Yao Zhou
Journal of Electrochemistry
Oxygen reduction reaction (ORR) plays a profound role in determining cathode performance in metal-air batteries and fuel cells. Owing to its inherently sluggish kinetics, high-performance ORR catalysts which favors the scissoring of O-O bond and formation of O-H bond are a requisite. In this regard, Pt has been explored as the most efficient ORR electrocatalysts. Nevertheless, due to its expensiveness, the usage of Pt catalysts represents one of the major sources of cost in those energy conversion devices. Thus, the development of alternative ORR electrocatalysts with minimized Pt utilization has been widely pursued over the past few decades. Metal-nitrogen-carbon catalysts …
Preparation And Electrochemical Evaluation Of Mos2/Graphene Quantum Dots As A Catalyst For Hydrogen Evolution In Microbial Electrolysis Cell,
2021
1. Department of Materials and Chemical Engineering, Taiyuan College, Taiyuan 030032, Shanxi, China;
Preparation And Electrochemical Evaluation Of Mos2/Graphene Quantum Dots As A Catalyst For Hydrogen Evolution In Microbial Electrolysis Cell, Hong-Yan Dai, Hui-Min Yang, Xian Liu, Xiu-Li Song, Zhen-Hai Liang
Journal of Electrochemistry
Microbial electrolysis cell (MEC) is a relatively new bioelectrochemical technology that produces H2 and meanwhile treats organic wastewater. Cathode hydrogen evolution catalyst plays a key role in MEC. The doping of Graphene Quantum Dots (GQDs) into MoS2 nanosheets can improve the catalytic activity of MoS2 by creating abundant defect sites both in the edge plane and the basal plane, as well as enhancing the electrical conductivity. In this paper, using Na2MoO4 , cysteine and GQDs as raw materials, a series of MoS2/GQDs composites were firstly synthesized via hydrothermal method, and then loaded …
Preparation Of Coo/Rgo@Ni Foam Electrode And Its Electrocatalytic Reduction Of Co2,
2021
College of Environment and Chemical Engineering, Jiangsu Ocean University, Lianyungang 222005, Jiangsu, China;
Preparation Of Coo/Rgo@Ni Foam Electrode And Its Electrocatalytic Reduction Of Co2, Qian Guo, Jia-Long Fu, Cheng-Yan Zhang, Chao-Yue Cai, Cheng Wang, Li-Hua Zhou, Rui-Bo Xu, Ming-Yan Wang
Journal of Electrochemistry
The worldwide extensive release of carbon dioxide (CO2) has caused serious environmental pollution and unprecedented climate change problems. Thus, for the sustainable development of human society, it is very necessary to convert CO2 to renewable fuels through clean and economical processes. The electrochemical CO2 reduction reaction (CO2RR) is regarded as a promising approach for the recycling of carbon resource and the generation of sustainable fuels. However, the slow kinetics and formation of multiple products in CO2RR hinder its large-scale application. Hence, great research efforts are made to develop electrocatalysts with high product …
No Ordinary Proteins: Adsorption And Molecular Orientation Of Monoclonal Antibodies,
2021
CUNY City College
No Ordinary Proteins: Adsorption And Molecular Orientation Of Monoclonal Antibodies, Ankit D. Kanthe, Andrew Ilott, Mary Krause, Songyan Zheng, Jinjiang Li, Wei Bu, Mrinal K. Bera, Binhua Lin, Charles Maldarelli, Raymond S. Tu
Publications and Research
The interaction of monoclonal antibodies (mAbs) with air/water interfaces plays a crucial role in their overall stability in solution. We aim to understand this behavior using pendant bubble measurements to track the dynamic tension reduction and x-ray reflectivity to obtain the electron density profiles (EDPs) at the surface. Native immunoglobulin G mAb is a rigid molecule with a flat, “Y” shape, and simulated EDPs are obtained by rotating a homology construct at the surface. Comparing simulations with experimental EDPs, we obtain surface orientation probability maps showing mAbs transition from flat-on Y-shape configurations to side-on or end-on configurations with increasing concentration. …
