Other Materials Science and Engineering Commons^™

Atomistic Simulation Studies Of Thin Film Growth And Plastic Deformation In Metals And Metal/Ceramic Nanostructures, Reza Namakian

LSU Doctoral Dissertations

Despite the significant improvements in manufacturing and synthesis processes of metals and ceramics in the past decades, there are still areas in which the procedure is still frequently more of an art or skill rather than a science. Therefore, systematic and combined experimental and computational studies are required to facilitate the development of techniques that offer thorough understanding of the events taking place during manufacturing and synthesis processes. With regard to these issues, it is paramount to address microscale characterizations and atomic scale understanding of the events during fabrication processes. One of the focuses of this study is unraveling fundamental …

Nanoclays‑Containing Bio‑Based Packaging Materials: Properties, Applications, Safety, And Regulatory Issues, Kalpani Y. Perera, Maille Hopkins, Amit K. Jaiswal Dr, Swarna Jaiswal

Articles

Food packaging is an important concept for consumer satisfaction and the increased shelf life of food products. The introduction of novel food packaging materials has become an emerging trend in recent years, which could be mainly due to environmental pollution caused by plastic packaging and to reduce food waste. Recently, numerous studies have been carried out on nanoclays or nanolayered silicate to be used in packaging material development as reinforcing filler composites. Different types of nanoclays have been used as food packaging materials, while montmorillonite (MMT), halloysite, bentonite (BT), Cloisite, and organically modified nanoclays have become of great interest. The …

Launching A 3d Printing Program For Students: Recommendations And Best Practices For Libraries, Wilhelmina Randtke, Lee Bareford

Georgia Library Quarterly

The Georgia Southern University Libraries launched a 3D printing program for students in July 2022. Prior to launch, library employees at two of Georgia Southern University’s campuses investigated options for implementing safe, affordable, and sustainable 3D printing in existing academic libraries without retrofitting costly ventilation systems into existing facilities. This article describes the reasons why the Georgia Southern University Libraries thought that a 3D printing program could fulfill a service need for students across university colleges and departments and outlines some of the challenges, best practices, and unique innovations that the library’s employees experienced throughout the program launch process. The …

Source Data For Xueyan Feng, Michael S. Dimitriyev & Edwin L. Thomas, "Soft, Malleable Double Diamond Twin", Xueyan Feng, Michael S. Dimitriyev, Edwin L. Thomas

Data and Datasets

Source data and code for Xueyan Feng, Michael S. Dimitriyev & Edwin L. Thomas, "Soft, malleable double diamond twin"

Drop Wetting And Sliding On Soft, Swollen Elastomers, Zhuoyun Cai

Theses and Dissertations--Chemical and Materials Engineering

Soft, slippery surfaces have gained increasing attention due to their wide range of potential applications, for example in self-cleaning, anti-fouling, liquid collection, and more. One design approach in creating slippery surfaces is using a swollen elastomer, which is a polymer network swollen with a lubricant. This type of surface may be beneficial for longer-term use than standard lubricant-infused surfaces, and provides a versatile surface with tunable mechanical properties. Hence, understanding the physics of soft surface interactions is important for fundamental soft matter physics, biomaterials, adhesives, and coatings. This research experimentally investigates wetting on soft infused networks, with the aim of …

Application Of Multi-Scale Computational Techniques To Complex Materials Systems, Mujan N. Seif

Theses and Dissertations--Chemical and Materials Engineering

The applications of computational materials science are ever-increasing, connecting fields far beyond traditional subfields in materials science. This dissertation demonstrates the broad scope of multi-scale computational techniques by investigating multiple unrelated complex material systems, namely scandate thermionic cathodes and the metallic foam component of micrometeoroid and orbital debris (MMOD) shielding. Sc-containing "scandate" cathodes have been widely reported to exhibit superior properties compared to previous thermionic cathodes; however, knowledge of their precise operating mechanism remains elusive. Here, quantum mechanical calculations were utilized to map the phase space of stable, highly-faceted and chemically-complex W nanoparticles, accounting for both finite temperature and chemical …

Clove Essential Oil And Nanoclays-Based Active Food Packaging, Kalpani Y. Perera, Shubham Sharma, Amit K. Jaiswal, Swarna Jaiswal

