The Optimization Of Failure Risk Estimation On The Uniform Corrosion Rate With A Non-Linear Function,
2022
Universitas Indonesia
The Optimization Of Failure Risk Estimation On The Uniform Corrosion Rate With A Non-Linear Function, Fernanda Hartoyo, Jaka Fajar Fatriansyah, Imam Abdillah Mas'ud, Farhan Rama Digita, Hanna Ovelia, D. Rizal Asral
Journal of Materials Exploration and Findings
Failures in the oil and gas pipeline system are conditions that must be avoided and anticipated because the losses due to the failures can occur at a very high level. Internal corrosion is one of the significant causes of the failures in pipeline systems. In addition, this type of corrosion is due to the high content of carbon dioxide and other corrosive substances in crude oil and natural gas. Therefore, an optimal inspection scheduling system is required to prevent the possibility of pipeline failures due to corrosion and to avoid any overspending on the budget due to excessive inspection scheduling. …
Dynamics Of Spatiotemporal Heterogeneities In Particulate Intercalation Electrodes,
2022
Washington University in St. Louis
Dynamics Of Spatiotemporal Heterogeneities In Particulate Intercalation Electrodes, Shubham Agrawal
McKelvey School of Engineering Graduate Student Theses & Dissertations
Electrochemical energy systems rely on particulate porous electrodes to store or convert energies. While the three-dimensional porous structures of the electrodes were introduced to maximize the interfacial area for better overall performance of the system, spatiotemporal heterogeneities arising from materials thermodynamics localize the charge transfer processes onto a limited portion of the available interfaces. These reaction heterogeneities may cause local hot and cold spots, and early battery failures. This dissertation focuses on the following three aspects of the dynamic reaction heterogeneities in the particulate cathodes and anodes in the lithium-ion batteries: (i) the real-time evolution of reaction heterogeneities in graphite …
Photochemical Formation Mechanisms And Applications Of Mn Oxide Nanomaterials,
2022
Washington University in St. Louis
Photochemical Formation Mechanisms And Applications Of Mn Oxide Nanomaterials, Zhenwei Gao
McKelvey School of Engineering Graduate Student Theses & Dissertations
Manganese (Mn) oxides are ubiquitous in aquatic and terrestrial environments, and the rich redox chemistry of manganese is of interest in engineered systems, such as batteries and water oxidation catalysts. Mn oxides have large surface areas and are highly active in adsorption and redox reactions. Our research group recently reported photochemically-assisted abiotic inorganic oxidation of Mn2+(aq) to δ-MnO2 nanosheets in the presence of nitrate and without a microorganism, demonstrating that abiotic Mn oxidation processes are not negligible. My doctoral work focuses on investigating the effects of various aquatic chemistry parameters, including reactive oxygen species (ROS), peroxyl radical (ROO•), reactive halogen …
The Generation And Transport Of Charged Aerosols: Fundamental Study And Applications In Medicine And Energy Conversion,
2022
Washington University in St. Louis
The Generation And Transport Of Charged Aerosols: Fundamental Study And Applications In Medicine And Energy Conversion, Hao Zhou
McKelvey School of Engineering Graduate Student Theses & Dissertations
Charged aerosols have significant implications in the field of functional material synthesis, pharmaceutical coating, and drug delivery. Electrospray systems are an effective methodology for generating highly charged monodispersed droplets in the size range from nanometer to micrometer. The prediction of surface charge, size and morphology of nanoparticles resulting from charged droplets are highly required for the precise control of nanoparticle properties and their effective utilization. However, the evolution of charged droplet is not well understood due to the existence of coulombic fission and ion evaporation processes. Thus, the goal of this dissertation is to elucidate how the precursor properties and …
Advancing Water Resource Assessment With Insar Data And Subsidence Models,
2022
Missouri University of Science and Technology
Advancing Water Resource Assessment With Insar Data And Subsidence Models, Ryan G. Smith
Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works
Over the past three decades, Interferometric Synthetic Aperture Radar (InSAR) has grown from a tool for monitoring earthquakes and other massive signature deformation events to tracking the subtle, slow deformation processes associated with changes in groundwater storage. Improvements in time-series processing and noise reduction, as well as improved models of deformation, have enabled this advancement. InSAR has proven to be a valuable tool for characterizing elastic deformation in regions experiencing little long-term storage loss, as well as inelastic deformation in over-stressed aquifers.
Contents,
2022
Universitas Indonesia
Contents, Jaka Fajar Fatriansyah
Journal of Materials Exploration and Findings
No abstract provided.
