Polymer and Organic Materials Commons^™

Effect Of Microwave Heating On The Migration Of Additives From Ps, Pp And Pet Container Into Food Simulants, Ruoyin Cai

Theses

Microwave food packaging has become a tremendous element in the food manufacturing process. The purpose of any food packaging regulations concerned with the safety of the food is to control and limit the migration of substances from the packaging into the food. The main objective of this thesis is to test three different microwaving packaging materials that are the most common material in the market, viz. polystyrene (PS), polypropylene (PP), and polyethylene terephthalate (PET), migrated into four food simulant solutions. Four different simulant solutions were used based on the food type and FDA recommendations and regulations. These food simulants include …

Flexural Rigidity Characterization Of Retrofitted Frp Plates, Steven J. Makonis Jr., Stella B. Bondi, Zia Razzaq

Civil & Environmental Engineering Faculty Publications

Presented herein is a procedure and numerical results for flexural rigidity characterization of Fiber Reinforced Polymer (FRP) plates retrofitted with various types of fabrics. The FRP plates were retrofitted with Kevlar® 49 (Aramid), Carbon Fiber (Harness-Satin H5), and Unidirectional Carbon Fiber (T700 Aerospace Grade) fabrics, respectively. The FRP plate flexural rigidity values were calculated with a central finitedifference iterative scheme while utilizing the experimental load-deflection relations based on bending tests. The tests were performed on each plate by applying a concentrated load at the center. A fourth-order partial differential equation of plate equilibrium was adopted to estimate the plate flexural …

Scaling Reversible Adhesion In Synthetic And Natural Adhesive Systems., Michael D. Bartlett, Duncan J. Irschick, Alfred J. Crosby

Michael Bartlett

No abstract provided.

Scaling Normal Adhesion Force Capacity With A Generalized Parameter, Michael D. Bartlett, Alfred J. Crosby

Michael Bartlett

Silica Nanoparticle-Based Coatings With Superhydrophilic And Superhydrophobic Properties, Robert Andrew Fleming

Graduate Theses and Dissertations

Superhydrophilic and superhydrophobic surfaces have potential for implementation into a variety of fields, including self-cleaning surfaces, anti-fogging transparent materials, and biomedical applications. In this study, sandblasting, oxygen plasma treatments, silica nanoparticle films, and a low surface energy fluorocarbon film were employed to change the natural surface wettability of titanium, glass, and polyethylene terephthalate (PET) substrates, with an aim to produce superhydrophilic and superhydrophobic behavior. The effects of these surface modifications are characterized by water contact angles (WCAs), surface wetting stability, surface morphology and roughness, surface elemental composition, and optical transmittance measurements. The results show that stable superhydrophilic and superhydrophobic surfaces …

Prediction Of Compressive Creep Bhaviour In Flexible Polyurethane Foam Over Long Time Scales And At Elevated Temperatures, Conor Briody, Barry Duignan, Stephen Jerrams, Stephen Ronan

Articles

Compressive creep gradually affects the structural performance of flexible polymeric foam material over extended time periods. When designing components, it is often difficult to account for long-term creep, as accurate creep data over long time periods or at high temperatures is often unavailable. This is mainly due to the lengthy testing times and/or inadequate high temperature testing facilities. This issue can be resolved by conducting a range of short-term creep tests and applying accurate prediction methods to the results. Short-term creep testing was conducted on viscoelastic polyurethane foam, a material commonly used in seating and bedding systems. Tests were conducted …

A Silicon Carbide Based Solid-State Fault Current Limiter For Modern Power Distribution Systems, Erik Darnell Johnson

Graduate Theses and Dissertations

The fault current limiter represents a developing technology which will greatly improve the reliability and stability of the power grid. By reducing the magnitude of fault currents in distribution systems, fault current limiters can alleviate much of the damage imposed by these events. Solid-state fault current limiters in particular offer many improved capabilities in comparison to the power system protection equipment which is currently being used for fault current mitigation. The use of silicon carbide power semiconductor devices in solid-state fault current limiters produces a system that would help to advance the infrastructure of the electric grid.