Articles

Active food packaging materials enhance the shelf-life of food products while reducing food waste. The current study aims to develop a biodegradable active food packaging material. The food packaging material was developed with the incorporation of clove essential oil, sodium alginate, gelatin, and nanoclay films were prepared. The influences of nanoclay and clove on the surface, optical, mechanical, chemical, barrier, and pH-indicating properties were studied. The lightness and yellowness increased by 1.06 folds and 3.34 folds when compared to clove (control), respectively. The UV barrier property 0.08±0.01nm in all films, while 8.37 folds reduction in transparency has been observed as …

Nanoclays And Curcumin Based Food Packaging Material For Intelligent Food Packaging Applications, Kalpani Y. Perera, Swarna Jaiswal, Amit K. Jaiswal, Shubham Sharma

Articles

Bionanocomposite packaging eco-friendly alternatives with enhanced characteristics. This study aimed to develop a bionanocomposite intelligent packaging. Sodium alginate, gelatin, Curcumin (Cur), glycerol, and Nanoclay (NC) films were prepared. The influences of nanoclay and curcumin on the surface, optical, mechanical, chemical, barrier, and pH-indicating properties were studied. The results showed that the lightness of films was reduced by 1.28 folds compared to NC (control) film, while the yellowness of films increased by 5.82 folds. Film transparency was reduced by 9.3 folds and a 3.46 folds increase in UV barrier properties was observed compared to NC (control) film. The highest tensile strength …

Cold Plasma Technology In Food Packaging, Kalpani Y. Perera, Jack Prendeville, Amit K. Jaiswal, Swarna Jaiswal

Articles

Cold plasma (CP) is an effective strategy to alter the limitations of biopolymer materials for food packaging applications. Biopolymers such as polysaccharides and proteins are known to be sustainable materials with excellent film-forming properties. Bio-based films can be used as an alternative to traditional plastic packaging. There are limitations to biopolymer packaging materials such as hydrophobicity, poor barrier, and thermos-mechanical properties. For this reason, biopolymers must be modified to create a packaging material with the desired applicability. CP is an effective method to enhance the functionality and interfacial features of biopolymers. It etches the film surface allowing for better adhesion …

Effects Of Surface Noise On Printing Artifacts: An Artistic Approach To Hiding Print Artifacts, Samuel New

All Theses

This research focuses on improving the quality of Fused Filament Fabrication (FFF) 3D printing by using fractal noise to mask certain print artifacts (e.g. layer lines and stair-stepping). The use of textures is quite common in digital sculpting for aesthetic reasons. This study focuses on finding specific textures that minimize visible 3D print artifacts.

Wet Chemical Synthesis And Properties Of Argyrodite Sulfide Solid Electrolytes For Solid State Lithium Batteries., William R. Arnold

Electronic Theses and Dissertations

The commercialization of the lithium-ion battery (LIB) in 1991 was responsible for the explosion in portable electronic technologies that has been seen over the past 30 years. With the advent of electric vehicles and other high-powered technologies, there is tremendous demand for LIBs with higher energy density and high safety. To achieve this, new electrode materials must be explored. The obvious choice of anode material would be pure metal lithium, which has a theoretical specific capacity of 3860 mAh g^-1 . Unfortunately, metal lithium anodes have not been widely commercialized due to their tendency to react violently with the …

An Application Of Optimized Bistable Laminates As A Low Velocity, Low Impact Mechanical Deterrent, Graham Lancaster

All Theses

This research considers the problem of using bistable laminates as a mechanical deterrent to the impending impact of a particle. The structure will be controlled through an algorithm that will utilize piezoelectric devices to activate them in unison with the bistable laminate to successfully deter. A novel experimental setup will be constructed to ensure that the bistable laminate stays fixed when acting as a mechanical deterrent. Piezoelectricity is the main driving force of the bistable laminate to morph and this study will use a Macro Fiber Composite (MFC) actuator that contains piezoelectric ceramic rods in a patch to transfer electrical …

Near-Ir Laser Ablation Of Simulated Radiologically Contaminated Oxides On Carbon Steel Feeder Pipes, Thao Viet Do

Electronic Thesis and Dissertation Repository

As nuclear power plants age and retire from service, many countries face significant challenges concerning the safe long-term storage and disposal of large volumes of low and intermediate level radioactive wastes (L&ILW). The volumes of metallic waste are of particular concern, as when metal corrodes it produces hydrogen that could lead to pressure build-up in interim storage and disposal. In Canada, a significant fraction of the metallic wastes for Canada Deuterium Uranium (CANDU) nuclear reactors are out-of-core reactor components, such as carbon steel (CS) feeder pipes. The radioactive contamination is expected to be largely confined to the surface oxide layers …

