Other Materials Science and Engineering Commons^™

Synthesis And Characterization Of Sodium Cathode Materials, He Zhou

McKelvey School of Engineering Theses & Dissertations

As sodium batteries hold great promise as a next-generation energy storage device to replace lithium batteries, the development of sodium battery materials has become increasingly urgent. The current study aims to investigate two potential sodium-ion battery cathode materials, Sodium Vanadium Phosphate, and Sodium Manganese Hexacyanoferrate, optimize the experimental procedures, conduct a systematic analysis of material properties and characterization, and ultimately determine the ideal synthesis conditions for these materials.

In the first part of the study, we focused on optimizing the synthesis of Sodium Vanadium Phosphate. By investigating various synthesis conditions, such as annealing temperature, pressure, ascorbic acid content, and material …

Development Of Novel Electrodes And Electrolytes For Safer Aqueous Ammonium Ion Batteries With Enhanced Performance., Shelton Farai Kuchena

LSU Doctoral Dissertations

The Lithium-ion battery (LIBs) system has dominated the battery market because of its superior energy and power density. Problems related to LIBs such as safety, scarcity of cobalt and lithium have led researchers to explore alternative battery systems. NH₄⁺ ion is a nonmetal charge carrier with lower molar mass (18 mol g^-1) and smaller hydrated ionic size (3.31 Å) which results in excellent electrochemical properties. Furthermore, NH₄⁺ ion has a tetrahedral structure that has no preferred orientation as compared to spherical metal ions giving a different intercalation chemistry based on hydrogen bonding. These properties …

Impact Resistance Of Hybrid Metal-Organic Frameworks/Carbon Fibers Composites, Derek Isaac Espinosa Ramirez

Doctoral Dissertations and Master's Theses

The increase in the use of carbon fiber-reinforced polymers (CFRPs) composites in the aerospace industry generated the need of improving the properties and capabilities of these composites by adding nano-reinforcements to the carbon fibers, also called hybrid fiber reinforced polymer composites. In this study, the energy absorption due to impact at low speed will be tested and simulated in four configurations of CFRPs utilizing the same [0/90]_S layout throughout them.

The carbon fiber configurations used during this study are de-sized, acid-activated, metal-organic frameworks (MOF), and carbon nanotubes (CNTs). Nickel (II) Nitrate, Methylimidazole, and Methanol were used to grow the …

Atomistic Simulation Studies Of Thin Film Growth And Plastic Deformation In Metals And Metal/Ceramic Nanostructures, Reza Namakian

LSU Doctoral Dissertations

Despite the significant improvements in manufacturing and synthesis processes of metals and ceramics in the past decades, there are still areas in which the procedure is still frequently more of an art or skill rather than a science. Therefore, systematic and combined experimental and computational studies are required to facilitate the development of techniques that offer thorough understanding of the events taking place during manufacturing and synthesis processes. With regard to these issues, it is paramount to address microscale characterizations and atomic scale understanding of the events during fabrication processes. One of the focuses of this study is unraveling fundamental …

Nanoclays‑Containing Bio‑Based Packaging Materials: Properties, Applications, Safety, And Regulatory Issues, Kalpani Y. Perera, Maille Hopkins, Amit K. Jaiswal Dr, Swarna Jaiswal

Articles

Food packaging is an important concept for consumer satisfaction and the increased shelf life of food products. The introduction of novel food packaging materials has become an emerging trend in recent years, which could be mainly due to environmental pollution caused by plastic packaging and to reduce food waste. Recently, numerous studies have been carried out on nanoclays or nanolayered silicate to be used in packaging material development as reinforcing filler composites. Different types of nanoclays have been used as food packaging materials, while montmorillonite (MMT), halloysite, bentonite (BT), Cloisite, and organically modified nanoclays have become of great interest. The …

Launching A 3d Printing Program For Students: Recommendations And Best Practices For Libraries, Wilhelmina Randtke, Lee Bareford

Georgia Library Quarterly

The Georgia Southern University Libraries launched a 3D printing program for students in July 2022. Prior to launch, library employees at two of Georgia Southern University’s campuses investigated options for implementing safe, affordable, and sustainable 3D printing in existing academic libraries without retrofitting costly ventilation systems into existing facilities. This article describes the reasons why the Georgia Southern University Libraries thought that a 3D printing program could fulfill a service need for students across university colleges and departments and outlines some of the challenges, best practices, and unique innovations that the library’s employees experienced throughout the program launch process. The …