A solid-state fault …

Design, Fabrication, Testing Of Cnt Based Isfet And Characterization Of Nano/Bio Materials Using Afm, Zhuxin Dong

Graduate Theses and Dissertations

A combination of Carbon Nanotubes (CNTs) and Ion Selective Field Effect Transistor (ISFET) is designed and experimentally verified in order to develop the next generation ion concentration sensing system. Micro Electro-Mechanical System (MEMS) fabrication techniques, such as photolithography, diffusion, evaporation, lift-off, packaging, etc., are required in the fabrication of the CNT-ISFET structure on p-type silicon wafers. In addition, Atomic Force Microscopy (AFM) based surface nanomachining is investigated and used for creating nanochannels on silicon surfaces. Since AFM based nanomanipulation and nanomachining is highly controllable, nanochannels are precisely scratched in the area between the source and drain of the FET where …

Titanium Aluminum Nitride Films Deposited By Ac Reactive Magnetron Sputtering: Study Of Positioning Effect In An Inverted Cylindrical Magentron Sputtering System, George C. Vandross Ii

Graduate Theses and Dissertations

TiAlN films were deposited on glass substrates by AC magnetron sputtering at 2 kW with constant Argon and Nitrogen gas flow rates to study the effects of positioning on the deposited films. The deposition system used was an ICM-10 IsoFlux cylindrical magnetron sputtering chamber. The samples were placed in different positions and tilts with respect to the location of the Titanium and Aluminum targets in the chamber. It was found that with change in position and application of tilts, deposited films acquired different physical and chemical properties. It is believed that the differences in these properties were caused by to …

Pulse Sharpening Effects Of Thin Film Ferroelectric Transmission Lines, Robert J. Sleezer

Graduate Theses and Dissertations

Advances in material science have resulted in the development of electrically nonlinear high dielectric thin film ferroelectrics, which have led to new opportunities for the creation of novel devices. This dissertation investigated one such device: a low voltage nonlinear transmission line (NLTL). A finite element simulation of ferroelectric transmission lines showed that NLTLs are capable of creating shockwaves. Additionally, if the losses are kept sufficiently low, it was shown that voltage gain should be possible. Furthermore, a method of accounting for material dispersion was developed. Results from simulations including material dispersion showed that temporal solitons might be possible from a …

P3ht:Pcpdtbt:Pcbm Multi- Polymer Single Layer Solar Cells, Ted Andreas

Physics

OPV efficiencies are limited by their narrow absorption; rather than using tandem architecture to overcome this obstacle, our group combined P3HT and PCPDTBT into a single layer BHJ solar cell that achieved 2.0% PCE. This is 33% higher than the pure P3HT control from this group, proving that multi-polymer solar cells have the potential to outperform their single-polymer components.

Calcium Phosphate-Based Resorbable Biomaterials For Bone Regeneration, Daniel O. Costa

Electronic Thesis and Dissertation Repository

Bone defects are a prevalent problem in orthopedics and dentistry. Calcium phosphate-based coatings and nanocomposites offer unique solutions towards producing scaffolds with suitable physical, mechanical and biological properties for bone regeneration.

We developed a novel method to synthesize hydroxyapatite (HA) particles with high aspect ratio using sol-gel chemistry and hydrothermal treatment. We obtained tunable pure-phase carbonated-HA in the form of micro/nanorods and nanowires (diameters 25-800 nm). To mimic the structure of bone, HA nanowires were homogenously mixed within poly(ε-caprolactone) (PCL) to produce nanocomposites with improved mechanical properties as determined by uniaxial tensile testing.

Surface chemistry and topography of biomaterials play …

Development Of A Novel Handheld Device For Active Compensation Of Physiological Tremor, Abhijit Saxena

Electronic Thesis and Dissertation Repository

In microsurgery, the human hand imposes certain limitations in accurately positioning the tip of a device such as scalpel. Any errors in the motion of the hand make microsurgical procedures difficult and involuntary motions such as hand tremors can make some procedures significantly difficult to perform. This is particularly true in the case of vitreoretinal microsurgery. The most familiar source of involuntary motion is physiological tremor. Real-time compensation of tremor is, therefore, necessary to assist surgeons to precisely position and manipulate the tool-tip to accurately perform a microsurgery. In this thesis, a novel handheld device (AID) is described for compensation …

Biaxial Bending And Lateral-Torsional Instability Of Imperfect Frp I-Beams Including Effects Of Retrofitting, Jodi Marie Knorowski

Civil & Environmental Engineering Theses & Dissertations

This thesis presents the outcome of a theoretical and experimental study of the behavior of Fiber Reinforced Polymer (FRP) I-beams susceptible to lateral-torsional instability or when subjected to biaxial bending. Laboratory experiments involved application of vertical and horizontal static loads to a 4 x 4 x ¼ in. I-beam with various lengths, and the resulting displacement, twist, and strain were recorded. In the vertical direction, the beam was loaded from different reference load heights with respect to the shear center of the beam. The governing biaxial flexure and torsion differential equations were modified to account for the presence of initial …