Synthesis And Consolidation Of Metal Oxide Nanocrystals Via Nonthermal Plasma,
2022
Washington University in St. Louis
Synthesis And Consolidation Of Metal Oxide Nanocrystals Via Nonthermal Plasma, Austin Cendejas
McKelvey School of Engineering Graduate Student Theses & Dissertations
Nonthermal plasmas offer a unique nonequilibrium environment that has been leveraged in a wide variety of applications in the fields of material processing, lighting, and waste management to name a few. In all of these cases, the plasma serves as a source of high energy electrons, ions, reactive gas species, and radicals that interact in several ways with surfaces brought into contact with the plasma. Specifically, nonthermal plasmas have been shown to be very successful in achieving continuous, high-throughput, monodisperse nanocrystals of a wide variety of materials. The crystallinity of nanoparticles synthesized in nonthermal plasmas can be attributed to the …
Advanced Nanomaterials And Module Designs For Efficient Photothermal Water Treatment,
2022
Washington University in St. Louis
Advanced Nanomaterials And Module Designs For Efficient Photothermal Water Treatment, Deoukchen Ghim
McKelvey School of Engineering Graduate Student Theses & Dissertations
Water scarcity is one of the most serious challenges that human beings face, and the demand for clean water will continuously increase as populations grow. Creating potable water from saline water is an important way to meet global freshwater demands. However, current desalination techniques require high energy consumption and a large scale to be efficient, restricting their utilization in remote and underdeveloped areas. These constraints motivate the development of sustainable water treatment methods that can be used with less energy input, in small modular configurations, and in off-grid water treatment systems. As an abundant and renewable energy source, sunlight has …
Nano-Bio Interactions: Implications And Applications,
2022
Washington University in St. Louis
Nano-Bio Interactions: Implications And Applications, Anushree Ghosh
McKelvey School of Engineering Graduate Student Theses & Dissertations
Rapid expansion of technology development at the nanoscale has underpinned a promising industry. Towards this, there remain significant information gaps which are critical with regard to decision making processes and ultimate industrial sustainability. From an implication point of view, understanding how common biological macromolecules, including glycolipids and/or biopolymers produced by bacteria and fungi, which are ubiquitous in the environment, is fundamental to predicting the behavior of released/produced nanoparticles. Conversely, other bio-based tailored macromolecules, including mussel foot protein (MFP), have significant potential as functional material coatings for advanced applications.This PhD thesis is focused on interfacial processes related to superparamagnetic iron oxide …
Droplet-Based Two-Phase Thermal Management,
2022
Washington University in St. Louis
Droplet-Based Two-Phase Thermal Management, Junhui Li
McKelvey School of Engineering Graduate Student Theses & Dissertations
The rapid development of electronic systems with ever-higher power densities in a wide range of applications requires new advanced thermal management methods. Droplet-based two-phase thermal management technologies are considered promising solutions to conquer the cooling challenges in the electronic industries. The heat transfer behavior of droplets is based on several important fundamental processes, such as droplet evaporation, droplet impact on heated surfaces, and molten droplet impact. In this dissertation, four research projects are completed to explore the insights of these fundamental processes. For droplet evaporation, I introduce an investigation of diffusion confinement of droplets evaporating on a supported pillar structure. …
Lead(Iv) Oxide In Drinking Water Systems: Formation, Dissolution, Redox-Driven Recrystallization, And Implications For Lead Control,
2022
Washington University in St. Louis
Lead(Iv) Oxide In Drinking Water Systems: Formation, Dissolution, Redox-Driven Recrystallization, And Implications For Lead Control, Weiyi Pan
McKelvey School of Engineering Graduate Student Theses & Dissertations
Lead (Pb) in tap water is mainly contributed by lead service lines (LSLs). The dissolved lead concentration is controlled by the solubilities of lead corrosion products that form on the inner surface of LSLs. Among these lead corrosion products, lead(IV) oxide (PbO2) has the lowest solubility and can maintain a low lead level when free chlorine is present. Current strategies to control the lead concentration include replacing the LSL, optimizing the water chemistry conditions, and using point-of-use (POU) filters. The present study investigated the effect of manganese (Mn) on the oxidation of the lead(II) carbonate solids by free chlorine, the …
Droplet Dynamics And Heat Transfer During Condensation On Lubricant-Infused Surfaces,
2022
Washington University in St. Louis
Droplet Dynamics And Heat Transfer During Condensation On Lubricant-Infused Surfaces, Jianxing Sun
McKelvey School of Engineering Graduate Student Theses & Dissertations