Merging Of Horizontally And Vertically Separated Small-Scale Buoyant Flames,
2021
Brigham Young University - Provo
Merging Of Horizontally And Vertically Separated Small-Scale Buoyant Flames, Thomas H. Fletcher, Denver Haycock, Seth Tollefsen, David Lignell
Faculty Publications
The purpose of this study was to investigate the merging behavior of small-scale buoyant flames that might be representative of flames from a leaf in a shrub. Zirconia felt pads soaked in n-heptane were suspended on thin rods and spaced both horizontally and vertically. Time-dependent video images from flames from two-pad and three-pad configurations were analyzed to determine merging probability, combined flame characteristics (height, area, and width), and changes in burn time. Correlations of these combined flame characteristics were developed based on horizontal and vertical spacing between the pads. Merging probability correlated with an exponential function that was quadratic in …
Engineering The Surface Of Fe3o4 Nanoparticles For Catalytic And Magnetic Applications,
2021
Louisiana State University and Agricultural and Mechanical College
Engineering The Surface Of Fe3o4 Nanoparticles For Catalytic And Magnetic Applications, Natalia Da Silva Moura
LSU Doctoral Dissertations
With the rapid depletion of the U.S. energy resources coupled with population growth, heat management technologies must be improved to sustain our quality of life. Precisely, in catalysis, it is estimated that only ~50% of the energy supplied to the reactor is used for product conversion due to dissipation losses. Among the emerging technologies with a promising reduction in heat losses is induction heating, offering targeted heat delivery with magnetic nanoparticles. Under alternating magnetic fields (AMF), these nanoparticles can absorb the energy from Radio-Frequency (RF) fields and dissipate it as heat on the nanoparticle surface. This in situ heat generation …
Gum Arabic-Capped Silver Nanoparticles For Electrochemical Amplification Sensing Of Methylene Blue In River Water,
2021
Menoufia University
Gum Arabic-Capped Silver Nanoparticles For Electrochemical Amplification Sensing Of Methylene Blue In River Water, Ziad Khalifa, Moustafa Zahran, Magdy Zahran, Magdi Abdelazzem
Chemical Engineering
Herein, a novel electrochemical amplification sensor is developed for detecting methylene blue (MB) us- ing gum Arabic-capped silver nanoparticles (AgNPs) for the first time. Gum Arabic-AgNPs were fabricated via a direct chemical reduction technique using silver nitrate as an AgNPs precursor and gum Arabic as a reducing and capping agent. They were characterized using ultraviolet-visible (UV–Vis) spectrophotom- etry, square wave voltammetry (SWV), and transmission electron microscopy (TEM). UV–Vis and SWV results show the characteristic absorption and electrochemical oxidation peaks of the AgNPs at 431 nm and 0.18 V, respectively. Additionally, TEM images of the AgNPs show that they are spherical …
Analytical Model For Electromagnetic Induction In Pulsating Ferrofluid Pipe Flows,
2021
University of Oklahoma
Analytical Model For Electromagnetic Induction In Pulsating Ferrofluid Pipe Flows, Huiyu Wang, John G. Monroe, Swati Kumari, Serhiy O. Leontsev, Erick S. Vasquez, Scott M. Thompson, Matthew J. Berg, Dibbon Keith Walters, Keisha B. Walters
Chemical and Materials Engineering Faculty Publications
No abstract provided.
