Environmental Engineering Commons^™

Environmental And Energy Saving Technologies Of Vinyl Chloride Production, Mykola Kurta

USF Tampa Graduate Theses and Dissertations

Recently, because of the increase of environmental concerns in process design, the need to enhance conversion to product and prevent generation of wasteful byproducts in the reactor network has become urgent. This prevents high cost treatment and separation costs downstream in the process. Therefore, in this thesis I focus on making production of vinyl chloride monomer (VCM) more efficient and on possible ways of industrial organochlorine waste (OCW) recycling. In particular, in the first experiment, we investigate how catalyst and its structure can affect product output.

Infrared spectroscopy and X-ray diffraction analysis were utilized to investigate the structure of the …

Smouldering Combustion For Soil Remediation: Two-Dimensional Experiments And Modelling, Tanzeer Hasan

Electronic Thesis and Dissertation Repository

Sustaining Treatment for Active Remediation (STAR) is a novel technology for the remediation of soils contaminated with Non-Aqueous Phase liquids (NAPLs). STAR is based upon the concept of liquid smouldering, in which NAPLs embedded in a porous medium are progressively destroyed via an exothermic oxidation reaction which propagates in a self-sustaining manner through the contaminated material. The In Situ Smouldering Model (ISSM), developed to simulate the propagation of STAR as a function of NAPL content and local air velocity, was calibrated for a suite of one-dimensional experiments (MacPhee et al., 2010). However, STAR application at field sites involves propagation of …

Analysis Of Coal Combustion By-Products Disposal Practices At The San Juan Mine: Hydrologic And Water Quality Issues, Bruce Thomson

Civil Engineering Faculty Publications

Coal Combustion By-Products (CCBs) are generated by the burning of coal for electric power generation and as waste streams from emissions control systems. They consist of bottom ash from the furnaces, fly ash from electrostatic precipitators, and flue gas desulfurization sludge from air pollution scrubbers. Depending on the characteristics of the coal, CCBs may contain high concentrations of metals or other constituents that present a threat to ground or surface water resources if not properly managed. This report describes results of an investigation of CCBs generated by a power plant in northwestern New Mexico. Coal Combustion By-Products from this plant …

Climate Change Adaptation Chapter: Marshfield, Massachusetts, Joshua H. Chase, Jonathan G. Cooper, Rory Elizabeth Fitzgerald, Filipe Antunes Lima, Sally R. Miller, Toni Marie Pignatelli

Sally Miller

Climate change, understood as a statistically significant variation in the mean state of the climate or its variability, is the greatest environmental challenge of this generation (Intergovernmental Panel on Climate Change, 2001). Marshfield is already being affected by changes in the climate that will have a profound effect on the town’s economy, public health, coastal resources, natural features, water systems, and public and private infrastructure. Adaptation strategies have been widely recognized as playing an important role in improving a community’s ability to respond to climate stressors by resisting damage and recovering quickly. Based on review of climate projections for the …

Using Ce-Qual-W2 To Model A Contaminant Spill Into The Wachusett Reservoir, Lillian M. Clark

Environmental & Water Resources Engineering Masters Projects

This research was done to understand the potential fate and transport of a contaminant spill into the Wachusett Reservoir utilizing the model CE-QUAL-W2 V3.6. The Wachusett Reservoir, located in central Massachusetts, is the main water supply for the Boston, MA metropolitan area. The reservoir has a capacity of approximately 65 billion gallons and receives about half of its total inflow from the Quabbin Reservoir, which has a capacity of 412 billion gallons. Water is transferred from the Quabbin Reservoir to the western end of the Wachusett Reservoir intermittently through the Quabbin Aqueduct typically from June through November to meet higher …

Chemical Compatibility Of Model Soil-Bentonite Backfill Containing Multiswellable Bentonite, Michael A. Malusis, Matthew D. Mckeehan

Faculty Journal Articles

The objective of this study was to evaluate the chemical compatibility of model soil-bentonite backfills containing multiswellable bentonite (MSB) relative to that of similar backfills containing untreated sodium (Na) bentonite or a commercially available, contaminant resistant bentonite (SW101). Flexible-wall tests were conducted on consolidated backfill specimens (effective stress =34.5 kPa) containing clean sand and 4.5–5.7% bentonite (by dry weight) using tap water and calcium chloride (CaCl2) solutions (10–1,000 mM) as the permeant liquids. Final values of hydraulic conductivity (k) and intrinsic permeability (K) to the CaCl2 solutions were determined after achieving both short-term termination criteria as …

Examining Consumer Behavior And Travel Choices, Kelly J. Clifton, Christopher Devlin Muhs, Sara Morrissey, Tomás Morrissey, Kristina Marie Currans, Chloe Ritter