Source Data For Xueyan Feng, Michael S. Dimitriyev & Edwin L. Thomas, "Soft, Malleable Double Diamond Twin", Xueyan Feng, Michael S. Dimitriyev, Edwin L. Thomas

Data and Datasets

Source data and code for Xueyan Feng, Michael S. Dimitriyev & Edwin L. Thomas, "Soft, malleable double diamond twin"

Wetting Transition Of Texturized Surfaces, Jenna Stephens

Williams Honors College, Honors Research Projects

Building on previous research, this project aims to continue the investigation of the wettability of various liquids on a uniform, texturized surface. Different surface energies can impact the wettability of a surface. The surface can be hydrophilic, hydrophobic, or in between. The goal of this project is to research how features of texturized surfaces affect the wetting transition of water, oil, and a mixture of both. Additionally, this project aims to improve the quality of the 3D printed surfaces. The surfaces that will be studied are constructed using UV cured resin 3D printing and are made up of an array …

Solid-State Shear Pulverization: A Comprehensive Study On Polymer Processing Technology From A Systematic Innovation Perspective, Tyler A. Will

Master’s Theses

Solid-state shear pulverization (SSSP) is a continuous and scalable processing technique that imposes mechanochemical changes in polymer-based materials. It has been shown to impart beneficial properties onto homopolymers or create copolymers and composites through continuous fragmentation and fusion. The unique technology employs cold temperature to keep the polymer in the solid state. This thesis investigates industrial polymer processing in the context of real-world applications. This thesis analyzes SSSP using an organized methodology called systematic innovation (SI). SI facilitates problem solving by assisting engineers in conducting root cause analysis around a material and studying the physical setup of the equipment.

This …

Development Of Interatomic Potential Of High Entropy Diborides With Artificial Intelligence Approach To Simulate The Thermo-Mechanical Properties, Nur Aziz Octoviawan

MSU Graduate Theses

The interatomic potentials designed for binary/high entropy diborides and ultra-high temperature composites (UHTC) have been developed through the implementation of deep neural network (DNN) algorithms. These algorithms employed two different approaches and corresponding codes; 1) strictly local & invariant scalar-based descriptors as implemented in the DEEPMD code and 2) equivariant tensor-based descriptors as included in the ALLEGRO code. The samples for training and validation sets of the forces, energy, and virial data were obtained from the ab-initio molecular dynamics (AIMD) simulations and Density Functional Theory (DFT) calculations, including the simulation data from the ultra-high temperature region (> 2000K). The study …

Fem Eem Dataset: Optimising Retrofitted Insulation For Irish Residential Building Walls, Rakshit D. Muddu, Aimee Byrne, Anthony Robinson Dr.

Datasets

A large number of combinations of Irish wall types, insulation materials, and heating fuel types were produced to compare the multiple variables which influence Optimal Insulation Thickness values. The total cost (TC) and carbon emission (CE) at optimum insulation thickness (OIT) for all combinations of insulation material and three types of fuel are considered. The dataset presents OIT for solid wall, cavity wall and cavity block wall types located in Monaghan, Dublin, and Kerry.

Hdd Dataset: Optimising Retrofitted Insulation For Irish Residential Building Walls, Rakshit D. Muddu, Aimee Byrne, Anthony James Robinson

Datasets

In this study, a thermal-economic analysis was conducted to determine the optimum insulation thickness of retrofitted insulation walls in different regions in Ireland. This was based on the Heating Degree Day method (HDD). This dataset contains optimum insulation thickness, payback period, cost savings and carbon emission for all 25 counties in the Republic of Ireland

Coolant Capability Study, Christina Grassi

Williams Honors College, Honors Research Projects

The scope of my project is a capability study on different coolants used in manufacturing plants. From this study, the coolant qualities and impact on the manufacturing process will be evaluated in that process and will be documented as a changed standard at the Timken company. Since coolants are sometimes the only fluid on the surface of the parts being manufactured, the rust preventative capabilities will also be studied and evaluated through humidity cabinet testing with and without spiking the coolant with chlorides and sulfates. This project will be carried out on my co-op rotation with the Timken company so …

Intergranular And Pitting Corrosion Mechanisms Of Sensitized Aluminum Alloy Aa5083, Clayton Egleston

Williams Honors College, Honors Research Projects

The motivation and objectives of this project is to examine the mechanisms of intergranular corrosion (IGC) and pitting corrosion of sensitized AA5083. In this regard, different characterization techniques were used, including optical analysis of microstructure, cyclic potentiodynamic polarization with Tafel fitting, electrochemical impedance spectroscopy with electrical equivalent circuit (EEC) fitting, and potentiostatic current transient monitoring. The transition from IGC to pitting corrosion occurs when the grain boundaries become saturated with the β-phase (Mg₂Al₃). It was found that AA5083 becomes more vulnerable to pitting corrosion as the degree of sensitization increases.