Elementary Reaction-Based Kinetic Model For The Fate Of: N -Nitrosodimethylamine Under Uv Oxidation,
2021
Michigan Technological University
Elementary Reaction-Based Kinetic Model For The Fate Of: N -Nitrosodimethylamine Under Uv Oxidation, Benjamin Barrios, Divya Kamath, Erica Coscarelli, Daisuke Minakata
Michigan Tech Publications, Part 1
UV photolysis is an effective process to remove nitrosamines from contaminated water resources. Nitrosamines represent a class of compounds with high potential for carcinogenicity and, therefore, there are serious concerns regarding their threat to human health and their environmental toxicity. Although the photochemical parameters of parent nitrosamines and their initial reaction pathways are well understood, the fate of nitrogen-containing species and reactive nitrogen species generated from nitrosamine degradation has not yet been elucidated. In this study, we develop an elementary reaction-based kinetic model for the photolysis of N-nitrosodimethylamine (NDMA) and the photochemical transformation products. We use density functional theory quantum …
Novel Method Of Manufacture Of Metal Nanoparticles And Metal Single-Atom Materials On Various Substrates And Novel Compositions,
2021
Missouri University of Science and Technology
Novel Method Of Manufacture Of Metal Nanoparticles And Metal Single-Atom Materials On Various Substrates And Novel Compositions, Xinhua Liang, Xiaofeng Wang
Chemical and Biochemical Engineering Faculty Research & Creative Works
The present invention discloses a novel method and novel compositions comprising well-dispersed particulate metal materials, including metal nanoparticles and/or metal single-atom materials, on various substrates, said method comprising the use of atomic layer deposition (ALD) and optimization of the metal precursor dose time and the number of ALD cycles. Illustrative of the metals are Fe, Ni, Co, Ru, Rh, Ir, Os, Pt, Pd, and the like; and illustrative of the various substrates are carbon nanotubes (CNTs) (including multi-walled carbon nanotubes (MWCNTs), SiO2, TiO2, alumina, CeO2, ZnO, ZrO2, activated carbon, CuO, Fe2 …
Heteroacene-Based Amphiphile As A Molecular Scaffold For Bioimaging Probes,
2021
University of Mississippi
Heteroacene-Based Amphiphile As A Molecular Scaffold For Bioimaging Probes, Tharindu A. Ranathunge, Mahesh Loku Yaddehige, Jordan H. Varma, Cameron Smith, Jay Nguyen, Iyanuoluwani Owolabi, Wojciech Kolodziejczyk, Nathan I. Hammer, Glake Hill, Alex Flynt, Davita L. Watkins
Faculty and Student Publications
The challenges faced with current fluorescence imaging agents have motivated us to study two nanostructures based on a hydrophobic dye, 6H-pyrrolo[3,2-b:4,5-b’]bis [1,4]benzothiazine (TRPZ). TRPZ is a heteroacene with a rigid, pi-conjugated structure, multiple reactive sites, and unique spectroscopic properties. Here we coupled TRPZ to a tert-butyl carbamate (BOC) protected 2,2-bis(hydroxymethyl)propanoic acid (bisMPA) dendron via azide-alkyne Huisgen cycloaddition. Deprotection of the protected amine groups on the dendron afforded a cationic terminated amphiphile, TRPZ-bisMPA. TRPZ-bisMPA was nanoprecipitated into water to obtain nanoparticles (NPs) with a hydrodynamic radius that was comparison, TRPZ-PG was encapsulated in pluronic-F127 (Mw = 12 kD), a polymer surfactant …
Electrochemical Micro-Aptasensors For Exosome Detection Based On Hybridization Chain Reaction Amplification,
2021
Zhengzhou University
Electrochemical Micro-Aptasensors For Exosome Detection Based On Hybridization Chain Reaction Amplification, Wenfen Zhang, Zhenhua Tian, Shujie Yang, Joseph Rich, Shuaiguo Zhao, Mikael Klingeborn, Po-Hsun Huang, Zhishang Li, Alexander Stout, Quinn Murphy, Edward Patz, Shusheng Zhang, Guozhen Liu, Tony Jun Huang
Faculty Publications
Exosomes are cell-derived nanovesicles that have recently gained popularity as potential biomarkers in liquid biopsies due to the large amounts of molecular cargo they carry, such as nucleic acids and proteins. However, most existing exosome-based analytical sensing methods struggle to achieve high sensitivity and high selectivity simultaneously. In this work, we present an electrochemical micro-aptasensor for the highly sensitive detection of exosomes by integrating a micropatterned electrochemical aptasensor and a hybridization chain reaction (HCR) signal amplification method. Specifically, exosomes are enriched on CD63 aptamer-functionalized electrodes and then recognized by HCR products with avidin-horseradish peroxidase (HRP) attached using EpCAM aptamers as …
Threshold Concentration And Random Collision Determine The Growth Of The Huntingtin Inclusion From A Stable Core,
2021
CUNY York College