Civil and Environmental Engineering Faculty Publications and Presentations

This study represents a first attempt to answer a few of the questions that have arisen concerning multimodal transportation investments and the impacts of mode shifts on the business community. This research aims to merge the long history of scholarly work that examines the impacts of the built environment on non-work travel with the relatively new interest in consumer spending by mode of travel. This empirical study of travel choices and consumer spending across 89 businesses in the Portland metropolitan area shows there are important differences between the amounts customers spend on average at various businesses by their mode of …

Leaching Of Metals And Metalloids From Highway Marking Glass Beads And The Potential Environmental Impact, Nimrat K. Sandhu

Dissertations

Glass beads are embedded in pavement markings to obtain retroreflectivity which plays a crucial role in the lighting-up effect needed for safe driving. Elevated metal and metalloid concentrations of As, Sb, and Pb have recently been observed in imported glass beads. The main objective of this research was to assess the environmental impact associated with applying these imported glass beads in highway markings. To achieve this objective, total metal concentrations were measured using two techniques: hydrofluoric acid digestion followed by inductively coupled plasma mass spectroscopy (HF/ICP-MS), and field portable x-ray fluorescence (FP-XRF) spectroscopy. A number of leaching studies were conducted …

Effects Of Molecular Structure Of The Oxidation Products Of Reactive Atmospheric Hydrocarbons On The Formation Of Secondary Organic Particulate Matter, Including The Effects Of Water, Negar Niakan

Dissertations and Theses

Organic aerosols have significant effects on human health, air quality and climate. Secondary organic aerosols (SOA) are produced by the oxidation of primary-volatile organic compounds (VOC). For example, α-pinene reacts with oxidants such as hydroxyl radical (OH), ozone (O₃), and nitrate radical (NO₃), accounting for a significant portion of total organic aerosol in the atmosphere. Experimental studies have shown that the oxidation process between α-pinene and ozone has the most significant impact in the formation of SOA (Hoffmann et al., 1997). Most of the models used to predict SOA formation, however, are limited in that they …

Solar And Visible Light Driven Photocatalysis For Sacrificial Hydrogen Generation And Water Detoxification With Chemically Modified Ti02, Pankaj Chowdhury

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Photocatalysis is a recognized approach where light energy is employed to excite the semiconductor material producing electron/hole pair which eventually involves in the detoxification of pollutants and/or water splitting producing hydrogen. Existing photocatalysts suffer from poor activity or no activity in visible light irradiation which restricts them from solar light utilization. This work is focused on two key applications of photocatalysis (i) sacrificial hydrogen generation, and (ii) phenol degradation in visible and/or solar light. Platinum was loaded on TiO2 photocatalyst by solar photo-deposition method. Eosin Y dye was used as a sensitizer for sensitization of platinum loaded TiO2 photocatalyst. The …

Change In Pore Size Distribution Of Compacted Soil Layers And Its Effect On Solute Breakthrough Curves, Sara Karimi

Electronic Thesis and Dissertation Repository

It is often useful to predict contaminant migration from waste containment systems, such as landfills, as part of the assessment of the overall impact of such systems on the receptor environment. In many instances, material properties, for example, those of the liner, are assumed to be constant. This study was conducted to evaluate the accuracy of considering constant material and transport parameters in the modelling of sodium and chloride breakthrough curves through a compacted soil layer using the commercial software, Pollute v.7. Experiments were conducted with three different mixtures of glass beads and varying amounts of kaolinite (30, 40 and …

University Of Massachusetts Amherst 2012-2021 Capital Improvement Projects, Douglas Vigneau, Juanita Holler, University Of Massachusetts Building Authority, John Mathews, Ludmilla Pavlova-Gillham, Ezra Small

Campus Planning Master Plans

In 2013 the University of Massachusetts, on behalf of the University of Massachusetts Building Authority and Massachusetts Division of Capital Asset Management and Maintenance (DCAMM), submitted an Expanded Environmental Notification Form for the University's 2012 - 2021 Capital Improvement Plan to the Executive Office of Energy and Environmental Affairs (EOEEA) Massachusetts Environmental Policy Act Office (MEPA).

Taken individually, the majority of the Projects, comprising of 13 building/space, 7 site/landscape, and 5 facility/ utility scale improvement projects, do not require MEPA review as most of the Project sites are confined to infill areas on campus that are currently or …

Umass Amherst Green Building Guidelines 2013, Ludmilla Pavlova-Gillham, Ted Mendoza, Ezra Small, Patricia O'Flaherty, Nariman Mostafavi, Mohamed Farzinmoghadam, Somayeh Tabatabaee Pozveh

Campus Planning Reports and Plans

Facilities & Campus Services, Sustainable UMass and Campus Planning support sustainability and energy conservation initiatives by providing in-house resources to campus staff as well as designers and contractors working with the University. The UMass Amherst Green Building Guidelines provide a framework for approaching new construction and major renovation projects at UMass Amherst that are undergoing LEED certification by focusing the conversation on green building aspects that are most important to the campus. They are intended to be the beginning of a dynamic conversation between designers, environmental consultants and constructors, university stakeholders, and users of new high performance buildings.