Biodegradable Active Bio-Nanocomposite Film For The Enhanced Shelf Life Of Tomatoes, Kalpani Y. Perera, Shubham Sharma, Brendan Duffy, Amit K. Jaiswal, Swarna Jaiswal

Articles

The increased environmental pollution has led to finding sustainable solutions for non-renewable plastic-based food packaging materials. Thus, the use of biomaterial-based packaging material has become an immense trend. This work aims at developing an antimicrobial biodegradable chitosanalginate bio-nano composite film with TiO2 nanoparticle (NPs) for food packaging applications. The film was developed by a solution casting method. The chemical, mechanical, thermal, barrier, antimicrobial, and biodegradable properties of the packaging films were evaluated. Packaging studies were performed for 15 days for cherry tomatoes. The designed packaging material had enhanced the mechanical properties with a significantly (p < 0.05) higher tensile strength of 15.76 folds and 2 fold higher elongation at break. The UV barrier properties increased by 88.6%, while the film transparency decreased by 87.23%. Molecular interaction of N-H covalent bonds was observed between alginate and chitosan together with TiO2 NPs. The developed bio-nano composite film showed antimicrobial activity against foodborne pathogens E. coli, S. aureus, S. typhi, and L. monocytogene with a log reduction of 7.08, 7.28, 6.04 & 6.02 log CFU/ml respectively at 24 hours incubation period. The film was completely biodegraded and a weight loss of 89.06% was observed in bio-nanocomposite film during the 3 months. Shelf-life estimation of cherry tomato using developed packaging films showed an increase in the shelf-life up to 8 days with stable pH, total soluble solids, and weight with no bacterial growth when packaged with prepared film. Owing to their improved mechanical, UV barrier, antibacterial, and biodegradability, the prepared active bio-nano composite packaging films could be considered a potential candidate for fruit packaging.

Sodium Alginate, Nanoclay And Curcumin Based Food Packaging Material For Intelligent Food Packaging Applications, Kalpani Y. Perera, Máille Hopkins, Shubham Sharma, Brendan Duffy, Amit K. Jaiswal, Swarna Jaiswal

Articles

Bionanocomposite food packaging contains materials of biological origin which display high-performance activity when compared to biopolymers and are eco-friendly alternatives to conventional packaging materials. Intelligent packaging monitors the condition of the food or environment surrounding the food and communicates changes to the consumer. This study aimed to develop a bionanocomposite intelligent packaging material by utilising sodium alginate, nanoclay and curcumin. Sodium alginate (2 W/V% SA) film incorporated with 0.3 W/V% curcumin (Cur), glycerol, and nanoclay (NC) in various concentrations (0, 0.5, 1 and 2 W/V %) was prepared using the solvent casting method. The influences of nanoclay and curcumin on …

Could The Inclusion Of Certain Building Information And Modelling Aspects Into The Leaving Certificate Engineering Syllabus, Aid The Transition Of Students Into Third Level Education, When Choosing A Course Within The Construction Industry, Joseph Boyle, Deborah M. Brennan

Capstone Reports

The paper investigates the effects of implementing several Building Information and Modelling (BIM) aspects into the Leaving Certificate Engineering Syllabus and examines the impact this has on students choosing third level Architectural Engineering and Construction (AEC) industry courses with the desire of improving the shortage in the sector. The method and content of the study was based on academic research on second level education in other European countries through the lens of a Literature Review. A sixteen-week pilot program was trialed with over one hundred students at Senior Cycle. The outcomes of the study were critically evaluated through stakeholder interviews …

Direct Calculation Of Configurational Entropy: Pair Correlation Functions And Disorder, Clifton C. Sluss

Doctoral Dissertations

Techniques such as classical molecular dynamics [MD] simulation provide ready access to the thermodynamic data of model material systems. However, the calculation of the Helmholtz and Gibbs free energies remains a difficult task due to the tedious nature of extracting accurate values of the excess entropy from MD simulation data. Thermodynamic integration, a common technique for the calculation of entropy requires numerous simulations across a range of temperatures. Alternative approaches to the direct calculation of entropy based on functionals of pair correlation functions [PCF] have been developed over the years. This work builds upon the functional approach tradition by extending …

Computational Characterization Of Nonwoven Fibrous Materials: Transport And Wetting Properties, Fang Wang