Inspired by pitcher plants, a micro/nano- structured solid surface infused with low-surface-tension lubricant constitutes a novel class of biomimetic surfaces—lubricant-infused surfaces (LISs). Unlike solid hydrophobic and superhydrophobic surfaces, a LIS is “hemi-solid and hemi-liquid”. The thin lubricating film can extraordinarily decrease adhesion and avoid contact line pinning between the working fluid and the underlying solid, displaying many desirable properties, such as excellent liquid repellency, suppression of fouling, and self-healing. Hence, LISs are ideal for applications where liquids or contaminants must be efficiently removed from surfaces in harsh environments. For example, LISs can promote stable dropwise condensation of water or low-surface-tension …
Nanoscale Interfacial Control Of Ion Behaviors And Caco3 Formation In Environmental Systems,
2022
Washington University in St. Louis
Nanoscale Interfacial Control Of Ion Behaviors And Caco3 Formation In Environmental Systems, Yaguang Zhu
McKelvey School of Engineering Graduate Student Theses & Dissertations
Interfaces in environmental systems can change the distribution of pollutants and nutrients, determine the fate and transport of nanoparticles, and affect the efficiency of engineering projects. Complex interactions, including electrostatic interactions, Van der Waals interactions, chemical interactions, and ion-surface specific interactions, can all contribute to different ion, ion-pair, and nanoparticle formations near interfaces. Although environmental interfaces play critical roles, only a limited number of studies have considered the nanoscale picture of how they control ions and nanoparticles. Thus, this dissertation addresses three research questions: (1) How does sulfate chemically interact with calcium carbonate (CaCO3) during its heterogeneous formation on quartz …
Nonordered Dendritic Mesoporous Silica Nanoparticles As Promising Platforms For Advanced Methods Of Diagnosis And Therapies,
2022
University of Manchester
Nonordered Dendritic Mesoporous Silica Nanoparticles As Promising Platforms For Advanced Methods Of Diagnosis And Therapies, S. Malekmohammadi, Riaz Ur Rehman Mohammed, H. Samadian, A. Zarebkohan, A. García-Fernández, G. R. Kokil, F. Sharifi, J. Esmaeili, M. Bhia, M. Razavi, M. Bodaghi, T. Kumeria, R. Martínez-Máñez
Department of Chemical and Biomolecular Engineering: Faculty Publications
Dendritic mesoporous silica nanoparticles (DMSNs) are a new generation of porous materials that have gained great attention compared to other mesoporous silicas due to attractive properties, including straightforward synthesis methods, modular surface chemistry, high surface area, tunable pore size, chemical inertness, particle size distribution, excellent biocompatibility, biodegradability, and high pore volume compared with conventional mesoporous materials. The last years have witnessed a blooming growth of the extensive utilization of DMSNs as an efficient platform in a broad spectrum of biomedical and industrial applications, such as catalysis, energy harvesting, biosensing, drug/gene delivery, imaging, theranostics, and tissue engineering. DMSNs are considered great …
3d Fracture Propagation Simulation And Pressure Decline Analysis Research For I-Shaped Fracture Of Coalbed,
2022
Edith Cowan University
3d Fracture Propagation Simulation And Pressure Decline Analysis Research For I-Shaped Fracture Of Coalbed, Chengwang Wang, Zixi Guo, Lifeng Zhang, Yunwei Kang, Zhenjiang You, Shuguang Li, Yubin Wang, Huaibin Zhen
Research outputs 2022 to 2026
After hydraulic fracturing, some treatments intended for production enhancement fail to yield predetermined effects. The main reason is the insufficient research about the fracture propagation mechanism. There is compelling evidence that I-shaped fracture, two horizontal fractures at the junction of coalbed and cover/bottom layer, and one vertical fracture in the coalbed have formed in part of the coalbed after hydraulic fracturing. Therefore, this paper aims at I-shaped fracture propagation simulation. A novel propagation model is derived on the basis of a three-dimensional (3D) model, and the coupling conditions of vertical fracture and horizontal fractures are established based on the flow …
Experimental Study On Co2-Sensitive Polyacrylamide As Potential In-Situ Sealing Agent For Co2 Leakage Pathways In Geological Storage Sites,
2022
Mississippi State University
Experimental Study On Co2-Sensitive Polyacrylamide As Potential In-Situ Sealing Agent For Co2 Leakage Pathways In Geological Storage Sites, Iris Laihmen Quan Lopez
Theses and Dissertations
As the world pushes for ‘greener’ technologies and carbon neutrality, efforts have focused on creating novel ways to mitigate humankind’s carbon footprint. Carbon capture and storage (CCS) has become a prevalent technique that has proven to be an effective long-term method to safely relocate excess carbon dioxide (CO2) into subsurface formations. However, CCS is a newer technique which requires constant monitoring due to potential leakage pathways present in CO2 storage sites; therefore, a preventive approach to seal leakage pathways is recommended. This dissertation explores the potential of CO2-sensitive polyacrylamide (CO2-SPAM) as a novel …
Ultraviolet Chiral Plasmonics,
2022
Louisiana State University and Agricultural and Mechanical College
Ultraviolet Chiral Plasmonics, Tiago Ramos Leite Da Silva
LSU Doctoral Dissertations