Threshold Concentration And Random Collision Determine The Growth Of The Huntingtin Inclusion From A Stable Core, Sen Pei, Theresa C. Swayne, Jeffrey F. Morris, Lesley Emtage
Publications and Research
The processes underlying formation and growth of unfolded protein inclusions are relevant to neurodegenerative diseases but poorly characterized in living cells. In S. cerevisiae, inclusions formed by mutant huntingtin (mHtt) have some characteristics of biomolecular condensates but the physical nature and growth mechanisms of inclusion bodies remain unclear. We have probed the relationship between concentration and inclusion growth in vivo and find that growth of mHtt inclusions in living cells is triggered at a cytoplasmic threshold concentration, while reduction in cytoplasmic mHtt causes inclusions to shrink. The growth rate is consistent with incorporation of new material through collision and coalescence. …
Droplet And Particle Dynamics In Aerosol Reactors And Environmental System,
2021
Washington University in St. Louis
Droplet And Particle Dynamics In Aerosol Reactors And Environmental System, Sukrant Dhawan
McKelvey School of Engineering Graduate Student Theses & Dissertations
Aerosol science and engineering is an enabler for continual advances in nanomaterial synthesis. The spray-based techniques have been used extensively for the large-scale production of nanoparticles. Synthesis of particles with a desired the size and morphology is of key importance for exploiting their properties for their use in several emerging technologies. In contrast to useful nanomaterials, the aerosols from industrial flue gas, dust, indoor cooking, pathogens, and wildfire etc. are harmful to human health. It is important to understand how these harmful aerosols travel through the environment and potentially impact the health. It is also very critical to improve the …
Influence Of Aerosols During Amine-Based Co2 Capture: Evolution And Control,
2021
Washington University in St. Louis
Influence Of Aerosols During Amine-Based Co2 Capture: Evolution And Control, David Immanuel Arthur Dhanraj
McKelvey School of Engineering Graduate Student Theses & Dissertations
Driven by escalating concerns on global warming and climate change, significant efforts have recently been initiated to reduce atmospheric CO2 concentration. Power generation from fossil fuels is the largest source of anthropogenic CO2. The US government has incentivized carbon capture through Section 45Q Tax code, which provides US$50/tCO2 (per metric ton) of qualified carbon dioxide captured and sequestered, as tax credits. The cost for carbon capture, transport and sequestration is US$75 – 150/t CO2, with the state-of-the-art capture technology costing between US$20 – 100/t CO2. Amine based post-combustion CO2 capture is the most economic technology suited for large power plants. …
Direct Activation Of Light Alkanes To Value-Added Chemicals Using Supported Metal Oxide Catalysts,
2021
Louisiana State Univ, Dept Chem Engn, Baton Rouge, LA
Direct Activation Of Light Alkanes To Value-Added Chemicals Using Supported Metal Oxide Catalysts, Md Ashraful Abedin
LSU Doctoral Dissertations
One of the most challenging aspects of modern-day catalysis is the conversion of methane. Direct conversion of methane via dehydroaromatization (MDHA) is a well-known process which can produce valuable hydrocarbons. Mo oxide supported on ZSM-5/MCM-22 has been studied extensively in recent years for MDHA. Mo carbides are responsible for activating methane by forming CHx species. These are dimerized into C2Hy and oligomerized on ZSM-5/MCM-22 Brønsted acid sites to form aromatics. Sulfated zirconia (SZ) supported Mo catalyst contains the acid sites necessary to produce benzene in MDHA. Here, sulfated hafnia (SH), a homologous oxide like SZ, has been proposed to provide …
Rapid Computation Of Effective Conductivity Of 2d Composites By Equivalent Circuit And Spectral Methods.,
2021
Brigham Young University
Rapid Computation Of Effective Conductivity Of 2d Composites By Equivalent Circuit And Spectral Methods., Ben J. Ransom, Dean R. Wheeler
Faculty Publications
This work presents models for homogenizing or finding the effective transport or mechanical properties of microscale composites formed from highly contrasting phases described on a grid. The methods developed here are intended for engineering applications where speed and geometrical flexibility are a premium. A canonical case that is mathematically challenging and yet can be applied to many realistic materials is a 4-phase 2-dimensional periodic checkerboard or tiling. While analytic solutions for calculating effective properties exist for some cases, versatile methods are needed to handle anisotropic and non-square grids. A reinterpretation and extension of an existing analytic solution that utilizes equivalent …