All Dissertations

Nonwoven fibrous materials represent a platform of flexible material substrates. Nonwovens are widely used in the production of napkins, paper, filters, wound covers and face masks. In addition, for many applications, nonwoven materials interact with fluids. For example, in filtration applications, nonwoven materials are used to clean fluids containing solid particles or emulsified droplets. The filtration performance is affected not only by the geometrical arrangement of fibers in non-woven materials but also wettability of fibers. Understanding the transport properties of nonwoven materials and interactions between the dispersed droplets and solid substrate is crucial for the design and optimization of filter …

Quantum-Mechanical Evaluation Of Defects In Uranium-Bearing Materials, Megan Hoover

All Dissertations

Quantum-mechanical calculations using density functional theory with the generalized gradient approximation were employed to investigate the effects dopants have on the uranium dioxide (UO₂) structure. Uraninite is a common U⁴⁺ mineral in the Earth's crust and an important material used to produce energy and medical isotopes. Though the incorporation mechanism remains unclear, divalent cations are known to incorporate into the uranium dioxide system. Three charge-balancing mechanisms were evaluated to achieve a net neutral system, including the substitution of (1) a divalent cation for a tetravalent uranium atom and oxygen atom; (2) two divalent cations for a tetravalent …

Controlled Manipulation Of Droplets On Fibers: Fundamentals And Printing Applications, Yueming Sun

All Dissertations

In this dissertation, the drop interactions with a single fiber is discussed under an application angle for the development on new Drop-on-Demand (DOD) printhead using a fiber-in-a-tube platform[1] to print highly viscous materials[2]. To control the drop formation and manipulation on fiber, one needs to know how the fiber wetting properties and the fiber diameter influence drop formation. And then, one needs to know the effects of fiber movement in the device on drop formation. These two questions constitute the main theme of this dissertation.

Before this study, it was accepted that the liquids could not form axisymmetric droplets if …

Development Of Smart Wearable Sensory Systems On Flexible And Fabric Platforms For Health Monitoring Applications, Simin Masihi

Dissertations

Wearable sensing technology has recently received an increased attention in both research and commercialization phases and has moved from a vision of science fiction to reality with a wide variety of applications. This incredible growth can be attributed to several factors, such as affordability and ergonomics provided by advances in flexible electronics. The other factors that realized wearable sensing technology include a critical need for more accessible health care services experienced during the recent COVID pandemic, integration to the Internet of Things (IoT), and a growing consumer desire for health awareness. This dissertation presents the fulfillment of three main projects …

Creep Behavior Of A Ti-Based Multi-Principal Element Alloy, Benjamin Elbrecht

All Theses

Abstract

The understanding of microstructural damage mechanisms is the foundation of better understanding existing materials and future material development. There are significant challenges to measuring these damage mechanisms in-situ as continuous observation of the state of the microstructure is difficult or impossible for many experimental setups. This thesis presents a method for measuring grain boundary sliding (GBS) and local strain concentrations in-situ via a Heaviside function based algorithm. GBS is the shearing of two grains along their shared grain boundary and is a common damage mechanism in creep which presents as a discontinuity that can be measured with a Heaviside …

Rheological Properties And Structural Build-Up Of 3d Printed Magnesium Potassium Phosphate Cement, Hui Zhi Zhao

International Conference on Durability of Concrete Structures

This paper focuses on the rheological properties of 3D printed magnesium potassium phosphate cements (MKPCs) with different magnesium-to-phosphate (M/P) mass ratio, MgO fineness and supplementary cementitious materials (SCMs) types. The variable shear rate tests were used to monitor the extrudability. The highest slope of the evolution of storage modulus (G') and the maximum static yield stress (M_τs) value were used as an indication of the rigidification rate. The increased M/P mass ratio, MgO fineness and SCMs addition resulted in the promoted structural build-up of 3D printed MKPCs. The consistency between the evolution of G' and M_τs with …

Mechanical Properties And Microstructure Of High Strength Lc3 Pastes With Varying Limestone/Calcined Clay Ratios And Different Curing Conditions, Yemin Dong

International Conference on Durability of Concrete Structures

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Mechanical And Thermal Insulation Properties Of Clay-Based Lightweight Concrete, Chuang Shi, Chuanlin Hu