Application Of Multi-Scale Computational Techniques To Complex Materials Systems, Mujan N. Seif

Theses and Dissertations--Chemical and Materials Engineering

The applications of computational materials science are ever-increasing, connecting fields far beyond traditional subfields in materials science. This dissertation demonstrates the broad scope of multi-scale computational techniques by investigating multiple unrelated complex material systems, namely scandate thermionic cathodes and the metallic foam component of micrometeoroid and orbital debris (MMOD) shielding. Sc-containing "scandate" cathodes have been widely reported to exhibit superior properties compared to previous thermionic cathodes; however, knowledge of their precise operating mechanism remains elusive. Here, quantum mechanical calculations were utilized to map the phase space of stable, highly-faceted and chemically-complex W nanoparticles, accounting for both finite temperature and chemical …

Drop Wetting And Sliding On Soft, Swollen Elastomers, Zhuoyun Cai

Theses and Dissertations--Chemical and Materials Engineering

Soft, slippery surfaces have gained increasing attention due to their wide range of potential applications, for example in self-cleaning, anti-fouling, liquid collection, and more. One design approach in creating slippery surfaces is using a swollen elastomer, which is a polymer network swollen with a lubricant. This type of surface may be beneficial for longer-term use than standard lubricant-infused surfaces, and provides a versatile surface with tunable mechanical properties. Hence, understanding the physics of soft surface interactions is important for fundamental soft matter physics, biomaterials, adhesives, and coatings. This research experimentally investigates wetting on soft infused networks, with the aim of …

Utilization Of Machine Learning To Investigate Material State, Ana B. Abadie

Honors College Theses

The ability to predict material behavior that undergoes various loading conditions is critical to the development of reliable and safe components. Thermal and mechanical fatigue loading can cause significant damage to materials, leading to failure and potential safety hazards. Machine learning algorithms have emerged as a promising tool for improving accuracy and efficiency of predicting material behavior under such loading conditions. This research provides a comprehensive overview of a machine learning algorithm that is able to analyze and predict material state independently of the loading sequence. Unidirectional carbon fiber reinforced polymer (UD CFRP) composite which has undergone two different loading …

Design And Fabrication Of A High-Performance Heat Exchanger Using An Optimized Three-Dimensional Surface Structure Through Additive Manufacturing, Seth T. Waters

Electronic Theses and Dissertations

A heat exchanger is a device used to transfer thermal energy between two intertwining fluid pathways. In this study, the design of a novel heat exchanger is proposed using functional gradient double gyroid structure. The complex internal geometries of the gyroid structure significantly increases the surface area to volume ratio, and potentially could expressively improve efficiency of the heat transfer. The proposed idea provides a new approach for the design of a high-efficiency heat exchanger. In order to fabricate the complex structured heat exchanger system additive manufacturing is adapted instead of traditionally subtractive manufacturing techniques or casting. The prototypes of …

Ambient Ammonia Synthesis Via Microwave-Catalytic Materials And Plasma Chemistry, Sean Brown

Graduate Theses, Dissertations, and Problem Reports

Ammonia is critical to supporting human life on earth because of its use as fertilizer. The Haber-Bosch process to produce ammonia has been practiced for over 100 years. This process operates at high pressure and temperature to overcome the thermodynamic and kinetic limitations of the ammonia synthesis reaction thus researchers have tried to overcome it for decades. At present this process represents 1% of global energy usage and 2.5% of global CO₂ emissions. The proposed chemical looping ammonia synthesis approach seeks to reduce the environmental impact of this critical process and to elucidate microwave-catalytic principles.

This research aims to …

Clove Essential Oil And Nanoclays-Based Active Food Packaging, Kalpani Y. Perera, Shubham Sharma, Amit K. Jaiswal, Swarna Jaiswal

Articles

Active food packaging materials enhance the shelf-life of food products while reducing food waste. The current study aims to develop a biodegradable active food packaging material. The food packaging material was developed with the incorporation of clove essential oil, sodium alginate, gelatin, and nanoclay films were prepared. The influences of nanoclay and clove on the surface, optical, mechanical, chemical, barrier, and pH-indicating properties were studied. The lightness and yellowness increased by 1.06 folds and 3.34 folds when compared to clove (control), respectively. The UV barrier property 0.08±0.01nm in all films, while 8.37 folds reduction in transparency has been observed as …