The far- (λ < 250 nm) ultraviolet (UV) chiroptical response from protein secondary structures can aid in understanding protein interactions for drug discovery. Chiral metasurfaces have attracted attention to enhance the intrinsically weak biomolecular optical activity for improved structural biology characterization. However, due to materials and fabrication challenges, current metasurfaces mostly operate in the visible and near-infrared regimes with limited, if any, response in far-UV. The large spectral mismatch between metasurface and biomolecular resonances limits the chiral enhancement factor. In this work, we study aluminum planar metamaterials which display optical activity in the UV region. In the first part of this work, we experimentally and computationally investigate the resonant plasmonic-biomolecular interactions in the far-UV. To the best of our knowledge, our work is the first to experimentally explore these resonant interactions in the biologically relevant far-UV regime. We demonstrate experimentally and computationally enhanced chiral sensing of sub-10 nm amino acid films. We develop a full-wave computational model of a biomolecular film on an aluminum gammadion array using experimentally derived chiral parameters (κ) for L- and DTyrosine films. Our model shows that detectable enhancements in the circular dichroism (CD) and birefringence (CB) signals from small amounts of biomolecules are only possible when tight spectral overlap exists between the plasmonic and biomolecular chiroptical signals. We support this conclusion experimentally by fabricating aluminum gammadion arrays on fused silica substrates and sublimating ultrathin racemic, L- and D- Tyrosine films on the arrays. Complete Mueller matrix analysis of the resonant plasmonic-biomolecular system agrees with our computational results and demonstrates the importance of using far-UV active metasurfaces for enhancing natural optical activity. In the second part of this work, we study hybrid aluminum reflective metasurfaces, which leverage both local and propagating surface plasmons (PSP). These materials display strong bi-anisotropy with rich polarization conversion properties. We explore several geometries and verify how their symmetry properties affect their far-field response. Our observations provide an opportunity for researchers to improve the chiral response of plasmonic metasurfaces, especially in the challenging ultraviolet regime.
Temporal Lidar Scanning In Quantifying Cumulative Rockfall Volume And Hazard Assessment: A Case Study At Southwestern Saudi Arabia,
2022
Missouri University of Science and Technology
Temporal Lidar Scanning In Quantifying Cumulative Rockfall Volume And Hazard Assessment: A Case Study At Southwestern Saudi Arabia, Abdullah A. Alotaibi, Norbert H. Maerz, Kenneth J. Boyko, Ahmed M. Youssef, Biswajeet Pradhan
Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works
Rockfalls and unstable slopes pose a serious threat to people and property along roads/highways in the southwestern mountainous regions of Saudi Arabia. In this study, the application of terrestrial light detection and ranging (LiDAR) technology was applied aiming to propose a strategy to analyze and accurately depict the detection of rockfall changes, calculation of rockfall volume, and evaluate rockfall hazards along the Habs Road, Jazan Region, Saudi Arabia. A series of temporal LiDAR scans were acquired at three selected sites. Our results show that these three sites have different degrees of hazard due to their geological differences. The mean volume …
A Novel Approach To Estimate Rock Strength Parameters From Multistage Triaxial Tests (The A-Has Method),
2022
Missouri University of Science and Technology
A Novel Approach To Estimate Rock Strength Parameters From Multistage Triaxial Tests (The A-Has Method), Abo Taleb T. Al-Hameedi, Husam H. Alkinani, Shari Dunn-Norman, Munir Aldin, Sudarshan Govindarajan
Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works
Rock strength parameters are vital to creating robust geomechanical models for wellbore stability, sand production, and hydraulic fracturing. Static rock strength parameters can be estimated from single stage triaxial tests (SST) or multistage triaxial tests (MST). Although SST tests are the most accurate way to estimate rock strength parameters, SST tests require at least four to five core plugs to estimate rock strength parameters. Thus, MST tests are used as an alternative method to estimate rock strength parameters from only one core plug to overcome the limitation of materials and save time and money. However, the currently used method to …
Impact Of Spray Coating On The Performance Of Hydrophobic Membranes,
2022
Purdue University
Impact Of Spray Coating On The Performance Of Hydrophobic Membranes, Dominick J. Maiorano, Hamid Fattahijuybari, David Warsinger
Discovery Undergraduate Interdisciplinary Research Internship
Membrane distillation (MD) is a rapidly emerging water treatment technology used to combat the global water crisis. Membrane pore wetting is a primary barrier to widespread industrial use of MD. The primary causes of membrane wetting are membrane fouling and an exceedance of liquid entry pressure. The development of different types of polymer membranes and the use of pretreatment have led to significant movement towards the prevention of wetting in MD. We sought to take a new approach to combat membrane wetting that involves coating these membranes with hydrophilic chemical compounds, which consequently would decrease their air permeability. Pulling data …