Integrated Data Fusion And Mining (Idfm) Technique For Monitoring Water Quality In Large And Small Lakes, Benjamin Vannah

Electronic Theses and Dissertations

Monitoring water quality on a near-real-time basis to address water resources management and public health concerns in coupled natural systems and the built environment is by no means an easy task. Furthermore, this emerging societal challenge will continue to grow, due to the ever-increasing anthropogenic impacts upon surface waters. For example, urban growth and agricultural operations have led to an influx of nutrients into surface waters stimulating harmful algal bloom formation, and stormwater runoff from urban areas contributes to the accumulation of total organic carbon (TOC) in surface waters. TOC in surface waters is a known precursor of disinfection byproducts …

Evaluation Of The Biodegradability And Toxicity Of Pca And Mpca, Juan Rueda

Electronic Theses and Dissertations

The main types of hypergolic propellants used at Kennedy Space Center (KSC) are hydrazine (HZ) and monomethylhydrazine (MMH). HZ and MMH are classified as hazardous materials and they are also known to be potentially carcinogenic to humans; therefore, handling these substances and their waste is strictly regulated. The wastes streams from HZ and MMH have been estimated to be the main hazardous wastes streams at KSC. Currently at KSC these wastes are first neutralized using citric acid and then they are transported on public roads for incineration as hazardous materials. A new method using alpha ketoglutaric acid (AKGA) was proposed …

Near-Road Dispersion Modeling Of Mobile Source Air Toxics (Msats) In Florida, Kurt Westerlund

Electronic Theses and Dissertations

There is a growing public concern that emissions of mobile source air toxics (MSATs) from motor vehicles may pose a threat to human health. At present, no state or federal agencies require dispersion modeling of these compounds, but many agencies are concerned about potential future requirements. Current air pollution professionals are familiar with Federal Highway Administration (FHWA) and U.S. Environmental Protection Agency (EPA) requirements for dispersion modeling to produce predicted concentrations for comparison with appropriate standards. This research examined a method in which the potential near-road concentrations of MSATs were calculated. It was believed that by assessing MSATs in much …

2013 Nebraska Water Monitoring Programs Report, Marty Link, Joe Kenning

Nebraska Department of Environmental Quality: Reports

The Nebraska Department of Environmental Quality (NDEQ) is charged with monitoring, assessing, and to the extent possible, managing the state’s water resources. The purpose of this work is to protect and maintain good quality water and encourage or execute activities to improve poor water quality. Monitoring is done on the over 16,000 miles of flowing rivers and streams, our greater than 148,000 acres of surface water in lakes and reservoirs, and the vast storage of groundwater in Nebraska’s aquifers.

Hydrologic Characterization Of A Rain Garden Mitigating Stormwater Runoff From A Commercial Area, John T. Mcmaine

Theses and Dissertations--Biosystems and Agricultural Engineering

Impervious surfaces such as roads, sidewalks, and roofs increase the volume of runoff generated in a watershed. Traditional stormwater management techniques emphasize conveyance of runoff away from impervious surfaces in order to reduce flooding. Rain gardens are becoming popular as a different means to manage stormwater in such a way that runoff is captured and infiltrated onsite rather than conveyed offsite. A stormwater management system consisting of a rainwater harvest system, rain garden, and infiltration chamber was built at the Coca-Cola Refreshments USA, Inc. distribution center in Lexington, Kentucky during the fall of 2011. Precipitation, inflow, and water level were …

Biological Control Of Manganese In Water Supplies In The Presence Of Humic Acids, Michael S. Snyder

Theses and Dissertations--Civil Engineering

The main objective of this study was to improve our understanding of biological filtration (biofilm type) treatment for manganese (Mn) removal in drinking water. Biological filtration treatment involves biofilms of Mn(II)-oxidizing microorganisms attached to solid filter material that remove and immobilize dissolved Mn(II) in raw water by conversion to black MnO_2(s) precipitates. Mn-biological filtration is an emerging green technology that can serve as an alternative to conventional physicochemical treatments but its full potential is hindered by various factors. These include lack of understanding the: (1) optimal removal conditions for Mn, (2) mechanisms for Mn releases of the accumulated Mn …

Assessment Of Seismic Damage Of Buildings And Related Environmental Impacts, Carley A. Feese

Dissertations, Master's Theses and Master's Reports - Open

Sustainable development has only recently started examining the existing infrastructure, and a key aspect of this is hazard mitigation. To examine buildings under a sustainable perspective requires an understanding of a building's life-cycle environmental costs, including the consideration of associated environmental impacts induced by earthquake damage. Damage repair costs lead to additional material and energy consumption, leading to harmful environmental impacts. Merging results obtained from a seismic evaluation and life-cycle analysis for buildings will give a novel outlook on sustainable design decisions. To evaluate the environmental impacts caused by buildings, long-term impacts accrued throughout a building's lifetime and impacts associated …