International Conference on Durability of Concrete Structures

建材生产和住宅采暖将消耗大量能源并排放大量CO_2。在混凝土制备中，使用陶土制备具有优异隔热性能的轻质混凝土，并使用煅烧粘土代替部分波特兰水泥，可以大大降低能耗。本研究采用页岩陶土和陶砂分别作为粗骨料和细骨料制备轻质混凝土。首先，确定最佳体积砂比。然后，使用煅烧粘土和石灰石的剂量从30%，50%到70%。研究了煅烧粘土和石灰石含量对混凝土微观结构、力学性能和隔热性能的影响。结果表明，最佳体积砂比为50%。当煅烧粘土和石灰石的用量为30%时，强度在所有年龄段最高，28 d时强度可达33.6 MPa，比对照组高12%。当更换水平不断增加时，所有年龄段的实力开始下降。所制备的粘土基轻质混凝土的导热系数低至0.144 W/mK，表现出优异的保温性能。本研究制备的轻质混凝土具有较高的强度和优异的保温性能，具有良好的应用前景。

Tensile Testing Of 3d Printed Tpu Samples For Pediatric Biomaterial Applications, Sheridan C. Perry, Rodriguez M. Rafael, Victor Huayamave, Bryan M. Gonzalez, Kim Dae-Won, Zachary R. Nadeau

PanaSoMM

Additive Manufacturing (AM) has, in recent years, become one of the most widespread and preferred prototyping methods. The most popular additive manufacturing method is Fused Deposition Modeling. FDM’s popularity is primarily attributed to its 3 major strengths of rapid prototyping, variability in material choice, and subject specific nature. The medical industry is one of the larger industries that has benefited from 3D printing especially in the terms of medical trainers. Unfortunately, most medical trainers that are developed (either being 3d printed or through traditional manufacturing processes) are poor substitutes for the human body. This can be attributed to either a …

Mechanical And Durability Properties Of Geopolymer Concrete – A Review, Lelian Elkhatib, Fadi Al Aridi, Adel Elkordi, Jamal Khatib

BAU Journal - Science and Technology

Owing to the ongoing increase in human population, there is a need for more construction projects including residential buildings and other amenities. Concrete is by far the dominant material used in construction and cement is a main ingredient. Cement manufacture is an energy intensive process and emit large amounts of carbon dioxide into the atmosphere. A reduction in the amount of cement used in construction is greatly beneficial. The use of geopolymer or alkali activated materials can serve this purpose as it attempts to totally replace cement in concrete. Geopolymers are materials that consist mainly of silica and alumina materials …

Damage In Non-Crimp Fabric Carbon Fiber Reinforced Epoxy Composites Under Various Mechanical Loading Conditions, Aaditya Pradeep Suratkar

Electronic Thesis and Dissertation Repository

Composite materials have emerged in the recent years as a frontrunning lightweight replacement for metals for structural applications in lightweight automobiles. However, the key adoption criteria for composites in lightweight vehicles is their crashworthiness, i.e., the amount of energy a structure made with composites would absorb in a crash event. The energy is absorbed in composites through various damage modes such as matrix cracks, delamination, fiber breakage, etc. Therefore, adoption of a certain composite material system requires thorough understanding of the initiation and propagation of damage until failure in that system under various mechanical loading conditions, which is also the …

Analysis Of Novel Corrosion Resistant Maraging Steels For Use In Additive Manufacturing, Bradley Michael Samuel, James Knowlton Smith

Materials Engineering

Stainless maraging steel has been proven to be an industry standard material for plastic injection molds. Its high hardness and corrosion resistance extend the lifetime of the tool. This alloy system is also well-suited to additive manufacturing, which can be utilized to form internal cooling channels, further increasing tool life. Using Rapid Alloy Development (RAD) Oerilkon METCO is developing a new composition of stainless maraging tool steel that has high hardness/strength, is corrosion resistant, and has additive-capable melting and solidification properties. This study tests the hardness and corrosion resistance of the new RAD alloys against the current market competitor Corrax …

Non-Destructive Material Analysis Of Metals And Composites Via Thermography, Jonathan R. Doubt, James L. Chapman

Materials Engineering

The Naval Surface Warfare Center, Port Hueneme Division, is interested in the development of non-destructive damage assessment of shipboard materials via drones at distance. Long Pulsed Thermography (LPT), a method of non-destructive evaluation, was investigated as a possible method for detecting damage in metals (5005h24 Al alloy and 1008 carbon steel) and composites (aramid fiber honeycomb sandwich structure) at distances from 0.5 m to 3.0 m. LPT was conducted using two 1000 W can lights to heat the samples, and a FLIR E8-XT thermal camera. The images were then analyzed using ImageJ software to determine if damage could be detected …