Hydrogel-Based Nanocomposites And Laser-Assisted Surface Modification For Biomedical Application, Pei Yin

Electronic Thesis and Dissertation Repository

Hydrogels can be used in contact lens, wound dressing, drug delivery and tissue scaffolds due to their good biocompatibility. However, the poor mechanical properties and non-specific protein adsorption of hydrogels limit their applications. The adverse effects of protein adsorption in hydrogels include biofouling, inflammation, or even body rejection. In this project, two different hydrogel materials, co-polymer 2-hydroxyethyl methacrylate with a low amount of 2-aminoethyl methacrylate, p(HEMA-co-AEMA) and silicone hydrogel were fabricated by photo-polymerization; the former has hydrophilic surface and the latter is hydrophobic. The silica (SiO₂) nanoparticle-loaded hydrogels have been developed by using in situ polymerization. The dispersion …

Dynamics And Kinetics Of Model Biological Systems, Stephen William Mirigian

Open Access Dissertations

In this work we study three systems of biological interest: the translocation of a heterogeneously charged polymer through an infinitely thin pore, the wrapped of a rigid particle by a soft vesicle and the modification of the dynamical properties of a gel due to the presence of rigid inclusions.

We study the kinetics of translocation for a heterogeneously charged polyelectrolyte through an infinitely narrow pore using the Fokker-Planck formalism to compute mean first passage times, the probability of successful translocation, and the mean successful translocation time for a diblock copolymer. We find, in contrast to the homopolymer result, that details …

Magnetic, Optical And Dielectric Effects On Photovoltaic Processes In Organic Solar Cells, Huidong Zang

Doctoral Dissertations

Organic bulk heterojunction photovoltaics have attracted extensive attention during the past decade due to the global energy crisis, and it had been nominated as one of the most promising substitution for the next generation of green energy. Organic Photovoltaics, also named as “plastic solar cells”, have many advantages including super-low cost, flexibility, and compatibility with the ink printing fabrication technique, etc. Although the photovoltaic efficiency of the organic bulk heterojunction is still not as high as that of the inorganic ones, its great potential makes it the most promising solar cells in the future. In this dissertation, Chapter 1 presents …

Modulation Of Bone And Nerve Cell Behavior Using Biodegradable Polymer Networks, Lei Cai

Doctoral Dissertations

This dissertation presents novel biodegradable and photo-crosslinkable building blocks to achieve polymer networks with controlled surface chemistry, stiffness, and topographical features for investigating cell-material interactions and targeting hard and soft tissue engineering applications. Chapter I reviews the recent progress in polymeric gel systems and how their physical properties can be tailored to regulate cell functions and satisfy the clinical needs. Chapter II presents a facile method to synthesize photo-crosslinkable poly(epsilon-caprolactone) acrylates (PCLAs) and reveal tunable cell responses to photo-crosslinked PCLAs. Chapter III investigates the mechanism of colorization in preparing crosslinkable polymers by reacting hydroxyl-containing polymers with unsaturated anhydrides or acyl …

Polymer Mediated Therapeutic Delivery For Neural Interface Applications, Yu Cao

Doctoral Dissertations

The technology of interfacing neurons with machines through implantable neural electrodes has significant implications. Although there have been studies implanting such electrodes in human to help patients with motor disorders, longevity of these implants remains an unresolved issue. One of the key factors influencing longevity has been adverse tissue response toward the implanted electrodes

The objective of this research is to engineer a comprehensive solution that can manage the response at the cellular level while preserving the electrode functions. Given the complexity of the host response, we hypothesize that a multi-pronged approach would better improve the longevity of the electrodes. …

Semiconductor Nanocrystals: From Quantum Dots To Quantum Disks, Zheng Li

Graduate Theses and Dissertations

The bottom-up colloidal synthesis opened up the possibility of finely tuning and tailoring the semiconductor nanocrystals. Numerous recipes were developed for the preparation of colloidal semiconductor nanocrystals, especially the traditional quantum dots. However, due to the lack of thorough understanding to those systems, the synthesis chemistry is still on the empirical level. CdS quantum dots synthesis in non-coordinating solvent were taken as a model system to investigate its molecular mechanism and formation process, ODE was identified as the reducing agent for the preparation of CdS nanocrystals, non-injection and low-temperature synthesis methods developed. In this model system, we not only proved …